CH: 2 Solutions

1. Minimum how many substances are present Column I Column II

in a mixture ? (A) Brass (i) Copper, zinc and
(A) One (B) Two nickel
(C) Two or more (D) Zero (B) German (ii) Copper and zinc
2. Brass is the mixture of …A… and …B…. silver
Here, A and B refer to (C) Bronze (iii) Copper and ion
(A) copper and nickel (B) copper and tin Codes :
(C) copper and zinc (D) tin and nickel A B C
3. Composition of German silver is the (A) 2 3 1
(A) mixture of copper, zinc, nickel (B) 2 1 3
(B) mixture of copper, tin, nickel (C) 1 2 3
(C) mixture of copper, zinc, tin (D) 3 1 2
(D) mixture of zinc, nickel, tin 12. Almost all processes in the body occur in
4. Identify the true statement. …A… . Here, A refer to
(A) Bronze consists of zinc and ion (A) solid solution (B) liquid solution
(B) Bronze consists of tin and copper (C) gas solution (D) None of the above
(C) Bronze consists of zinc and copper 13. Tetraethyl lead is used as
(D) None of the above (A) mosquito repellent(B) pain killer
5. Full form of ppm is (C) fire extinguisher (D) petrol additive
(A) parthy per million (B) per part million 14. The exposure of …A… substance is rare to
(C) parts per million (D) None of these our life. Here, A refers to
6. Which of the ions are required to prevent (A) mixture (B) pure
both decay ? (C) element (D) all of these
(A) Chloride ions (B) Fluoride ions 15. A solution is a …A… mixture of two or
(C) Iodide ions (D) Bromide ions more than two components. Here, A refers
7. …A… ppm of …B… ions in water prevent to
tooth decay ? (A) Solid (B) Homogeneous
(A) 1; fluoride (B) 10; fluoride (C) Liquid (D) Gas
(C) 1; iodide (D) 10; iodide 16. What is true about homogeneous mixture ?
8. The approximate concentration of fluoride (A) Homogeneous mixture is the mixture of
ion which results to mottled teeth is two or more than two components
(A) 1.0 ppm (B) 1.25 ppm (B) In homogeneous mixture, the
(C) 1.50 ppm (D) 1.75 ppm composition and properties are uniform
9. Name the sodium salt which is used as rate throughout the mixture
poison. (C) Both (A) and (B) are true
(A) NaCl (B) NaI (D) None of the above
(C) NaF (D) NaBr 17.
10. …A… injections are dissolved n water
containing salts at particular …B…
concentrations that matches …C…
Identify, (A) and (B) in the figure
concentration. Here, A, B and C refer to
(A) intravenous, ionic, blood plasma (A) (A)  solute; (B)  solvent
(B) intravenous, blood plasma, ionic (B) (A)  solvent; (B)  solute
(C) blood plasma, intravenous, ionic (C) (A)  solution; (B)  solute
(D) blood plasma, ionic, intravenous (D) (A)  solution; (B)  solvent
11. Match the following Column and choose the 18. In …A…, component that is present in …
correct option from the codes given below. quantity called solvent. Here, A and B refer to
(A) solution, larger (B) solution, small
(C) solute, larger (D) solute, small
WWW.REALCHEMISTRY.CO.IN
90995 99791
19. Component present in …A… other than (A) hydration energy (B) lattice energy
solvent is called …B… . Here, A and B (C) internal energy (D) bond energy
refer to 26. Match the terms given in Column I and
(A) solution, solute (B) solute, solution Column II and choose the correct option
(C) mixture, solution (D) None of these from the codes given below.
20. Match the following Column and choose the Column I Column II
correct option from the codes given below. (A) Saturated 1 Solution having same
Column I Column II solution osmotic pressure at a
(A) Chloroform mixed (i) Gaseous given temperature as
with nitrogen gas solution that of solution
(B) Ethanol dissolved in (ii) Solid (B) Binary 2 Solution whose
water solution solution osmotic pressure is
(C) Amalgam of mercury (iii) Liquid less than that of
with sodium solution another
Codes : (C) Isotonic 3 Solution with two
A B C solution components
(A) 1 2 3 (D) Hypotonic 4. Solution which
solution contains maximum
(B) 1 3 2
amount of solute that
(C) 2 1 3 can be dissolved in
(D) 2 3 1 given amount can be
21. Identify the solute and solvent in the option dissolved in given
given below, for a solution as amalgam of amount of solvent at
mercury with sodium. given temperature
Solute Solvent (E) Solid 5. A solution whose
(A) Solid Liquid solution osmotic pressure is
(B) Solid Solid more than that of
(C) Liquid Solid another
(D) Solid Gas (F) Hypertonic 6. A solution in solid
22. Match the following Column and choose the solution phase
correct option from the codes given below. Codes :
Column I Column II A B C D E F
(A) Mixture of oxygen (i) Solid (A) 1 2 3 4 5 6
with nitrogen gas solutions (B) 4 3 1 5 6 2
(B) Oxygen dissolved in (ii) Liquid (C) 4 3 1 2 6 5
water solutions (D) 6 5 4 3 2 1
(C) Camphor in nitrogen (iii) Gas solutions 27. Match the terms given in Column I with the
gas type of solutions given in Column II.
(D) Solution of hydrogen in Column I Column II
palladium (A) Soda water 1 A solution of gas in solid
(E) Copper dissolved in (B) Sugar 2 A solution of gas in gas
gold solution
(C) German 3 A solution of solid in
Codes : silver liquid
A B C D E (D) Air 4. A solution of solid in
(A) 3 2 3 1 1 solid
(B) 3 1 3 2 2 (E) Hydrogen gas 5. A solution of gas in
(C) 2 3 1 2 1 in palladium liquid
(D) 2 3 2 1 2 6. A solution of liquid in
solid
23. A binary solution suppose to contain
(A) one component (B) two components
(C) three components (D) four components Codes :
24. Which of the following is not an example of a solution ? A B C D E
(A) Air (B) Brass (A) 5 6 4 2 1
(C) Amalgam (D) Benzene in water (B) 5 3 4 2 1
25. The energy that is responsible for the (C) 1 2 3 4 5
dissolution of a solute is (D) 1 2 3 4 6

WWW.REALCHEMISTRY.CO.IN
90995 99791
28. Solid solution in which the solute is gas (C) Volume & of the component
(A) copper dissolved in gold Total volume of solution
(B) camphor in nitrogen gas   100
Volume of the component
(C) solution of hydrogen in palladium
(D) None of the above
(D) all of the above
37. What is the volume percentage of the
29. Composition of the solution can be expressed by
ethanol solution in water if 10 mL of ethanol
expressing its …A… . Here, A refers to
is dissolved in water and the total volume of
(A) concentration (B) mole fraction
the solution is 100 mL ?
(C) mass percentage (D) None of these
(A) 5% ethanol solution
30. Dilute solution means relatively
(B) 10% ethanol solution
(A) very small quantity of solute
(C) 15% ethanol solution
(B) very small quantity of solvent
(D) 20% ethanol solution
(C) very large quantity of solute
38. Name the chemical which is used as an
(D) None of the above
antifreeze in cooling the engine of cars.
31. Concentrated solution means relatively
(A) Ethylene (B) Glycerol
(A) very small quantity of solute
(C) Ethylene glycol (D) Glycol
(B) very large quantity of solute
39. Which of the following statement is true ?
(C) Both (A) and (B)
(A) Antifreeze lowers the freezing point of water
(D) None of the above
(B) Antifreeze increases the freezing point
32. What is the formula of mass percentage of a
of water
component in a solution ?
(C) Antifreeze can lower or increases the
Mass of the component in the solution
(A)  100 freezing point of water
Total mass of the solution (D) None of the above statement is true
Mass of all the component in the solution 40. Convert the 255.4 K to °C
(B)  100
Total mass of the solution (A) 17.6°C (B) –17.6°C
Mass of each component in the solution (C) 0°C (D) 22.4°C
(C)  100 41. Complete the following statement.
Total mass of the solution …A… (V/V) solution of ethylene glycol, an
Total mass of the solution antifreeze lowers the freezing point of water
(D)  100
Mass of the component in the solution to 255.4 K. Here, A refers to
33. What does this statement signifies? “10 per (A) 20% (B) 25%
cent glucose in water by mass”. (C) 30% (D) 35%
(A) 10 g of glucose is dissolved in 100 g of water 42. Select the correct statement
(B) 10 g of glucose is dissolved in 90 g of water (A) Mass by volume (W/V) percentage is a
(C) 20 g of glucose is dissolved in 200 g of water unit commonly used in medicine and
(D) 20 g of glucose is dissolved in 90 g of water pharmacy
34. 110g of glucose dissolved in 190 g of water results in (B) Mass of solute dissolved in 100 mL of
(A) 110 g solution (B) 200 g solution the solution give mass by volume percentage
(C) 120 g solution (D) 130 g solution (C) Mass of solute dissolved in 100 mL of
35. Composition of commercial bleaching solution is solvent give mass by volume percentage
(A)3.62 mass percentage ofsodium chlorite in water (D) Only (A) and (B) are correct
(B)3.62 mass percentage of sodium chloride in water 43. What is the formula of ppm ?
(C) 3.62 mass percentage of sodium (A) Number of parts of component
 106
Total number of parts of all components of the solution
hypochlorite in water
(D) 3.62 mass percentage of sodium (B) Number of parts of component
103
Total number of parts of all components of the solution
hypochloride in water
36. Which of the following formula is true ? (C) Total number of parts of all components of the solution
 106
Number of parts of components
(A) Volume % of the component
(D) Total number of parts of all components of the solution
 103
Volume of the component
  100 Number of parts of components
Total volume of solution 44. Concentration in parts per million can also
(B) Mass % of component be expressed as
Total mass of the solution (A) mass to mass (B) volume to volume
  100
Mass of component in solution (C) mass to volume (D) All of these are true
WWW.REALCHEMISTRY.CO.IN
90995 99791
45. Which one of the following is used to The option with all temperature independent
express the concentration of pollutant in concentration term is
water or atmosphere ? (A) I, II, III (B) II, III, IV
(A) ppm (B) µg/mL (C) III, IV, I (D) All of these
(C) g/L (D) Both (A) and (B) 53. Match the terms given in Column I with
46. Mole fraction of a component is equal to expressions given in Column II.
Number of moles of the component
(A)
Total number of moles of all component
Total number of moles of all component
(B)
Number of moles of the component
Number of mass of the component
(C)
Total number of moles of all component
Total number of moles of all component
(D)
Number of mass of the component
47. Which of the following statement(s) is/are true ?
I. In a binary mixture, mole fraction of A is
nA
xA  .
nA  nB
II. For solution containing i number of
Codes :
components; x i  n i A B C D E
n i
(A) 4 3 1 2 5
III. Sum of all mole fractions is one.
(B) 4 3 2 1 5
Select the option with true statements.
(C) 4 3 2 5 1
(A) I and II (B) II and III
(D) 4 3 1 5 2
(C) III and I (D) I, II and III
54. 4 L of 0.02 M aqueous solution of NaCl was
48. Molarity is
diluted by adding one litre of water. The
(A) number of moles of solute dissolved in
molarity of resultant solution is …A… .
one litre of solution
Here, A refers to
(B) number of moles of solute dissolved in
(A) 0.004 (B) 0.008
one mL of solution
(C) 0.012 (D) 0.016
(C) number of moles of solvent dissolved in
55. A solution containing 0.2 mole of each A, B
one litre of solution
and C. The sum of the mole fractions of A,
(D) number of moles of solvent dissolved in
B and C is an aqueous solutions is
one mL of solution
(A) 0.6 (B) 0.2
49. One litre is equal to
(C) 1.0 (D) 1.2
(A) 1 cm3 (B) 1 dm3
3 56. Which of the following units is useful in
(C) 1 mm (D) None of these
relating concentration of solution with its
50. Number of moles of solute per kilogram of
vapour pressure ?
the solvent is expressed as
(A) Mole fraction (B) Parts per million
(A) molarity (B) molality
(C) Mass percentage (D) Molality
(C) mole fraction (D) mass percentage
–1 57. Calculate the molarity of Na2CO3 solution if
51. What does 1 mol kg KCl solution signifies ?
the normality of Na2CO3 solution is given
(A) 1 mole of KCl is dissolved in 1 kg of water
(0.2 N)
(B) 1 mole of KCl is dissolved in 1 L of water
(A) 0.1 M (B) 0 M
(C) 1 mole of KCl is dissolved in 1 mL of water
(C) 0.4 M (D) 0.2 M
(D) None of the above
58. Concentration term which are independent
52. Choose the concentration term which is
of temperature.
temperature independent.
(A) Mole fraction and molality
I. Mass percentage
(B) Mole fraction and molarity
II. ppm
(C) Molarity only
III. Mole fraction
(D) None of the above
IV. Molarity
WWW.REALCHEMISTRY.CO.IN
90995 99791
59. Find out the molarity of barium hydroxide Reason (R) : Like dissolves like
solution in the given statement. “25 mL of (A) Both A and R are correct; R is the
barium hydroxide solution is titrated with correct explanation of A
0.1 molar solution of HCl to give a titre (B) Both A and R are correct; R is not the
value of 35 mL”. correct explanation of A
(A) 0.14 (B) 0.28 (C) A is correct; R is incorrect
(C) 0.07 (D) 0.35 (D) R is correct; A is incorrect
60. Strength of aqueous solution of glucose is 68. When a solid solute is added to the solvent,
20%. 1 g mole of glucose is dissolved in some solute dissolves and its concentration
…A… L of solution of same strength. Here, increases in solution. This process is known as
A refers to (A) saturation (B) dissolution
(A) 9 L (B) 1.8 L (C) unsaturation (D) crystallization
(C) 8 L (D) 0.9 L 69. Solute particles in solution collide with the
61. 25 mg of CaCO3 is dissolved in 5 L of solid solute particles and get separated out
solution. The approximate concentration of of solution. This process is known as
solution is (A) dissolution (B) saturation
(A) 25 ppm (B) 2500 ppm (C) crystallization (D) unsaturation
(C) 1 ppm (D) 5 ppm 70. Which of the two processes occur at the
62. Suppose 3.50 weight per cent of aqueous same rate in order to achieve this
solution of NaCl is sea water. What is the equilibrium ?
molality of sea water ? Solute + Solvent  Solution
(A) 6.2 m (B) 0.062 m (A) Saturation, unsaturation
(C) 0.62 m (D) 0.0062 m (B) Saturation, crystallization
63. Solubility of a substance is its (C) Crystallization, dissolution
(A) maximum amount that can be dissolved (D) Unsaturation, crystallization
in a specified amount of solvent at a 71. A solution in which no more solute can be
different temperature dissolved at the same temperature and
(B) minimum amount that can be dissolved pressure is called a
in a specified amount of solvent at a (A) unsaturated solution
different temperature (B) saturated solution
(C) maximum amount that can be dissolved (C) dissolution (D) crystallization
in a specified amount of solvent at a 72. A solution in which more solute can be
specified temperature dissolved at the same temperature
(D) minimum amount that can be dissolved (A) Saturated solution
in a specified amount of solvent at a (B) Unsaturated solution
specified temperature (C) Dissolution (D) Crystallization
64. Solubility depends upon the nature of 73. Which of the following statement is true
I. solute and solvent about saturated solution ?
II. temperature (A) A solution in which no more solute can
III. pressure be dissolved at the same temperature and
The option with all correct choice is pressure
(A) Only I (B) Only II (B) The solution which is in dynamic
(C) Only III (D) All of these equilibrium with undissolved solute and
65. In which solvent does sodium chloride and contains maximum amount of solute
sugar dissolves ? dissolves in solvent
(A) Naphthalene (B) Water (C) The solution in which more solute can
(C) Anthracene (D) All of these be dissolved at the same temperature
66. Naphthalene and anthracene dissolves (D) Only (A) and (B)
readily in …A… . Here, A refers to 74. Solubility of one substance into another
(A) water (B) ethyl acetate depends upon
(C) benzene (D) None of these (A) nature of substances
67. Assertion (A) : Polar solute dissolves in (B) temperature
polar solvents and non-polar solute dissolves (C) pressure
in non-polar solvents. (D) None of these
WWW.REALCHEMISTRY.CO.IN
90995 99791
75. If solubility of a solid in a liquid is affected (C) temperature and pressure
by temperature changes. (D) None of the above
Solute + Solvent  Solution 84. Solubility of gases increases with …A… of
This dynamic equilibrium must follow pressure. Here, A refers to
(A) Le-Chateller’s principle (A) increases (B) decrease
(B) Dynamic principle (C) increase/decrease (D) No effect
(C) Both (A) and (B) (D) None of these 85. What does dynamic equilibrium signifies if
76. For nearly saturated solution dissolutions is in the system ? If lower part is solution and
(A) exothermic upper part is gaseous system.
(B) Dynamic principle (A) Rate of gaseous particles entering and
(C) sometimes (A) and (B) leaving the solution phase is not equal
(D) Can’t be predicted (B) Rate of gaseous particles entering and
77. If in …A… solution, the dissolution process leaving the solution phase is equal
is …B… . Here, A and B refer to (C) Rate of gaseous particles entering is
(A) exothermic, saturated more than leaving the solution
(B) saturated, endothermic (D) Rate of gaseous particles entering is less
(C) exothermic than leaving the solution
(D) endothermic, saturated
78. What happens to the solubility of substance 86.
with the rise in temperature, if the
dissolution process is endothermic ?
(A) Increases (B) Decreases Gather the true information from the above
(C) Increases or decreases depend on nature diagram.
of substance (A) The pressure increases over the solution
(D) No effect of temperature on solubility phase by compressing the gas to a smaller volume
79. Solubility decreases with the rise in (B) There is increase in the number of
temperature during …. Process. gaseous particles per unit volume over the
Fill in the blank with an appropriate word. solution by increasing the pressure
(A) exothermic (B) endothermic (C) By applying the pressure, there is
(C) May be (A) or may be (B) increase in the rate of gaseous particles
(D) None of these which are striking the surface of solution for
80. Assertion (A) : Pressure does not have any entering into the solution
significant effect on solubility of solids in (D) All of the above information is correct
liquids. 87. Which is the first law to give the
Reason (R) : Solids and liquids are highly quantitative relation between pressure and
incompressible and remain unaffected by solubility of a gas in a solvent ?
change in pressure (A) Raoult’s law (B) Dalton’s law
(A) Both A and R are correct; R is the (C) Henry’s law (D) All of these
correct explanation of A 88. Which of the following statement is true
(B) Both A and R are correct; R is not the about Henry’s law ?
correct explanation of A (A) The solubility of solid in a liquid is
(C) A is correct; R is incorrect directly proportional to the partial pressure
(D) R is correct; A is incorrect of the solid present above the surface of
81. It is the dissolved …A… which sustains all liquid or solution
aquatic life. Here, A refers to (B) The solubility of a gas in a liquid is
(1) nitrogen (B) hydrogen directly proportional to the partial pressure
(C) oxygen (D) helium of gas present above the surface of liquid or
82. Oxygen is …A… soluble and hydrogen solution
chloride (HCl) gas is …B… soluble in (C) The solubility of a liquid in gas is
water. Here, A and B refer to directly proportional to the partial pressure
(A) partly, highly (B) highly, partly of liquid present above the surface of gas
(C) partly, partly (D) highly, highly (D) The solubility of a gas in solid is
83. Solubility of gases in liquids is affected by directly proportional to the partial pressure
(A) temperature (B) pressure of gas present above the surface of solid
WWW.REALCHEMISTRY.CO.IN
90995 99791
89. Dalton also concluded that solubility of gas 94. In the graph given below, what does the
in a liquid solution is a function of slope of the line represent ?
(A) partial pressure of the gas
(B) partial pressure of the liquid
(C) partial pressure of gas/liquid
(D) None of the above
90. Identify the correct statement regarding
Henry’s law.
(A) Mole fraction of gas in the solution is (A) Partial pressure of the gas in vapour
proportional to the partial pressure of the gas phase (p)
over the solution (B) Mole fraction of gas in the solution (x)
(B) The solubility of a gas in a liquid is (C) Henry’s law constant (KH)
directly proportional to the partial pressure of gas (D) All of the above
present above the surface of liquid or solution 95. Which of the following statement(s) is/are
(C) Both (A) and (B) true ?
(D) None of the above I. Different gases have different KH values at
91. The most commonly and advanced used the same temperature.
form of Henry’s law statement is ….A… . II. KH is a function of the nature of the gas.
Here, A refers to Choose the correct option.
(A) The solubility of a gas in a liquid is directly (A) Only I (B) Only II
proportional to the partial pressure of the gas (C) Both I and II (D) None of these
present above the surface of liquid or solution 96. According to the Henry’s law
(B) The mole fraction of gas in solution is (A) Higher the value of KH at a given
proportional to the partial pressure of the gas pressure, lower is the solubility of the gas in
over the solution the liquid
(C) The partial pressure of the gas in vapour (B) Higher the value of KH at a given
phase is proportional to the mole fraction of pressure, higher is the solubility of the gas in
the gas in the solution the liquid
(D) All of the above (C) Lower the value of KH at a given
92. What does p, x, KH signifies in the Henry’s pressure, lower is the solubility of the gas in
law expression, i.e., p = KHx ? the liquid
(D) None of the above
(A) (a) ppartial pressure; (b) xmole
97.
fraction of the gas in the solution; (c)
Gas Temperature/K KH/bar
KHHenry’s law constant He 293 144.97
(B) (a) ppartial pressure of the gas in vapour H2 293 66.16
pressure; (b) xmole fraction of the liquid in the N2 293 76.48
solution; (c) KHHenry’s law constant N2 303 88.84
(C) (a) ppartial pressure of gas in liquid O2 293 34.86
phase; (b) xmole fraction of gas in the O2 303 46.82
solution; (c) KHHenry’s law constant Conclusion KH value for both N2 and O2
(D) None of the above increases with increase of temperature.
93. Which of the following curve represents the Interpretation : Solubility of gases increases
Henry’s law ? with decrease of temperature.
Select out the correct statement based on the table.
(A) Both conclusion and interpretation are
(A) (B) correct
(B) Only conclusion is correct and
interpretation is wrong
(C) Conclusion is wrong and interpretation
is correct
(C) (D) (D) Conclusion and interpretation both are
wrong
98. Why aquatic species are more comfortable
in cold water rather than in warm water ?
WWW.REALCHEMISTRY.CO.IN
90995 99791
 (A) Aquatic species feel hot in cold water 105. Assertion (A) : When the divers come
rather than in warm water towards surface their capillaries get block,
(B) Solubility of gas increases with decrease which is painful and dangerous to life.
in temperature Reason (R) : There is release of the
(C) Solubility of gas decreases with dissolved gases as the pressure decreases
decreases in temperature and leads to the formation of bubbles of
(D) No statement is the correct explanation nitrogen in the blood.
of the above question (A) Both A and R are correct; R is the
99. Match the following Henry’s law constant correct explanation of A
value for gases in water at 298 K. (B) Both A and R are correct; R is not the
Column I Column II correct explanation of A
(Henry’s law constant) (C) A is correct; R is incorrect
A. Argon 1. 1.83 × 10–5 (D) R is correct; A is incorrect
B. CO2 2. 0.413 106. Which of the following statement is true
C. Formaldehyde 3. 40.3 about bends ?
D. Methane 4. 0.611 (A) Capillaries are blocked and it create
E. Vinyl chloride 5. 1.67
medical condition known as bends
Codes :
(B) It is painful and dangerous to life
A B C D E
(C) Only (B) is true
(A) 3 4 2 1 4
(D) (A) and (B) both are correct
(B) 3 1 5 2 4
107. Bends occur due to ionic effect of the high
(C) 3 5 1 2 4
concentration of
(D) 3 2 5 1 4
(A) oxygen in blood (B) CO2 in blood
100. Henry’s law have applications in …A… and
(C) nitrogen in blood (D) helium in blood
explain …B… phenomena. Here, A and B
108. What is the composition of gases in the
refer to
tanks used by the scuba divers ?
(A) Aindustry; Bbiological (A) 11.7%Helium, 32.1% Nitrogen, 56.2% Oxygen
(B) Abiological; Bindustry (B) 11.7% Helium, 56.2% Nitrogen, 32.1% Oxygen
(C) Both (A) and (B) (C) 56.2% Helium, 11.7% Nitrogen, 32.1% Oxygen
(D) None of the above (D) 56.2% Helium, 32.1% Nitrogen, 11.7% Oxygen
101. Which of the following gas(es) is/are present 109. At high altitude partial pressure of oxygen is
in the soft drinks and soda water ? …A… than that at ground level. Here, A
(A) He (B) Ne refers to
(C) CO2 (D) All of these (A) more (B) less
102. To increase the solubility of CO2 in soft (C) same (D) more/less
drinks and soda water 110. Which of the following statement(s) is/are
(A) the bottle is sealed under high pressure true ?
(B) the bottle is sealed under low pressure (A) At high altitudes, there is low
(C) the bottle is remain opened concentration
(D) the bottle is sealed under high temperature (B) For climbers, partial pressure of oxygen
103. Scuba drivers cope with …A… is less at the high altitude
concentrations of dissolved gases while (C) Low blood oxygen causes climbers to
breathing air at …B… pressure under water. become weak and unable to think clearly.
Here, A and B refer to This condition is known as anoxia
(A) Ahigh; Blow (D) All of the above
(B) Alow; Bhigh 111. Solubility of gases in liquid
(C) Ahigh; Bhigh (A) Increases with rise in temperature
(D) Alow; Blow (B) Decrease with rise in the temperature
104. Solubility of gases in blood (C) Increase or decrease with rise in the
(A) increases with increase in the pressure temperature
(B) decreases with increase in the pressure (D) No effect with rise in the temperature
(C) increase with decrease in the pressure 112. The process of dissolution is similar to
(D) None of the reason support the statement …A… and heat is …B… . When the gas
because gases are not soluble in the blood molecules are dissolved in the liquid phase.
WWW.REALCHEMISTRY.CO.IN
90995 99791
 Here A and B refer to (A) HCHO < CH4 < CO2 < Ar
(A) Acondensation; Babsorbed (B) HCHO < CO2 < CH4 < Ar
(B) Acondensation; Bevolved (C) Ar < CO2 < CH4 < HCHO
(C) Asolution; Babsorbed (D) Ar < CH4 < CO2 < HCHO
(D) Asolution; Bevolved 120. Which of the following factor(s) affect the
113. Dissolution of gases in the liquid is an solubility of gaseous solute in the fixed
exothermic process, solubility of gases volume of liquid solvent …(I)… nature of
decreases with …A… of temperature. Here, solute …(II)… temperature …(III)…
A refers to pressure ? Here, (I), (II) and (III) refer to
(A) decrease (B) increase (A) (I) at constant T, P (B) (II) at constant P
(C) Both (A) and (B) (D) None of the above (C) (III) at constant T (D) All of these
114. Significance of Henry’s law constant is 121. Select the correct curve of the Henry’s law
(A) higher the value of Henry’s law
constant, lower is the solubility of gas in the
liquid (A) (B)
(B) higher the value of Henry’s law
constant, higher is the solubility of gas in the
liquid
(C) lower the value of Henry’s law constant
lower is the solubility of gas in the liquid
(D) All of the above (C) (D)
115. On dissolving sugar in water at room
temperature solution feels cool to touch.
Under which of the following cases 122. A supersaturated solution is a metal stable
dissolution of sugar will be most rapid ? state of solution in which solute
(A) Sugar crystals in cold water concentration.
(B) Sugar crystals in hot water (A) continuously change
(C) Powdered sugar in cold water (B) exceed than its solubility
(D) Powdered sugar in hot water (C) equal to the solubility of that substance
116. At equilibrium, the rate of dissolution of a in water
solid in a volatile liquid solvent is …A… . (D) less than its solubility
Here, A refers to 123. Maximum amount of a solid solute that can
(A) less than the rate of crystallisation be dissolved in a specified amount of a
(B) greater than the rate of crystallisation given liquid solvent does not depend upon
(C) equal to the rate of crystallisation …A… . Here, A refers to
(D) zero (A) temperature (B) nature of solute
117. A beaker contains a solution of substance ‘A’. (C) pressure (D) nature of solvent
Precipitation of substance ‘A’ takes place when 124. Ratio of O2 and N2 in the air is 1 : 4. Find
small amount of ‘A’ is added to the solution. The out the ratio of solubilities in terms of mole
solution is …A… . Here, A refers to fraction of O2 and N2 dissolved in water at
(A) saturated (B) supersaturated atmospheric pressure and room temperature
(C) unsaturated (D) concentrated  K H (O 2 )  3.30 107 torr 
118. Find out the millimoles of N2 gas that is  
 K H (N 2 )  6.60 10 torr 
7
dissolved in 1 L of water if the N2 gas is
bubbled through water at 298 K. (A) 1 : 2 (B) 2 : 1
(Partial pressure of N2 is 0.987 bar, Henry’s (C) 1 : 1 (D) None of these
law constant is 76.48 kbar) 125. Calculate the concentration of nitrogen
(A) 0.129 mmol (B) 0.716 mmol present in the water. Assuming that the
(C) 1.29 mmol (D) 7.16 mmol temperature is 25°C, total pressure is 1 atm
119. KH value of Ar(g), CO2(g), HCHO(g) and and mole fraction of nitrogen is 0.78. [KH
CH4(g) are 40.39, 1.67, 1.83 × 10–5 and for nitrogen = 8.42 × 10–7 M/mmHg]
0.413 respectively. (A) 4.99 M (B) 4.99 × 10–2 M
Arrange these gases in the order of their –4
(C) 4.99 × 10 M (D) None of these
increasing solubility
WWW.REALCHEMISTRY.CO.IN
90995 99791
126. In the liquid solution
(A) gas  solute liquid  solvent
(B) liquid  solute liquid  solvent
(C) solid  solute liquid  solvent
(D) gas/liquid/solid  solute liquid  solvent
127. What is true about the liquid solutions ?
(A) Solution may contain one or more
volatile components
(B) The solute may or may not be volatile
(C) Generally the liquid solvent is volatile
(D) All of the above
128. Binary solution contain two components,
namely, the solution of
(A) liquids in liquids (B) solids in liquids
(C) gas in liquids (D) All of these
129.
Which statement support the figure ?
(A) In a closed vessel, both the components
would evaporate and an equilibrium would
be established between vapour phase and
liquid phase
(B) In a closed vessel, both the components
would evaporate but equilibrium would not
be established between vapour phase and
liquid phase
(C) In a close vessel, none of components
would evaporate and no equilibrium would
be established between vapour phase and
liquid phase
(D) None of the above
130. I. pTotal  Total vapour pressure
II. p1  Partial pressure of component 1
III. p2  Partial pressure of component 2
IV. Partial pressure are related to the mole
fractions x1 and x2 of the two components 1
and 2
Select the correct denotion or statement
(A) I, II and III (B) II, III and IV
(C) I, II, III and IV (D) III, IV and I
131. The …A… chemist, …B… Raoult gave the
Raoults law. Here, A and B refer to
(A) AFrench; BFrancois marte
(B) AFrancois Marte; BFrench
(C) AGerman; BFrancois Marte
(D) AFrancois Marte; BGerman
132. Raoult law was given in
(A) 1885 (B) 1886
(C) 1887 (D) 1889
133. Raoult’s law states that
WWW.REALCHEMISTRY.CO.IN
90995 99791
(A) the partial pressure of the gas in vapour
phase is proportional to the mole fraction of
gas in the solution
(B) for solutions of volatile liquids, the
partial vapour pressure of each components
of the solution is directly proportional to its
mole fraction present in the solution
(C) the solubility of volatile liquid is directly
proportional to partial pressure of the given
(D) None of the above
134. What does p1° and p2° signifies in the given
relation p1 = p1°x1 and p2 = p2°x2 ?
(A) p1°partial pressure of component 1;
p2°partial pressure of component 2
(B) p1°partial pressure of component 2;
p2°partial pressure of component 1
(C) p1°partial pressure of component 1 or
2; p2°partial pressure of component 2 or 1
(D) p1°vapour pressure of pure
component 1; p2°vapour pressure of pure
component 2
135. The total pressure (ptotal) over the solution in
the container will be the sum of the partial
pressure of the component of the solution
(A) Raoult’s law (B) Henry law
(C) Dalton’s law of partial pressure
(D) All of the above
136. Dalton’s law of partial pressure is given by
(A) p1 = p1°x1 (B) ptotal = p1 + p2
(C) p2 = p2°x2 (D) p = KHx
137. ptotal = x1p1° + x2p2° = p1° + (p2° – p1°)x2
I. Total vapour pressure of the solution is
related to the mole fraction of any one
component.
II. Total vapour pressure of the solution
varies exponentially with the mole fraction
of component 2
III. Depending on the vapour pressure of
pure components 1 and 2, total vapour
pressure over the solution decreases or
increases with the increase of the mole
fraction of component 1.
Select the correct conclusion derived from
the equation.
(A) I and II (B) II and III
(C) III and I (D) I, II and III
 Directions : (Q. No. 138-Q.No. 140) The
diagram given below represents the vapour
pressure and mole fraction of an ideal
solution of component 2
 (A) KH = p1° (B) KH > p1°
(C) KH < p1° (D) KH  p1°
146. During the comparisons of equations for
Raoult’s law and Henry’s law
(A) partial pressure of the volatile
component is directly proportional Henry’s
138. x1 = 1 signifies constant
(A) only component 1 is present (B) partial pressure of the volatile
(B) only component 2 is present component is directly proportional to its
(C) component 1 and 2 both are present mole fraction in solution
(D) No component is present (C) partial pressure of the volatile
139. What does line I, line II and line III indicate ? component is greater than its mole fraction
(A) I  p1, II  ptotal, III  p2 solution
(B) I  p2, II  p1, III  ptotal (D) partial pressure of the volatile
(C) I  p1, II  p2, III  ptotal component is less than its mole fraction in
solution
(D) I  p1, II  ptotal, III  p1
147. Which of the compound is/are soluble in
140. Which of the following statement is true
water ?
about the diagram ?
(A) Sodium chloride (B) Glucose
(A) component 1 is more volatile than
(C) Cane sugar (D) All of these
component 2
148. Sulphur is completely soluble in
(B) component is less volatile than
(A) H2O (B) benzene
component 2
(C) carbon disulphide (D) toluene
(C) component 1 is equal volatile than
149. The liquids at a given temperature vaporise
component 2
and under equilibrium conditions the
(D) None of the above is true
pressure exerted by the vapours of the liquid
141. y1 and y2 are the mole fraction of
over the liquid phase is called
components 1 and 2 in …A… phase than by
(A) vaporisation (B) pressure
using …B… law of partial pressure p1 =
(C) vapour pressure (D) condensation
ptotal y1 and p2 = y2 ptotal. Identify (A) and (B)
150. Name the (appropriate) process that occur in
in order to complete the above statement.
the closed container
(A) Aliquid; BDalton
(B) Avapour; BDalton
(C) Avapour; BHenry
(D) Aliquid; BHenry
142. At equilibrium, more volatile component in
the solution has
(A) higher vapour phase of that component (A) Pressure (B) Vapour pressure
(B) lower vapour phase of that component (C) Evaporation (D) Cannot predict
(C) Both (A) and (B) 151. In … liquid the entire surface is occupied by
(D) Above options do not support the the molecules of the liquid.
statement Fill in the blank with an appropriate option.
143. The vapour pressure of a volatile component (A) impure (B) pure
in a given …A… is given by pi = xipi°. (C) Both (A) and (B) (D) None of these
Here, A refers to 152. Non-volatile solute is added to solvent to
(A) solute (B) solvent give …A… . Here, A refers to
(C) solution (D) all of these (A) solute (B) solvent
144. One of the component is so volatile that it (C) solution (D) None of these
exists as …A… in the solution of gas in 153. Interpret the correct statement for the
liquid. Here A refers to following figure.
(A) solid (B) liquid
(C) gas (D) All of these
145. Raoult’s law becomes a special case of
Henry’s law when

WWW.REALCHEMISTRY.CO.IN
90995 99791
 (A) Solute
(B) Solvent
(C) Solute and solvent both
(D) None of these
159. Which of the following plot obeys the
Raoult’s law for all concentration ?

(A) Vapour pressure of the solution in

beaker (A) is more than in the beaker (B)
(B) Vapour pressure of the solution in (A) (B)
beaker (A) is less than in the beaker (B)
(C) Vapour pressure of the solution in both
the beaker is same
(D) None of these
154. Assertion (A) : When non-volatile solute is
added to solvent the vapour pressure of the
solution decrease. (C) (D)
Reason (R) : Number of solvent molecules
escaping from the surface is reduced, the
vapour pressure of the solution is also 160. What does (A) point signifies in the figure
reduced. given below ?
(A) Both A and R are correct; R is the
correct explanation of A
(B) Both A and R are correct; R is not the
correct explanation of A
(C) A is correct; R is incorrect
(D) R is correct; A is incorrect
155. Decrease in the vapour pressure of the (A) Vapour pressure of solute
solvent depends on (B) Vapour pressure of pure solvent
(A) nature of non-volatile solute (C) Vapour pressure of solution
(B) quantity of non-volatile solute (D) None of the above
(C) nature of solution 161. Solution follows Raoult’s law, if one
(D) quantity of solution component comes over the range 0  x1  1.
156. “1 mole of sucrose is added to 1 kg of water Then second component must follow
and 1 mole of urea is added to another 1 kg Raoult’s law in range when x2 is
of water”. In which solution, the decrease in (A) close to zero (B) close to one
the vapour pressure is maximum at same (C) 0  x2  0.5 (D) 0  x2  1
temperature ? 162. Two beakers of capacity 500 mL were
(A) Sucrose solution taken. One of these beakers, labeled as “A”,
(B) Urea solution was filled with 400 mL water whereas the
(C) Remain same in both cases beaker labeled “B” was filled with 400 mL
(D) No vapour pressure exist of 2 M solution of NaCl. At the same
157. According to the Raoult’s law “The partial temperature both the beakers were placed in
vapour pressure of each …A… component closed containers of same material and same
in the solution is directly proportional to its capacity as shown in figure.
…B… fraction.” Here, A and B refer to
(A) Amole; Bnon-volatile
(B) Avolatile; Bmole
(C) Avolatile; Bmass
(D) Amole; Bvolatile
158. Solute in non-volatile and only solvent At a given temperature, which of the
molecule is volatile. Which of the following following statement is correct about the
has maximum contribution in vapour phase ? vapour pressure of pure water and that of
NaCl solution ?
WWW.REALCHEMISTRY.CO.IN
90995 99791
 (A) Vapour pressure in container A is more n 
than that in container B (C) p0 = psn2 (D) ps  p0  1 
(B) Vapour pressure in container A is less  n2 
than that in container B 169. Select the correct statement(s)
(C) Vapour pressure is equal in both the (A) Solubility of Glauber’s salt (Na2SO4 ·
containers 10H2O) always increases
(D) Vapour pressure in container B is twice (B) Solubility of Glauber’s salt (Na 2SO4 ·
the vapour pressure in container A 10H2O) first decreases upto 32.4°C and then
163. The mole fraction of gaseous H2O (water increases
vapour) in air is 0.0287. If the total vapour (C) Solubility of Glauber’s salt (Na2SO4 · 10H2O) first
pressure is 0.977 atm. Calculate the partial increases upto 32.4°C and then decreases
pressure of dry air. (D) Solubility of Glauber’s salt always decreases
(A) 94.9 atm (B) 949 atm 170. xA and xB are the mole fraction of A and B
(C) 0.949 atm (D) 9.49 atm respectively yA and yB are the mole fraction
164. Henry’s law constant for the molality of methane the vapour phase. Find out the slope of
in benzene at 298 K is 4.27 × 105 mm Hg. straight line if a graph is plotted 1/YA along
(A) 1.78 × 10–3 (B) 1.78 × 10–2 y-axis against 1/xA along x-axis give straight
(C) 1.78 × 10 –1
(D) 1.78 line [ pA and pB are vapour pressure of pure
165. Benzene and naphthalene form an ideal components A and B]
solution over the entire range of
(A) pB / pA (B) pA / pB
composition. The vapour pressure of pure
benzene and naphthalene at 300 K are 50.71 (C) pB  pA (D) pA  pB
mm Hg and 32.06 mm Hg respectively. 171. Liquid-liquid solution are classified into
Calculate the mole fraction of benzene in (A) ideal solution
vapour phase if 80 g of benzene is mixed (B) non-ideal solution
with 100 g of toluene (C) ideal and non-ideal solution
(A) 0.675 (B) 0.325 (D) solution
(C) 42.65 (D) 13.85 172. Liquid-liquid solution are classified on the
166. The air is a mixture of a number of gases. basis of
The major components are oxygen and (A) Dalton’s law of partial pressure
nitrogen with approximate proportion of (B) Henry’s law
20% is to 79% by volume at 298 K. The (C) Raoult’s law (D) None of the above
water is in equilibrium with air at a pressure 173. The solution which obey Raoult’s law over
of 10 atm. At 298 K if the Henry’s law the entire range of concentration is called
constants for oxygen and nitrogen at 298 K a/an …A… . Here, A refers to
are 3.30 × 107 mm respectively. Calculate (A) ideal solution
the composition of these gases in water. (B) non-ideal solution
(A) N2 = 4.6 × 10–5; O2 = 9.22 × 10–5 (C) positive deviation from Raoult’s law
(B) N2 = 2.3 × 10–5; O2 = 4.8 × 10–5 (D) negative deviation from Raoult’s law
(C) N2 = 9.22 × 10–5; O2 = 4.6 × 10–5 174. Which case is valid for an ideal solution ?
(D) N2 = 4.8 × 10–5; O2 = 2.3 × 10–5 (A) mixH = 0; mixV = 0
167. At 40°C, the vapour pressure of pure liquids, (B) mixH > 0; mixV  0
benzene and toluene, are 160 mm Hg and 60 (C) mixH < 0; mixV < 0
mm Hg respectively. At the same
(D) mixH > 0; mixV < 0
temperature, the vapour pressure of an
175. Which of the following statement(s) is/are
equimolar solution of the two liquids, true for an ideal solution ?
assuming the ideal solution should be (A) No heat is absorbed or evolved when the
(A) 140 mm Hg (B) 110 mm Hg components are mixed
(C) 220 mm Hg (D) 100 mm Hg (B) Volume of solution = sum of volume of
168. If p0 and ps are vapour pressures of the two component
solvent and solution respectively, n1 and n2
(C) Intermolecular attraction forces between
are the mole fraction of solvent and solute A – A and B – B are equal to A – B
respectively.
(D) All of the above
(A) ps = p0n1 (B) ps = p0n2
WWW.REALCHEMISTRY.CO.IN
90995 99791
176. I. n-hexane + n-heptane 183. What does the following figure represent ?
II. acetone + ethanol
III. bromoethane + chloroethane
IV. benzene + toluene
Which of the following combination is an
example of ideal solution ?
(A) I, II, III (B) II, III, IV
(C) III, IV, I (D) IV, I, II
177. When a solution does not obey …A… law
over the entire range of concentration, then
it is called non-ideal solution. Here, A refers to
(A) Dalton (B) Raoult
(C) Henry (D) Neutron
(A) Non-ideal solution
178. The vapour pressure of non-ideal solution is
(B) Positive deviation from Raoult’s law
either …… than predicted by Raoult’s law.
(C) Negatiave deviation from Raoult’s law
Fill in the blank with the best suitable word
(D) Only (A) and (B)
(A) A – B > A – A or B – B
184. “The intermolecular attractive forces
(B) A – B < A – A or B – B
between A – A and B – B are weaker than
(C) A – B = A – A or B – B
between A – B, leads to decrease in vapour
(D) None of the above
pressure.
180. A – B interactions are weaker than between
Above statement is defined as
A – A or B – B means
(A) Positive deviation from Raoult’s law
(A) intermolecular attractive forces between
(B) Negative deviation from Raoult’s law
solute-solvent molecules are weaker than between
(C) Ideal solution (D) None of the above
solute-solute and solvent-solvent molecule
185. The hydrogen bonding in between phenolic
(B) intermolecular attractive forces between
…A… and …B… on nitrogen atom of
solute-solute are weaker than between
aniline is …C… than hydrogen bonding
solvent-solvent and solute-solvent
between the similar molecule. Here, A, B
(C) intermolecular attractive forces between
and C refer to
solvent-solvent are weaker than between
solute-solute and solvent-solute (A) Alonepair, Bhydrogen,
(D) intermolecular attractive forces between Cstronger
solvent-solvent is equal between solute- (B) Ahydrogen, Blone pair, Cweaker
solute and solvent-solute (C) Ahydrogen, Blone pair,
181. Assertion (A) : Ethanol and acetone show Cstronger
positive deviation from Raoult’s law (D) Alone pair, Bhydrogen, Cweaker
Reason (R) : Pure ethanol, molecule show 186. Chloroform and acetone from solution with
hydrogen bond and on adding acetone …A… deviation from Raoult’s law. Here, A
hydrogen bond between ethanol molecule break refers to
(A) Both A and R are correct; R is the (A) positive (B) negative
correct explanation of A (C) same (D) None of these
(B) Both A and R are correct; R is not the 187. What does the dashed line represent in the
correct explanation of A given molecules
(C) A is correct; R is incorrect
(D) R is correct; A is incorrect
182. Addition of carbon disulphide to acetone,
dipolar interactions between solute-solvent (A) Ionic bond
are …A… than interactions among solute- (B) Coordinate bond
solute and solvent-solvent molecules. Here, (C) Hydrogen bond
A refers to (D) van der Waal’s forces
(A) larger (B) same 188. Which of the following statement(s) is/are
(C) weaker (D) None of these true for the diagram ?

WWW.REALCHEMISTRY.CO.IN
90995 99791
 195. Solution of azeotropic nitric acid mixture contain
(A) 32% HNO3, 68% H2O by mass
(B) 68% HNO3, 32% H2O by mass
(C) 50% HNO3, 50% H2O by mass
(D) 30% H2O, 70% HNO3 by mass
196. Boiling point of azeotropic nitric acid
(A) 300.0 K (B) 350.0 K
(C) 393.5 K (D) 395.5 K
197. Considering the formation, breaking and
strength of hydrogen bond, product which of
(A) The escaping tendency of molecule the following mixtures will show a positive
decrease for each component deviation from Raoult’s law
(B) Vapour pressure of the solution (A) Methanol and acetone
decreases (B) Chloroform and acetone
(C) Solution show negative deviation from (C) Nitric acid and water
Raoult’s law (D) Phenol and aniline
(D) All of the above 198. On the basis of information given below
189. Azeotropes are formed by mixing the liquids mark the correct option.
which are having same composition in …A… Information : On adding acetone to
and …B… phase and boil at …C… temperature methanol some of the hydrogen bonds
(A) Aliquid Bvapour Cconstant between methanol molecules break.
(B) Asolid Bliquid Cconstant (A) At specific composition methanol-
(C) Avapour Bliquid Cdifferent acetone mixture will form minimum boiling
(D) Asolid Bvapour Cdifferent azeotrope and will show positive deviation
190. The solution which show large positive from Raoult’s law
deviation from Raoult’s law form (B) At specific composition methanol-
(A) maximum boiling azeotrope at a specific acetone mixture forms maximum boiling
composition azeotrope and will show positive deviation
(B) maximum freezing azeotrope at a from Raoult’s law
specific composition (C) At specific composition methanol-
(C) minimum boiling azeotrope at a specific acetone mixture will form minimum boiling
composition azeotrope and will show negative deviation
(D) minimum freezing azeotrope at a from Raoult’s law
specific composition (D) At specific composition methanol-
191. Products obtained from the fermentation of sugar acetone mixture will form maximum boiling
(A) mixture of acetone and water azeotrope and will show negative deviation
(B) mixture of acetonitrile and water from Raoult’s law
(C) mixture of ethanol and water 199. On the basis of information given below
(D) mixture of methanol and water mark the correct option.
192. On fractional distillation, ethanol-water Information
mixture give …A… % by volume of I. In bromoethane and chloroethane mixture
ethanol. Here, A refers to intermolecular interactions of A-A and B-B
(A) 5 (B) 90 type are nearly same as A-B type
(C) 10 (D) 95 interactions
193. Azeotrope mixture can be separated by II. In ethanol and acetone mixture A-A or B-B
(A) distillation type intermolecular interactions are stronger
(B) fractional distillation than A-B type interactions
(C) steam distillation III. In chloroform and acetone mixture A-A or
(D) azeotrope cannot be separated B-B type intermolecular interactions are
194. Solution of azeotropic nitric acid mixture contain weaker than A-B type interactions
(A) Apositive Bmaximum (A) Solution II and III will follow Raoult’s law
(B) Anegative Bmaximum (B) Solution I will follow Raoult’s law
(C) Apositive Bminimum (C) Solution II will show negative deviation
(D) Anegative Bminimum from Raoult’s law
WWW.REALCHEMISTRY.CO.IN
90995 99791
 (D) Solution III will show positive deviation 207. Colligative properties depends on …A… of
from Raoult’s law solute particle irrespective of …B… of solute
200. Intermolecular forces between two benzene particle in solution. Here, A and B refer to
molecules are nearly of same strength as (A) Anumber, Bnature
those between two toluene molecules. For a (B) Anature, Bnumber
mixture of benzene and toluene, which of (C) Anature, Bnature
the following are not true ? (D) Anumber, Bnumber
(A) mixH = zero 208. In colligative,
(B) mixV = zero (A) co means collection ligare means long
(C) These will form minimum boiling (B) co means together ligare means bind
azeotrope (C) co means bind ligare means together
(D) These will form ideal solution (D) co means long ligare mass collection
201. Which of the following binary mixture will 209. Vapour pressure of solvent is …A… than of
have same composition in liquid and vapour pure solvent. Here, A refers to
phase ? (A) less (B) more
(A) Benzene/toluene (C) less/more (D) equal
(B) Water/nitric acid 210. Lowering of vapour pressure depends on
(C) Water/hexane …A… of the solute particle and …B… of
(D) n-hexane/n-heptane their identity
202. Azeotropic mixture of HCl and water has (A) Anature, Bdependent
(A) 48% HCl (B) 22.2% HCl (B) Aconcentration, Bdependent
(C) 36% HCl (D) 20.2% HCl (C) Aconcentration, Bindependent
203. Formation of a solution from two (D) None of the above
components can be considered as 211. Reduction in the vapour pressure of solvent
I. pure solvent  separated solvent molecules, H1 is/are represented by
II. pure solute  separated solute molecules, H2 (A) p1 (B) p1° – p1
III. separated solvent and solute molecules  (C) p1° (D) Both (A) and (B)
solution, H3 212. Solution containing …A… solute, lowering
Solution so formed will be ideal if of the vapour pressure depends on the sum
(A) Hsolution = H1 – H2 – H3 of the …B… of different solute. Here, A and
(B) Hsolution = H3 – H1 – H2 B refer to
(C) Hsolute = H1 + H2 + H3 (A) Anon-volatiale, Bmole fraction
(D) Hsolution = H1 + H2 – H3 (B) Avolatile, Bmole fraction
204. Arrange the following in the increasing (C) Anon-volatiale, Bmasses
order of their solubility in n-octane based on (D) A volatiale, Bmass
solute-solvent interaction 213. Relative lowering of the vapour pressure is
(A) KCl < CH3CN < CH3OH < cyclohexane equal to mole fraction of …A… . Here, A
(B) KCl < Cyclohexane CH3OH < CH3CN refers to
(C) KCl < CH3OH < CH3CN < cyclohexane (A) solute (B) solvent
(D) KCl < cyclohexane < CH3CN < CH3CN (C) solution (D) None of these
205. When non-ideal solution was prepared by 
p p n2
mixing 30 mL chloroform and 50 mL 214. Equation 1  1  is modified into
acetone. The volume of mixture will be p1 n1  n 2
(A) > 80 mL (B) = 80 mL p1  p1 n 2
(C) < 80 mL (D)  80 mL  for (where 1solute and
p1 n1
206. Which of the following is/are the colligative
properties(s) ? 2solvent)
(A) Relative lowering of vapour pressure of (A) dilute solution
solvent (B) concentrated solution
(B) Depression of freezing point and (C) any solution (D) All of these
elevation of boiling point 215. Liquid boils at the temperature at which its
(C) Osmotic pressure of the solution …A… is equal to atmospheric pressure.
(D) All of the above Here, A refers to

WWW.REALCHEMISTRY.CO.IN
90995 99791
 (A) boiling point (B) freezing point
(C) vapour pressure (D) All of these
216. What is the boiling point of water ?
(A) 100°C (B) 100 K
(C) 200°C (D) 200 K
217. Vapour pressure of water is …A… in order
to boil at 100°C. Here, A refers to
(A) 1.013 bar (B) 1 atm
(C) Both (A) and (B) (D) None of these
218. Vapour pressure of the solvent …A… in the
presence of non-volatile solute. Here, A
refers to
(A) increases (B) decreases
(C) remain same (D) Both (A) and (B)
219. In order to make the aqueous solution of
sucrose to boil
(A) the vapour pressure of sucrose solution
must be lessthan 1.013 bar by raising the
temperature above the boiling temperature
of pure solvent
(B) vapour pressure of sucrose solution must
be increased to 1.013 bar by raising the
temperature above the boiling temperature
of pure solvent
(C) Both (A) and (B)
(D) None of the above
220. What does point (A) and (B) represent in the
following diagram ?
Point A Point B
(A) Boiling point of solvent Boiling point of solution
(B) Boiling point of solution Boiling point of solvent
(C) Boiling point of solute Boiling point of solvent
(D) Boiling point of solvent Boiling point of solute
221. …A… boiling point depends on …B… of
solute molecules rather than their …C… .
Here, A, B and C refer to
(A) AElevation of, Bnature, Cnumber
(B) AElevation of, Bnumber, Cnature
(C) ADepression in, Bnature, Cnumber
(D) ADepression in, Bnumber, Cnature
222. Tb° is the boiling point of …A… and T b is
the boiling point of …B… . Here, A and B
refer to
(A) Asolution, Bpure solvent
(B) Asolution, Bpure solute
(C) Apure solvent, Bsolution
(D) Apure solvent, Bpure solute
WWW.REALCHEMISTRY.CO.IN
90995 99791
223. Tb is
(A) depression in boiling point of solvent in
solution
(B) elevation of boiling point of solvent in
solution
(C) Both (A) and (B)
(D) None of the above
224. For …(I)… solutions, elevation of boiling
point is directly proportional to …(II)…
concentration of the solute in a solution.
Here, (I) and (II) refer to
(A) (i) concentrated (ii) molal
(B) (i) concentrated (ii) molar
(C) (i) dilute (ii) molal
(D) (i) dilute (ii) molar
225. Tb = Kbm; Kb is
(A) boiling point elevation constant
(B) molal elevation constant
(C) ebullioscopic constant
(D) All of the above
226. On the basis of information given below
mark the correct option
Information : Tb = Kbm
(A) Molality (m) is the number of mole of
solute dissolved in 1 kg of solvent
(B) Unit of Kb is K kg mol–1
1000  w 2  K b
(C) M 2 
Tb  w1
M2 = molar mass of solute
w2 = mass of solute dissolved in w1 gram of solvent
(D) All of the above
227. Temperature at which the vapour pressure of
the substance in its liquid phase is equal to is
vapour pressure in the solid phase is called
(A) vapour pressure (B) boiling point
(C) freezing point (D) None of these
228. Mark the correct option(s) for the freezing
point of a substance
(A) Solid phase is in dynamic equilibrium
with liquid phase
(B) Lowering of vapour pressure of solution
causes lowering of freezing point as
compared to pure solvent
(C) A solution will freeze when its vapour
pressure equals to the vapour pressure of
pure solid solvent
(D) All of above information is true
229. Assertion (A) : Freezing point of solvent is
less than that of solution
Reason (R) : Non-volatile solid is added to
the solvent its vapour pressure increases and
become equal to solid solvent at the lower
temperature
 (A) Both A and R are correct; R is the Column I Column II
correct explanation of A A. Kf 1. Gas constant
(B) Both A and R are correct; R is not the B. Kb 2. Enthalpies for fusion of solvent
correct explanation of A C. R 3. Enthalpies for vaporization of solvent
(C) A is correct; R is incorrect D. Tf 4. Cryoscopic constant
(D) R is correct; A is incorrect E. Tb 5. Freezing point of pure solvent
F. fusH 6. Ebullioscopic constant
230. Identify (i), (ii), (iii) in the following
G. vapH 7. Boiling point of pure solvent
diagram.
Codes :
A B C E E F G
(A) 1 2 3 4 5 6 7
(B) 7 6 5 4 3 2 1
(C) 6 4 1 5 7 2 3
(D) 4 6 1 5 7 2 3
235. Fill up the box of formula with an
appropriate designation
R  M1  Tf2 R  M1  Tb2
Kf  ; Kb 
1000  A 1000  B
Here, (i), (ii) and (iii) refer to (A) (A) vapH (B) fusH
(A) (i) solution; (ii) Frozen solvent; (B) (A) fus(B) vapH
(iii) Liquid solvent (C) (A) subH (B) vapH
(B) (i) Frozen solvent; (ii) Solution
(D) (A) fusH (B) subH
(iii) Liquid solvent
236 Brine is
(C) (i) Frozen solvent; (ii) Liquid solvent
(A) sodium hydroxide solution
(iii) Solution
(B) salt water
(D) (i) Solution; (ii) Liquid solvent;
(C) cold water (D) hot water
(iii) Frozen solvent
237. Match the following Column I with Column
231. Tf is II. Select an appropriate answer from the
(A) freezing point of the solution given options.
(B) elevation in the freezing point of the solution Column I Column II
(C) depression in the freezing point A. Wilted flower revive 1. Placed in fresh water
(D) freezing point of the solvent when 2. Placed in saline water
232. Depression of freezing point for …(I)… is B. Blood cell collapse
directly proportional to …(II)… . Here, (I) when
and (II) refer to C. Raw mangoes
(A) (i) dilute solution, (ii) molarity shrivel when
(B) (i) dilute solution, (ii) molality Codes :
(C) (i) concentrated solution, (ii) molality A B C
(D) (i) concentrated solution, (ii) molarity (A) 1 2 2
233. Mark the correct option for the Kf. (B) 2 1 2
I. Kf depends on nature of solvent (C) 2 1 1
II. Kf know as freezing point depression (D) 1 1 2
consant/molal depression constant. 238. Semipermeable membrane can be
III. Kf known as cryoscopic constant. (A) animal or vegetable origin
IV. Unit of Kf = K kg mol–1 (B) pigs bladder or parachment
K  w1  1000 (C) cellophane (D) All of the above
V. M2  f 239. Information
Tf  w 2
I. Semipermeable membrane contains network
where w2 is the mass of solute having molar
of submacroscopic holes or pores
mass of M2 present in w1 gram of solvent
II. Semipermeable membrane appears to be
(A) I, II, III (B) I, II, III, IV
continuous sheets or films
(C) I, II, III, IV, V (D) II, III, IV, V
III. Solvent molecule cannot pass through the
234. Match the following Column I with Column
holes of semipermeable membrane but
II. Select an appropriate answer from the
solute molecule can pass
codes given below.
WWW.REALCHEMISTRY.CO.IN
90995 99791
 On the basis of the information given above (A) Only I (B) Only II
select the correct option. (C) Only III (D) I, II, III
(A) Only I (B) Only II 244. Osmotic pressure depends on …A… . Here,
(C) Only III (D) I, II and III A refers to
(A) nature of solute particles dissolved in
solution
(B) the number of solute particles in solution
(C) the physical properties of solute particles
(D) nature of solvent particles
245. Osmotic pressure depends on …A… . Here,
A refers to
240.
(A) molarity of solution
(B) molality of solution
(C) normality of solution
(D) formality of solution
246. Osmotic pressure is given by the expression
…A.. . Here, A refers to
(A)  = CRT
Mark the correct information derived from n 
(B)    2  RT (n2  moles of solute)
the diagram. V
(A) Solute molecule passes through the w RT
semipermeable membrane from pure solvent (C)   2 (w2  gram of solute, M2 
to the solution M 2V
(B) The level of solution increases due to osmosis molar mass of solute)
(C) Solvent molecules flow through (D) All of the above
membrane from solution to pure solvent 247. Osmotic pressure determine the molar
(D) All of the above mass(es) of
241. Which of the following statement(s) is/are (A) proteins (B) polymers
true about osmotic pressure ? (C) macromolecules (D) All of the above
I. Flow of solvent from solution across the 248. Consider the following statements.
semipermeable membrane can be stopped if I. Molarity of the solution is used instead of
extra pressure is applied on solution molality.
II. It is pressure that stops the flow of solvent II. Magnitude is very large even for dilute
III. It is pressure that allow flow of solvent solutions.
across the semipermeable membrane III. Molar mass of biomolecules can be
(A) I, II (B) II, III determined as they are not stable at higher
(C) I, III (D) I, II, III temperature.
242. Flow of solvent from …(i)… to …(ii)… IV. Determine the molar mass of polymer as
across semipermeable membrane is due to they are having poor solubility.
osmosis. Here, (i) and (ii) refer to Which of the above statement(s) is/are
(A) (i) dilute solution, (ii) concentrated solution responsible for advantage of osmotic
(B) (i) lower concentration, (ii) higher concentrated pressure over the other colligative properties ?
(C) (i) pure solvent, (ii) solution (A) I and II (B) III and IV
(D) All of the above (C) I, II and IV (D) None of these
243. Where excess pressure is to be applied in the 249. In the isotonic condition …A… . Here, A
given diagram to prevent osmosis ? refers to
(A) both the solution have same osmotic
pressure
(B) both the solution do not have the same
osmotic pressure
(C) both the solution have same boiling
point
(D) both the solution have different boiling
point
WWW.REALCHEMISTRY.CO.IN
90995 99791
250. Osmotic pressure present in the fluid inside
the blood cell is equivalent to
(A) 0.9% (m/V) NaCl solution
(B) less than 0.9% (m/V) NaCl solution 255.
(C) more than 0.9% (m/V) NaCl solution
(D) 0.9% (m/V) Na2SO4 solution
251. Match the terms given in Column I with Select the basics process/processes which
expression given in Column II. Select an occur in this figure
appropriate answer from the codes given (A) Condensation (B) Evaporation
below. (C) Osmosis (D) Both (A) and (B)
Column I Column II 256. Meat and fruits are preserved by salting and
A. Isotonic 1. Salt concentration is less adding sugar respectively because
solution than 0.9% (m/V), water will (A) bacteria do to not grow in this media
flow into cell and it will (B) of osmosis
swell
(C) bacterium on salted meat or candid fruit
B. Hypertonic 2. Salt concentration is more
solution than 0.9% (m/V) NaCl,
loses water, shrives and dies
water will flow out of cell (D) All of the above
and will shrink 257. Which of the following statement(s) is/are
C. Hypotonic 3. No osmosis occur if false for reverse osmosis ?
solution solution is separated by (A) The direction of osmosis can be
semipermeable membrane reversed if pressure larger than osmotic
Codes : pressure is applied to solution side
A B C (B) Pure solvent flows out of solution
(A) 3 1 2 through semipermeable membrane
(B) 3 2 1 (C) Variety of polymer membranes are
(C) 1 2 3 available for reverse osmosis
(D) 2 1 3 258. Desalination of sea water is due to …A… .
252. Which colligative properties is responsible Here, A refers to
for raw mango to shrivel into pickle when it (A) osmosis
is placed in concentration salt solution (B) reverse osmosis
(A) Relative lowering of vapour pressure (C) relative lowering of vapour pressure
(B) Elevation in boiling point (D) depression in freezing point
(C) Depression in freezing point 259. Reverse osmosis occur when pressure
(D) Osmosis …A… than osmotic pressure is applied to
253. A carrot become limp due to …(i)… and the solution. Here, A refers to
become firm when placed in water due to (A) same (B) larger
…(ii)… . Here, (i) and (ii) refer to (C) smaller (D) larger/smaller
(A) (i) water gain; (ii) osmosis 260. Complete the (A) and (B) in the diagram for
(B) (i) water loss; (ii) osmosis desalination of sea water. Here A and B
(C) (i) water gain; (ii) reverse osmosis refer to
(D) (i) water loss; (ii) reverse osmosis
254. Assertion (A) : People taking a lot of salty
food experience the puffiness of swelling
called edema.
Reason (R) : There is water retention in
tissue cells and intercellular spaces because
of osmosis (A) Asalt water, Bfresh water
(A) Both A and R are correct; R is the (B) Afresh water, Bsalt water
correct explanation of A (C) Asolid salt, Bfresh water
(B) Both A and R are correct; R is not the (D) Afresh water, Bsolid salt
correct explanation of A 261. Select the true statement(s) about cellulose
(C) A is correct; R is incorrect acetate
(D) R is correct; A is incorrect (A) Cellulose acetate is the porous
membrane used for the reverse osmosis
WWW.REALCHEMISTRY.CO.IN
90995 99791
 (B) Cellulose acetate is permeable to the Column I Column II
water A. Raoult’s law 1. Tf = Kfm
(C) Cellulose acetate is impermeable to B. Henry’s law 2.  = CRT
impurities and ions present in sea water C. Elevation of boiling point 3. p = x1p1° + x2p2°
(D) All of the above D. Depression in freezing 4. Tb = Kbm
262. In comparison to a 0.01 M solution of point
glucose, the depression in freezing point of a E. Osmotic pressure 5. p = KH · x
0.01 M MgCl2 solution is …A… . Here, A Codes :
refers to A B C D E
(A) the same (B) about twice (A) 5 3 4 1 2
(C) about three times (D) about six times (B) 5 3 4 1 2
263. Which of the following statement is false ? (C) 3 5 4 1 2
(A) Two different solutions of sucrose of (D) 3 5 2 1 4
same molality prepared in the different  Directions (Q.No. 266-269) In the
solvents will have the same depression in following questions a statement of assertion
freezing point followed by a statement o reason is given.
(B) The osmotic pressure of a solution is Choose the correct answer out of the
given by the equation  = CRT (where C is following choices.
the molarity of the solution) 266. Assertion (A) : Molarity of a solution in the
(C) Decreasing order of osmotic pressure for liquid state changes with temperature.
0.01 M aqueous solutions of barium Reason (R) : The volume of a solution
chloride, potassium chloride, acetic acid and changes with change in temperature
sucrose is BaCl2 > KCl > CH3COOH > (A) Both A and R are correct; R is the
sucrose correct explanation of A
(D) According to Raoult’s law, he vapour (B) Both A and R are correct; R is not the
pressure exerted by a volatile component of correct explanation of A
a solution is directly proportional to its mole (C) A is correct; R is incorrect
fraction in the solution (D) R is correct; A is incorrect
264. Consider the figure and mark the correct 267. Assertion (A) : When methyl alcohol is
option. added to water, boiling point of water
decreases
Reason (R) : When a volatile solute is
added to a volatile solvent elevation in
boiling point is observed
(A) Both A and R are correct; R is the
correct explanation of A
(B) Both A and R are correct; R is not the
correct explanation of A
(A) Water will move from side (A) to side (C) A is correct; R is incorrect
(B) if a pressure lower than osmotc pressure (D) R is correct; A is incorrect
is applied on piston (B) 268. Assertion (A) : When NaCl is added to
(B) Water will move from side (B) to side water a depression in the freezing point is
(A) if a pressure greater than osmotic observed.
pressure is applied on piston (B) Reason (R) : The lowering of vapour
(C) Water will move from side (B) to side pressure of a solution causes depression in
(A) if a pressure equal to osmotic pressure is the freezing point
applied on piston (B) (A) Both A and R are correct; R is the
(D) Water will move from side (A) to side correct explanation of A
(B) if pressure equal to osmotic pressure is (B) Both A and R are correct; R is not the
applied on piston (A) correct explanation of A
265. Match the laws given in Column I with (C) A is correct; R is incorrect
expressions given in Column II. Select an (D) R is correct; A is incorrect
appropriate answer from the codes given
below.
WWW.REALCHEMISTRY.CO.IN
90995 99791
269. Assertion (A) : When a solution is (A) elements and compounds
separated from the pure solvent by a (B) mixture and elements
semipermeable membrane, the solvent (C) cations and anions
molecules pass through it from pure solvent (D) mixture and compounds
side to the solution side. 275. Assertion (A) : Experimentally determined
Reason (R) : Diffusion of solvent occurs molar mass is always lower than the true value
from a region of high concentration solution Reason (R) : It is due to dissociation of
to a region of low concentration. solute into ion.
(A) Both A and R are correct; R is the (A) Both A and R are correct; R is the
correct explanation of A correct explanation of A
(B) Both A and R are correct; R is not the (B) Both A and R are correct; R is not the
correct explanation of A correct explanation of A
(C) A is correct; R is incorrect (C) A is correct; R is incorrect
(D) R is correct; A is incorrect (D) R is correct; A is incorrect
270. For a binary ideal liquid solution, the 276. Which of the following statement(s) is/are
variation in total vapour pressure versus correct about the molecule of ethanoic acid
composition of solution is given by which of in benzene ?
the curves ? (A) It dimerize due to the hydrogen bonding
(B) It is the solvents of low dielectric constant
(C) There is association of the molecule
(A) (B) (D) All of these above
277. Tb or Tf for ethanoic acid will be ..(i).. of
normal value and molar mass will be ..(ii)..
of expected value. Here, (i) and (ii) refer to
(A) (i) half (ii) half
(C) (D) (B) (i) twice (ii) half
(C) (i) half (ii) twice
(D) (i) twice (ii) twice
271. 1.26 g of the protein is present in the 278. Molar mass that is either lower or higher
aqueous solution of 200 cm3. Calculate the than the expected or normal value is called
molar mass of the protein if the osmotic …A… . Here, A refers to
pressure of such solution is 2.57 × 10–3 bar (A) molecular mass
at 300 K (B) normal molar mass
(A) 61000 g mol–1 (B) 61022 g mol–1 (C) abnormal molar mass
(C) 60000 g mol –1
(D) 61009 g mol–1 (D) molecular weight
272. Assertion (A) : Melting point of a substance 279. van’t Hoff factor (i) is introduced in ..(I)..
is used for testing the purity of the and it is given by the expression ..(II).. .
substance. Here, (I) and (II) refer to
Reason (R) : There is no other method to Normal molar mass
(A) (I) 1880 (II) i 
determine the purity of substance. Abnormal molar mass
(A) Both A and R are correct; R is the Observed colligative property
correct explanation of A (B) (I) 1880 (II) i 
Calculated colligative property
(B) Both A and R are correct; R is not the Total number of moles of particles
correct explanation of A
(C) A is correct; R is incorrect (C) (I) 1880 (II) i  after association / dissociation
Number of moles of particles before
(D) R is correct; A is incorrect
273. A substance is deliquescent if its vapour pressure association / dissociation
(A) is equal to that of water vapour in air (D) All of the above
(B) is equal to the atmospheric pressure 280. During the experimental determination of
(C) is more than that of water vapour in air the abnormal molar mass, it is assumed that
(D) is less than that of water vapour in air non-volatile solute is
274. Ionic compounds dissociate into …A… and (A) associated (B) dissociated
…B… when dissolved in water. Here, A and (C) either associated or dissociated
B refer to (D) neither associated nor dissociated
WWW.REALCHEMISTRY.CO.IN
90995 99791
281. For association i is …A… than 1, for dissociation
i is …B… than 1. Here, A and B refer to
(A) less, more (B) more, less
(C) more, same (D) same, more
282. Match the following terms given in Column
I with the Column II
Column I Column II
(van’t Hoff factor)
A. KCl 1. 0.5 (approx. factor)
B. Ethanoic acid 2. 2 (approx.)
C. K2SO4 3. 3(approx.)
Codes :
A B C (A) INo change is observed, IIHypertonic
(A) 2 3 1 solution, IIIHypotonic solution
(B) 1 3 2 (B) IOuter shell of egg dissolves,
(C) 2 1 3 IIHypertonic solution, IIIHypotonic solution
(D) 1 2 3 (C) IOuter shell of egg dissolves,
283. van’t Hoff factor can be applied to the IIHypertonic solution, IIIHypertonic
(A) relative lowering of vapourpressure of solvent solution
(B) elevation of boiling point (D) INo change is observed, IIHypotonic
(C) osmotic pressure of solution solution, IIIHypertonic solution
(D) all colligative properties 289. Which of the following statements is false ?
284. We have three aqueous solutions of NaCl (A) Units of atmospheric pressure and
labeled as ‘A’, ‘B’ and ‘C’ with osmotic pressure are the same
concentrations 0.1 M, 0.01 M and 0.001 M, (B) In reverse osmosis, solvent molecules
respectively. The value of van’t Hoff factor move through a semipermeable membrane
for these solutions will be in the order from a region of lower concentration of
(A) iA < iB < iC (B) iA > iB > iC solute to a region of higher concentration
(C) iA = iB = iC (D) iA < iB > iC (C) The value of molal depression constant
285. Determine the amount of CaCl2 (i = 2.47) depends on nature of solvent
dissolved in 2.5 L of water such that its (D) Relative lowering of vapour pressure, is
osmotic pressure is 0.75 atm at 27°C. the dimensionless quantity
(A) 1.0 g (B) 9.2 g (C) 3.42 g (D) 2.42 g 290. Which of the following aqueous solutions
286. Determine the osmotic pressure of the should have the highest boiling point ?
solution prepared by dissolving 25 mg of (A) 1.0 M NaOH (B) 1.0 M Na2SO4
K2SO4 in 2 L of water at 25°C. (Assuming it (C) 1.0 M NH4NO3 (D) 1.0 M KNO3
is to be completely dissociated) 291. At a given temperature, osmotic pressure of
(A) 5.27 × 10–4 atm (B) 5.2 × 10–3 atm the concentrated solution of a substance.
(C) 5.27 × 10–2 atm (D) 5.27 × 10–1 atm (A) is higher than that at a dilute solution
287. The degree of dissociation () of a weak (B) is lower than that of a dilute solution
electrolyte AxBy is related to van’t Hoff (C) is same as that of a dilute solution
factor (i) by the expression (D) cannot be compared with osmotic
i 1 i 1 pressure of dilute solution
(A)   (B)  
(x  y  1) x  y 1 292. ….A…. thermometer can be used for the
x  y 1 x  y 1 accurate measurement of small difference in
(C)   (D)   temperature. Here, A refers to
i 1 i 1
(A) contact (B) clinical
288. Complete the statement (I), (II), (III) in the
(C) Beckmann’s (D) Platinum resistance
following figure
293. Cooking time is reduced by the pressure
cooker because
(A) the higher pressure inside the pressure
cooker crushes the food material
(B) the heat is more evenly distributed in
cooking space
WWW.REALCHEMISTRY.CO.IN
90995 99791
 (C) the cooking involves chemical changes 302. Order of depression in freezing point of water
helped by rise in temperature when same amount of acetic acid, trifluoroacetic
(D) the boiling point of water involved in acid and trichloroacetic acid is added
cooking is increased (A) CH3COOH < CCl3COOH < CF3COOH
294. How much of ethylene glycol should be (B) CH3COOH > CCl3COOH > CF3COOH
added to the 4 kg of water in order to (C) CH3COOH < CF3COOH < CCl3COOH
prevent it from freezing at –6°C (Kf of water (D) CCl3COOH < CH3COOH < CF3COOH
= 1.886 K kg mol–1 and molar mass of 303. Relative lowering of the vapour pressure is a
ethylene glycol = 62 g mol–1) colligative property because
(A) 400 g (B) 804 g (A) it depends on the concentration of a non-
(C) 204 g (D) 304 g electrolyte solute in the solution and does not
295. Maximum freezing point falls in depend on the nature of the solute molecules
(A) naphthalene (B) camphor (B) it depends on number of particles of
(C) benzene (D) Water electrolyte solute in the solution and does not
296. 6 g of compound exerts the same osmotic depend on the nature of the solute particles
pressure as that of 0.05 M glucose solution. Find (C) it depends on the concentration of a non-
out the molecular formula of compound if the electrolyte solute in the solution as well as on the
empirical formula of non-electrolyte is CH2O. nature of the solute molecules
(A) C2H4O2 (B) C3H6O3 (D) it depends on the concentration of an electrolyte or
(C) C5H10O5 (D) C4H8O4 non-electrolyte solute in the solution as well as on the
297. Concentrated nitric acid used in laboratory nature of solute molecules
work is 68% nitric acid by mass in aqueous 304. Calculate the mass of urea (NH2CONH2)
solution. What should be the molarity of required in making 2.5 kg of 0.25 molal
such a sample of the nitric acid if the density aqueous solution.
of the solution is 1.504 g mL–1 ? (A) 37 g (B) 35 g
(A) 16.23 M (B) 17.00 M (C) 34 g (D) 32 g
(C) 15.00 M (D) 15.23 M 305. Calculate the mole fraction of ethylene
298. If the solubility product of CuS in 6 × 10–16, glycol (C2H6O2) in a solution containing
calculate the maximum molarity of CuS in 20% of C2H6O2 by mass
an aqueous solution. (A) 0.068 (B) 0.932
(A) 2.45 × 10–8 mol L–1 (B) 2.45 × 10–7 mol L–1 (C) 0.078 (D) 0.010
(C) 2.45 × 10–6 mol L–1 (D) 2.45 × 10–5 mol L–1 Directions : (Q.No. 306 to 308) : Answer
299. Assertion (A) : High blood pressure patients the following question on the basis of the
are advised to take the minimum quantity of salt. statement given below. “Vapour pressure of
Reason (R) : Na+Cl– ion concentration chloroform and dichloromethane at 298 K
increases in the body fluid which may are 200 mm Hg and 41.5 mm Hg”.
rupture the blood cells. 306. What is the vapour pressure of solution
(A) Both A and R are correct; R is the prepared by mixing 25.5 g of CHCl3 and 40
correct explanation of A g of CH2Cl2 at 298 K?
(B) Both A and R are correct; R is not the (A) 347.9 mmHg (B) 300 mmHg
correct explanation of A (C) 200 mmHg (D) 147.9 mmHg
(C) A is correct; R is incorrect 307. Calculate the mole fractions of each
(D) R is correct; A is incorrect component in vapour phase.
300. One litre of N/2 HCl solution is heated in a (A) yCH2Cl2  285; yCHCl3  62.4
beaker and it is observed that when volume
was reduced to 600 mL, 3.25 g of HCl is (B) yCH2Cl2  0.18; yCHCl3  0.82
lost. Calculate the normality of new solution (C) yCH2Cl2  0.82; yCHCl3  0.18
(A) 0.50 N (B) 0.60 N
(D) yCH2Cl2  62.4; yCHCl3  285
(C) 0.68 N (D) 0.70 N
301. Find out the osmotic pressure of 0.1 M 308. Which one of them is more volatile
monobasic acid if pH = 2.0 at 25°C. component ?
(A) 2.69 atm (B) 26.9 atm (A) CH2Cl2 (B) CHCl3
(C) 0.269 atm (D) None of these (C) Both (A) and (B)
(D) Not able to determine
WWW.REALCHEMISTRY.CO.IN
90995 99791
309. 1.00 g of a non-electrolyte solute is 313. Compound A undergoes tetramerisation in
dissolved in 50 g of benzene which lower the given solvent. The van’t Hoff factor is
the freezing point of benzene by 0.40 K. The (A) 2.0 (B) 0.5
freezing point depression constant of (C) 0.25 (D) 0.125
benzene is 5.12 K kg mol–1. Find the molar 314. The boiling point of benzene is 353.23 K.
mass of the solute. When 1.80 g of a non-volatile solute was
(A) 206 g mol–1 (B) 226 g mol–1 dissolved in 90 g of benzene, the boiling
–1
(C) 246 g mol (D) 256 g mol–1 point is raised to 354.11 K. Calculate the
310. A solution containing 2.675 g of CoCl3 · molar mass of the solute.
6NH3 (molar mass = 267.5 g mol–1) is (Kb for benzene is 2.53 K kg mol–1)
passed through cation exchanger. The (A) 58 g mol–1 (B) 49 g mol–1
–1
chloride ion obtained in the solution were (C) 55 g mol (D) 94 g mol–1
treated with excess AgNO3 to give 4.78 g of 315. The depression in the freezing point of 0.02
AgCl (molar mass = 143.5 g mol–1). The m aqueous solution of urea, NaCl, CaCl2 is
formula of the complex is in the ratio of
[atomic mass of Ag = 108 u] (A) 1 : 1 : 1 (B) 1 : 2 : 3
(A) [CoCl2(NH3)4]Cl (B) [CoCl(NH3)5]Cl2 (C) 1 : 2 : 4 (D) 2 : 2 : 4
(C) [ClCl3(NH3)3] (D) [Co(NH3)6]Cl3 316. 45 g of ethylene glycol (C2H6O2) is mixed
311. …A… mL of 0.1 M HCl are required to with 600 g of water then find out the
react completely with 1 g mixture of depression in freezing point
Na2CO3 and NaHCO3 containing equimolar
amount of these two ? Here, A refers to (A) 1.1 K (B) 2.2 K
(A) 157.8 mL (B) 0.1578 mL (C) 2.3 K (D) 3.3 K
(C) 210.4 mL (D) 105.2 mL 317. 45 g of ethylene glycol (C2H6O2) is mixed
312. Water boils at 95°C in Leh the 3524 mile with 600 g of water. Find out the freezing
high City. What is the atmospheric pressure point of the solution.
in Denur ? (A) 273.15 K (B) 270.95 K
(vap H of H2O = 40.67 kJ mol–1) (C) –273.15 K (D) –270.95 K
(A) 1 atm (B) 0.738 atm
(C) 0.837 atm (D) None of these

WWW.REALCHEMISTRY.CO.IN
90995 99791
 ANSWER KEY
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
(C) (C) (A) (B) (C) (B) (A) (C) (C) (A) (B) (B) (D) (B) (B)
16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
(C) (A) (A) (A) (B) (C) (A) (B) (D) (A) (C) (B) (C) (A) (A)
31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
(B) (A) (B) (B) (C) (A) (B) (C) (A) (B) (D) (D) (A) (D) (D)
46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
(A) (D) (A) (B) (B) (A) (A) (C) (D) (C) (A) (A) (B) (C) (D)
61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
(D) (C) (C) (D) (B) (C) (B) (B) (C) (C) (B) (B) (D) (D) (A)
76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
(B) (B) (A) (A) (A) (C) (A) (C) (A) (B) (D) (C) (B) (A) (C)
91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
(C) (A) (A) (C) (C) (A) (A) (B) (C) (A) (C) (A) (C) (A) (A)
106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
(D) (C) (B) (B) (D) (B) (B) (B) (A) (D) (C) (B) (B) (C) (D)
121 122 123 124 125 126 127 128 129 130 131 132 133 134 135
(A) (B) (C) (A) (C) (D) (D) (D) (A) (C) (A) (B) (B) (D) (C)
136 137 138 139 140 141 142 143 144 145 146 147 148 149 150
(B) (C) (A) (C) (B) (B) (A) (C) (C) (A) (B) (D) (C) (C) (B)
151 152 153 154 155 156 157 158 159 160 161 162 163 164 165
(B) (C) (A) (A) (B) (C) (B) (B) (C) (B) (D) (A) (C) (A) (B)
166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
(C) (B) (A) (C) (B) (C) (C) (A) (A) (D) (C) (B) (C) (B) (A)
181 182 183 184 185 186 187 188 189 190 191 192 193 194 195
(A) (C) (D) (B) (C) (B) (C) (D) (A) (C) (C) (D) (D) (B) (B)
196 197 198 199 200 201 202 203 204 205 206 207 208 209 210
(C) (A) (A) (B) (C) (B) (D) (C) (C) (C) (D) (A) (B) (A) (C)
211 212 213 214 215 216 217 218 219 220 221 222 223 224 225
(D) (A) (A) (A) (C) (A) (C) (B) (B) (A) (B) (C) (B) (C) (D)
226 227 228 229 230 231 232 233 234 235 236 237 238 239 240
(D) (C) (D) (C) (C) (C) (B) (B) (D) (B) (B) (A) (D) (B) (B)
241 242 243 244 245 246 247 248 249 250 251 252 253 254 255
(A) (D) (A) (B) (A) (D) (D) (C) (A) (A) (B) (D) (C) (A) (C)
256 257 258 259 260 261 262 263 264 265 266 267 268 269 270
(D) (D) (B) (B) (B) (D) (C) (A) (B) (C) (A) (D) (A) (C) (D)
271 272 273 274 275 276 277 278 279 280 281 282 283 284 285
(B) (C) (D) (C) (A) (D) (C) (C) (D) (D) (A) (C) (D) (A) (C)
286 287 288 289 290 291 292 293 294 295 296 297 298 299 300
(B) (A) (B) (B) (B) (A) (C) (D) (B) (B) (D) (A) (A) (C) (C)
301 302 303 304 305 306 307 308 309 310 311 312 313 314 315
(A) (A) (A) (A) (A) (A) (C) (A) (D) (D) (A) (C) (C) (A) (B)
316 317
(B) (B)

WWW.REALCHEMISTRY.CO.IN
90995 99791