Molecular mass of SO, = 80 Vapour density of S0},0= 5? = 40 ‘Vapour density of mixture, d= ie, 34.174 Let the degree of dissociation be x Dad | 40~34.174 | 5.826x2 ret 74. 5.826%2 9.34 = e Nes 34174 2) or x= 34% dissociated hue, SO, is 34% dissociated. Example 22. Densiy of equilibrium mixture of NO, and NO; at Vatm and 384K is 184 g dm”, Calculate the ‘equilibrium constant of the reaction. N,0, =2N0, ‘We know that, P= dRT 1x m= 1.84 0.0821 384 m=29x2 Vapour density (dat equilibrium = 29 Initial vapour density = M/2= 92/ 2= 46 D-d _ 46-29 “G-pd N:0, = 2NO, Solution: = 0.586 4p _ 4 (0586)? x1 1-2 1-(0.586)" Example 23. For the reaction, NII(@) —4Nite)+3H(8) ‘show that degree of dissociation of NH is given as: “| where, °p'is equilibrium pressure. IK, ofthe above reaction is 78.1 atm at 400°C. calculate K . Solution: 7 =209atm Nay) 2 4N> + ZHaGe) Tout moles eo ° ° 1 ea at sa? tea fie {3a 2 eth Geol (ital ana Te)?” ea) (ats ey GRLB, PHYSICAL CHemistrY FoR COMPETITIONS int? tH? * | Solving for c., we get ae K, K, = 781;T = 673K; dn=1 Example 24. The equilibrium constant Ky for the reaction, Ny + 3H —*2NH, is 1.64 x 10 at 400°C and 0.144 x 10 at 00°C. Caleulate the ‘mean heat of formatign of | mole of NH from its elements in his temperature range. AH L Solution: Wetnow tha fg A= AH 3) ald Zs) 2.303 x 1.987x 10 (673773, AH =~25.14 kcal for 2 mole 12.57 kcal mol”! . ‘Example 25. When limestone is heated, quicklime is Jormed according to the equation, CaCOy(s) = CaO(s)+ C0; (8) The experiment was carried out in the temperature range '800--900°C. Equilibrivm constant K , follows the relation, log K, = 7.282- 8500/7 where, T is temperature in Kelvin. At what temperature she decomposition will siveCOs(g) at 1 atm? Solutions 994.26°C Example26. Equilibrium constant for the reaction of ‘iodine with propane according to the following equation was determined. ‘Some results obtained at $45 K were as given ahead: