방

역 에

a
히
 R

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Seco d ay
P r Aa ans le
N

CI43

S dsuy
N-
eteg
B
aaoce
 ne 9 ou
react amiieS),
인rato nat e oy actds.

aylatia wt ary ChlondeLacid anbydtide

tleplslic Substtution wlth Halogeno alKarrs,
(ab y c acd e
ad ayCa bo y acds.
deptatarate 영, oSeS
beri
S
1Sf
at'on H
ls ( ilh acicL anlaydcde)
 9rW20 3
Reactons ot asuitacid
H

1 Cacble aid
audt.
t
Cineue up

ee

H
HtH,0

Pouo r Tegdai Mlolecule Aad facedat Small

(nacniaiye
addot4 olecole edtethner

addo_ olymneS
reaptesalkens
Cogedention
( o
mec
tOH
ystCs
NH
p yaides.
oaly eder
-po jeumde.
AddiHon_po y erisat ton
(oi eona fon o perS ffo otsol
o gethocçoly et no.hec predoets
yV LU V "

ni y
(unden ttoa eStion.
fo matton o po g necsFroe da s k ol e

ainae a Q
ots atte(nolecule
( gw udtec todosel as el.

Addttion_Polymecs:
aanides
(arbo y iteactd+dianine

Ceh0tt
Co0 Ntty

CoL H0

po bikguatt () a lu u
ka London
d

Tces

ina_polyam:de Cose y dsgca ondtiag due

tlae H

laus
u ledpiost
e
 ADDITION & CONDENSATION POLYMERS

Addition polymers Condensation polymers

what they are and

long chain molecules made from joining together long chain molecules made from joining together
formed many shorter molecules (monomers) together to many shorter molecules (monomers) together to
how they are
form a long chain molecule, with nothing else form a long chain molecule, with some one
produced. small molecule also formed (e.g. water).

monomers
dicarboxylic acids with diols
molecules with C=C bonds dicarboxylic acids with diamines
amino acids

examples poly(ethene) polyesters (e.g. terylene)

PVC polyamides (e.g. nylon, Kevlar)

poly(propene)

non-biodegradable (due to absence of polar biodegradable (due to the presence of polar C-N
biodegradability
bonds in the main chain (all bonds are C-C)) Or C-O bonds in the main chain)

ADDITION POLYMERS

Monomer Polymer

Name Structure Name Structure Repeating unit

(H I-
chloroethene
Chloro H

Propene poly(pro pene)

H
poly(ethenol)
ethano

EBut-2-ene poly(But-2-ena
CHa

H H

dichloropropene H-C-C=C poly dichloro

Proper
H CI CI

© www.CHEMSHEETS.co.uk Chemsheets A2 1093

16-July-2016
8 H AU— C|- Ret
t
onT
ac d
fa
(

t sin- uf foren an .

yeshtcS
dtol
(00H C0 H.

1O +H 0

epeatny*

eo terylenel
 (combustion)

mIteuU2

(incompler
ombustion)

KCN in ethanol,
reflux

HX(e.g. HBr )

O in ethanol, reflux

nocleodalke S słoki warm

NH (excess)
in ethesotic Cond hions H-
or H,0
1rY alcohol, héat,
reflux .
distillation
y Aldeyde

1"Y alcohol, reflux

(arb (C Cctd

2rY alcohol, reflux

(Velor K (r07/
| y
3ry alcohol
no reaction