3.

3 The Tait equation for liquids is written for an isotherm as:

Where V molar specific volume, is the hypothetical molar or specific volume at

zero pressure, and A and B are positive constants. Find an expression for the
isothermal compressibility consistent with this equation.
AB
Ans: ( B + P)( B + P − AP)

3.6 Five kilograms of liquid carbon tetrachloride undergo a mechanically reversible,

isobaric change of state at 1 bar during which the temperature changes from 273.15 K
(0 ) to 293.15 K (20 ). Determine . The properties for
liquid carbon tetrachloride at 1 bar and 273.15 K may be assumed independent of
temperature : .
t 3 t t
Ans:△V =0.00007638 m , W= -7.638J, Q=84 KJ. △H =84 KJ, △U =83.99 KJ

3.14 A tank of 0.1- volume contains air 298.15 K (25 ) and 101.33 kPa. The tank
is connected to a compressed-air line which supplies air at the constant conditions of
318.15 K (45 ) and 1500 kPa. A valve in the line is cracked so that air flows slowly
into the tank until the pressure equals the line pressure. If the process occurs slowly
enough that the temperature in the tank remains at 298.15 K (25 ),how much heat is
lost from the tank ? Assume air to be an ideal gas for which

Ans:-172.71 KJ

3.15 Gas at constant T and P is contained in a supply line connected through a valve
to a closed tank containing the same gas at a lower pressure. The valve is opened to
allow flow of gas into the tank,and then is shut again.
(a) Develop a general equation relating , the moles (or mass) of gas in tank
at the beginning and end of the process, to the properties , the internal
energy of the gas in the tank at the beginning and end of the process, and H’ , the