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ABSTRACT
INTRODUCTION
25 0.6
0.6
600
Fractional change in
15 0.4 0.4
400
Stress (MPa)
0.3 0.3
10
Strain (με)
0.2 200 0.2
5 0.1
0.1
0 0.0 0 0.0
-5 -0.1 -0.1
-200 -0.2
-10 -0.2
-0.3 -0.3
-15 -400
0 100 200 300 400 500 0 100 200 300 400 500
Time (s) Time (s)
(a) (b)
Figure 2. Variation of the fractional change in electrical resistivity with stress (a) and strain (b) of
concrete with SSSW under 7 times of cyclic compressive loading.
120 10 12 Stress
1.0
11 0.9
Flexural-tensile stress (MPa)
100 5 10
Fractional change in
9
80 0 8 0.7
7 0.6
60 -5 6 0.5
5 0.4
40 -10 4 0.3
3
20 Stress -15 2 0.2
Fractional change in electrical resistivity 0.1
1
0 -20 0 0.0
0 1000 2000 3000 4000 5000 6000 0 100 200 300 400 500 600 700
Strain (με) Strain(με)
Figure 3. The relationship between monotonic Figure 4. The relationships between flexural-
compressive strain, stress and fractional change tensile strain, stress and the fractional change in
in electrical resistivity of concrete with SSSW. electrical resistivity of concrete with SSSW.
Fractional change
Sample 4
0.4 Sample 5
Sample 6
0.2
0.0
-0.2
0 5 10 15 20 25 30 35
Stress / MPa
As shown in Figure 7, the spiky spherical nickel particles have nano-tip on their
surface. Figure 8 shows the sensing property of concrete with spiky spherical nickel
particles under uniaxial compression. It can be seen from Figure 8 that the relative
electrical resistivity of these composites decreases by 0.69 maximum. In addition, the
decrease of the electrical resistivity reaches 0.63 within the elastic regime. The stress
sensitivity coefficient and strain sensitivity coefficient (gauge factor) decrease with
increase of compressive stress and strain. They can reach 0.124/MPa and 1930
(extraordinarily high compared to the values of around 2 for conventional resistive
strain gauges and 100-200 for silicon pressure-sensitive sensors) respectively at a low
stress and strain level. The sharp nano-tips on the surface of spiky spherical nickel
particles is responsible for generating field-assisted tunneling conduction, which leads
to the strong responses of electrical conductivity of the composites to external force or
deformation [7].
1.0 1.0
-1
0.124MPa 1930
0.8 0.8
0.102MPa
-1 1373
0.6 0.6
-1
0.050MPa 896
0.4 0.4
0.37 0.37
0.31 0.31
0.2 0.2
0 10 20 30 40 2.0 1.5 1.0 0.5 0.0
3
/ MPa / 10
Figure 7. SEM photograph of spiky Figure 8. Sensing property of concrete with
spherical nickel particles. spiky spherical nickel particles.
Intrinsic Self-Sensing Concrete with CNT
Figure 9 depicts the variation of the electrical resistance of concrete with CNT
under repeated compressive loading and impulsive loading. Figure 9(a) shows that the
electrical resistance of the composite decreases upon loading and increases upon
unloading in every cycle under repeated compressive loading with amplitude up to 6
MPa. It indicates that the response of electrical resistance of this composite to
compressive stress is regular under repeated compressive loading. The change in
electrical resistance reaches about 1500 Ω maximum as compressive stress is 6 MPa.
As shown in Figure 9(b), the impulsive loadings also cause regular changes in the
electrical resistance of concrete with CNT. According to these results, it can be seen
that the response of electrical resistance of concrete with CNT to compressive stress is
reversible and sensitive, which means that the concrete with CNT has excellent
sensing capability.
0 0
in electrical resistivity /%
in electrical resistivity /%
-2
Fractional change
-2
Fractional change
-4 -4
-6 -6
-8 -8
-10 -10
-12 -12
0 2 4 6 8 0 1 2 3 2 4 5
Compressive stress /MPa Compressive strain/10 με
Figure 10. Relationships between compressive stress/strain and fractional change in electrical resistivity of
concrete with CF and CB.
Grapes
15 15 5
25
electrical resistivity(%)
10 10 20
Fracrional change in
electrical resistivity(%)
2
3
Fractional change in
5 5 15
2 10
0 0 1 5
-5 -5 0 0
-1 -5
-10 -10 -10
-2
-15 -15 -3 -15
-20
-20 -20 -4
-25
-5
-25 -25 0 50 100 150 200 250 300 350 400
0 50 100 150 200 250 300 350 400
Time (s)
Time (s)
(a) stress and fractional change in resistivity (b) strain and fractional change in resistivity
Figure 12. Compressive stress/strain and fractional change in electrical resistivity of concrete with 2.40
vol.% CNT/NCB composite fillers under repeated compressive loading with stress amplitude of
8MPa.
CONCLUSIONS
In this study, six types of ISSC concrete with SSSW, CF, nickel powder, CNT, CF
and CB, or electrical self-assembled CNT/NCB are investigated. By measuring
electrical resistance of the ISSC, the stress, strain, crack and damage can be in situ
monitored. In general, ISSC with nanoscale fillers have much more stable and stronger
sensing behaviors than that of ISSC with microscale fillers. Compared with ISSC with
single filler, ISSC with hybrid fillers can improve the linearity of sensing property. It
should be noted that hybrid CNT and NCB in special structure, i.e. electrostatic self-
assembled, can highly enhance the sensing property. Till now, ISSC has been used in
structural health monitoring and traffic detection. It is expected that ISSC will provide
a high-performance and mutifunctional/smart material support to build smart railway
system and even smart city (as shown in Figure 13).
Figure 13. Smart city in the future.
ACKNOWLEDGMENTS
The authors thank the funding supported from the National Science Foundation of
China (51578110 and 51428801).
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