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Lakshya JEE (2024)

Electro Chemistry DPP-02

1. The increase in equivalent conductivity of a strong 6. The variation of molar conductivity with
electrolytic solution with dilution is attributed to concentration of an electrolyte (X) in aqueous
(1) increase in number of ions per unit volume solution is shown in the given figure.
(2) increase in molecular attraction
(3) increase in degree of dissociation
(4) increase in ionic mobility

2. The equivalent conductivity of 0.1 M weak acid is

100 times less than that at infinite solution. The
degree of dissociation of weak electrolyte at 0.1 M is
(1) 100 The electrolyte X is
(2) 10 (1) HCl (2) NaCl
(3) 0.01 (3) KNO3 (4) CH3COOH
(4) 0.001
7. The resistance of 0.5 M solution of an electrolyte in
3. The molar conductivity and equivalent conductivity a cell was found to be 50. If the electrodes in the
are same for the solution of cell are 2.2 cm apart and have an area of 4.4 cm2 then
(1) 1 M NaCl the molar conductivity (in S m2 mol–1) of the solution
(2) 1 M Ba (NO3)2 is
(3) 1 M Ca (NO3)2 (1) 0.2 (2) 0.02
(4) 1 M Th (NO3)4 (3) 0.002 (4) None of these

4. Specific conductance of 0.1 M nitric acid is 8. The electrical resistance of a column of 0.05 M
6.3 × 10–2 ohm–1 cm–1. The molar conductance of NaOH solution of diameter 1 cm and length 50 cm is
solution 5.55 × 103 ohm. Calculate its molar conductivity.
(1) 630 ohm–1 cm2 mole–1 (1) 229.6 S cm2 mol–1
(2) 315 ohm–1 cm2 mole–1 (2) 129.6 S cm2 mol–1
(3) 100 ohm–1 cm2 mole–1 (3) 269.6 S cm2 mol–1
(4) 6300 ohm–1 cm2 mole–1 (4) 169.6 S cm2 mol–1

5. Equivalent conductivity of Fe2(SO4)3 is related to 9. Identify the incorrect statement(s):

molar conductivity by the expression (1) m increase with increase in temperature
(1) ⋀eq = ⋀m (2) m decreases with increase in concentration.
(2) ⋀eq = ⋀m/3 (3) Specific conductance increase with increase in
(3) ⋀eq = 3⋀m concentration.
(4) ⋀eq = ⋀m/6 (4) Specific conductance decreases with increases in
temperature.
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10. The increase in the molar conductivity of HCl with 13. 0.05 M NaOH solution offered a resistance of 31.6
dilution is due to ohm in a conductivity cell at 298 K. If the cell
(1) Increase in the self ionisation of water constant of the cell is 0.367 cm–1, calculate the molar
(2) Hydrolysis of HCl conductivity of the sodium hydroxide solution.
(3) Decrease in the self ionisation of water (1) 232.3 (2) 240.3
(4) Decrease in the interionic forces (3) 223.3 (4) 243.3

11. The value of molar conductivity of HCl is greater than 14. Mark the correct choice of electrolytes represented in
that of NaCl at a particular temperature because the graph:
(1) Molecular mass of HCl is less than that of NaCl

 m(scm mol )
(2) Velocity of H ions is more than that of Na

–1
ions.

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(3) HCl is strongly acidic A
(4) Ionization of HCl is larger than that of NaCl B

12. An increase in equivalent conductance of a strong

c1/2 (mol–1)
electrolyte with dilution is mainly due to: (1) A→NH4OH, B → NaCl
(1) Increase in number of ions (2) A→NH4OH, B → NH4Cl
(2) Increase in ionic mobility of ions (3) A→ CH3COOH, B → CH3COONa
(3) 100% ionization of electrolyte at normal dilution (4) A→ KCl, B → NH4OH
(4) Increase in both, i.e., number of ions and ionic
mobility of ions
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.

Answer Key
1. (4) 8. (1)
2. (3) 9. (4)
3. (1) 10. (4)
4. (1) 11. (2)
5. (4) 12. (2)
6. (4) 13. (1)
7. (3) 14. (4)

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