15. Match List-I with List-II. 17.

Match List-I with List-II

List-I List-II List-I
(Polymer) (Monomer)
(A) Neoprene (I) Acrylonitrile (A) Glucose + HI
(B) Teflon (II) Chloroprene (B) Glucose + Br2 water
(C) Acrilan (III) Tetrafluoroethene
(C) Glucose + acetic anhydride
(D) Natural rubber (IV) Isoprene
Choose the correct answer from the option given (D) Glucose + HNO3
below: List-II
(A) (A)-(II), (B)-(III), (C)-(I), (D-(IV)
(B) (A)-(II), (B)-(I), (C)-(III), (D-(IV) (I) Gluconic acid
(C) (A)-(II), (B)-(I), (C)-(IV), (D-(III) (II) Glucose pentacetate
(D) (A)-(I), (B)-( II), (C)-(III), (D-(IV) (III) Saccharic acid
Official Ans. by NTA (A)
Allen Ans. (A) (IV) Hexane
16. Choose the correct answer from the options given
chlorine. It dissolves readily in water to give a below:
solution that turns litmus red. Titration of
(A) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
is 131 2. When a sample (B) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
(C) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
which contains N but not Cl. Treatment of the (D) (A)-(I), (B)-(III), (C)-(IV), (D)-(II)
obtained liquid with nitrous acid followed by
phenol gives orange precipitate. The compound Official Ans. by NTA (A)
Allen Ans. (A)
18. Which of the following enhances the lathering
property of soap?
(A) Sodium stearate
(A) (B) Sodium carbonate
(C) Sodium rosinate
(D) Trisodium phosphate
Official Ans. by NTA (C)
Allen Ans. (C)
19. Match List-I with List-II
List-I (Mixture)
(B)
(A) Chloroform & Aniline
(B) Benzoic acid & Napthalene
(C) Water & Aniline
(D) Napthalene & Sodium chloride
List-II (Purification Process)
(C) (I) Steam distillation
(II) Sublimation
(III) Distillation
(IV) Crystallisation
(A) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(B) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
(D) (C) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
(D) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
Official Ans. by NTA (D) Official Ans. by NTA (D)
Allen Ans. (D) Allen Ans. (D)
4
20. Fe3 cation gives a prussian blue precipitate on 4. When a certain amount of solid A is dissolved in

addition of potassium ferrocyanide solution due to 100 g of water at 25°C to make a dilute solution,

the formation of: the vapour pressure of the solution is reduced to

(A) [Fe(H2O)6 ]2 [Fe(CN)6 ] one-half of that of pure water. The vapour pressure
of pure water is 23.76 mmHg. The number of
(B) Fe2 [Fe(CN)6 ]2
moles of solute A added is________. (Nearest
(C) Fe3[Fe(OH)2 (CN)4 ]2
Integer)
(D) Fe 4 [Fe(CN)6 ]3
Official Ans. by NTA (3)
Official Ans. by NTA (D)
Allen Ans. (3 or 6)
Allen Ans. (D)
5. [A] [B]

SECTION-B Reactant Product

1. The normality of H2SO4 in the solution obtained on If formation of compound [B] follows the first

mixing 100 mL of 0.1 M H2SO4 with 50 mL of 0.1 order of kinetics and after 70 minutes the

M NaOH is_______×10 1 N. (Nearest Integer) concentration of [A] was found to be half of its

Official Ans. by NTA (1) initial concentration. Then the rate constant of the
6
reaction is x × 10 s 1. The value of x is______.
Allen Ans. (1)
(Nearest Integer)
2. for a real gas at 25°C temperature and high
pressure (99 bar) the value of compressibility Official Ans. by NTA (165)

factor is 2, so the value of Vander Waa nt Allen Ans. (165)

2 1
L mol (Nearest 6. Among the following ores Bauxite, Siderite,
integer) (Given R = 0.083 L bar K 1 mol 1) Cuprite, Calamine, Haematite, Kaolinite,
Official Ans. by NTA (25) Malachite, Magnetite, Sphalerite, Limonite,

Allen Ans. (25) Cryolite, the number of principal ores if (of) iron

3. A gas (Molar mass = 280 g mol 1) was burnt in is_______.

excess O2 in a constant volume calorimeter and Official Ans. by NTA (4)

during combustion the temperature of calorimeter Allen Ans. (4)
increased from 298.0 K to 298.45 K. If the heat
7. The oxidation state of manganese in the product
1
capacity of calorimeter is 2.5 kJ K and enthalpy
obtained in a reaction of potassium permanganate
of combustion of gas is 9 kJ mol 1 then amount of
and hydrogen peroxide in basic medium is______.
gas burnt is_______g. (Nearest Integer)
Official Ans. by NTA (4)
Official Ans. by NTA (35)
Allen Ans. (4)
Allen Ans. (35)
5