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08 10 23 JR Iit Star Co Scmodel A Jee Adv 2021P Ii Cat 12 QP
08 10 23 JR Iit Star Co Scmodel A Jee Adv 2021P Ii Cat 12 QP
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 7 – 12) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 13 – 16) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 20 – 25) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 26 – 31) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 32 – 35) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 36 – 38) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 39 – 44) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 45 – 50) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 51 – 54) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 55 – 57) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60
1
f x 1, y 1 f x 1, y 1 1 if xy 0
f ( x, y ) 2 , then which among the following
0 if xy 0
2. The bisector of internal angles A and ABC meets BC in point D such that BD = 4 and
CD = 2. If altitude AE 10 and AB and AC are integers, then AC may be
A) 4 B) 5 C) 6 D) none
2 5 2 5 2 5 2 5
A) B) C) D)
2 5 1 2 5 1 2 5 1 2 5 1
A) M = 49 B) N = 98 C) S = 49 D) W = 2
1 1
and such that m n 0 . Then the possible integral values in the range of q
can be :
A) 1 B) 2 C) 3 D) 4
I I
6. If both A and A are orthogonal matrix, then which of the following statements are
2 2
3
B) A2 I
4
D) A is orthogonal
9. If (a, b) is incentre of the triangle ABC then (a b) has the value equal to ……….
10. If ( x1 , y1 ) and ( x2 , y2 ) are the co-ordinates of the point B and C respectively, then the
2 2 2
1 1
A) 1 B) C) 2 cos D) sin cos sin cos
2 2
14. Number of values of in 0, 2 for which at least two roots are equal, is
A) 2 B) 3 C) 4 D) 5
15. If 1, 3 and 7 are the first three terms of a sequence whose sum of first n -terms
1
is given by Sn then
n2 S n . S n 1
is equal to :
1 1
A) 1 B) C) D) 2
4 2
1 1 1 1
16. The value of lim 2 3 ....... n is equal to:
pqr p q r p q3 r 3 p qn r n
n 2 2
1 1 25 26
A) B) C) D)
26 27 26 27
x log8 x
log8 ( xy ) 3 log8 x . log8 y and 4 log8 ; then the value of x1 x2 y1 y2 is …….
y log8 y
R 10 gh 10 gh
A) VCM R B) VCM C) VCM D) VCM
2 13 7
A) B)
C) D)
A B
23. The potential energy function of a particle is given by U (r ) , where A and B
2r 2 3r
are constants and r is the radial distance from the centre of the force. Choose the correct
option(s).
2A
A) The equilibrium distance will be r0
B
3A
B) The equilibrium distance will be r0
B
B2 r
C) If the total energy of the particle is , then its radial velocity will vanish at 0 ,
6A 3
where r0 is the equilibrium distance.
B2 r
D) If the total energy of the particle is , then its radial velocity will vanish at 0 ,
6A 2
where r0 is the equilibrium distance.
C) Work done by friction acting on the sphere is equal to its total kinetic energy.
25. A uniform rope of linear mass density and length l is coiled on a smooth horizontal
surface. One end is pulled up by an external agent with constant vertical velocity v.
Choose the correct option(s).
lv 2
D) Energy lost during the complete lift of the rope is
2
v0 = vA + vB …. (i)
1 2 1 2 1 2
mv0 mv A mvB
2 2 2
v02 v A2 v B2 …. (ii)
Both the above equations (i) and (ii) are plotted on vA – vB plane as shown in figure (ii).
This plot can be used to find the unknowns vA and vB.
For example, the solution of the situation in figure (i) is vA = 0, vB = v0 (point y in the
plot)
A) B)
C) D)
A B
U (r ) ; where r is the distance from the centre of the force and A & B are
r2 r
positive constants.
35. The work required to move the particle from equilibrium distance to infinity is
B2 4B 2 B2 4B 2
A) B) C) D)
4A A 4A A
1
37. The graph show the variation of (where V is the velocity of the particle) with
V
respect to time. Then find the value of acceleration ( m / s 2 ) at t = 3 sec.
38. In order to simulate different values of “g”, aspiring astronauts are put on a plane
which dives in a parabola given by the equation : x2 = 500y, where x is horizontal y is
vertically upward; both being measured in metre. The x-component of the velocity of the
plane is constant throughout, and has the value of 360 km/h. The effective g
(“g-force”) experienced by an astronaut on the plane equals N times g. The value of N is
B) A 8m3 sphere with 1 mole He and a 1m3 sphere with 2 mole CH 4 were at same
pressure, then the ratio of collision frequency of He to that of CH 4 on the respective
surface area of spheres is <2
D) As a gas effuses out into a vacuum, mean free path & temperature of the remaining
gas decreases
40. Empirical formula of a chloride of titanium is TiClx and its 0.01 mol on treatment with
excess of AgNO3 gives 5.74 g of AgCl. Which of the following statements regarding
TiClx is/are true? (Atomic mass of Ti = 48, Molar mass of AgCl=143.5 )
Column-A Column-B
(I) C2 H 4 (P) 3c – 2e bonds
Molecular plane is nodal plane for
(II) B2 H 6 (Q)
bond
(III) N 2 H 4 (R) Non-polar molecule
(IV) Al2Cl6 (S) Coordinate bond
(T) Non-planar molecule
A) (I) – Q, R B) (II) – P, R, S, T C) (III) – R, T D) (IV) – R, S, T
43. The incorrect order for the given properties among the following is/are
1. P S
Q g NH 3 g , PT at equilibrium 8cm Hg
2. Y s
Z g NH 3 g , PT at equilibrium 26cm Hg
A) K eq I 16
B) k eq II 169
45. If A is reacted with H 2 , two products are formed. The sum of total number of atoms in
each molecule of both products____
46. If x = max no.of atoms that can lie in a single plane in compound C.
xy
Calculate
xy
A 2 B4 g
A 2 g 2B2 g
The vapour densities are measured at various time of dissociation and observed value are
V.D. A 2 B4
If. 5
V.D. A 2
48. If percent degree of dissociation of A2B4 at 10 min is 10x ; Order of the reaction is y;
Vapor density of mixture at 30 min is z. Then the value of x + y + 0.1375z is
Dissociation constants K a , K a and K a of H 3PO 4 are 103 ,108 and 1013 respectively.
1 2 3
52. If 100 mL of 0.4 M Compound A and 200 mL of 0.2 M of compound C is mixed to form
a solution then total concentration of Chloride ions is (assume both are 100% ionized):
If a 40.65 gm sample of K 2SO 4 and BaSO 4 is dissolved in 900 gm of pure water to form
a solution ‘A’ at 57ºC its vapour pressure is found to be 39.6 torr while vapour pressure
pure water at 57ºC is 40 torr. Density of solution A is 1.24 g/ml.
In different experiment when small amount of pure BaSO 4 is mixed with water at 57ºC
it gives the osmotic rise of 4.05 105 atm.
56. An oxide of chromium has magnetic moment of 3.87 B.M. per Cr. Let x,y and z be the
number of electrons having l 0, l 1 and l 2 per formula-unit of the compound,
respectively. Then find the value of y x z 5 . Here l is azimuthal-quantum number
and assume the compound to be ionic.
57. A weak acid type indicator was found to be 60% dissociated at pH = 9.18. What will be
percentage dissociation at pH = 9.00? (log 2 = 0.3, log 3 = 0.48) Give your answer after
dividing by 10