TOPIC: MATTER TRUST ACADEMY Objectives a. describe the formation of a covalent bond by the sharing of a pair of electrons in order to gain the electronic configuration of an inert gas. b. describe, using dot-and-cross diagrams, the formation of covalent bonds between non- metallic elements. c. relate the physical properties (including electrical properties) of covalent compounds to their structure and bonding.
THE COVALENT BOND
As you saw previously in ionic bonding, atoms bond in order to gain a stable outer shell of electrons, like the noble gas atoms. So when sodium and chlorine react together in ionic bonding, each sodium atoms give up an electron to a chlorine atom. But that is not the only way, atoms can also gain a stable outer shells by sharing electrons with each other. Covalent compounds are formed when electrons are shared between atoms. Only non-metal elements participate in covalent bonding. When two non-metal atoms react together both need to gain electrons to achieve stable outer shells and they manage this by sharing electrons. Example 1: formation of water molecule (H2O) Oxygen has six electrons in its outermost shell so it needs to gain or share so as to achieve stability or noble gas configuration. Hydrogen atoms have each one electron so 2 hydrogen atoms are needed to share electrons with oxygen atom so that each have a full shell. Therefore, 2hydrogen atoms have to bond covalently with one oxygen atom to form water molecule as shown below. NB: Only the outer shells are drawn in these diagrams. Fig 1: covalent bonding in H2O
Example 2: hydrogen chloride (HCl)
The chlorine atom shares one electron with the hydrogen atom. Both now have a stable arrangement of electrons in their outer shells.
Fig 2: hydrogen chloride molecule.
Example 3: formation of carbon dioxide (CO2)
Carbon has four electrons in its outer most shell and oxygen has 2. So carbon needs 2 oxygen atoms so that they share so as to obtain a noble gas configuration as shown below.
Fig 3: covalent bonding in CO2
PROPERTIES OF COVALENT BONDS 1. There Are usually gases and liquids. 2. Does not conduct electricity in any state. 3. Have low melting points. 4. Insoluble in water.