08 10 23 JR Iit Star Co Scmodel B Jee Adv 2021P I Wat 23 QP

Sec: JR.
IIT _*CO-SC(MODEL-B) Date: 08-10-23

Time: 3 Hrs Max. Marks: 180
08-10-23_JR.IIT_STAR CO-SC(MODEL-B) _JEE ADV_WAT-23_SYLLABUS
MATHEMATICS: 100% COMPLETE LIMITS
PHYSICS: PRESENT WEEK (80%): Elasticity & Viscosity: Elastic behaviour,
stress-strain relationship,Hooke's Law,Young's modulus,bulk modulus,
Elasticity experiment: Young's modulus of elastisity of the material of a
metallic wire Viscosity: Viscus force between two layers,stoke's law
terminal velocity, Rynolds number & Critical Velocity, Experiment:
Young’s modulus - elasticity of the material (Exclude: thermal stess)
PREVIOUS WEEK (20%): Fluid Dynamics: General Characteristics of
liquid flow, types of Fluid flow (Stream line and turbulent flow).
Equation of Continuity. Bernoulli's theorem, Applications of Bernoulli's
theorem: Velocity of efflux, horizontal range of the escaping liquid time
of emptying of the vessel. Impact force of liquid, Venturimeter, sprayer
(or) atomizer, narrowing water jet, siphon,Pitot tube, dynamic lift, thrust
on a rocket, magnus effect,Problems in fluid Dynamics
CHEMISTRY: PRESENT WEEK (80%): Group 13: Electronic configuration and
general trends in physical and chemical properties of elements across
the periods and down the groups; unique behaviour Boron, Reactions of
Boron and Aluminium with air, water, acids, alkali and halogen, uses of
Boron and Aluminium, Preparation, properties of diborane. Boron
halides- Lewis acid strength, Hydrolysis- Preparation , properties and
uses of Boron trifloride Preparation , properties and uses of Orthoboric
acid, Borax, Aluminium chloride, alums (Exclude: Isolation of B,
extraction of Al)
PREVIOUS WEEK (20%): Anamolous properties of Li & Mg ; diagonal
relationship between Li & Mg, Preparation & properties of NaOH,
Preparation & properties of Na2CO3, CaO, CaCO3, Preparation &
properties of Na2CO3, CaO, CaCO3, CaSO4, gypsum, cement,
biological importance of sodium, potasium, magnesium & calcium
(Exclude: Compounds of Mg, Na2S2O3, Na2SO4, microcosmic bead test)
Narayana IIT Academy 08-10-23_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-23_QP
TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 5 – 10) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 11 – 16) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60
PHYSICS
Sec – III (Q.N : 30 – 35) +4 -2 6 24
Total 19 60
CHEMISTRY
Sec – III (Q.N : 49 – 54) +4 -2 6 24
Total 19 60
JR.IIT_*CO-SC Page. No. 2

MATHEMATICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
 k2 k2  1
1. The value of k such that lim cosec    exists
x 1
 ln x x  1 
A)   2, 2  
B) ,  2    2,  
C)  , 2  D) none of these
 
sin 2 x
2. Lt 1 cos ec 2 x
2 cos ec 2 x
     n cos ec 2 x

x 0
A) 0 B) 1 C) n D) n+1
1
e x log(2 x 1) x
 (2  1) sin x
x x
3. Let f ( x)    ,then lt f ( x) 
 e x log x  x 0 
1
A) log e 2 B) e(log e 2) C) (log e 2) D) e 2 (log e 2)
e
4. If Lim
x
 x6  ax5  bx3  cx  d  x6  2x5  x3  x  1  2 then 
A) b = –2 B) a = –2 C) a = 2 D) b = -5
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 5 and 6:
sin x  ae x  be  x  c log 1  x 
f ( x)  where a,b,c are real and lim f  x  be finite.
x3 x0
5. The value of a  3b is
6. The value of 2a  6b  3c is

lim f ( x ). g ( x )
lim 1  f ( x)  is of the form 1 then given limit equals e xa
g ( x)
If
xa
2 x4
 x6
7. If lim    ek then the value of k is
x  x  1 
1 x2 1
 tan x 
8. If lim    e m then the value of m is
x 0  x 

lim  f ( x )1 g ( x )
Consider the standard result of lim f ( x) g ( x)
e xa
, if
xa
lim f ( x)  1 & g ( x)   also we know the limit exists when LHL = RHL
x a
2
 1  x
tan
9. If x  0 
Lt 1  x  x
 equals e , then  
 e 
 
cos  x  , x  0
10. Let f  x    where [x] denotes the greatest integer  x and a  0 . If
 x  a, x  0
lim f  x  exists then a =
x 0

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 tan 2{x}
 x 2  [ x]2 : x0

11. If f ( x)   1 if x0 then

 {x}cot{x} if x0

A) lim f ( x)  1 B) lim f ( x)  1
x 0 x 0
  1 
2
C) cot 1 lim f ( x) D) tan 1 lim f ( x) 
x 0 x 0 4
 1 n  2
12. lim  an    b; then
n 
 1  n 
A) a =1 B) b = 0 C) ab = 0 D)b = 1
  1  cos x  
m
13. If lim sin   exists, where m, n  N , then

x 0  xn 
 
A) m  N , n  3 B) m  N , n  N C) m  N , n  2 D) m  N , n  1
ax cos x  bsin x  c
14. Lt  4 then
x 0 3 5
sin x sec x
A) a  12, b  12 B) a + b = 0
C) a  11, b  12 D) a  12, b  12
x2
a a x  2 2
15. Let L  lim 2 , a>0. If L is finite, then

x 0 4
x
1 1
A) a=1 B) a=2 C) L  D) L
8 16
cos 2  cos 2 x
16. lim is
x 1 x2  x
A) 2 sin 2 B) –2 sin 2 C) 2 cos 2 D) – 2cos 2
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
[x]  1, x  n; n  0,  1,  2,....
17. Let f (x)  
 3, otherwise
 x 2  1, x  3, x  0

and g(x)   3, x0 then, lim g(f (x)) is, where [.] denotes the
x 0
 5, x 3

greatest integer function.
a n  bn
18. If 0 < b < a, then lim n 
n  a  b n
1  9 
19. If f  n  1   f  n    where n  N and f  n   0n  N and nLt f  n  exist
2  f  n   
then the value of Lt f  n  

n 

PHYSICS MAX.MARKS: 60
20. A uniform homogeneous bar of mass M, length L, cross sectional area A, and Young’s
modulus Y is moving with a constant acceleration as shown due to applied force F on a
smooth horizontal surface. Find the stress in the bar as a function of x from the left end
F Fx Fx F L  x
A) B) C) D)
2A A L  x AL AL
21. Two different types of rubber are found to have the stress-strain curves as shown in the
figure
The following are two situations, where rubber is required.
i. A heavy machine is to be installed in a factory. To absorb the vibrations of the

machine,a block of rubber, is to placed between the machinery and the floor.
ii. A rubber tyre for car has to be manufactured.
Which of the following statements is/are correct?
A) R2 is suggested for (i) and (ii) B) R1 is suggested for (i) and (ii)
C) R1 is suggested for (i) and R2 for (ii) D) R1 is suggested for (ii) and R2 for (i)

22. A body is in the form of solid revolution, radius of upper face of the body is r0 and
volumetric density is  . The solid body supports a load P. If the compressive stress at
all cross-sections should be same, then the radius r as a function of y (see figure ) is
  r 2 g  y /2 P    r 2 g  y /2 P   r 2g  y / P   2 r 2 g  y / P 
r  0   0   0   
A) r  0 e 
B) r  r0e 
C) r  r0e 
D) r  r0e 0 
2
23. Water is flowing on a horizontal fixed surface, such that its flow velocity varies with y
 2 y 2 y3 
(vertical direction) as, v  k1  2
 3  , where k1 and k2 are positive constants. If
 k2 k2 
coefficient of viscosity for water is  , what will be the shear stress between layers of
water at y  k2 ?
 k1   k2  k2
A) B) C) D)
k2 k1k2 k1 k12  k22

In the figure shown, a large closed cylindrical tank containing water. Initially, the air
trapped above the water surface has a height h0 and pressure 20 where 0 is the
atmospheric pressure. There is a hole in the wall of the tank at a depth h1 below the top
from which water comes out. A long vertical tube is connected as shown.
( p0  103 pascal ,   103 kg / m3 , g  10 m / s 2 , h0  0.1 m & h1  0.2 m )

24. The height h2 of the water in the long tube above the top, initially, is _______( in meter)
25. The speed with which water comes out of the hole, initially, is _______ (in m/s)
A tube of length l and radius R carries a steady flow of fluid whose density is  and
 R2  r 2 
viscosity is  . The velocity of flow is given by v  v0  2  , where r is the distance of
 R 
the flowing from the axis.
( v0  10 ms 1 , l  2cm, R  2 m ,   100 kg / m3 ,   3.14 )
26. Volume of fluid, flowing across the section of the tube, in unit time is________
( in m3 / s ) nearest integer
27. Kinetic energy of the fluid within the volume of the tube is(nearest integer)_____
(in joule)

A solid has a volume V0 when external pressure is p0 . The bulk modulus of the material
is B. Now, the pressure is increased to p.
( p  20 N / m 2 , p0  10 N / m 2 , v0  2m3 , B  2x106 N / m 2 )
28. What is the decrease in volume of the solid _______ ( in mm3 )
29. What additional energy per unit volume is now stored in the material________ (in micro
joule)

correct options.
option.
30. A member PQRS is subjected to point loads F1 , F2 , F3 and F4 as shown in the figure. Given,
F1  4500 kg , F3  45000kg , F4  13000kg and modulus of elasticity  2.1 106 kg cm 2 . Choose
the correct option(s).
A) For equilibrium, F2  36500kg B) Total elongation is 0.98 mm
C) For equilibrium, F2  26500kg D) Total elongation is 0.49 mm
31. A solid shaft radius R, length L, coefficient of modulus of rigidity G, can transmits
power of P watts at cnstant angular speed  .
Now, choose the correct option(s)
A)A power and torque (T) are related as P  T
B)Torque   R 4
C)Torque   R 3
T G  G r
R
D)   , where   and j  2  r 3 dr ,
j L r L 0

32. Three vertical wires 1,2 and 3 are supporting a rod of mass M in horizontal position as
shown in the figure. The wires are of equal length and equal cross-sectional area& equal
extension. It is given that Y2  Y3 . The wires 1 and 3 are attached at the extreme ends of
the rod. Choose the correct option(s)  Y1, Y2 & Y3  be their respective young’s modulus of
wire 1,2&3.
Mg
A) T1  2T3 B) 2T1  T3 C) T2  T3 D) T1 
5
2
33. A circular cylinder of radius R and height H is filled with water to a height H . It starts
3
rotating about its axis with constantly increasing angular speed choose the correct
statement(s)
A) At all speeds, shape of the free surface is paraboloid
B)The free surface touches first the brim of the cylinder and then the base of the
cylinder.
C)The free surface cannot touch the base without spilling water.
D) The free surface touches the brim as well as the base at the same instant.

34. A cubical block of side a and density  slides over a fixed inclined plane with constant
velocity v. There is a thin film of viscous fluid of thickness t between the plane and the
block. Then, the coefficient of viscosity of the thin film cannot be
 a gt sin   a gt  a gt sin   a gt
A) B) C) D)
v v sin  2v 2v sin 
35. A U-tube acts as a water siphon. The bend in the tube is 1 m above the water surface.
The tube outlet is 7m below the water surface. The water issues from the bottom of the
siphon as a free jet at atmospheric pressure. Speed of jet is v and minimum absolute
pressure in the bend is 
( Given,  atm  1.01105 Nm 2 , g  9.8ms 2 and  water  1000km3 ) choose the correct option(s)
A) v  11.7ms 1 B) v  13.2ms 1 C)   2.27 104 Nm2 D)   3.27 104 Nm2

36. A space 2.5 cm wide between two large plane surfaces is filled with oil. Force required
to drag a very thin plate of area 0.5 m 2 just midway the surfaces at a speed of 0.5 ms 1 is
1N. If the coefficient of viscosity of oil is 5 103 kg  sm 2 , then find the value of 
37. A cube of wood of mass 0.5kg and density 800 kgm 3 is fastened to the free end of a
vertical spring of spring constant k  50 Nm1 , fixed at the bottom. Now, the entire system
is completely submerged in water. The elongation of compression of the spring in

equilibrium is cm . Find the volume of  (given, g  10 ms 2 )
2
38. A block of mass m produces an extension of 9 cm in the elastic spring of length 60 cm

when it is hung by it and is in equilibrium. The spring is cut into two parts of 30 cm and
30 cm lengths. The same block hangs in equilibrium with the help of these two parts

(in parallel). The extension in this case is cm . Find the value of  .
4

CHEMISTRY MAX.MARKS: 60
39. The increasing order of atomic radii of the following Group 13 elements is
A) Al  Ga  In  Tl B) Ga  Al  In  Tl C) Al  In  Ga  Tl D) Al  Ga  Tl  In
40. Among the following the incorrect statement is
A) Al  CH 3 3 has the three-centre two-electron bonds in its dimeric structure
B) BH 3 has the three-centre two-electron bonds in its dimeric structure
C) AlCl3 has the three-centre two-electron bonds in its dimeric structure
D) The Lewis acidity of BCl3 is greater than that of AlCl3
41. The compound which reacts with NH 3 to give boron nitride(BN) is
A) BCl3 B) B2 H 6 C)Boron D) HBF4
42. Colour of the bead in borax bead test is mainly due to the formation of:
A) Metal oxides B) boron oxide
C) metal metaborates D) elemental boron

Aluminium chloride also known as aaluminium tri chloride. It forms hexa hydrate
containing six water molecules of hydration. Metal carbides on hydrolysis produce
hydrocarbons.

43. Co-ordination number of Al in liquid state of AlCl3 is
44. The mass of methane (in grams) produced on hydrolysis of one mole of aluminium
carbide is____

Borax is a salt, a hydrated borate of sodium with Formula Na2 H 20 B4O17 it is colourless
solid
45. The number of oxygen atoms which are covalently bonded with two boron atoms
directly in a molecule of crystalline borax is______
46. The number of crystalline water in one molecule of Borax is _______

A compound X, of boron, reacts with NH3 on heating to give another compound Y.
Compound Y is called inorganic benzene because it has a similar structure to benzene
and it is not organic in nature
47. Maximum no of atoms present in same plane in compound X is...
48. Total no of hybrid orbitals of all B atoms in compound Y is....

correct options.
option.
49. Identify correct orders
A) Atomic radius : B  Ga  Al  In  Tl
B) Ionisation enthalpy (IP):  IP1  : In  Al  Ga  Tl  B
C) Electro negativity: B  Al  In  Ga  Tl
D) Order of stability Tl1  Tl 3

50. Which of the following is/ are correct statement(s)?
A) is positive is negative
B) Among the elements of boron family boron has maximum melting point and gallium
has lowest melting point.
C) H 3 BO3 dissolve in liquid HF due to formation of compound ‘X’ . the hybridization of

central atom in compound ‘X’ is sp3
D) In B2 H 6 only two hydrogen atoms can be replaced by methyl groups.
51. B2 H 6  H 2O 
lowtemparature
 Z  H 2 which of the following statementsis/ are correct about
the compound ‘Z’?
A) Boron atom is sp 2 hybridized
B) In solid state it exist as giant polymeric hard solid
C) It act as monobasic protic acid
D) It act as monobasic Lewis acid
52. Which of the following is/ are correct?
A) The B—F bond length in BF3 is shorter than that in  BF4 


B) The aqueous solution of potash alum is basic in nature.
C) Aqueous solution of Borax acts as Buffer
D) The acidic nature of orthoboric acid is increased in the presence of cis-diol.
53. The crystalline form of borax has

2
A) Tetranuclear  B4O5  OH 4  unit
B) In solid state it exists as three dimensional network polymeric solid
C)Equal number of sp 2 and sp 3 hybridized boron atoms
D) One terminal hydroxide per boron atom

54. The correct statement(s) for orthoboric acid is/are
A) It behaves as a weak acid in water due to self-ionization
B) Acidity of its aqueous solution increases upon addition of ethylene glycol
C) It has a three dimensional structure due to hydrogen bonding
D) It is a weak electrolyte in water

55. How many of the following oxides(s) is (are) amphoteric ?
MgO, K 2O, CaO, BeO, Al2O3 , Na2O
56. B  H  B bridge in B2 H 6 is formed by the sharing of ' X ' electrons. Then ' X ' is
57. Ocatahedral Borax is also called as Jeweller’s Borax, which is denoted by the formula
Na x B y O7 .ZH 2O . Then 'Y  Z ' is

08 10 23 JR Iit Star Co Scmodel B Jee Adv 2021P I Wat 23 QP

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Sec: JR.

IIT _*CO-SC(MODEL-B) Date: 08-10-23

JR.IIT_*CO-SC Page. No. 2

JR.IIT_*CO-SC Page. No. 3

Question Stem for Question Nos. 9 and 10:

SECTION - 3 (Maximum Marks : 24)

13. If lim sin   exists, where m, n  N , then

15. Let L  lim 2 , a>0. If L is finite, then

then the value of Lt f  n  

JR.IIT_*CO-SC Page. No. 5

The following are two situations, where rubber is required.

i. A heavy machine is to be installed in a factory. To absorb the vibrations of the

ii. A rubber tyre for car has to be manufactured.

Which of the following statements is/are correct?

JR.IIT_*CO-SC Page. No. 6

SECTION - 2 (Maximum Marks : 12)

JR.IIT_*CO-SC Page. No. 7

Question Stem for Question Nos. 26 and 27:

the flowing from the axis.

( v0  10 ms 1 , l  2cm, R  2 m ,   100 kg / m3 ,   3.14 )

Question Stem for Question Nos. 28 and 29:

28. What is the decrease in volume of the solid _______ ( in mm3 )

JR.IIT_*CO-SC Page. No. 8

the correct option(s).

A) For equilibrium, F2  36500kg B) Total elongation is 0.98 mm

C) For equilibrium, F2  26500kg D) Total elongation is 0.49 mm

Now, choose the correct option(s)

A)A power and torque (T) are related as P  T

JR.IIT_*CO-SC Page. No. 9

A) At all speeds, shape of the free surface is paraboloid

JR.IIT_*CO-SC Page. No. 10

A) v  11.7ms 1 B) v  13.2ms 1 C)   2.27 104 Nm2 D)   3.27 104 Nm2

JR.IIT_*CO-SC Page. No. 11

38. A block of mass m produces an extension of 9 cm in the elastic spring of length 60 cm

JR.IIT_*CO-SC Page. No. 12

40. Among the following the incorrect statement is

A) Al  CH 3 3 has the three-centre two-electron bonds in its dimeric structure

B) BH 3 has the three-centre two-electron bonds in its dimeric structure

C) AlCl3 has the three-centre two-electron bonds in its dimeric structure

D) The Lewis acidity of BCl3 is greater than that of AlCl3

41. The compound which reacts with NH 3 to give boron nitride(BN) is

A) BCl3 B) B2 H 6 C)Boron D) HBF4

A) Metal oxides B) boron oxide

C) metal metaborates D) elemental boron

SECTION - 2 (Maximum Marks : 12)

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Question Stem for Question Nos. 45 and 46:

Question Stem for Question Nos. 47 and 48:

SECTION - 3 (Maximum Marks : 24)

B) Ionisation enthalpy (IP):  IP1  : In  Al  Ga  Tl  B

D) Order of stability Tl1  Tl 3

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C) H 3 BO3 dissolve in liquid HF due to formation of compound ‘X’ . the hybridization of

D) In B2 H 6 only two hydrogen atoms can be replaced by methyl groups.

the compound ‘Z’?

A) Boron atom is sp 2 hybridized

B) In solid state it exist as giant polymeric hard solid

C) It act as monobasic protic acid

D) It act as monobasic Lewis acid

52. Which of the following is/ are correct?

A) The B—F bond length in BF3 is shorter than that in  BF4 

B) The aqueous solution of potash alum is basic in nature.

C) Aqueous solution of Borax acts as Buffer