08 10 23 SR Iit Star Co Scmodel A&b Jee Adv 2018 p1 Pta 10 QP

SEC:SR_*CO-SC(MODEL-A&B) Date: 08-10-23
Time: 3 Hrs Max. Marks: 180

08-10-23_SR.IIT_STAR CO-SC(MODEL-A&B) _JEE ADV_PTA-10_SYLLABUS
MATHEMATICS: PRESENTWEEK (100%): Indefinite Integration: integration as the
inverse process of differentiation, indefinite integrals of standard
functions. integration by parts, integration by the methods of
substitution and partial fractions.
 ax 2  bx  c dx and   ax  b  ax 2  bx  c dx
Definite Integration: definite integrals and their properties,

fundamental theorem of integral calculus. definite integrals as a limit
of sum
PHYSICS: PRESENTWEEK (100%): Current Electricity + Capacitors + RC

Circuits: Capacitance; Parallel plate capacitor with and without
dielectrics; Capacitors in series and parallel; Energy stored in a
capacitor. Electric current; Ohm’s law; Series and parallel
arrangements of resistances and cells; Kirchhoff’s laws and simple
applications; Heating effect of current.
CHEMISTRY: PRESENTWEEK (100%): Aldehydes and Ketones :Preparation of
aldehydes and ketones from acid chlorides and nitriles; aldehydes from
esters; benzaldehyde from toluene and benzene; Reactions: oxidation,
reduction, oxime and hydrazone formation; Aldol condensation,
Cannizzaro reaction; Haloform reaction; Nucleophilic addition reaction
with RMgX, NaHSO3, HCN, alcohol, amine.
Carboxylic Acids: Physical properties; Preparation: from nitriles,
Grignard reagents, hydrolysis of esters and amides; Preparation of
benzoic acid from alkylbenzenes; Reactions: reduction, halogenation,
formation of esters, acid chlorides and amides.
Polymers: Types of polymerization (addition, condensation); Homo and
copolymers; Natural rubber; Cellulose; Nylon; Teflon; Bakelite; PVC;
Bio-degradable polymers; Applications of polymers.
Narayana IIT Academy 08-10-23_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_PTA-10_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
PHYSICS:
+Ve - Ve
Marks Marks
Sec – I(Q.N :19 – 24) +4 -2 6 24
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N : 33-36) +3 -1 4 12
Total 18 60
:CHEMISTRY
+Ve - Ve
Marks Marks
Sec – I(Q.N:37 – 42) +4 -2 6 24
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec –III(Q.N : 51-54) +3 -1 4 12
Total 18 60
SR.IIT_*CO SC Page No:2

MATHEMATICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1.  3 3

Let aa e x  e x dx  f  a  , where a  R . Then
A) f 1 is less than 2e B) f 1 is less than 1
1
C) f  1 is less than – 2e D) f 1 is less than e   2
e
2. If f  x   

ecos x 2 cos3 x sin x  sin x cos 2 x  4sin x cos x  dx where f  π   0
 
3
2
2 1  cos x  2
A) f    2e B) f    C) f    D) f   
π π 2e 2π 1 2π 1
3   
3 4  3  12e  3  24e
sin 2x a  b cos x
3. If  dx   e where a, b, c, d are positive integers and e is
 3  4cos x  c  3  4cos x 
3 d
arbitrary constant then
A) The value of a + b is 11 B) The value of a + b is 6
C) The value of c + d is 18 D) The value of c - d is 14
sin 2x  2 tan x 1 δ γ
4. If  dx  n β   c where c is constant of integration
 cos 6
x  6cos2 x  4  α cos x cosδ x
γ
and α,β, γ, δ  N and γ  δ , then which of the following is ‘TRUE’
A) α  12 B) β  1 C) γ  4 D) δ  6

2
e nx
5. Let S   dx then which of the following is/are correct?
1 x
 1 
A) S  2  e  
1
B) S   e  1  2  
 e  e
2
C) S   t e t dt D) 3  S  5
0
6. If exhaustive set of values of x satisfying cos1 x  sin 1 x  tan 1 x  π  cot 1 x is equal

to interval α,β , then which of the following is/are correct?
A) Last digit of  2013 is cos  αβ 

2012
β tan 1 x
B)  dx is equal to 1/2
α cot 1 1  x  x 2  
π/2
C)  sin  2  α  β  x  sin  sin βx  dx is equal to 2  sin1  cos1
0
D) 2 sin x  cos x  2sin x  cos x is true  x  α,β
SECTION - II
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
a
1  r cos u
7. Let I r  a    1  2r cos u  r du , then the value of limIr 15  ____ ( . denotes
a
2
 r1  
G.I.F.).
 
2
8. The value of  1  x 3  3 x 2  2x dx equals
0
1
3x 2  3/4 
 x  . Find the value of   f  f  x   dx  .
1
9. Let f  x   x  3
2 4  1/4 
  n  mr 
   is  . Then the value of 𝜆
2
 mn 2
10. The value of lim  lim     2 2 2 2 2
n  m 


 r 1  k 1 m n  k n  r
       

160
is_____
11. I1  0
 sin 884x sin1122x 1x
dx, I '  0
238
x 1768
 1
dx then find the value of
I1
.
sin x x 2
 1 I'

1 1 1 1
12. If f  x   ,  x  , n  0,1, 2.... and f  0   0 then  f  x  dx  ________
2n 2n 1 2n 0
f ' x  x  f  x   f x  x 
13. If  dx is equal to m tan 1    c , where m, n  R and ‘c’
f  x   x  f  x  x  x2 

nx 

m
is constant of integration  x  0  then is equal to
n
14. If y 
x
, then 
 y  x  dx  f  y  then 𝑓′(4) is equal to
2
x2 
x  x  y  x  y 
2 2
x  ....
2
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 15 to 16:
10π cos 6x cos 7x cos8x cos9x
Consider the integral I   3
dx
0 1  e2sin 4x
π/4
15. If I  λ  cos 6x cos8x cos 2x dx then λ is
0
A) 5 B) 10 C) 20 D) 5/2
16. The value of I is
5π 5π 5π 5π
A) B) C) D)
4 16 32 8
If f : R  R be a differentiable function such that  f  x    x  f  x  then
7
2
17. The value of  f 1  x  dx is
0
A) 3 2 B) 2 C) 3 D) 1
3
18.  f  x  dx is
0
 3  8  3  8
  3    3   sq.units
f f
 3  sq.units B)
7 7
A)  3 f  4f  3 f
8  4 
 3  4
  3 
f
C)  3f  3    sq.units  3  sq.units
93 8
D)  3 f  4f
 8  8 

PHYSICS MAX.MARKS: 60
SECTION- I
correct options.
option.
19. Three capacitors of capacity 2F,2F,1F and two ideal cells of emf 10V and 5V are
connected in a circuit through a switch ‘S’. Initially switch is opened for a long time
and then it is closed. Choose the correct option(s) after switch is closed.
4
A) Charge passing through 10V cell is C
3
B) Work done by 5V battery is 10J
C) Charge on 1F capacitor is 6C
5
D) Total heat dissipated in the circuit after switch is closed J
3
20. Between two thin parallel metal plates having charges +q and –q is inserted a thick
metal slab having charge +q so that distance between the upper plate and top face of
the slab is 2d and the distance between lower plate and bottom face of the slab is d.
Adjacent surface of the plates and that of the slab are equal in area and parallel to each
other. Now the upper and the lower plates are earthed by closing the switches A and B
simultaneously. Identify correct statement(s). (Plates area >>d)

4q
A) Charge flow through switch A is from plate to ground
3
q
B) Charge flow through switch A is from ground to plate
3
4q
C) Charge flow through switch B is from plate to ground
3
q
D) Charge flow through switch B is from ground to plate
3
21. In the given circuit the potential difference between a and b is 300V. The resistors are
of 100  each. Mark correct option(s).
A) If the upper meter M 1 is ideal voltmeter and lower is ideal ammeter M 2 , reading of
voltmeter is 300V.
B) If both meters are ideal voltmeters , they show 200V each.
C) If both meters are ideal ammeters , they read 6A each.
D) If the upper meter M 1 is ideal voltmeter and lower is ideal ammeter M 2 , reading of
Ammeter is 3A.

22. Initially the switch ‘S’ is open for a long time. Now the switch ‘S’ is closed at t  0
(R1  2, R 2  2, C1  1F and C2  1F). Then choose correct statement(s)
1
A) The current through the wire AB at t  2 sec is ampere.
2e
B) The current through the wire AB at t  2 sec is 1/e ampere.
C) The charge on the capacitor C 2 , which was initially uncharged , at t  2 sec is
 1 
1   coulombs.
 2e 
 1 
D) The charge on the capacitors C1 at t  2 sec is 1   coulombs.
 2e 
23. All the batteries in the infinite chain shown in the figure have emf  and internal
resistance r. Identify Correct Statements.
A) effective internal resistance of battery system across AB is  

3 1 r
B) effective emf of battery system across AB is 3
C) If a resistance of value r is connected across AB the terminal voltage across the
battery system is 

D) Short circuit current across AB for the above system is
r

24. A varying voltage is applied to the clamps AB (Figure (a)) such that voltage across the
capacitors plates varies as shown in Figure (b). Voltage across the clamp CD ( Vc  VD )
is.
A) Constant from t 0 to 2t 0 B) Positive from 2t 0 to 3t 0
C) Negative from 3t 0 to 5t 0 D) Positive from t 0 to 2t 0
SECTION - II
25. In the circuit shown, all capacitors are identical, initially the switch is open and only
the capacitor A is charged. After the switch is closed and a steady-state is established,
charge on the capacitor A become 5.0C . Initial charge on this capacitor is closest to
(in  C )

26. Two identical potentiometer wires P1 and P2 of equal length , resistance R 1 , R 2 are
connected with a battery of emf  0 and internal resistance 1 , through two switches S1
and S2 . A battery of emf  is balanced on these potentiometer wires one by one. If
resistance of wire R 1 is 3.68  and balancing length is on it, when S1 is closed and
2
2
S2 is open. On closing S2 and opening S1 the balancing length on P2 is found to be ,
3
then the resistance of wire R 2 is k . Find the value of k.
27. Three identical capacitors C1 , C 2 and C 3 have a capacitance of 1.0 F each and they are
uncharged initially. They are connected in a circuit as shown in the figure and C1 is
then filled completely with a dielectric material of relative permittivity r . The cell
electromotive force (emf) V0  8V . First the switch S1 is closed while the switch S2 is
kept open. When the capacitor C 3 is fully charged. S1 is opened and S2 is closed
simultaneously. When all the capacitors reach equilibrium, the charge on C 3 is found to
be 5 C . The value of r .

28. Consider the meter bridge circuit without neglecting end corrections. If we used 100 
and 200  resistance in place of R and S respectively, we get null deflection at
1  33.0cm from end A. If we interchange the resistances, the null deflection was
found to be at 2  67.0cm from end A. If  and  are the end correction, then the
value of    (in cm) should be
29. The space between the rectangular plates with sides b and l of a parallel plate capacitor
of separation d is filled with a solid dielectric of dielectric constant k  2 . The capacitor
is charged to potential difference Vo and disconnected from the source. Now the
dielectric is slowly moved out of the capacitor as shown. At any instant x is the length
of dielectric outside the capacitor.  1 is charge density on air capacitor (on the part of
capacitor plate of length x) and  2 be the charge density an dielectric capacitor (on the

part of capacitor plates of length l  x ) at any instant. Then if the ratio 2  N find
1
value of N.
30. In a laboratory where room temperature is 0  0 0C , temperature of a cylindrical

conductor connected across a battery reaches a value   20 2  0
C in steady state.
Now the cylinder is uniformly stretched to   2 times of its initial length and left
connected across the same battery in the same surroundings. If resistivity of material of
the conductor remains unchanged on stretching , find its temperature( in 0 C ) when it
comes again in a steady state.(rate of heat transfer to surrounding is proportional to
temperature difference between cylinder and surrounding)

31. Rated powers of bulbs is shown in figure. Then what will be the safe maximum power
produced by combination.
32. Figure shows the two plane conducting medium of electric conductivity  and 3 the
direction of electric current density are as shown by the arrow. The dotted line shows
the normal of the boundary surface. Then, find the value of  (in degrees).
SECTION – III
(COMPREHENSIN TYPE)
15 identical voltmeters and 15 non identical ammeters are connected to a battery as shown in
figure. The reading of the first voltmeter is V = 9 V, the readings of the first two
ammeters are I1 = 2.9 mA and I2 = 2.6 mA.

33. What is the sum of the readings of all the other voltmeters (i.e from 2 nd voltmeter to
15th voltmeter)
A) 78 volt B) 54 volt C) 100 volt D) 26 volt
34. What is the internal resistance of a voltmeter?
A) 30K B) 40K C) 10K D) 50K

In the network shown in the figure, ammeters A1 ,A 2 and A 3 are identical and internal
resistances of the ammeters are much smaller than the six resistances connected in the
network.
35. The reading of ammeter A1 is
A) 0.1A B) 0.2A C) 0.3A D) 0.4A
36. The reading of ammeter A2 is
A) 0.1A B) 0.2A C) 0.3A D) 0.4A

CHEMISTRY MAX.MARKS: 60
SECTION- I
correct options.
option.
37. Among the following reaction one which gives phenyl / aryl ketone as a major product
O  C  Cl
AlCl3

A) NO2
O O
O  C  CH 3 O  C  Ph
BF3


B)
Ph
O 2 / Pt
HBr, 
C)
CH 3
|
D) Ph  C  CH  Ph 
HNO 2


| |
OH NH 2

38. Identify the correct reactions from the following (not balanced) about major product
CN CHO
SnCl2  HCl
H 2O
A)
CN CH2  CH  O
CH 3  Mg  Br
H 3O 
B)
CH  O CH2  OH
CH 2 O / OH 
C)
O O
Ph Br Ph
Br2 / AcOH
D)
39.
O
P2 O5
'X '

A O
 NH 4 2 CO3 ,1100 C
'Y '
Correct statements about above reaction/products
A) ‘Y’ in more basic than pyridine
B) ‘X’ is more reactive than benzene towards EAS [Electrophilic aromatic substitution]
C) Both X and Y are aromatic in nature
D) ‘Y’ is less basic than Aniline

40. Correct options about acidic strength in the following is
COOH COOH OH
 
Cl F NO2
A)
COOH COOH COOH

CH 3
 
NO2 OCH 3
B)
COOH
H COOH H
C) H COOH H COOH
COOH COOH COOH

Me Me Me
 
NO2 OCH 3
D)
41. Choose the CORRECT options from the following
A) Propanal on treatment with Fehling’s solution gives Red precipitate of CuO
B) Acrolein on treatment with Tollen’s reagent gives white coating of silver on the
walls of test tube
C) Formic acid gives +ve test with both Tollen’s and Fehling’s solution
D) Cinnamaldehyde gives +ve test with Br2 / CCl4 .

42. Choose the CORRECT options from the following which gives aldehyde as product
OH
Br
AgNO3
CH3 OH 
C NaOH, 
A) H CN B) Ph
OH
CH 2  CN
1) CHCl3 / NaOH
DIBAL  H
2) H  water
C) D)
SECTION - II
43.
 
CH 2  COOC2 H5 2 1)NaOEt / OEt 1)NaOH
Product  CO2  Alcohol
1mole  2)H3O
3) 
O
 2 moles 
The molecular weight of the product is…….
44. A cyclic six-membered optically active compound gives following tests.
i) reacts with Na – metal and liberates H 2 gas.
ii) Gives +ve haloform test
iii) Forms cyonohydrin
iv) Gives violet / purple colorization with neutral FeCl3 .
v) It also gives Pthalein derivative with pthalic anhydride
What is the lowest possible molecular weight of the above compound
(Assume no heavy isotope is present)

45. In the following reaction, compound Q is obtained from compound P via an ionic
intermediate
What is the degree of unsaturation of Q?

46. How many of the following compounds undergo nucleophilic addition at a faster rate
than 4-methylbenzaldehyde?
47. 1) Beckmann’s rearrangement

2) Hoffmann’s rearrangement
3) Curtius rearrangement
4) Shmidt rearrangement
5) Baeyer Villigar oxidation
6) Cumene hydroperoxide rearrangement
7) Pinacol – Penacalone rearrangement
From the above named reactions
Number of reactions in which electron deficient oxygen is migrating terminius = (x)
Number of reaction in which electron deficient nitrogen is migrating terminius = (y)
Number of reaction in which electron deficient carbon is migrating terminius = (z)
Then  y  z  x  is…….

48. Magnesium carbide (8.4 gr) on hydrolysis gives an organic compound (x) which on
treating with HgSO4  H2SO4 1% forms (Y) (Atomic weight of Na – 23, O – 16, C – 12,
I – 127)
 Y  
NaOH / 
  Z 
1) NaOI
2) H 
 P  Q
C6 H 8 O 2 coloured ppt
weight of ‘Q’ formed in the reaction is……..

(if all reactions takes place with 100% efficiency)
49. I)
O
Cl C  Cl
H 2 O 2 / NaOH
X
H 
work up 
O
NO2
 Pr oduct  P2 
II)
The difference in the molecular weights of | P1 - P2 | is….

50. Among the following number of condensation of polymers is
i) Polythene ii) Nylon – 6
iii) PVC iv) Teflon
v) Novolac vi) Neoprene
vii) Glyptal viii) Dacron
ix) Buna – S x) Melamine formaldehyde resin
xi) Amylose xii) Cellulose

SECTION – III
(COMPREHENSIN TYPE)
Treatment of benzene with CO/HCl in the presence of anhydrous AlCl3 / CuCl followed
by reaction with Ac2O / NaOAc gives compound X as the major product. Compound X
upon reaction with Br2 / Na 2CO3 , followed by heating at 473 K with alc. KOH furnishes
Y as the major product. Reaction of X with H2 / Pd  C, followed by H3PO4 treatment
gives Z as the major product
51. The compound Y is
A) B)
C) D)
52. The compound Z is
A) B)
C) D)

One of the best method for the regioselective alkylation of ketones consists in an
activation of the required  -carbon atom. For example.
53. Identify structure of ‘ D2 ’ in the above conversation
A) B)
C) D)
54. Most appropriate structure of D1 is
A) B)
C) D)

SPACE FOR ROUGH WORK



08 10 23 SR Iit Star Co Scmodel A&b Jee Adv 2018 p1 Pta 10 QP

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08 10 23 SR Iit Star Co Scmodel A&b Jee Adv 2018 p1 Pta 10 QP

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SEC:SR_*CO-SC(MODEL-A&B) Date: 08-10-23

Time: 3 Hrs Max. Marks: 180

Definite Integration: definite integrals and their properties,

PHYSICS: PRESENTWEEK (100%): Current Electricity + Capacitors + RC

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A) f 1 is less than 2e B) f 1 is less than 1

arbitrary constant then

A) The value of a + b is 11 B) The value of a + b is 6

C) The value of c + d is 18 D) The value of c - d is 14

and α,β, γ, δ  N and γ  δ , then which of the following is ‘TRUE’

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6. If exhaustive set of values of x satisfying cos1 x  sin 1 x  tan 1 x  π  cot 1 x is equal

A) Last digit of  2013 is cos  αβ 

D) 2 sin x  cos x  2sin x  cos x is true  x  α,β

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B) If both meters are ideal voltmeters , they show 200V each.

C) If both meters are ideal ammeters , they read 6A each.

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B) The current through the wire AB at t  2 sec is 1/e ampere.

C) The charge on the capacitor C 2 , which was initially uncharged , at t  2 sec is

A) effective internal resistance of battery system across AB is  

B) effective emf of battery system across AB is 3

C) If a resistance of value r is connected across AB the terminal voltage across the

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A) Constant from t 0 to 2t 0 B) Positive from 2t 0 to 3t 0

C) Negative from 3t 0 to 5t 0 D) Positive from t 0 to 2t 0

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30. In a laboratory where room temperature is 0  0 0C , temperature of a cylindrical

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A) 78 volt B) 54 volt C) 100 volt D) 26 volt

34. What is the internal resistance of a voltmeter?

A) 30K B) 40K C) 10K D) 50K

Paragraph for Question Nos. 35 to 36:

35. The reading of ammeter A1 is

A) 0.1A B) 0.2A C) 0.3A D) 0.4A

36. The reading of ammeter A2 is

A) 0.1A B) 0.2A C) 0.3A D) 0.4A

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Correct statements about above reaction/products

A) ‘Y’ in more basic than pyridine

C) Both X and Y are aromatic in nature

D) ‘Y’ is less basic than Aniline

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COOH COOH COOH

COOH COOH COOH

41. Choose the CORRECT options from the following

A) Propanal on treatment with Fehling’s solution gives Red precipitate of CuO

D) Cinnamaldehyde gives +ve test with Br2 / CCl4 .

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What is the degree of unsaturation of Q?

47. 1) Beckmann’s rearrangement

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weight of ‘Q’ formed in the reaction is……..

The difference in the molecular weights of | P1 - P2 | is….

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52. The compound Z is

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