JEE (Main)-2022 : Phase-2 (26-07-2022)-Evening

CHEMISTRY

SECTION – A 3. Highest spin only magnetic moment is shown by

which of the following compound?
Multiple Choice Questions: This section contains 20
MnF2, MnF3, MnF4, MnO2
multiple choice questions. Each question has 4 choices (1) MnF2 (2) MnF3
(1), (2), (3) and (4), out of which ONLY ONE is correct. (3) MnF4 (4) MnO2
Choose the correct answer : Answer (1)
1. Which group-13 element has the lowest melting Sol. Compound Spin only magnetic moment
point and is close to metalloid? ()
MnF2(d5) 35 B.M.
(1) Al (2) Ga
MnF3(d4) 24 B.M.
(3) In (4) Tl
MnF4(d3) 15 B.M.
Answer (2)
MnO2(d3) 15 B.M.
Sol. In group-13, Gallium has the lowest melting point
4. Which among the following is a broad spectrum
as it exists as Ga2 molecules. There are weak antibiotic drug?
vander Waal’s force of attraction between Ga2 (1) Ofloxacin (2) Penicillin G
molecules. Gallium is also close to a metalloid. (3) Novestrol (4) Terpineol

2. Consider the following statements : Answer (1)

Sol. Antibiotics which kill or inhibit a wide range of gram
Assertion: Boric acid is a weak acid in aqueous positive and gram negative bacteria are said to be
solution. broad spectrum antibiotics.
Ofloxacin is an example of broad spectrum
Reason: It acts as a Lewis acid due to the presence antibiotic drug.
of incomplete octet of boron. 5. Which of the following metals is not extracted from
sulphide ore?
(1) Assertion is correct, Reason is correct and (1) Al (2) Fe
Reason is the correct explanation for Assertion (3) Zn (4) Cu
(2) Assertion is correct, Reason is correct, but Answer (1)
Reason is not the correct explanation Sol. Al cannot be extracted from sulphide ore. It is
usually extracted from Bauxite ore Leaching of
(3) Assertion is correct and Reason is incorrect bauxite ore is done followed by electrolytic
reduction.
(4) Assertion is incorrect and Reason is correct
6. Which one of the following is not a benzenoid
Answer (2)

Sol. Assertion is correct as Boric acid is a weak acid.

Reason is also correct as it acts as a Lewis acid (1) (2)

due to incomplete octet.

Being a Lewis acid does not explain the reversibility

(3) (4)
of the reaction.

Hence, Reason is not the correct explanation. Answer (1)

-7-
 JEE (Main)-2022 : Phase-2 (26-07-2022)-Evening

Answer (1)
Sol. Sol. DIBAL– H can reduce both esters and –CN group

Is not a Benzenoid compound. Benzenoid to aldehyde

compound contain benzene rings.
7. Vulcanised Rubber can be prepared from,
(1) Styrene + Isoprene
(2) Isoprene + Sulphur
(3) Neoprene + Sulphur 9. If degree of freedom is n, then ratio of CP and CV
will be
(4) Neoprene + Styrene
n+2 n +1
(1) (2)
Answer (2) n 2
Sol. Heating isoprene with sulphur at a temperature n
(3) (4) None of these
n+2
range between 373k to 415 K
Probable structure of vulcanised rubber is, Answer (1)
Sol. If n is the degree of freedom of a gas then
nR
CV = , and
2
nR n+2
CP = +R =  R
2  2 
CP n + 2
8. Consider the following reaction =
CV n
10. Which of the following is also known as animal
starch
(1) Glycogen (2) Starch
(3) Sucrose (4) None of these
The product formed is Answer (1)
Sol. Carbohydrates are stored in animal body as
glycogen. It is also known as animal starch because
its structure is similar to amylopectin and is rather
(1) more highly branched.
11. Assertion: LiF is sparingly soluble in water.
Reason: Radius of Li+ is the least among its group
members and hence its hydration enthalpy is very
(2)
less.
(1) Assertion is correct and Reason is correct
explanation of Assertion

(3) (2) Both Assertion and Reason are correct and

Reason is not the correct explanation of
Assertion
(3) Assertion is correct and Reason is incorrect
(4)
(4) Assertion is incorrect and Reason is correct

Answer (3)

-8-
 JEE (Main)-2022 : Phase-2 (26-07-2022)-Evening

Sol. LiF is sparingly soluble due to high lattice energy 14. (A) ASSERTION : Phenolphthalein is an organic
+ – indicator.
(due to small size of Li and F ). Due to small size
(R) REASON : Phenolphthalein is a weak acid and
of Li+1,it has high hydration energy. does not dissociate in a basic solution.
So, Assertion is correct but Reason is a wrong (1) A and R both are correct and R is correct
explanation of A
statement.
(2) A and R both are correct and R is not correct
explanation
(3) A is correct but R is incorrect
12. (4) A is incorrect and R is correct
Answer (3)
Sol. Phenolphthalein is an organic indicator used in
acid-base titration. So, assertion is true.
Correct set of reagent for the above conversion is It is a weak acid and does not dissociate in an acidic
(1) NaNO2/HCl; KI solution. It is colourless in the undissociated form.
But it dissociates in a basic solution to give pink
(2) KI; NaNO2/HCl coloured conjugate base. So, reason is incorrect.
(3) Fe/HCl; NaNO2 + HCl; KI 15. Which of the following complex is diamagnetic in
nature
(4) NaNO2 + HCl; CH3I (1) K3 [Fe(CN)6] (2) K4[Fe(CN)6]
Answer (1) (3) K2[Cu(CN)4] (4) None
Sol. Answer (2)
Sol.
K4[Fe(CN)6]
Fe+2 = [Ar]3d6

13. Consider a particle of mass m at rest which

m 2m
explodes into two particles of masses and
3 3 No unpaired electron so diamagnetic in nature.
respectively (m < m). What will be the ratio of
16. Arrange the following in increasing order of
de-Broglie wavelengths of the particles emitted?
covalent character
(1) 1 : 1 (2) 2 : 1
(1) CaI2 < CaBr2 < CaCl2 < CaF2
(3) 1 : 2 (4) 4 : 1
(2) CaF2 < CaCl2 < CaBr2 < CaI2
Answer (1) (3) CaF2 < CaCl2 < CaI2 < CaBr2
Sol. Applying momentum conservation,
Initial momentum = Final momentum (4) CaI2 < CaCl2 < CaBr2 < CaI2
m 2m Answer (2)
0= v1 + v2
3 3 Sol. According to Fajan’s rule, for the same metal ion,
mv1 2mv 2 as the size of anion increases, polarizability of
=
3 3 anion increases and hence the covalent character
v
v2 = 1 of the given ionic compound increases.
2
h  The correct increasing order of the given
1 mv m v 1 1 compounds is
 = 1 1 = 2 2 = 2 =
2 h m1v1 2 1
m2 v 2 CaF2 < CaCl2 < CaBr2 < CaI2

-9-
 JEE (Main)-2022 : Phase-2 (26-07-2022)-Evening

17. When potassium permanganate is reacted with SECTION - B

H2O2 in acidic medium, then the products formed Numerical Value Type Questions: This section
are, contains 10 questions. In Section B, attempt any five
(1) Mn+4 and H2O only questions out of 10. The answer to each question is a

(2) Mn+2 and H2O only NUMERICAL VALUE. For each question, enter the
correct numerical value (in decimal notation,
(3) Mn+2, H2O and O2
truncated/rounded-off to the second decimal place; e.g.
(4) Mn+4, H2O and O2
06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the
Answer (3)
mouse and the on-screen virtual numeric keypad in the
− + +2
Sol. 2MnO + 6H + 5H2O2 → 2Mn + 8H2O + 5O2
4 place designated to enter the answer.

The above reaction shows reducing action of H2O2

21. Haemoglobin contains 0.34% iron (by mass). What
in acidic medium
mass of iron (in mg) is present in 33 gm of
Products formed are, Mn+2, H2O and O2 haemoglobin? (Round off to the nearest integer)
18. The ratio of masses of two nuclei of an element is
Answer (112)
4 : 3. What will be the ratio of density for such
nuclei? Sol. Mass of iron present in 100 gm of haemoglobin =
(1) 3 : 4 (2) 4 : 3 0.34 gm
(3) 1 : 2 (4) 1 : 1
Mass of iron present in 33 gm of haemoglobin =
Answer (4) 0.34  33
= 0.1122 gm 112 mg
Sol. r = r0 (A) 1/3 100

r1  A 1 
1/3
22. H2F2 (g) → H2 (g) + F2 (g)
= 
r2  A 2 
If U for the above reaction is –59.6 kJ/mol at 27ºC,
1/3
4 then find the value of H (in kJ) at the same
= 
3 temperature (R = 8.314 J K–1 mol–1) (Consider

r13 4 magnitude of H only)

=
r23 3
Answer (57.11)
m1
d1 v m v Sol. H = U + ( ng )RT
, = 1 = 1 2
d2 m2 m2 v1
v2 As ng = 1, H = U + 8.314 × 300

m1 r23
=  Magnitude of H (in kJ) = 57.11
m2 r13
23. A is a non-volatile solute. If for 1 molal solution, Tb
4 3 1
=  =
3 4 1 is 3 K and for 2 molal solution, Tf is 6 K, then find

19. the ratio of Kb and Kf.

20. Answer (01.00)

- 10 -
 JEE (Main)-2022 : Phase-2 (26-07-2022)-Evening

Sol. Tb = iKb m 26. AB2 dissociates with t1/2 = 200 seconds and the half
life remains same irrespective of the initial
3 = iKb × 1 …(i) concentration. Find the time taken for 80%
completion of the reaction. (in seconds)
Tf = iKf m
[Take log5 = 0.7 and log2 = 0.3]
6 = iKf (2) …(ii)
(Round off to nearest integer)
Dividing (i) and (ii), we get Answer (467)
Sol. As half life remains same irrespective of the initial
1  Kb  1
=  concentration, the reaction is a first order reaction
2  Kf  2
 0.6909   100 
 200   t = 2.303log  100 − 80 
Kb
=1    
Kf
0.6909
 t = 2.303log5
200
24. CH3CH2MgBr + CH3OH → Products
200
Total number of gaseous product(s) formed in the t=  0.7 = 466.67
(0.3)
above reaction is
467 seconds
Answer (01.00)
27. A chemistry teacher tells you to make a solution of
Sol. CH3CH2MgBr + CH3OH → pH 8.26. If you have 0.2 M solution of NH3 in 1 L,
how many moles of NH4Cl will be added to make
CH3CH3(g) + Mg(OCH3)Br the required solution.

25. A and B form an ideal solution. If mole fraction of A Given pKb for NH3 = 4.74

is 0.3 in liquid phase and vapour pressure of pure Answer (2)

A and B are 100 torr and 150 torr respectively, then Sol. A mixture of NH3 and NH4Cl will form a basic
find the mole fraction of A in vapour phase. buffer.
pH of the final solution = 8.26
Answer (0.22)
or, pOH of the final solution = 5.74
Sol. XA = 0.3
Let the number of moles of NH4Cl added to 1 L
solution of NH3 be x.
PT = PAo XA + PBo XB
Using Henderson equation,
= 100(0.3) + 150(0.7)
[NH4 Cl]
pOH = pK b + log
= 30 + 105 [NH3 ]

x
= 135 torr 5.74 = 4.74 + log
0.2

XA  PAo = YA  PT On solving,
x=2
(0.3) × 100 = YA(135)
28.
30
YA = = 0.22 29.
135
30.

- 11 -