Exercise 2 1682934866

JEE (MAIN + ADVANCED) : ENTHUSIAST COURSE
SUBJECT : PHYSICAL CHEMISTRY

Topic : Thermochemistry Exercise : S-I
1. TC0023
Ans. (178.00 kJ)
Sol. CaCO3 ® CaO(s) + CO2(g)
34ml — —
— 16 ml 20 lit
DU = q + w Þ 180 – 1 éê 20 ´
100 ù
®
ë 1000 úû
Q only gaseous compoent

Þ 178 kJ
2. TC0025
Ans. (1000.00 cal)
Sol. 3A(g) + 2B(g) ® 4C(g)
moles 5 4 –
10 20
A is L.R. 0 moles moles formed
3 3
®
w = – DngRT Þ RT æç - ö÷ Þ RT
20 25 5
è 3 3 ø 3
5
Þ × 2 × 300 cal
3
Þ 1000 cal
3. TC0093
Ans. (–741.50 kJ/mole)
Sol. DH = DU + DngRT
Dng = 1 + 1 – 3/2 = 1/2
1 1
So DH = DU + RT = – 742.7 + × 8 × 300
2 2
®
= – 742.7 kJ + 1.2 kJ
= – 741.5 kJ Ans.
4. TC0094
Ans. (–3.50 kJ)
Sol. For 2 moles of 'A' heat released is 20 kJ
now DH = DU + DngRT
as in closed container DU is as bed so
DU = DH – DngRT
®
Dng = 4 – 2 – 3 = – 1
DU = DH + RT
= – 20 + 8.3 × 300
= – 17.51 for 2 moles of 'A'
-17.51´ 0.4
for 0.4 moles of A Þ
2
Þ – 3.502
5. TC0004
Ans. (– 139.60 )
Sol. L.R. will decide DU
C2H4(g) + HCl(g) ® C2H5Cl(g) DH = – 72.3 kJ/mole
2.5 mole 2 moles
DH = DU + DngRT
®
8.314 ´ 300
Þ – 72.3 = DU –
1000
Þ DU = – 69.80 kJ
For 2 moles Þ – 69.80 × 2 Þ – 139.6 kJ
6. TC0003
Ans. (189.40 kcal)
Sol. qV = DU Again DH = DU + DngRT
2 ´ 2 ´ 300
Þ – 380 = DU – kCal
1000
Þ – 380 + 1.2 Þ – 378.8 Kcal
®
for 0.5 moles Þ – 378 × 0.5
Þ – 189.4 Kcal
7. TC0001
Ans. (–0.30 kJ)
Sol. C2H4(g) + H2(g) ® C2H6(g)
1.5(50 - 100) 100
DH = DU + PDV Þ – 0.31 = DU + ´ kJ
1000 1000
–0.31 + 0.0075 = DU Þ – 0.3025 kJ
®
8. TC0095
Ans. (–80.00)
Sol. DH o = 2 ´ DH fo NH 3(g) - DH fo N 2 H 4(g )
DH rxn
o
+ DH fo N 2 H 4(g )
DH of NH 3 =
2
-40 - 120
®
= = - 80kJ/mole
2
9. TC0096
Ans. (–1560.00)
Sol. DHrxn
o
=DHCo [C3H8(g) ] + DHoc [H2O(g)] -DHco[C2H6 (g)] -DHco[CH4 (g)]
– 55.7 = – 2220 – 285.7 – DH CC 2H6 +890

o
DH CC
o
= – 2220 – 285.7 + 890 + 55.7
®
2 H6
= – 1560 kJ/mole
10. TC0097
Ans. (129.00 kJ)
Sol. C(s) + 2S(s) ® CS2(l)
DH orxn = DH fo CS2(l ) = +DH CS(s)

o
+ 2XDHS(s)
o
- DH CCS
o
2(l)
= – 393 – 2 × 293 + 1108
®
= + 129 kJ/mole
11. TC0008
Ans. (–3201, – 3199.75 kJ/mole)
5
Sol. C6H5COOH(s) + O 2 (g) ® 7CO2(g) + 3H2O(l)DHC
2
(i) DHC = S(DHf)P – S(DHf)R
Þ 7(–393) + 3(–286) – (– 408)
®
Þ – 3201 kJ/mole
(ii) DU DH = DU + DngRT
(7 - 7.5) ´ 8.314 ´ 300kJ

–3201 = DU +
1000
DU = – 3199.75 kJ/mole
12. TC0006
Ans. (–88.00 kJ mol )–1
7
Sol. C2H6(g) + O (g) ® 2CO2(g) + 3H2O(l)
2 2
3120
DHr = DHc = –
2
®
3120
DHC = – = 2(–395) + 3(–286) – DHf(C2H6)
2
DHfC2H6 = – 88kJ/mole
13. TC0007
Ans. (–266.00 kJ/mol & –825 kJ/mole)
1
Sol. Target equation Fe(s) + O 2 (g) ® FeO(s)
2
From given equation, above equation can be formed using Hess law as : equation (2) + equation (3)
– equation (4)
®
Þ –155 – 393 + 282
Þ – 255 kJ/mole.
3
Target equation 2Fe(s) + O 2 (g) ® Fe2O3(s)
2
Using Hess law – equation (1) + 3 equation (3) – 3 equation (4)
Þ – 492 + 3(–393) – 3(–282)
Þ – 825 kJ/mole.
14. TC0005
Ans. (–41.20 kJ)
Sol. From Kirchoffic equation
DH T2 - DH T1
DCp = ...(1)
T2 - T1
®
DCP = (SCp)p – (SCp)R DH300 = SDHP – SDHR
Þ 37 + 29 – 29 – 33 Þ – 393 + 0 – (–110 – 241)
Þ 4J/kmole Þ –393 + 351
Þ – 42 kJ/mole
4 DH500 - (-42)
from equation (1) kJ =
1000 200
DH 500 = -41.2kJ
15. TC0098
Ans. (i) –885 kJ/mol (ii) – 890 kJ/mole)
Sol. CH4(g) + 2O2(g) ® CO2(g) + 2H2O(l)
For 0.01 moles CH4, DU = 17.7 × 0.5 = 8.85 kJ
For one mole, DU = – 885 kJ/mole
DH = DU + DngRT
®
300
= – 885 + – 8.31 × @ – 890 kJ/mol
1000
16. TC0099
Ans. (602.49 kJ/mole)
Sol. q = 6 × 1.25 = 7.5 kJ for 1 gm sample of NH4NO3
Molar mass of NH4NO3 = 80 g/mol
so; qv = 80 × 7.5 = 600 kJ
DH = DU + DngRT
®
300
= 600 + 1 × 8.3 ×
1000
= 602.49 kJ
17. TC0010
Ans. (4.50%)
Sol. Total moles in mixture PV = nRT
Þ 1 × 0.821 = n × 0.0821 × 300
Þ n = 1/30
By unitary method 200 Kcal ® 1 mole
®
1 kcal = 1/200 moles
Also heat absorbed = heat released
1200 ´ 0.25
= = 0.3Kcal
1000
0.3 / 200
Mole % of CH4 = ´100 Þ 4.5%
1/ 30
18. TC0100
Sol. DH = 4 B.E.(N – H) + B.E.(N – N) – 2 B.E(N – H) – B. E.(N = N) – B.E.(H – H)
Þ 109 = 4 × 391 + 163 – [2 × 391 + B.E. (N = N) + 436]
Þ B.E.(N = N) = 2 × 391 + 163 – 436 – 109
= 400 kJ
®
19. TC0101
Ans. (20.60 kcal/mole)
Sol. DH = [DH(C(s) ® C(g)) + 4B.E(H – H)] – [2B.E(C = C) + 2B.E(C – C) + 8B.E(C – H)]
= 20.60
®
20. TC0011
Ans. (– 266 kJ/mole)
Sol.
®
Also B.E.(H – H) = 2 × 218 kJ/mole
B.E.(O2) = 249 × 2 kJ/mole
DHf(CH3OH),l + 38 = 715 + [4 × 218 + 249] – [3 × 415 + 356 + 463]
DHf(CH3OH, l) = – 266 kJ/mole
21. TC0013
Ans. (–72 kJ/mole)
Sol. DH = B.E.(C = C) – 2B.E.(C – C) = 590 – 2 × 331 = – 72 kJ/mole
®
22. TC0014
Ans. (201.00 kJ)
Sol.
1565 = 59 + 6(P – P)
®
BE(P – P) = 201 kJ/mole
23. TC0017
Ans. (5.00 kJ/mole)
Sol.
®
715 + 500 – 2 × 800 + R.E. = – 390
|R.E| = 5 kJ/mole
24. TC0015
Ans. (–2669.00 kJ/mole)
Sol.
®
(DHC)theo + 3R.E CO2 = (DHC)obs + 4 × All vap H2O(l)
8(C – H) + 2(C – C) + 5(0 = 0) – [3 × 2(C = O) + 4 × 2(O – H) + 3(–143) = (DHC)Obs + 4 × 41]

(DHC)Obs = – 2669 kJ/mole
25. TC0016
®
Sol.
–116.2 = |R.E| + 7(–28.6)

R.E. = – 84K cal/mole
26. TC0102
Sol. Na(g) ® Na(g) DH = 101
Na(g) ® Na (g)
+
DH = 494
1/2F 2 ® F(g) DH = +80
F(g) + e –
® F (g)
–
DH = x
®
Na +(g) + F–(g) ® NaF(s) DH = – 894
Na(s) + 1/ 2F2 (g) ® NaF(s) DH = – 571.0
So 101 + 494 + 80 + x – 894 = – 571.0

x = – 352
27. TC0103
Sol. (1) ® CuSO4(aq); DH = – 16 Kcal
CuSO4 + aq ¾¾
(2) ® CuSO(aq); DH = 3 Kcal
CuSO4 . 5H2O + aq ¾¾
Substracting (1) – (2) we get:
CuSO 4 + 5H 2O ¾¾
® CuSO 4 .5H 2O DH = – 19 Kcal
®
28. TC0021
Sol. ® H+(aq) + Cl–(aq)

HCl(g) ¾¾
DH = DH of [H + (aq)] + DH fo [Cl - (aq)] - DH fo [HCl(g)]
= 0 + DHof [Cl–] – DHof [HCl(g)]
= – 170 + 90
®
DH = – 80 kJ/mole
29. TC0104
Ans. (6.00 kJ/mole)
Sol. Given is –14Kcal/eq so for 2eq it will be = – 28 Kcal is observed for H2A is – 11 × 2 = – 22 Kcal
So heat of ionisation = + 6Kcal/molse.
®
30. TC0105
Ans. (5.00 kJ/mole)
Sol. H3PO3 is dibasic acid
So for 2H+ + 2HO– ® 2H2O
DH = – 55.84 × 2
= 111.68 kJ but observation
®
– 106.68 so heat of dissociation = 5 kJ
31. TC0106
Sol. HA + NaOH As Heat released = Heat absorbed

400 × 0.2 × 1 100 × 0.80
Þ 80 meq. 80 meq. Heat absorbed = 500 × 4.2 × 1.2 by
®
80 × 10–3 moles
500 ´ 4.2 ´ 1.2

\ By 1 mole kJ/mole
80 ´ 10-3 ´ 103
= 31.5 kJ/mole

Exercise 2 1682934866

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Exercise 2 1682934866

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JEE (MAIN + ADVANCED) : ENTHUSIAST COURSE

SUBJECT : PHYSICAL CHEMISTRY

Q only gaseous compoent

– 55.7 = – 2220 – 285.7 – DH CC 2H6 +890

DH orxn = DH fo CS2(l ) = +DH CS(s)

= – 393 – 2 × 293 + 1108

(7 - 7.5) ´ 8.314 ´ 300kJ

8(C – H) + 2(C – C) + 5(0 = 0) – [3 × 2(C = O) + 4 × 2(O – H) + 3(–143) = (DHC)Obs + 4 × 41]

–116.2 = |R.E| + 7(–28.6)

Na(s) + 1/ 2F2 (g) ® NaF(s) DH = – 571.0

So 101 + 494 + 80 + x – 894 = – 571.0

Sol. ® H+(aq) + Cl–(aq)

Sol. HA + NaOH As Heat released = Heat absorbed

Þ 80 meq. 80 meq. Heat absorbed = 500 × 4.2 × 1.2 by

500 ´ 4.2 ´ 1.2

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