07 10 2023 SR Super60 NUCLEUS & STERLING BT Jee Main RPTM 10 KEY

SRI CHAITANYA IIT ACADEMY, INDIA 07‐10‐23_ Sr.
Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐10_KEY &SOL’S
Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS&STERLING_BT JEE-MAIN Date: 07-10-2023
Time: 09.00Am to 12.00Pm RPTM-10 Max. Marks: 300
KEY SHEET
PHYSICS
1) 1 2) 2 3) 2 4) 4 5) 3
6) 4 7) 2 8) 3 9) 3 10) 1
11) 1 12) 4 13) 2 14) 4 15) 2
16) 1 17) 3 18) 4 19) 3 20) 3
21) 20 22) 20 23) 6 24) 47 25) 5
26) 48 27) 13 28) 4 29) 40 30) 1250
CHEMISTRY
31) 1 32) 2 33) 3 34) 4 35) 4
36) 4 37) 3 38) 3 39) 3 40) 1
41) 3 42) 1 43) 2 44) 1 45) 3
46) 2 47) 4 48) 1 49) 4 50) 1
51) 4 52) 1 53) 3 54) 1 55) 5
56) 1 57) 1 58) 8 59) 2 60) 8
MATHEMATICS
61) 1 62) 2 63) 4 64) 1 65) 4
66) 1 67) 2 68) 1 69) 1 70) 1
71) 1 72) 2 73) 4 74) 2 75) 3
76) 2 77) 1 78) 4 79) 3 80) 3
81) 216 82) 130 83) 2 84) 2 85) 5
86) 69 87) 1 88) 2 89) 1 90) 2
Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 1

SRI CHAITANYA IIT ACADEMY, INDIA 07‐10‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐10_KEY &SOL’S
SOLUTIONS
PHYSICS
1. 1 1
F L  mv 2
2 2
1 AY (L)2 1 2
 mv
2 L 2
Y  4.42  104 N / m 2
2. Let F be the force at distance x from the front end
F 2 F0 2F X
 F  0
X L L
L
d 2 F0 X strees 2F X
Strain    ;  d   0 dX ;
dX YAL Y YSL
0
2
2 F0  x 2  FL
    0
YS  2  SY
3. dr r1  r2 Ldr
tan    dy 
dy L r1  r2
F .dy F Ldr FL dr
de    .
 r2 y  r 2 y (r1  r2 )  Y (r1  r2 ) r 2
r
FL r1 dr FL  1  1
  Y (r1  r2 ) r2 r 2  Y (r1  r2 )  r  r
de  
2
FL  1 1 
   
 Y (r1  r2 )  r1 r2 
FL r1  r2 FL
 e
 Y (r1  r2 ) r1r2  Yr1r2
4. Assuming Hookes law to be valid.
T  (l )
T  k (l )
Let , l0  natural length ( original length )
 T  k (l  l0 )
So, T  k (l1  l0 ) and 2T  k (l2  l0 )
T l l
  1 0
2T l2  l0
 l0  2l1  l2

5.
W  T .A  T .21 x
 7.2  102  2  10  102  2  103
 28.8  106  2.88  105 J
6.
PV = constant
 4T  4 3  4T 4 3  4T 4 3
 P0    a   P0    b   P0   c
 a 3  b 3  c 3
 P0 (a3  b3  c3 )  4T (c 2  a 2  b 2 )
P0 (a3  b3  c3 ) P0 (63  53  43 )a 27 P0a
T   
2 2 2 2 2 2 20
4(c  a  b ) 4(4  5  6 )
7. If R be the meniscus radius R
cos(   )  b
Excess pressure on concave side of meniscus
2S

R
2S 2S
h g   cos    
R b
2S
h cos    
b g
8.
c  90
For water oil interface
9. Vt R 2 ;V2  4V
10.  2 r 2 2 (2 rdr )  2 r 4 4 r 4 2
     P   2 
 h  h h
11. v
mg sin   fv   a 2
t
mgt sin   agt sin 
  
a 2v v
12. Terminal velocity of a spherical body in liquid

Vt r
Vt r 2  x f   2.
Vt r
Vt (0.1)
  100%  2  100  4%
Vt 5
AlsoVt r 2Vt r 2
Re ason Ris false
13. When the oil is poured, the fraction of ice in the water decreases, i.e., volume of ice
melted into water is greater than volume of water displaced by ice. So water level
rises. Overall volume of ice will decrease as it melts. So the upper level of oil falls.
14. VAa A  vB  aB  v A  4  vB  2 vB  2v A ---------------(i)
1 1 1 1
Again,  v A2   ghA  p A   vB 2   ghB  pB  v A2  p A   vB 2  pB
2 2 2 2
1
2
1
2
  1
 PA  PB   (vB 2  v A2 )   1  4v A2  v A2  3  1  1000   1  3  v A2
2
2
( PA  PB  2cm of water column  3  1  1000dyn / cm
9000
vA   54.77cm / s
3
So the rate of flow = v Aa A  54.77  4  219cm3 / s
15. 15 15
2
Heat required (Q) =  msdt   1 (0.2  0.14t  0.023t )dt  41cal
5 5
16. dw dQ  dU dU 1 3 2
 1 1 1 
dQ dQ dQ  5 5
2 2
dw  dQ; pdt  Fds
5 5
2  ds  2 P
 P  ( P0 A  mg )     
5  dt  5 ( P0 A  mg )
17. Statement-I
T1   73 C  200 K
T2  527  C  800 K
3 RT1
V1 M  T1 200 1
  
V2 3 RT2 T2 800 2
M
V2  2V1
Statement  II
PV  nRT
18. Statement-I
When elevator is moving with uniform speed T  Fg
Statement-2
When elevator is going down with decreasing speed, its acceleration is upward.
W
Hence W  N    a
g
 a
N  W 1   i.e morethan weight
 g
19.
F cos53  Mg
F sin 53  Ma
 a  g tan 53
20. Initially image is formed at A itself.
After refraction from lens the rays must be incident normally on the plane mirror.
1 1 1
 
v O A f
f  O A  18 cm
1 3  1 1 
   1  
f 2  R R 
R  f  18 cm
A'
L
M
O
After filling the liquid between lens and mirror and placing the object at A ' same
thing Occurs.
3  3
 1  1  1  
  2  2
v OA1 R  R 
 
 
3
 1 1 1 
 1   2
 24 36 18
3
1 
 2  1  1
18 36 24
3
1   12 3 1 5
 2   1   
18 36  24 2 4 4
21. v
: 0.1  5  103  0.2 
v
| F |  A
h 20  103
v  0.02 m / s or v  20  103 m / s
22. 1
Slope 
YA
1
 Y
( slope) A
1
Y
2  106 (0.25  105 )
Y  2  1011 N / m2
23. Surface tension =T
R: Radius of bigger drop
R: Radius of smaller drop
Volume will remain same
4 3 4
 R  216   r 3  R  6r
3 3
i  T .4 R 2
 f  T .4 r 2  216
 f 216r 2
 6
i R 2
24. For continuity equation
a
av1  v2  v2  2 v1
2
from Bernoulie ' s theorem ,
1 1
P1   gh1   v12  P2   gh2   v2 2
2 2
 v 2  v 2  
P1  P2     2 1   g (h  h ) 
2 1
  2 
 
 4v 2  v 2  
4100  1000   1 1   10  (0  1) 
  2 
 
41 3v 2
 10  1
10 2
47
 v1   x  47
5
25. t2
Given s  m , m=10kg
4
ds 1 t 2
 2 t    1; V  1m / s
dt 4 2 2
1 1
W  K E  m v 2   10  1  5 J
2 2
26. D  D
1  1 and  2  2
d d
 2  16 mm and  2  12 mm
so LCM ( 1,  2 )  48 mm
So at 48 mm distance both bright fringes will be found.
27. m
f
u f
f
m       (i )
 10  f
f The magnification in case of lens,
m       ( ii )
 20  f
( i ) / ( ii )
f  20
1 
f  10
10  f  f  20  f  15
f
m
u f
f
m       (i )
8  f
f
m       (ii )
18  f
(i ) / (ii )
f  18
1 
f 8
8  f  f  18  f  13
28. (3v  (v))
upper 2R  4

lower v
2R
29. 1 2
K .ETranslational mv
 2  60%  KErotational  100  60  40%
K .ETotal 1 2  K 2
mv 1  2 
2  R 

30. From principle of calibration of thermometers
X  ( LEP)1 Y  ( LEP) 2

(UFP)1  ( LEP )1 (UFP) 2  ( LEP)2
x  125 40  70
 
500 40

CHEMISTRY
st
31. In the 1 option bulky Me groups are at anti position. It has least eclipsing as well as least
van der-waal strain.
32. In presence of sunlight free radical substitution takes place. To form stable free radical, 
-hydrogen will be removed first.
Br
Br2 , hv
H3 C  C H 2  C H  C H 2 H 3C  CH  CH  CH 2  H 3C  CH  CH  CH 2
   
(E) Major product
Br
H 3C  CH  CH  CH 2
Intermediate: stable intermediate
33. CH 3  CH 2  CH 2  Cl
AlCl3  Rearrangement
CH 3  CH 2  CH 2
1 
2
34. 1
2 6 Mo2 O3
+ 4H 2
3 773K
5
4 10-20-atm
Mo2O3 at 773K temperature and 10-20 atm pressure aromatising agent which converts
open alkyl chain into aromatic compound
35. CH 2  Cl CH 2  N  C
HCHO AgCN
HCl (Covalent)
36. S N 1 is two step reaction where in step (1) formation of carbocation takes place which is
slow and requires more Ea is RDS.
1 is wrong as step (1) has less Ea i.e., less formation of carbonation.
2 is wrong as it is P.E diagram of single step reaction
3 is wrong as both steps have almost same Ea .
P.E diagram for S N 1
T.S.I
T.S.II
PE RDS
Progress of reaction
37. Cl
dry ether
MgCl
+ Mg C2 H 5 OH
+ C2 H 5 OMgCl
(A)
(Major product)
38.
In is nucleophilic substitution reaction and cleavage of ethers with HI

39. Alkaline KMnO4 oxidizes 1 benzylic carbon to – COOH group.
CH 3 COOH
Alkaline KMnO4
H
OCH 3 OCH 3
(X)
40. (i)
O O O
H 2C  CH  C  NH  CH 2  C  NH  CH  C  OH
GLY
CH 2  CH 2 4
O  C  OH NH 2
ASP
LYS
O
Number of C groups =4
Number of peptide linkages =2 Total =4+2=6
(ii) Monomer of Nylon is caprolactum
O
H
N
'N' - Hetero atom within the cyclic system.

i.e One Hetero atom
41. BeCl2 has a chain structure in solid state

Cl Cl Cl
Be Be Be
Cl Cl Cl
BeCl2 in vapour phase exist as chloro bridged dimer state
42. Concept
43. Concept
44. Conceptual
45. H X  X (KJ/mole)
Bond Dissociation Enthalpy order
Cl2  Br2  F2  I 2
242.6 192.8 158.8 151.1
46. Conceptual
47. Two lone pair electrons at equitorial position give more stability due to minimum
repulsion than axial position in BrF3 molecule
48. Conceptual
49. Moist SO2 act as reducing agent
50. H 2 O to H 2Te thermal stability decreases due to increase in bond length and increase in
reducing nature
51. Hypophosphoric acid - H 4 P2 O6
O O
OH P P
OH
OH OH
4  1  2  x  6  (2)  0  x  4
52.  - Sulphur and  -sulphur are diamagnetic in nature while S2 is paramagnetic as it has
two unpaired e s according to molecular orbital theory (MOT) which is similar to O2
53. Perchloric acid ( HClO4 ) contains 3( Cl = O ) bonds as shown
OH
Cl
O O
O
54. F
F F F
F
F I
I
F F F F
F F
55. O O
H O S O O S O H
O O
P= +6
Q= 1
R=2
P + Q – R = 6 + 1 – 2=5
56. X=  Fe( H 2 O )5 NO  “Brown ring complex”
2
x  5(0)  1( 1)  2
x  1
57. hypophosphoric acid = H 4 P2O6 X=0
Pyrophosphoric acid = H 4 P2 O7 Y=1
X + Y = 0 + 1 =1
58. H 2 SO4 = moderate oxidising agent OX-state of S = +6 Q=6
SO2 has canonical structure P = 2 P + Q = 2+6=8
59. Number of incorrects are ii, v only
60. P = NO2 ; Q= NO x. y  4  2
x + 2(-2) = 0 y + 1(-2) =0 8
x = +4 y= 2
MATHEMATICS
61. a, b, c are In A.P  2b  a  b ax  by  2b  a  0
a  x  1  b  y  2   0 represents family of lines passing through the point 1, 2  the
2 2
equation of circle with 1, 2  and radius r is  x  1   y  2   r 2  1
Given circle x 2  y 2  4 x  4 y  1  0  2 1 and 2 are orthogonally
62.  10      3 6  
Let C    ,  E  ,  lies on
 4   2 8 
6 x  10 y  59  0    10 C  10,5 
Also reflection of A about CF lies on BC find equation BC, solve BC and BE

63. Combined equation of pair of tangents s12  s.s11 of these lines meets X-axis at A and B
8h
AB 
h 2  16
4h 2
Area of PAB   f h
2
h  16
f is min  f 1  h   0  h  4 2
64. 1 a 1 a  2 1 a  1 a 
   2h,2k  x  y  
2
Let P  , x  y0
 2 2   2   2 
1 a 1 a 
   h, k  x  y  2hx  2ky  0
2 2
Centre   ,
 4 4 
Let  ,   be any point on x+y=0
The equation of the chord whose mid point  ,   is S  S11
 x   y  h  x     k  y      2   2  2hr  2k
2 2  3  h  k   2h 2  2k 2  0
  0 since these existy two chords
2
 
9  h  k   8 2k 2  2h2  0 , 7 k 2  7 h 2  8hk  0
2 2  1  a2 
1 a  1 a 
7   7   18    0 , a2  8
 4   4  
 16 
65. Let eq of AB is 7 x  y  4  0  m1  7
Let eq of AC is x  y  1  0  m2  1
Slope of BC is m
m1  m m  m2
Tan    1/ 3, 3
1  mm1 1  mm2
66. Orthocentre is (2,-1)
Circumcentre is (1,-2)
67. a a
Use  f  x dx   f  a  x dx
0 0
68. f x
L  lt  finite,  f 1  0  L  l t f 1  x   f 1 1
x 1 x  1 x 1
Now f  x   f 1  x   f 11  x   x5  6 x  1,
Clearly f  x  is a poly nomial of degree 5
f 1  x   f 11  x   f 111  x   5 x 4  2
f 11  x   f 111  x   f 1  x   20 x3  3
f 111  x   f 1V  x   f v  x   60 x 2  4
From 3-4  f 11  x   f V  x   20 x3  60 x 2
f 11  x   120  20 x3  60 x 2  f 2  x  120
f 11  x   20 x3  60 x 2  120
x  1  f 11 1  40  120  80
From 1 f 1  f 1 1  f 11 1  1  64
0  f 1 1  80  65 f 1 1  15
69. 3 2 1 4
3sin t  4  1,sin t  3  2 0 8 4 6
0 0  1 2
Rank A = Rank AB=3  Unique Solution
70.  1 2 22 
 
 1 / 2 1 2 
 1/2 
 2 1 / 2 1 
A2  3 A, A3  32 A
2 3 10 2
 39  1 
9
A  A  ....  A  3 A  3 A  .....  3 A  A3  
 3 
 
71. 2
x 3
2  4 
But x 2  1 t I  x
 2x  dx  dt
2 2 3
x  x 
x2  x 2  1
72. We have y 5  9 xy  2 x  0
dy  dy  dy 9y  2
5 y4  9 x  y   2  0 
dx  dx  dx 5 y 4  9 x
 dy 
For Horizontal  9 y  2  0   0
 dx 
y2/9
y5
x , at y=2/9 not defined
2  9y
For vertical 5 y 4  9 x  0
5 y4 5 y4 5 y4 5
x , y5  9 y  2. 0  y  0, , N=2
9 9 9 18
73.  5 4 
f 1  x   3sin x  4cos x, n  ,  f 1  x   0
 4 3 
f  x  is decreasing
4
An min of f  x  is at x 
3
4
3
 4  3 1
f     3sin t  4cos t dt   2 3
 3  5 2 2
4
74. x  y 2
x2 y 2
 1
9 4
Area = Area of ellipse-Area of Square
75. a  b  c  c is perpendicular to a  b
b  c  a  a is perpendicular to b  c
So a, b, c are mutually perpendicular
c
ab  c  a b  c  b 
2
bc  a  b c  a  c  2
b 1
1)  abc    cab   2  abc   2 a b c  8
2) a is parall to b  c
So Projection of a on b  c 

a bc    abc  4  2
bc b c 2
2 2 2 2
3) 3a  b  2c  9 a  b  4 c  53
76. dy
 2Tanx  cos x  y   2Tanx cos x  2 yTanx
dx
dy
  2Tanx  y  2Tanx cos x
dx
1 2
I.F  e 
2Tanxdx
 y sec2 x  c
cos 2 x cos x
 
Parsing through  ,0   c  2 2
4 
f  x   2cos x  2 2 cos 2 x
77. x 1 y 1 z
Equation of plane 1 2 1 =0
1 1 2
78. Let A= (0,0), B= (4,0), c= (0,3)
5
Circumcentre of circle S is (2,3/2) and circumradius =
2
25
Equation of S is ( x  2)2  ( y  3 / 2)2  ------------(1)
4
If circle S1 is having radius r1 and touching AB and AC  Its centre is ( r1, r2 ).
S1 and S touch internally  (r1  2)2  (r1  3 / 2)2  r1  5 / 2
 r12  2r1  0  r1  2
If S 2 is having r2 and touching AB and AC  centre of S 2 = ( r1, r2 )
S 2 touches S externally  (r2  2) 2  (r2  3 / 2) 2 = ( r2  5 / 2) 2
 r22  12r2  0  r2  12  r1r2  24
79. Let r be the radius of the circle and A = (0,0) AB is along x-axis and y-axis.
Equation of circle is ( x  r ) 2  ( y  r ) 2  r 2 --------------(1)
C (PA)
D
A M B
Equation of MN is x  y  r

Now  lar distance from C(p, q) to the above line is 5

pqr
  5  ( p  q  r )2  50 -------------(2)
2
(p, q) lies on circle (1)  p 2  q 2  2r ( p  q )  r 2  0
 ( p  q  r ) 2  2 pq  0
50  2 pq  0  pq  25
Area of rectangle ABCD is 25
80. Clearly x  y  2  0 ,
x  y  1  0 are perpendicular to each other
BAC  90
 A is the ortho centre of le ABC
 1 3 
Mid point of BC = P = circum centre =  , 
 2 2 
 PA2  DE 2  9  4  13
A
90
D(-1 , -1)
E(2,1)
B C
P
81. Sum of the squares of maximum and minimum distances from  2,3 to circle
   9  2 2 
2 2 2 2
a  b   cp  r    cp  r   92 2
82.   x y 3
Eq of AB is x cos  y sin  p,  P
3 3 2 2
 2 
A  2 P, O  , B  O, P
 3 
98 1 2 98
Area OAB  3  2P  P  3  P 2  49
3 2 3 3
4 P 2 8 2 392
a 2  b2  4 P 2   P 
3 3 3

83.
9 4
Eq of chord PQ is 2x+3y=0, AR  , BR 
3 13
Areaof APQ AR
8 8  18
Areaof BPQ BR
84. x 2  f 2  x   9  f 1  x   f 11  x 
At minima  f 1  x   0  f 11  x   0
x2  f 2  x   9  0 , x2  y 2  9  0
P lies out side the circle x 2  y 2  8
85. 1
Area of PAB  10cos 10cos  sin  2  = 102 cos3  sin 
2
1
cos 2  cos 2  cos 2   cos6 4
l  sin 2   cos 2   sin 2      4 .sin   2
3 3 3  33 
 
3 3 3 3
cos3  .sin   100cos3  .sin   100.
16 16
3
3 3 3  3 1
cos  .sin     .
16  2  2
1 3 1
sin   ,cos  T an  
2 2 3
r
TanAPC Tan 
10cos
86. Distance between AC  65

87. L11L22  0
a 2  ab  1  0
0
b2  4  0
b   2,2 
88. Equation of any plane containing the general plane is
x  y  2 z  3    2 x  3 y  4 z  4  0  1
1
If plane 1 is parallel to z-axis    
2
The plane parallel to z-axis is y  2  0  2
89. Apply expansions
90.  2 1
1  4 x ; 0  x  2

f  x   4 x 2  1;1 / 2  x  1
 1 1  x  2



07 10 2023 SR Super60 NUCLEUS & STERLING BT Jee Main RPTM 10 KEY

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07 10 2023 SR Super60 NUCLEUS & STERLING BT Jee Main RPTM 10 KEY

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SRI CHAITANYA IIT ACADEMY, INDIA 07‐10‐23_ Sr.

Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐10_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 1

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 2

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Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 7

In is nucleophilic substitution reaction and cleavage of ethers with HI

'N' - Hetero atom within the cyclic system.

41. BeCl2 has a chain structure in solid state

Also reflection of A about CF lies on BC find equation BC, solve BC and BE

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 14

Now  lar distance from C(p, q) to the above line is 5

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 15

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 16

Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 17

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