Sec: JR.

IIT_*COSC(MODEL-A) WAT-23 Date: 08-10-23

Time: 3 Hrs 2021_P1 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 D 2 D 3 C 4 B 5 0
6 2 7 1 8 1 9 1 10 2
11 ABC 12 ACD 13 AD 14 BD 15 AC
16 BCD 17 7 18 2 19 9

PHYSICS
20 C 21 B 22 D 23 A 24 5

25 9 26 1 27 2 28 6 29 4

30 AD 31 AB 32 ABCD 33 AC 34 BC

35 AC 36 5 37 4 38 0

CHEMISTRY
39 D 40 D 41 A 42 D 43 9
44 9 45 1.5 46 1 47 2 48 2
49 ABC 50 ABD 51 ABC 52 ABC 53 ABCD
54 C 55 4 56 2 57 6
Narayana IIT Academy 08-10-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_WAT-23_KEY&SOL
SOLUTIONS
MATHS
3. f (x)  27x 3  3x
At x  , f (x)  27x 3
x1/3
f 1 (x) 
3
f (27x)  f 1 (x)
1
lim
x  x1/3
11. (a) lim Nr  0  3  2a  1  0  a  2
x 1

(b) lim Nr  0  12  2a  a  1  0  a  13
x 2

3x 2  2x  1 6x  2 4
(c) lim 2  lim 
x 1 x  x  2 x 1 2x  1 3
3x  13x  14
2
6x  13 1
(d) lim  lim 
x 2 x x2
2 x 2 2x  1 3
3
 1  1 3  1 
3
1  1 1
14. Let t r        3   
 r(r  1)   r r  1  r (r  1) r(r  1)  r(r  1) 
3

2
1 1  (r  1)  r  1 1 1 1  1 1 
= 3  3  , tr  3   3 2  2 
 6  
r (r  1) 3
 r(r  1)  r (r  1) 3
 r (r  1)   r r  1 
n
 1   2 2   1 
 t  lim  1    3    1  6  1  
 (n  1)   6   n 1 
r 3
n  6
r 1

lim  t r  10  2
n 

(1  c)x 4  (A  2)x 3  (A  7)x 2  5x  2

18. Lim
x 
x 4  Ax 3  Ax 2  x  1  cx 4  2x 3  7x 2  4x  1
 If coeff. of x 4 & x 3 are not zero, L does not exists
5
 A  2, C  1  L  
2
PHYSICS
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24.

x
T a
x

Energy stored in the small consider element

1
U  ( stress ) 2 ( Ax)
2Y

1  x a 
2

    Ax  , where    A
2y  A 
a l  2 a 2 Al 3
Total energy U   U 
2 AY 0
xx 
6Y
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Narayana IIT Academy 08-10-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_WAT-23_KEY&SOL
CHEMISTRY
39. Acidic strength : BF3  BCl3  BBr3  BI3
40. BeCl2  H 2 O  Be  OH 2  2HCl
41. BF4  no back bonding ; BF4  BF2 NH 2  BF2 OH  BF3
 3
42.  K  H 2 O 6   Al  OH 2 6  SO 4 2
45 & 46.
NaCl  H 2 O 
electrolysis
 NaOH  H 2  Cl2
 2Na  Al  OH 4   3H 2
2Al  2NaOH  6H 2 O 
P4  3NaOH  3H 2 O 
 PH 3  3NaH 2 PO 2
47 & 48.
A  Na 2 B4 O 7 B  NaBO 2 C  H 3 BO 3 D  Na 2  B2  O 2 2  OH 4 
F  Na 2 B4 O 7 .10H 2 O
49. Symmetrical  CO, NMe3 , Me 2S
Unsymmetrical  MeNH 2
 H   BF4 

50. HF  BF3 
SP 2  B SP3  B
51. Gypsum added to slow down the setting process
52. Na 2 B4 O7  10H 2 O 
H 2O
 2H 2 BO3  2NaBo 2

  BH 2  NH 3 2   BH 4 

B2 H 6  2NH 3 
low T


B2 H 6  NH 3   BN  H 2
H 3 BO 3 
370 k
 HBO 2  H 2 O
53. NaBO 2  H 2 O 2  Na 2  OH 2 B  O  O 2 B  OH 2  .6H 2
55. 2NaBH 4  I 2 
 2NaI  B2 H 6  H 2
1mol 1 1
mol mol
2 2
n=1
1  0.08  300
v L
1
= 24L
56. y = 3; x = 5

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