You are on page 1of 20

Sec: JR.

IIT _*CO-SC(MODEL-A) Date: 08-10-23


Time: 3 Hrs Max. Marks: 180
08-10-23_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-12_SYLLABUS

PHYSICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 07-10-23

CHEMISTRY: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 07-10-23

MATHEMATICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 07-10-23


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 7 – 12) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 13 – 16) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 20 – 25) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 26 – 31) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 32 – 35) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 36 – 38) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 39 – 44) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 45 – 50) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 51 – 54) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 55 – 57) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

JR.IIT_*CO-SC Page. No. 2


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
MATHEMATICS MAX.MARKS: 60
SECTION - 1 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. The function f : (a, b)  R (where (a, b)  W ) satisfying

1
  f  x  1, y  1  f  x  1, y  1  1 if xy  0
f ( x, y )   2 , then which among the following
 0 if xy  0

option(s) is/are true ?

A) f (3,5)  15 B) f (5,3)  15 C) f (9, 2)  18 D) f (2,9)  18

2. The bisector of internal angles A and  ABC meets BC in point D such that BD = 4 and
CD = 2. If altitude AE  10 and AB and AC are integers, then AC may be

A) 4 B) 5 C) 6 D) none

3. Let point A be (1, 1) and equation of BC is ( x  y  1)   (2 x  y  4)  0 and area of  ABC


is maximum, then slope of the line AB and AC, may be equal to (Given AB = AC and
BC = 2 units).

2  5 2 5 2 5 2 5
A) B) C) D)
2 5 1 2 5 1 2 5 1 2 5 1

4. If a1 , a2 , ......, an is a sequence of positive numbers which are in A.P. with common


difference d and a1  a4  a7  ........  a16  147 then a1  a16  M and a1  a6  a11  a16  N .
16

Maximum value of a1a2 ......... a16   


S
(where S and W are coprime), then:
W 

A) M = 49 B) N = 98 C) S = 49 D) W = 2

JR.IIT_*CO-SC Page. No. 3


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
5. Let  and  are two roots of the equation x 2  px  q  0 , where p and q are real

numbers, and q  0 . Now suppose another quadratic equation x 2  mx  n  0 with roots

1 1
 and   such that m  n  0 . Then the possible integral values in the range of q
 

can be :

A) 1 B) 2 C) 3 D) 4

I I
6. If both A  and A  are orthogonal matrix, then which of the following statements are
2 2

incorrect ? (where I is an identity matrix order same as that of A).

A) A is skew-symmetric matrix of odd order

3
B) A2  I
4

C) A is skew-symmetric matrix of even order

D) A is orthogonal

SECTION - 2 (Maximum Marks : 12)


This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 7 and 8:
The first four terms of a sequence are given by T1  0, T2  1, T3  1, T4  2 . The general term

is given by Tn  A n 1  B n 1 where A, B,  ,  are independent of n and A is positive.

7. The value of  2   2    is equal to ……..

8. The value of 5  A2  B 2  is equal to …………

JR.IIT_*CO-SC Page. No. 4


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
Question Stem for Question Nos. 9 and 10:
Consider a triangle ABC with vertex A(2,  4) . The internal bisectors of the angles B and

C are x  y  2 and x  3 y  6 respectively. Let the two bisectors meet at I.

9. If (a, b) is incentre of the triangle ABC then (a  b) has the value equal to ……….

10. If ( x1 , y1 ) and ( x2 , y2 ) are the co-ordinates of the point B and C respectively, then the

value of  x1 x2  y1 y2  is equal to ………

Question Stem for Question Nos. 11 and 12:


Let f ( x) be a polynomial of degree 5 with leading coefficient unity, such that

f (1)  5, f (2)  4, f (3)  3, f (4)  2 and f (5)  1, then

11. f (6) is equal to ………..

12. Sum of the roots of f ( x) is equal to ……….

SECTION - 3 (Maximum Marks : 12)


This section contains TWO (2) Paragraphs. Based on each paragraph, there are 2 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer. For
each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Negative Marks: –1 In all other cases.
Question Stem for Question Nos. 13 and 14:
Consider the cubic equation in x, x3  x 2   x  x 2  sin    x  x 2  cos    x  1 sin  cos   0

whose roots are  ,  ,  .

  
2 2 2

13. The value of         


 2   2  2

1 1
A) 1 B) C) 2 cos D)  sin   cos   sin  cos  
2 2

14. Number of values of  in  0, 2  for which at least two roots are equal, is

A) 2 B) 3 C) 4 D) 5

JR.IIT_*CO-SC Page. No. 5


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
Question Stem for Question Nos. 15 and 16:
Let P( x)  x5  9 x 4  px3  27 x 2  qx  r ( p, q, r  R) be divisible by x 2 and  ,  and  are the
P( x)
positive roots of the equation  0.
x2

15. If   1,   3 and   7 are the first three terms of a sequence whose sum of first n -terms

1
is given by Sn then 
n2 S n . S n 1
is equal to :

1 1
A) 1 B) C) D) 2
4 2

 1 1 1 1 
16. The value of lim   2  3  .......  n  is equal to:
 pqr p q r p  q3  r 3 p  qn  r n 
n  2 2

1 1 25 26
A) B) C) D)
26 27 26 27

SECTION - 4 (Maximum Marks : 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
17. Let p( x) be a polynomial of degree 6 with leading coefficient unity and

p ( x)  p ( x)  x  R . Also  p (1)  3  p 2 (2)   p (3)  5   0 then 4  p(0) is …………


2 2

If the number of the positive integral solutions of the equation      is n, then is


x x n
18.
 9  11  3

_____ (where [.] denotes the greatest integer function)

19. If  x1 , y1  and  x2 , y2  are solutions of the system of simultaneous equations

 x  log8 x
log8 ( xy )  3 log8 x . log8 y and 4 log8    ; then the value of x1 x2  y1 y2 is …….
 y  log8 y

JR.IIT_*CO-SC Page. No. 6


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
PHYSICS MAX.MARKS: 60
SECTION - 1 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
20. Two discs A and B each of mass 2 kg and radius 0.5 m are rigidly fixed to the ends of
a thin shaft S, which is supported in horizontal position with the help of two smooth
bearings at points P1 and P2. Two blocks of masses 2 kg and 1 kg are connected to the
light cords wrapped around the discs as shown in the figure. There is no slipping
between the cord and the discs. If the system is released from rest from the position
shown, then mark the correct statement(s). (Take g = 10 m/s2)

A) Power developed by tension in cord connected to 2 kg block is, negative.


B) Acceleration of each block is 2 m/s2.
C) Total work done by tension on the discs is zero during the motion.
D) Acceleration of each block is 1 m/s2.
21. A uniform ball of radius R rolls without slipping between the rails such that the
horizontal distance is 3 R between the two contact points of the rails of the ball.
Figure (a) shows the front view of the ball and figure (b) shows the side view of the ball
VCM is the velocity of centre of mass of the ball and  is the angular velocity of the ball
after rolling down a distance 2h along the incline then

R 10 gh 10 gh
A) VCM  R B) VCM   C) VCM  D) VCM 
2 13 7

JR.IIT_*CO-SC Page. No. 7


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
22. A solid spherical ball is released from rest on an incline of inclination angle  (which
can be varied) but through a fixed vertical height h. The coefficient of static and kinetic
friction are both equal to  . If E represents the total kinetic energy of the ball at the
bottom of the incline as a function of the angle of inclination  . W represents the work
done by friction for the whole time of motion as a function of the angle of inclination  .
Choose the correct graph(s).

A) B)

C) D)
A B
23. The potential energy function of a particle is given by U (r )   , where A and B
2r 2 3r
are constants and r is the radial distance from the centre of the force. Choose the correct
option(s).
2A
A) The equilibrium distance will be r0 
B
3A
B) The equilibrium distance will be r0 
B
B2 r
C) If the total energy of the particle is , then its radial velocity will vanish at 0 ,
6A 3
where r0 is the equilibrium distance.
B2 r
D) If the total energy of the particle is , then its radial velocity will vanish at 0 ,
6A 2
where r0 is the equilibrium distance.

JR.IIT_*CO-SC Page. No. 8


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
24. A plank with a uniform sphere placed on it rests on a smooth horizontal plane. The
plank is pulled to right by a constant force F. If the sphere does not slip over the plank,
then

A) Both have the same acceleration.

B) Acceleration of the centre of sphere is less than that of the plank.

C) Work done by friction acting on the sphere is equal to its total kinetic energy.

D) Total kinetic energy of the system is equal to work done by force F.

25. A uniform rope of linear mass density  and length l is coiled on a smooth horizontal
surface. One end is pulled up by an external agent with constant vertical velocity v.
Choose the correct option(s).

A) Power developed by external agent as a function of x is P   xgv

B) Power developed by external agent as a function of x is P  ( v 2   xg )v

C) Energy lost during the complete lift of the rope is zero.

lv 2
D) Energy lost during the complete lift of the rope is
2

JR.IIT_*CO-SC Page. No. 9


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 26 and 27:
A soft plastic bottle, filled with water of density 1 gm/cc, carries an inverted glass test-
tube with some air (ideal gas) trapped as shown in the figure. The test-tube has a mass of
5 gm, and it is made of a thick glass of density 2.5 gm/cc. Initially the bottle is sealed at
atmospheric pressure p0 = 105 Pa so that the volume of the trapped air is v0 = 3.3 cc.
When the bottle is squeezed from outside at constant temperature, the pressure inside
rises and the volume of the trapped air reduces. It is found that the test tube begins to
sink at pressure p0  p without changing its orientation. Let
v  X cc and  p  Y  10 3 Pa .
(At constant temperature, the product of pressure of ideal gas (air in this case) and
volume occupied by ideal gas remains constant. i.e., PV = constant)

26. The value of X is _______________.


27. The value of Y is _______________.
Question Stem for Question Nos. 28 and 29:
A pendulum consists of a bob of mass m = 0.1 kg and a massless inextensible string of
length L = 1.0 m. It is suspended from a fixed point at height H = 0.9 m above a
frictionless horizontal floor. Initially, the bob of the pendulum is lying on the floor at
rest vertically below the point of suspension. A horizontal impulse P = 0.2 kg-m/s is
imparted to the bob at some instant. After the bob slides for some distance, the string
becomes taut and the bob lifts off the floor. The magnitude of the angular momentum of
the pendulum about the point of suspension just before the bob lifts off is J kg-m2/s. The
kinetic energy of the pendulum just after the lift-off is K Joules.
28. The value of J is ____________.
29. The value of K is ___________.

JR.IIT_*CO-SC Page. No. 10


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
Question Stem for Question Nos. 30 and 31:
Thin plate of diameter L = 1m is rotating about a vertical axis passing through its centre
with angular velocity 1 rad/s. A block and a sphere are tied with string and kept on
diametrically opposite end on plate as shown in figure. Mass of sphere and block is 20
kg & 10 kg respectively. Coefficient of friction between block and table is 0.2 while that
between sphere and table is 0.1. Tension in the string is T (in N) and friction force on the
block is F (in N).

30. The value of T is ____________.

31. The value of F is ____________.

SECTION - 3 (Maximum Marks : 12)


This section contains TWO (2) Paragraphs. Based on each paragraph, there are 2 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer. For
each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Negative Marks: –1 In all other cases.
Question Stem for Question Nos. 32 and 33:
Graphical solution of a two body head on collision
A block A of mass m moving with a uniform velocity v0 strikes another identical block
B kept at rest on a horizontal smooth surface as shown in the figure-(i). We can conserve
linear momentum.

JR.IIT_*CO-SC Page. No. 11


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
So, mv0 = mvA + mvB (vA and vB are the velocities of the blocks after collision)

 v0 = vA + vB …. (i)

If the collision is perfectly elastic

1 2 1 2 1 2
mv0  mv A  mvB
2 2 2

 v02  v A2  v B2 …. (ii)

Both the above equations (i) and (ii) are plotted on vA – vB plane as shown in figure (ii).
This plot can be used to find the unknowns vA and vB.

For example, the solution of the situation in figure (i) is vA = 0, vB = v0 (point y in the
plot)

Because vA = v0, vB = 0 (point x in the plot) is not physically possible.

Now anwer the following questions based on the above comprehension.

32. If the collision is perfectly inelastic, then the vA – vB plot is

A) B)

C) D)

JR.IIT_*CO-SC Page. No. 12


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
33. In a situation, block A is moving with velocity 2 m/s and strikes another identical block
B kept at rest. The vA – vB plot for the situation is shown. m and l are the intersection
points whose vA, vB coordinates are given in the figure. The coefficient of restitution of
the collision is

A) 1/2 B) 1/3 C) 1 D) Collision not possible

Question Stem for Question Nos. 34 and 35:


In a conservative force field we can find the radial component of force from the potential
dU
energy function by using F   . Here a positive force means repulsion and a
dr
negative force means attraction. From the given potential energy function U(r) we can
find the equilibrium position where force is zero. We can also find the ionisation energy
which is the work done to move the particle from a certain position to inifinity. Let us
consider a case in which a particle is bound to a certain point at a distance r from the
centre for the force. The potential energy of the particle is ____

A B
U (r )   ; where r is the distance from the centre of the force and A & B are
r2 r
positive constants.

34. The equilibrium position is

A) stable B) Unstable C) neutral D) Cannot be predicted

35. The work required to move the particle from equilibrium distance to infinity is

B2 4B 2 B2 4B 2
A) B) C) D)
4A A 4A A

JR.IIT_*CO-SC Page. No. 13


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
36. A solid cylinder rolls from the back of a large truck travelling at 10 m/s to the right. The
cylinder is travelling horizontally at 8 m/s to the left relative to an observer in the truck.
The ball lands on the roadway 1.25 m below its starting level. How far behind the truck
does it land (in m)?

1
37. The graph show the variation of (where V is the velocity of the particle) with
V
respect to time. Then find the value of acceleration ( m / s 2 ) at t = 3 sec.

38. In order to simulate different values of “g”, aspiring astronauts are put on a plane
which dives in a parabola given by the equation : x2 = 500y, where x is horizontal y is
vertically upward; both being measured in metre. The x-component of the velocity of the
plane is constant throughout, and has the value of 360 km/h. The effective g
(“g-force”) experienced by an astronaut on the plane equals N times g. The value of N is

JR.IIT_*CO-SC Page. No. 14


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
CHEMISTRY MAX.MARKS: 60
SECTION - 1 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
39. Choose the correct option(s), assuming ideal-gas behavior

A) Vrms of a gas mixture consisting equal moles of H 2 & He is  4  Vrms of O3 at the


same temperature

B) A 8m3 sphere with 1 mole He and a 1m3 sphere with 2 mole CH 4 were at same
pressure, then the ratio of collision frequency of He to that of CH 4 on the respective
surface area of spheres is <2

C) for gas-phase single-step reaction P  g   P  g   P2  g  , if E a is 10 times the average


dk dT
KE per mole of reactant atoms at 300K, then ratio of to is independent of T.
k T
Assume A is constant with T.

D) As a gas effuses out into a vacuum, mean free path & temperature of the remaining
gas decreases

40. Empirical formula of a chloride of titanium is TiClx and its 0.01 mol on treatment with
excess of AgNO3 gives 5.74 g of AgCl. Which of the following statements regarding
TiClx is/are true? (Atomic mass of Ti = 48, Molar mass of AgCl=143.5 )

A) Its empirical formula TiCl3 B) Its Molecular formula TiCl4

C) TiCl x has 25.26% Ti by weight D) TiCl x has 31% Ti by weight

JR.IIT_*CO-SC Page. No. 15


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
41. Match and correct option:

Column-A Column-B
(I) C2 H 4 (P) 3c – 2e bonds
Molecular plane is nodal plane for
(II) B2 H 6 (Q)
  bond
(III) N 2 H 4 (R) Non-polar molecule
(IV) Al2Cl6 (S) Coordinate bond
(T) Non-planar molecule
A) (I) – Q, R B) (II) – P, R, S, T C) (III) – R, T D) (IV) – R, S, T

42. Select correct order(s) of bond angle

A) OCl2  SF2  AsH 3 B) NH 3  PF3  PH 3

C) XeO3  ClO 4  SO 42 D) N  SiH 3 3  O  SiH 3 2  O  CH 3 2

43. The incorrect order for the given properties among the following is/are

A) LiH  NaH  KH Thermal stability

B) MgSO 4  CaSO 4  SrSO 4 So lubility

C) MgO  CaO  SrO Basic nature

D) Li 2CO3  Na 2CO3  K 2CO3 Thermalstability

44. Consider the following equilibriua

1. P  S 
 Q  g   NH 3  g  , PT at equilibrium  8cm Hg

2. Y  s  
 Z  g   NH 3  g  , PT at equilibrium  26cm Hg

A) K eq  I   16

B) k eq  II   169

C) PTotal  27.20 when P and Y decomposed together

D) PTotal  34.0 when P and Y decomposed together

JR.IIT_*CO-SC Page. No. 16


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 45 and 46:
NH 4Cl  A 
C H Cl
6
140º 150ºC
5
 B 
NaBH
C 4

C compound can be called as borazine.

45. If A is reacted with H 2 , two products are formed. The sum of total number of atoms in
each molecule of both products____

46. If x = max no.of atoms that can lie in a single plane in compound C.

y = total no. of Bond angles in compound A.

xy
Calculate
xy

Question Stem for Question Nos. 47 and 48:


For the reaction started with 1 mol A 2 B4  g  is

A 2 B4  g  
 A 2  g   2B2  g 

The vapour densities are measured at various time of dissociation and observed value are

(i) at time t = 0 min VD = 50

(ii) at time t = 10 min VD = 25

(iii) at time t = 20 min VD = 20

V.D.  A 2 B4 
If. 5
V.D.  A 2 

47. The ratio of atomic mass of A and B is ___

48. If percent degree of dissociation of A2B4 at 10 min is 10x ; Order of the reaction is y;
Vapor density of mixture at 30 min is z. Then the value of x + y + 0.1375z is

JR.IIT_*CO-SC Page. No. 17


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
Question Stem for Question Nos. 49 and 50:
100 ml of 0.1M H 3PO 4 solution is titrated with 0.5 M NaOH solution till the second
equivalent point. At second equivalent point the pH of the solution was found to be x.
after second equivalent point 10 ml of 0.5M HCl solution is added to the resulting
solution and the pH of the solution after adding HCl was found to be y.

Dissociation constants K a , K a and K a of H 3PO 4 are 103 ,108 and 1013 respectively.
1 2 3

49. The value of x is _____

50. The value of y is _____

SECTION - 3 (Maximum Marks : 12)


This section contains TWO (2) Paragraphs. Based on each paragraph, there are 2 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer. For
each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Negative Marks: –1 In all other cases.
Question Stem for Question Nos. 51 and 52:
Look at the following flowchart:

JR.IIT_*CO-SC Page. No. 18


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
51. Select a correct statement:

A) The flowchart is for the formation of Magnesium sulphate.

B) Compound B is more soluble than potassiumbicarbonate.

C) The flowchart is for Solvay’s process

D) The product which can be reused is compound C

52. If 100 mL of 0.4 M Compound A and 200 mL of 0.2 M of compound C is mixed to form
a solution then total concentration of Chloride ions is (assume both are 100% ionized):

A) 0.1 B) 0.2 C) 0.3 D) 0.4

Question Stem for Question Nos. 53 and 54:


Colligative property measurement is one of the techniques used in the measurement of
chemical quantities with reasonable accuracy.

If a 40.65 gm sample of K 2SO 4 and BaSO 4 is dissolved in 900 gm of pure water to form
a solution ‘A’ at 57ºC its vapour pressure is found to be 39.6 torr while vapour pressure
pure water at 57ºC is 40 torr. Density of solution A is 1.24 g/ml.

In different experiment when small amount of pure BaSO 4 is mixed with water at 57ºC
it gives the osmotic rise of 4.05  105 atm.

(R = 0.082 Lt. –atm/mol-K ; K = 39, Ba = 137, S = 32, O = 16)

53. Percentage of K 2SO 4 in the sample is:

A) 65.75% B) 72% C) 60.35% D) 78.74%

54. Solubility product of BaSO 4 in water at 57ºC is:

A) 5  1019 B) 3.125  1013 C) 5.625  1013 D) 2.25  1012

JR.IIT_*CO-SC Page. No. 19


Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-12_QP
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
55. Volume of NH 3  g  was measured to be 25 mL at 100 atm. pressure and 273K
temperature. If
van der waal constant b of ammonia is expressed as x  103 L / mole then find the value
x
of ?
10

Take volume of ideal – gas as 22.4L at STP(1 atm, 273K)

(Round off to nearest integer)

56. An oxide of chromium has magnetic moment of 3.87 B.M. per Cr. Let x,y and z be the
number of electrons having l  0, l  1 and l  2 per formula-unit of the compound,
respectively. Then find the value of y   x  z  5  . Here l is azimuthal-quantum number
and assume the compound to be ionic.

57. A weak acid type indicator was found to be 60% dissociated at pH = 9.18. What will be
percentage dissociation at pH = 9.00? (log 2 = 0.3, log 3 = 0.48) Give your answer after
dividing by 10

JR.IIT_*CO-SC Page. No. 20

You might also like