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Abstract
The Awash River, (AR) is used for different purposes such as drinking, industrial supply,
hydropower, and agriculture. These uses of the water have resulted in the rapid
deterioration of water quality. The performance of wastewater treatment plants (WWTPs)
situated with the river catchment area have been assessed together with the impact on
the surface water quality of the Awash River. The study has been completed using five
years water quality data from 5 sampling stations and wastewater data from more than
30 industries and 2 flower farms. In addition, questionnaires, interviews, and wastewater
sampling have been used to evaluate pollution causes. Most of the surveyed industries use
partially operated treatment plants and accumulated high amounts of sludge. This is due
to different reasons, including lack of facilities, poor management, limited capital, limited
technical manpower, and, poor maintenance. All these have contributed to the inefficiency
of wastewater treatment plant. Out of the 30 industries sampled, 23% of them did not
have well-constructed treatment plant and 73% of industries discharged their untreated
effluents directly into the river without treatment. Consequently, the wastewater samples
analysis showed extremely high value of EC (14,000μS/cm), TDS (10,000 mg/L) and EC
(12,030 μS/cm), TDS (8,060 mg/L) were seen in the first and second survey respectively. In
line with these, the five years of spatial and temporal physico-chemical trend data also
showed an increasing pollution in the river system. Based on this investigation, it is
possible to conclude that the untreated industrial wastewater disposal and agricultural
runoff strongly degraded the quality of the AR. Thus, it is time to make urgent
improvements to deal with the poor performance of WWTPs and to limit the untreated
waste being discharged into the river system.
Key Words: Inefficient Treatment Plant, Untreated Waste Disposal, Effluents, Source of
degradation
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Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
Lake Abbie, which has a basin area of 30°C at Dubti. Akaki and Modjo Rivers are
113,467 Km2. The mean annual rainfall the major tributaries situated in the study
over the entire western catchment is 850 area and received untreated domestic and
mm and in Awash-Awash sub-basin is industrial waste from different industries
600mm. The mean annual temperature in and towns that are carried into the main
Addis Ababa is 16.7°C compared to nearly river (Table 1 and Fig 1a and1b).
Fig. 1a: Map of Surveyed Industries in Upstream Koka Fig. 1b: Map of Sampling Stations (Study Area)
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Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
Table 2: The water quality parameters and their analytical method in this study
Parameters Units Instruments/Apparatus
pH Unit less Z-WAG-WE 30020 pH/Temperature
EC μS/cm 5 Series Portable Conductivity/TDS/Salinity meter
TDS mg/L 5 Series Portable Conductivity/TDS/Salinity meter
TH mg/L Titration with 0.05 N EDTA
Mg2+, Ca2+ mg/L Titration with 0.05 N EDTA
Na+, K+ mg/L Flame Photometer
Fluoride, F- mg/L Spectrophotometer HACH
Chloride, Cl- mg/L Titration using 0.014 N AgNO3 (Argentiometric)
Alkalinity mg/L Titration with 0.01 N H2SO4
Bicarbonate, HCO3 - mg/L Titration with 0.01 N H2SO4
Ammonia, NH3 mg/L Spectrophotometer Hach Company
Nitrate, NO3 - mg/L Spectrophotometer Hach Company
Sulfate, SO4 2- mg/L Spectrophotometer Hach Company
Phosphate, PO43- mg/L Spectrophotometer Hach Company
DO mg/L Azide modification Water proof Hand-held DO 300 meter
BOD mg/L Azide modification Water proof Hand-held DO 300 meter
COD mg/L APHA 5220B. Open Reflux Methods
N.B Salinity % 5 Series Portable Conductivity/TDS/Salinity meter
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
(Mg2+), nitrate (NO3-), bicarbonate the river water qualities with regard to the
(HCO3-), and Phosphate (PO43-) showed an above-mentioned parameters had fallen
increasing trend in almost all sites over the from the slight to moderate degree of
past 5 consecutive years. Thus, the trend deterioration; the same findings were also
analysis obtained in Table 3 indicate that reported by AAiT (2016)
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Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
EC in μS/cm
TDS in mg/L
14,120
13,390
6,340 2,270
4,650
1,580
In order to assess the pollution load of very high concentration of conductivity and
industrial liquid waste, wastewater samples total dissolved solids. The highest EC
were collected in two rounds before they (12,030μS/cm) and TDS (8,060 mg/L)
entered into the surrounding water bodies values were recorded in Friendship and
(Modjo and Akaki Rivers), from November Hora tanneries in Modjo town (Fig. 3).
01-10/ 2016 (Fig. 2), and from June 02- Correspondingly, EC recorded in Colba
06/2018 (Fig. 3). Figures 2 and 3 show Tannery 13,390 μS/cm in fig. 2 and 10,720
results of wastewater analysis, high values μS/cm in fig. 3, and Friendship Tannery
of EC (14,120μS/cm) and TDS (10,000 6650μS/cm in fig. 2 and 6460μS/cm in fig.
mg/L) were recorded at Gelan Tannery and 3. This might be due to the poor
the lowest values of EC (2,270 μS/cm) and management of salt used to preserve
TDS (1,580 mg/L) were observed at Luna rawhide and skin which was found to be
ISAH. washed away as effluents (Zeleke, 2011).
The wastewater analysis result shows This is an indicative of the pollution load of
that almost all sampled effluents exhibited industrial wastewater on water bodies.
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
1630
SWA 2020 TDS EC
1630
MSD 2430
1201
SSD 1910
4400
FrT 6460
8060
FeT 12030
7340
BaT 10960
7200
CoT 10720
8060
HoT 12030
4820
NAT 7160
According to Nadia (2006) discharge of salinity was 0.09% recorded. This might
wastewater with a high TDS level would indicate that most of the surveyed industries
have adverse impact on aquatic life, released untreated (partly treated) and
rendering the receiving water unfit for highly saline wastewater into the
drinking and domestic purposes, and reduce neighbouring water bodies.
crop yield if used for irrigation. Figure 3 The discharge of effluent from
reflects the pollution strength of the wastewater treatment plants (WWTPs) has
wastewater and the practice of very poor major detrimental effects on the health of
liquid wastewater management existence in aquatic ecosystems. Waste from WWTPs
the surveyed industries and there has also outfall can deposit large amounts of organic
been no significant improvement in matter and nutrients into the receiving water
wastewater management in most surveyed bodies (Steven et al., 2008; Alexandera and
industries in the last 2 years. As seen in Fig. Jeroen, 2006). Due to rapid industrialization
2, 3, & 4 the chemical composition of the new chemical compounds are continuously
wastewater discharge varied from industry being developed and brought to the market
to industry. Some industries discharge hard and sooner or later they will emerge into the
wastewater with a pH value range 7.6 to 8.2 aquatic systems (Harikishore et al., 2012).
and soft wastewater with a pH value range During the time of the visit, the physical
6.7 to 7.5 and some others above these range observation of the Modjo River indicated a
8.58 and 10.14 were recorded (Sulaiman et high level of pollution downstream of the
al., 2016). The total hardness exhibited in point sources with an unusual smell, highly
NAT, HoT, CoT, BaT, and FeT was 370 colored (black), turbid, and the river water
mg/L, 500 mg/L, 410 mg/L, 380mg/L and showed a high salinity hazard (EC, 2606
200 mg/L respectively. In fig. 4 the highest μS/cm and TDS, 1689 mg/L) and the water
salinity value 0.66% and the lowest value of became unsuitable for various uses.
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Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
12 0.7
10 0.6
0.5
8
pH values
0.4
6
0.3
4
0.2
2 0.1
0 0
NAT HoT CoT BaT FeT FrT SSD MSD SWA
pH 8.58 7.98 7.65 7.42 6.75 7.12 8.58 10.14 7.95
Salinity 0.33 0.66 0.51 0.52 0.58 0.3 0.09 0.11 0.1
However, farmers surrounding the the AR. Among these, Red-Fox Flower,
river were pumping polluted water from Syngenta, Flourensis Abyssinia and other
the river Modjo. Remarkably farmers International flower farms are found near
knew that the water was polluted, but still to the AR and Koka dam and also used the
used it as a source of water for their farms. river water for flower farming. However,
Moreover, they knew vegetables grown in the wastewater effluents of the industries
this polluted water would be harmful to were discharged back to the AR and Koka
health, but used it as a source for farming dam without proper treatment. However,
as there were no other alternative water the remaining salty water that consists of
sources in their areas (Selamawit, 2008). high EC value was discharged into
Similarly, farmers near Trunesh Beijing wetlands or/and into the AR. Water that is
Hospital were pumping the river water drained from these farms consists of
from little Akaki and some farmers who fertilizers, insecticides, and pesticides that
farm at the back of Eastern Industrial Zone when discharged into the river, degrade
(i.e Dukem town) used wastewater the water quality of the river. Some
discharged from Eastern Industrial Zone insecticides, like DDT are particularly
for irrigation purposes. dangerous when allowed to enter into
In addition to the above itemized and bodies as they result in increased
unlisted industries, agricultural activities concentrations along the food chain (Owa,
such as horticulture and floriculture might 2014).
affect the water quality and causes serious Organic Matter (DO, BOD & COD)
pollution in nearby water bodies due to the Analysis
usage of fertilizers and pesticides Organic matter water samples were
(Shunthirasingham, et al., 2010; Brown, et collected from 4 sampling to assess the
al., 2009). There are a number of existing water quality of organic matter
floriculture and horticulture farms around load in the stations situated at the
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
upstream of Koka. All sampling sites (i.e from the tannery discharge, BOD is
SATB, SAZR, SMDF, & SAKD) revealed directly and indirectly affected by the
dissolved oxygen (DO) below 3 mg/L presence of toxic metals (Mittak and
which is very detrimental to most aquatic Ratra, 2000).
organisms. For instance, DO in the Modjo In addition to the above SW stations,
River, MR downstream of the factory was samples also collected from industrial
nil. The low level of DO was due to the point sources (Fig. 5). All sample showed
discharge of industrial effluents and the a higher COD level than WHO limit
toxicity of the combined effects of (2008). Water with high COD value in the
chemical and heavy metals (Jonathan et MR station downstream of the factory also
al., 2008). Biological oxygen demand indicates the presence of inadequate
(BOD) value varies from 3 mg/L in the oxygen in the water samples. In the same
great Akaki River near Trunesh Bejing station, (MR) high values of BOD, 63
Hospital to 63 mg/L at the Modjo River. mg/L and COD, 200 mg/L were recorded.
The concentration of BOD obtained in the According to Anil (2017) less than 20
Modjo River was high due to the industrial mg/l is the recommended (BIS limit) limit
discharge of untreated wastes from of COD for inland waters. In general, the
tanneries and slaughter houses that high values of BOD and COD show high
contained extra organic loads. Due to the amount of untreated wastewater
presence of toxic metal like chrome (VI) discharged into the MR.
using Logarithmic scale
10000
1000
100
10
1
0.1 pH EC TDS DO BOD COD
Similarly samples were taken from the than biologically oxidized. This includes
industrial WW discharge points before chemicals toxic to biological life, which
entering the river and hence the result of can make COD tests very useful when
EC, DO, COD and BOD value exhibited testing industrial sewage as they will not
indicates that the IWW drained into the be captured by BOD testing. The higher
rivers was poorly treated (seems the BOD/COD the more oxygen stripping
untreated) which has a profound influence capacity the discharged effluent has when
on the receiving water bodies. As seen in discharged into receiving waters (oxygen
Fig 5, COD is high; normally its value is is used biologically/chemically to break
higher than BOD due more organic down the organic matter) and the more
compounds can be chemically oxidized potential for damage to biological life in
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Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
those waters. As seen in the above figure WHO limit (Fig 6). In this study the value
the maximum ratio of BOD:COD was of Cr+6 ranged maximum 0.22 mg/L in
54.73 in East Africa Tannery while the BaT and minimum 0.09 mg/L in FeT. Cr-
best ratio exhibited 3.44 in Luna ISAH. VI is the most toxic form of chromium and
Astonishingly most of the surveyed having equivalent toxicity to cyanides. It
industries΄ treatment plant and facilities can cause skin ulcer, convulsions, kidney
were not working properly and regularly and liver damage. The toxicity of
during the visit. It was also observed that chromium through drinking water is the
in most of the industries the willingness to major problem for human health (Javaid
show the treatment plant was a deliberate and Chaudhary, 2008). It has also been
act. During the time of observation, most reported that intensive exposure to Cr
observed industries did not have a compounds may lead to lung cancer in
wastewater quality laboratory, and most man (Jordao et al., 2002). In addition to
industries did not have efficient this the concentration of sulfide varies
wastewater treatment plants. This from 0.01mg/L (HoT) to 0.5mg/L (BaT).
indicated that the existing wastewater The level of sulfide at BaT was high; the
management systems of most industries noxious odor of the river Modjo water
are poor. Yet, some industries like Silva might be due to the high sulfide values
water bottling; BJI, Heineken, and Meta being there.
Abo Breweries were working relatively The Current Status of Wastewater
better than the others. However, in most of Treatment Plants
the surveyed industries poor screening of The wastewater generated from all
solids, sewer collection systems and surveyed industries was disposed into
sludge management were observed. neighboring water bodies without proper
Based on the results of observation treatment. The following questions were
and interview, it is concluded that lack of distributed to a selected sample of
facilities, ownership and capital, technical respondents on the existing performance
manpower, poor maintenance and and efficiency of the wastewater treatment
capacity of experts, lack of responsibility plant, wastewater dumping area, and
and other reasons, resulted in inefficient wastewater management systems of the
treatment in most industries. This idea is industries. Accordingly, respondents were
supported by Zeleke (2011) the tannery asked to give their opinions on whether
wastewater treatment plant performance “experts in environmental protection
efficiency monitoring system was weak. authority (EPA) have done much on
Thus, they discharged their wastewater industrial waste management problems”
without proper treatment and polluted the (item number 1). As seen in figure 6, out
receiving water bodies. of the interviewed respondents, 63.3%
Cr (III) is essential nutrient for animal replied that there had been no work done
and essential to ensure human and animal by the EPA. In contrast, 36.7% of
lipids’ effective metabolism but Cr (VI) is respondents agreed that EPA experts tried
carcinogenic. Out of surveyed industries to create awareness of the industrial waste
on june-2018, samples were taken from management system.
five tanneries wastewater discharged into
the river and the result showed beyond the
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
the waste of
discharged?
industries
to lagoon
to soil
to river
the problem of the
Item 2. What do
All
industrial waste
you think about
industries not
management
systems?
Poor control of regular bodies
Lack of professionals
Lack of capital
With regard to item number 2, “Why Akaki River and three more disposed of it
do you think industries do not apply into its tributaries, while the rest disposed
proper industrial waste management of their liquid waste into the open drainage
systems?”, 60% of respondents replied of the city.
that it was due to lack of capital, 13.3% In addition, respondents were also
due to lack of professionals, 13.3% due to asked their opinions on how the industries
lack of poor control of regulatory bodies treat the effluents (item 4; Fig 7).
and the remaining 13.3% due to lack of Accordingly, in number 12 or 40% of
professionals and capital, poor control of respondents were agreed that their
regulatory bodies and carelessness or poor industries discharged well and adequately
practices of the management systems (Fig. treated wastewater into water bodies. On
6). This is supported by Selamawit, (2008) the contrary, 60% of respondents replied
the problem of industrial waste is not that their industries did not treat their
properly investigated because of a lack of wastewater well and enough. A study on
awareness and technology. effluents of selected industries in and
To know where industries discharge around Addis Ababa indicated that all the
their industrial waste, the question of industries generate wastes that carry
"Where is the waste from industries pollutants which are beyond the
discharged? (Item 3) was raised to the internationally accepted pollution
respondents. Accordingly, 73.3% of standards (UNIDO & ESID, 2001).
respondents replied that their industries Concerning the question on the status of
discharged wastewater into the river, 10% wastewater discharge by the industries
replied that they discharged into the closed (Item 5, Fig. 8), 43.3% of respondents
valley, 10% replied that they discharged replied that their industries discharge
into lagoons and the remaining 6.7% partly treated waste, 26.7% agreed that
agreed that they discharged their their industries discharge untreated
industries effluent into land (Fig. 6). wastewater and 30% responded that they
Ghirmay (2000) indicated that ten discharge properly treated wastewater into
industries out of twenty-five disposed of the River.
their untreated wastewater into little
386
Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
Response in Percent
100%
50%
0%
Yes No Yes No Yes No
Item 1. In your opinion Item 4. Do you believe Item 7. Do you have
has the EPA done much that your industry treat permanent & regular
about industrial waste effluents well & enough? treatment programs?
Fig. 7: The respondents΄ view with regard to the wastewater treatment plant efficiency
With regard to the treatment method courses, open spaces, canals, streams, and
used prior to the discharge of industry’ lagoons. Similarly, (in item 7 Figure 7),
waste (Item 6), about 46.3% of 63% of respondents replied that their
respondents replied that they discharged industrial treatment plants didn’t work
primarily treated wastewater (i.e regularly due to problems associated with
sedimentation, coagulation, and maintenance, power interruptions, and
flocculation takes place using chemical lack of facilities. Other findings also
like coagulants) into the environment, indicated that lack of a power supply
26.7% agreed that they released hinders water and wastewater treatment to
secondarily treated wastewater into the a great extent in Africa (Wang et al.,
water bodies, 23.3% responded that they 2012). The remaining 36.7% agreed that
discharge preliminarily treated their treatment plants were working
wastewater (i.e removal of heavy regularly. This was also confirmed by
inorganic solids such as sand, gravel, large other scholars indicating most of the
suspended or floating solids, coarse of industries didn’t manage their wastes
screening) and the remaining (6.7%) properly (Selamawit, 2008;
responded that their industries discharge WHO/FAO/IWMI/IDRC/CRDI, 2010).
tertiary treated wastewater into the With regard to the result of the
environment and water bodies (Fig. 8). interview, farmers who lived adjacent to
Industrial wastewater needs to be the industries at the Modjo River
adequately treated prior to its disposal or expressed their feelings that the pollution
reuse in order to protect the receiving level of the river was dramatically
water bodies from contamination increasing from year to year over the last
(Edokpayi et al., 2015). Yet, especially in 10 years due to the expansion of industries
Modjo town, out of the surveyed around the river. However, farmers
industries, 87.5 % of tanneries, slaughter surround the Modjo River after
and abattoir houses, and textile and downstream of factory were pumping
garment industries discharge their polluted water from the river at the time of
industrial wastewater without applying the sampling was made with high salinity
proper treatment into the adjoining water hazard (high TDS & EC). They agreed
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
that the use of untreated wastewater for Similar thought was reflected by farmers
irrigation purpose can affect the land and studied by Shobha (2004) in Tunisia.
its value of productivity in the long term.
50%
45%
Respondents In Percentage
40%
35%
30%
25%
20%
15%
10%
5%
0%
Properly Partly treated Untreated Primary Secondary Tertiary Preliminary
treated waste waste waste treatment treatment treatment treatment
Item 5. What is the current status of your Item 6. Which treatment method does your industry
industry on discharging wastewater? use prior to discharging of wastewater?
Fig. 8 The respondents΄ view with regard to the treatment methods and status
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Ethiopian Journal of Environmental Studies and Management Vol. 13 no.3 2020
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Assessment on the Performance of Wastewater Treatment Plants................Yosef et al.
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