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Module 3 - Vapour Absorption Refrigeration System
Module 3 - Vapour Absorption Refrigeration System
➢ VARS belong to the class of vapour cycles similar to vapour compression refrigeration systems.
➢ Unlike vapour compression refrigeration systems, the required input to absorption systems is in the form of
heat.
➢ Hence these systems are also called as heat operated or thermal energy driven systems.
➢ Since conventional absorption systems use liquids for absorption of refrigerant, these are also sometimes called
as wet absorption systems.
➢ Similar to vapour compression refrigeration systems, vapour absorption refrigeration systems have also been
commercialized and are widely used in various refrigeration and air conditioning applications.
➢ Since these systems run on low-grade thermal energy, they are preferred when low-grade energy such as
waste heat or solar energy is available.
➢ Since conventional absorption systems use natural refrigerants such as water or ammonia they are environment
friendly.
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
3 Introduction
Faraday’s Experiment In 1824 Faraday conducted an experiment for liquification of
gases.
𝑵𝑯𝟑
𝑵𝑯𝟑
Absorbed
by AgCl Vaccum
Liquid 𝑵𝑯𝟑
AgCl
Powder Heat Water
C 𝑊𝑖𝑛
Evaporator 1 Evaporator
Absorber
𝑞𝑒 𝑞𝑒
𝑄𝑎 𝑎𝑡 𝑇𝑜
VCRS
VARS
𝑸𝒆
𝑪𝑶𝑷𝑽𝑪𝑹𝑺 =
𝑾𝒄
𝑸𝒆 𝑸𝒆
𝑪𝑶𝑷𝑽𝑨𝑹𝑺 = ≈
𝑸𝒈 + 𝑾 𝒑 𝑸𝒈
➢ Thus, absorption systems are advantageous where a large quantity of low-grade thermal energy is available
freely at required temperature.
➢ However, it will be seen that for the refrigeration and heat rejection temperatures, the COP of vapour
compression refrigeration system will be much higher than the COP of an absorption system as a high grade
mechanical energy is used in the former, while a low-grade thermal energy is used in the latter.
➢ However, comparing these systems based on COPs is not fully justified, as mechanical energy is more
expensive than thermal energy.
𝑻𝒆
𝑪𝑶𝑷𝑪𝒂𝒓𝒏𝒐𝒕 =
𝑻𝒄 − 𝑻𝒆
𝑸𝒆 𝑸𝒆
𝑪𝑶𝑷𝑽𝑨𝑹𝑺 = ≈
𝑸𝒈 + 𝑾 𝒑 𝑸𝒈
➢ If it is assumed that heat rejection at the absorber and condenser takes place at same external heat sink
temperature 𝑻𝒐 , then a vapour absorption refrigeration system operates between three temperature levels, 𝑻𝒈 ,
𝑻𝒐 and 𝑻𝒆 .
➢ The maximum possible COP of a refrigeration system operating between three temperature levels can be
obtained by applying first and second laws of thermodynamics to the system.
𝑄𝑒 𝑄𝑔 𝑄𝑎+𝑐
∆𝑆𝑠𝑢𝑟𝑟 = − − + ≥0
𝑇𝑒 𝑇𝑔 𝑇𝑜
Substituting the expression for first law of thermodynamics in the above equation
𝑇𝑔 − 𝑇𝑜 𝑇𝑜 − 𝑇𝑒
𝑄𝑔 ≥ 𝑄𝑒 − 𝑾𝒑
𝑇𝑔 𝑇𝑒
➢ Neglecting solution pump work, Wp; the COP of VARS is given by:,
𝑄𝑒 𝑇𝑒 𝑇𝑔 − 𝑇𝑜
𝐶𝑂𝑃𝑉𝐴𝑅𝑆 = ≤
𝑄𝑔 𝑇𝑜 − 𝑇𝑒 𝑇𝑔
An ideal vapour absorption refrigeration system is totally reversible (i.e., both internally and externally reversible).
For a completely reversible system the total entropy change (system+surroundings) is zero according to second
law, hence for an ideal VARS
∆𝑆𝑡𝑜𝑡𝑎𝑙 = ∆𝑆𝑠𝑦𝑠 + ∆𝑆𝑠𝑢𝑟𝑟 = 0
∆𝑆𝑡𝑜𝑡𝑎𝑙,𝑟𝑒𝑣 = 0, ∆𝑆𝑠𝑢𝑟𝑟,𝑟𝑒𝑣 = 0
𝑄𝑒 𝑄𝑔 𝑄𝑎+𝑐
∆𝑆𝑠𝑢𝑟𝑟 = − − + =0
𝑇𝑒 𝑇𝑔 𝑇𝑜
➢ Hence combining first and second laws and neglecting pump work, the maximum possible COP of an ideal
VARS system is given by:
𝑄𝑒 𝑇𝑒 𝑇𝑔 − 𝑇𝑜
𝐶𝑂𝑃𝑖𝑑𝑒𝑎𝑙 𝑉𝐴𝑅𝑆 = =
𝑄𝑔 𝑇𝑜 − 𝑇𝑒 𝑇𝑔
Thus, the ideal COP is only a function of operating temperatures similar to Carnot system. It can be seen from
the above expression that the ideal COP of VARS system is equal to the product of efficiency of a Carnot heat
engine operating between 𝑇𝑔 and 𝑇𝑜 and COP of a Carnot refrigeration system operating between 𝑇𝑜 and 𝑇𝑒 , i.e.,
𝑄𝑒 𝑇𝑒 𝑇𝑔 − 𝑇𝑜
𝐶𝑂𝑃𝑖𝑑𝑒𝑎𝑙 𝑉𝐴𝑅𝑆 = = = 𝐶𝑂𝑃𝐶𝑎𝑟𝑛𝑜𝑡 𝜂𝐶𝑎𝑟𝑛𝑜𝑡
𝑄𝑔 𝑇𝑜 − 𝑇𝑒 𝑇𝑔
𝑇𝑔
𝑄𝑔
E 𝑾𝑬
𝑄𝑎
𝑇𝑜
𝑄𝑐 𝐶𝑂𝑃𝑖𝑑𝑒𝑎𝑙 𝑉𝐴𝑅𝑆 = 𝐶𝑂𝑃𝐶𝑎𝑟𝑛𝑜𝑡 𝜂𝐶𝑎𝑟𝑛𝑜𝑡
𝑾𝑬 R
𝑄𝑒
𝑇𝑒
➢ Efforts are also being made to develop other refrigerant- absorbent combinations.
𝑄𝑐 𝑪 𝑄𝑔
Rectifier 𝑮
✓ Ammonia is a refrigerant and water is
absorbent
✓ Both have strong affinity to each other
✓ Two are mutually soluble for a wide range of
operating conditions
✓ Both are highly stable and compatible with
𝑄𝑎 𝑨
most of the material found in the 𝑬
𝑄𝑒
refrigeration system.
𝑾𝒆𝒂𝒌 𝑺𝒐𝒍𝒖𝒕𝒊𝒐𝒏
✓ Therefore, mechanical pump and expansion devices are 𝑄
𝑒 Evaporator pump
not required in this system.
✓ The entire cycle is done entirely by the gravity flow of the
refrigerant.
✓ Hydrogen gas-only rotates from the absorber to the 𝑵𝑯𝟑 & 𝑯𝟐 𝑯𝟐
evaporator and back.
✓ This type of machine efficiency is not important because
𝑄𝑎 Absorber
the energy input is small. Generator
𝑵𝑯𝟑 +Water
(Strong Solution) 𝑄𝑔
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
16 Electrolux / Domestic VARS
Principle. 𝑄𝑐
𝑵𝑯𝟑 𝒗𝒂𝒑𝒐𝒖𝒓
The principle involved makes use of the properties of gas- 𝑄𝑐 Condenser
vapor mixtures. If a liquid is exposed to an inert atmosphere, it
will evaporate until the atmosphere is saturated with the vapor
of the liquid. This evaporation requires heat which is taken
Bubble
𝑾𝒆𝒂𝒌 𝑺𝒐𝒍𝒖𝒕𝒊𝒐𝒏
from the surroundings in which the evaporation takes place. A
𝑄𝑒 Evaporator pump
cooling effect is thus produced. The partial pressures of the
refrigerant vapor (in this case ammonia) must be low in the
𝑵𝑯𝟑 & 𝑯𝟐 𝑯𝟐
evaporator, and higher in the condenser. The total pressure
throughout the circuit must be constant so that the only
𝑄𝑎 Absorber
movement of the working fluid is by convection currents. The Generator
𝑵𝑯𝟑 +Water
partial pressure of ammonia is kept low in requisite parts of the (Strong Solution) 𝑄𝑔
circuit by concentrating hydrogen in those parts..
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
17 Electrolux / Domestic VARS
Working.
The ammonia liquid leaving the condenser enters the evaporator and 𝑵𝑯𝟑 𝒗𝒂𝒑𝒐𝒖𝒓
𝑄𝑐 Condenser
evaporates into the hydrogen at the low temperature corresponding
to its low partial pressure. The mixture of ammonia and hydrogen
passes to the absorber into which is also admitted water from the
𝑾𝒆𝒂𝒌 𝑺𝒐𝒍𝒖𝒕𝒊𝒐𝒏
separator. The water absorbs the ammonia and the hydrogen returns Bubble
to the evaporator. In the absorber the ammonia therefore passes
𝑄𝑒 Evaporator pump
Steam Ejector
Warm Water
Condenser
Evaporator
Cooling Water
Flash Chamber
Cold Water
Water Make-up Pump
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
19 Steam- Jet Refrigeration system
➢ Steam jet ejector usage high pressure steam to generate vacuum in flash chamber.
➢ Due to vacuum generation in flash chamber water evaporates and provides cooling effect.
➢ Water evaporation also takes away water from the chamber therefore water needs to be
makeup to keep refrigeration system working.
➢ Steam of ejector is cooled at condenser and generally sent to boiler as boiler feed water.
➢ Steam jet refrigeration is widely used in paper mills, breweries, food processing plants, gas
plants etc.
➢ Because of water is used as refrigerant, it cannot be used for applications below 0°C
Disadvantages
➢ The use of direct evaporation to produce chilled water is usually limited as tremendous volume of
vapor is to be handled.
➢ About twice as much heat must be removed in the condenser of steam jet per ton of refrigeration
compared with the vapor compression system.
➢ The system is useful for comfort air-conditioning, but it is not practically feasible for water temperature
below 4℃
Compressed Air
Hot Tube
Cold Air
Hot Air
Diaphragm Chamber
Valve
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
24 Vortex Tube Refrigeration system
➢ Compressed air is passed through the nozzle as shown in figure above. Here, air expands and acquires high
velocity due to particular shape of the nozzle.
➢ A vortex flow is created in the chamber and air travels in spiral like motion along the periphery of the hot side.
This flow is restricted by the valve.
➢ When the pressure of the air near valve is made more than outside by partly closing the valve, a reversed axial
flow through the core of the hot side starts from high-pressure region to low-pressure region.
➢ During this process, heat transfer takes place between reversed stream and forward stream.
➢ Therefore, air stream through the core gets cooled below the inlet temperature of the air in the vortex tube,
while air stream in forward direction gets heated up.
➢ The cold stream is escaped through the diaphragm hole into the cold side, while hot stream is passed through
the opening of the valve.
➢ By controlling the opening of the valve, the quantity of the cold air and its temperature can be varied.
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
26 Vortex Tube Refrigeration system
Advantages
Disadvantages
➢ Its low COP, limited capacity and only small portion of the compressed air appearing as
➢ the cold air limits its wide use in practice.
reduces.
➢ Now, the supply of high-pressure gas is stopped Coolant
out Gas In
and the inlet valve is closed.
➢ The exhaust valve now opens and gas is
Coolant Gas
exhausted lowering temperature inside the tube. in Source
Coolant
Tank
Refrigeration & Air-conditioning Dr. Mukesh Sharma
Vapour Absorption Refrigeration System
32 Pulse tube Refrigeration system
➢ The air leaving the pulse tube also becomes cooler. Inlet
Valve
➢ It is possible to use this cool air to cool down hot Air
Compressor
compressed air entering the pulse tube with the
help of a heat exchanger. Air In
Gas + Air out Pulse
➢ This further lowers the temperature of the pulse Tube
Exhaust
tube. Valve
➢ Temperature as low as 190°K is achieved by the
pulse tube. Coolant
➢ Thus, a pulse tube is a preferred choice if cooling is out Gas In
➢ This technique can be used to attain extremely low temperatures (well below 1 kelvin), as well as
the ranges used in common refrigerators, depending on the design of the system.
➢ The Magneto caloric effect (MCE, from magnet and calorie) is a magneto-thermodynamic
➢ Magnets: -
Magnets are the main functioning element of the magnetic refrigeration. Magnets
provide the magnetic field to the material so that they can loose or gain the heat to the surrounding
The hot heat exchanger absorbs the heat from the material used and gives off to the
Adiabatic magnetization:
➢ The substance is placed in an insulated environment.
➢ The increasing external magnetic field (+H) causes the magnetic dipoles of the atoms to align, thereby
decreasing the material's magnetic entropy and heat capacity.
➢ Since overall energy is not lost (yet) and therefore total entropy is not reduced (according to
thermodynamic laws), the net result is that the item heats up (𝑇 + Δ𝑇𝑎𝑑 ).
Isomagnetic enthalpic transfer:
➢ This added heat can then be removed by a fluid like water or helium for example (-Q).
➢ The magnetic field is held constant to prevent the dipoles from reabsorbing the heat.
➢ Once sufficiently cooled, the magnetocaloric material and the coolant are separated (H=0).
Adiabatic demagnetization:
➢ The substance is returned to another adiabatic (insulated) condition, so the total entropy remains constant.
➢ However, this time the magnetic field is decreased, the thermal energy causes the domains to overcome
the field, and thus the sample cools (i.e. an adiabatic temperature change).
➢ Energy (and entropy) transfers from thermal entropy to magnetic entropy (disorder of the magnetic dipoles).
Isomagnetic entropic transfer:
➢ The magnetic field is held constant to prevent the material from heating back up.
➢ The material is placed in thermal contact with the environment being refrigerated.
➢ Because the working material is cooler than the refrigerated environment (by design), heat energy migrates
into the working material (+Q).
➢ Once the refrigerant and refrigerated environment is in thermal equilibrium, the cycle begins a new one.