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SAFETY DATA SHEET Revision Date: 11/15/2021

Print Date: 8/30/2023
SDS Number: R0001171
SULPHAMIC ACID Version: 1.4

941146

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : SULPHAMIC ACID

Product code : 941146

Company : Solenis (Shanghai) Chemicals Co., Ltd.
688 Shen Fu Road, Xin Zhuang Industrial Zone
Post code: 201108
Shanghai
China

E-mail address : EHSProductSafetyTeam@solenis.com

Telephone : +86-21-54422323

Telefax : +86-21-54421739

Emergency telephone number : 0532 8388 9090

Use of the Substance/Mixture : Industrial chemical

2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance : crystalline
Colour : white
Odour : odourless
May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Harmful to
aquatic life with long lasting effects.
GHS Classification
Acute toxicity (Oral) : Category 5

Skin corrosion/irritation : Category 2

Serious eye damage/eye : Category 2A

irritation

Short-term (acute) aquatic : Category 3

hazard

Long-term (chronic) aquatic : Category 3

hazard

GHS label elements

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SAFETY DATA SHEET Revision Date: 11/15/2021

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SDS Number: R0001171
SULPHAMIC ACID Version: 1.4

941146

Hazard pictograms :

Signal word : Warning

Hazard statements : H303 May be harmful if swallowed.

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements
:
Prevention:
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P312 Call a POISON CENTER/ doctor if you feel unwell.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Physical and chemical hazards

Not classified based on available information.
Health hazards
May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation.
Environmental hazards
Harmful to aquatic life. Harmful to aquatic life with long lasting effects.
Other hazards which do not result in classification
None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Substance name : sulphamidic acid; sulphamic acid; sulfamic acid

CAS-No. : 5329-14-6

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SAFETY DATA SHEET Revision Date: 11/15/2021

Print Date: 8/30/2023
SDS Number: R0001171
SULPHAMIC ACID Version: 1.4

941146

Components
Chemical name CAS-No. Concentration (% w/w)
SULFAMIC ACID 5329-14-6 >= 90 -<= 100

4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled : If breathed in, move person into fresh air.

If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact : Remove contaminated clothing. If irritation develops, get

medical attention.
If on skin, rinse well with water.
Wash contaminated clothing before re-use.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Protect unharmed eye.

If swallowed : IF SWALLOWED: Call a POISON CENTER/ doctor if you feel

unwell.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Most important symptoms : May be harmful if swallowed.

and effects, both acute and Causes skin irritation.
delayed Causes serious eye irritation.
Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
irritation (nose, throat, airways)
Cough
Shortness of breath
lung edema (fluid buildup in the lung tissue)
Pulmonary edema may be delayed.

Notes to physician : No hazards which require special first aid measures.

5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
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SAFETY DATA SHEET
SULPHAMIC ACID
941146
Unsuitable extinguishing
media
Specific hazards during
firefighting
Hazardous combustion
products
Specific extinguishing
methods
Special protective equipment :
for firefighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
Environmental precautions
Methods and materials for
containment and cleaning up
Prevention of secondary
hazards
7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion
Advice on safe handling
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Revision Date: 11/15/2021
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SDS Number: R0001171
Version: 1.4
: High volume water jet
: Organic dusts at sufficient concentration can form explosive
mixtures in air.
Do not allow run-off from fire fighting to enter drains or water
courses.
: acid vapors
Ammonia
sulfur oxides
Nitrogen oxides (NOx)
: Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Product is compatible with standard fire-fighting agents.
In the event of fire, wear self-contained breathing apparatus.
: Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
: Keep in suitable, closed containers for disposal.
: Comply with all applicable federal, state, and local regulations.
: Avoid dust formation.
Take measures to prevent the build up of electrostatic charge.
Provide appropriate exhaust ventilation at places where dust
is formed.
: Avoid dust formation.
Do not breathe vapours/dust.
Do not smoke.
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SAFETY DATA SHEET
SULPHAMIC ACID
941146
Avoidance of contact
Storage
Conditions for safe storage
Further information on
storage stability
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Engineering measures
Personal protective equipment
Eye/face protection : Safety glasses
Skin and body protection
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Revision Date: 11/15/2021
Print Date: 8/30/2023
SDS Number: R0001171
Version: 1.4
When diluting, always add the product to water. Never add
water to the product.
Container hazardous when empty.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.
: Chlorine
strong bases
strong mineral acids
Strong oxidizing agents
: Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
No smoking.
Electrical installations / working materials must comply with
the technological safety standards.
: Keep in a dry place.
No decomposition if stored and applied as directed.
: Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.
Provide appropriate exhaust ventilation at places where dust
is formed.
: Wear as appropriate:
Safety shoes
Wear resistant gloves (consult your safety equipment
supplier).
Wear as appropriate:
Safety shoes
Dust impervious protective suit
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
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SAFETY DATA SHEET Revision Date: 11/15/2021

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941146

Discard gloves that show tears, pinholes, or signs of wear.

Hand protection
Material : polyvinyl chloride

Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves.

Hygiene measures : Avoid breathing dust.

Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : crystalline

Colour : white

Odour : odourless

Odour Threshold : No data available

pH : 0.4 - 2.0

Melting point/freezing point : 205 °C

Boiling point/boiling range : 401.0 °F

(1013 hPa)

Flash point : Not applicable

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Self-ignition : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : ca. 0.25 Pa (100 °C)

Relative vapour density : No data available

Relative density : ca. 2.115 (77.00 °F)

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SAFETY DATA SHEET Revision Date: 11/15/2021

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SDS Number: R0001171
SULPHAMIC ACID Version: 1.4

941146

Density : ca. 2.115 g/cm3 (25 °C)

Bulk density : 74.92 kg/m3

Solubility(ies)
Water solubility : soluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Oxidizing properties : No data available

Molecular weight : 97.1 g/mol

10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : Stable under recommended storage conditions.

Possibility of hazardous : Product will not undergo hazardous polymerization.

reactions

Conditions to avoid : excessive heat

Keep away from heat, flame, sparks and other ignition

sources.

Incompatible materials : Chlorine

strong bases
strong mineral acids
Strong oxidizing agents

Hazardous decomposition : acid vapors

products Ammonia
Nitrogen oxides (NOx)
Sulphur oxides

11. TOXICOLOGICAL INFORMATION

Acute toxicity
May be harmful if swallowed.
Product:
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SAFETY DATA SHEET Revision Date: 11/15/2021

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SDS Number: R0001171
SULPHAMIC ACID Version: 1.4

941146

Acute oral toxicity : LD50 (Rat): 3,160 mg/kg

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Method: OECD Test Guideline 402
GLP: yes
Assessment: Not classified as acutely toxic by dermal
absorption under GHS.

Components:

SULFAMIC ACID:
Acute oral toxicity : LD50 (Rat): 3,160 mg/kg

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Method: OECD Test Guideline 402
GLP: yes
Assessment: Not classified as acutely toxic by dermal
absorption under GHS.

Skin corrosion/irritation
Causes skin irritation.
Product:
Result : Severely irritating to skin

Remarks : May cause skin irritation and/or dermatitis.

Components:

SULFAMIC ACID:
Result : Severely irritating to skin

Serious eye damage/eye irritation

Causes serious eye irritation.
Product:
Result : Irritating to eyes

Remarks : Product dust may be irritating to eyes, skin and respiratory

system.
Causes serious eye irritation.

Components:

SULFAMIC ACID:
Result : Irritating to eyes

Respiratory or skin sensitisation

Skin sensitisation
Not classified based on available information.

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SAFETY DATA SHEET Revision Date: 11/15/2021

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SULPHAMIC ACID Version: 1.4

941146

Respiratory sensitisation
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Product:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative

Components:

SULFAMIC ACID:
Genotoxicity in vitro
: Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative

Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information

Product:
Remarks : No data available

12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

SULFAMIC ACID:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 70.3 mg/l
Exposure time: 96 h
Test Type: static test
Method: OECD Test Guideline 203

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SAFETY DATA SHEET
SULPHAMIC ACID
941146
Toxicity to daphnia and other :
aquatic invertebrates
Toxicity to algae/aquatic
plants
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological
information
13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
Contaminated packaging
14. TRANSPORT INFORMATION
International Regulations
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SDS Number: R0001171
Version: 1.4
EC50 (Daphnia magna (Water flea)): 71.6 mg/l
Exposure time: 48 h
Test Type: semi-static test
Method: OECD Test Guideline 202
: EC50 (Desmodesmus subspicatus (green algae)): 48 mg/l
End point: Growth inhibition
Exposure time: 72 h
Test Type: static test
Method: OECD Test Guideline 201
NOEC (Desmodesmus subspicatus (green algae)): 18 mg/l
End point: Growth inhibition
Exposure time: 72 h
Test Type: static test
Method: OECD Test Guideline 201
: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Harmful to aquatic life with long lasting effects.
: The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
: Empty remaining contents.
Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.
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SAFETY DATA SHEET Revision Date: 11/15/2021

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941146

IATA-DGR
UN number : UN 2967
Proper shipping name : Sulphamic acid
Class : 8
Packing group : III
Packing instruction (cargo : 864
aircraft)
Packing instruction : 860
(passenger aircraft)
IMDG-Code
UN number : UN 2967
Proper shipping name : SULPHAMIC ACID
Class : 8
Packing group : III
EmS Code : F-A, S-B
Marine pollutant : no

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

GB 6944/12268
UN number : UN 2967
Proper shipping name : SULPHAMIC ACID
Class : 8
Packing group : III
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

15. REGULATORY INFORMATION

National regulatory information

Regulations on Safe Management of Hazardous Chemicals in China (Decree 591)
List of dangerous goods GB12268-2012
Classification and code of dangerous goods （GB6944-2012）
General rules for preparation of chemical safety data sheet （GB/T 16483-2008）
Guidelines for the preparation of chemical safety data sheets (GB/T 17519-2013)

Regulations on Safety Management of Hazardous Chemicals

Catalogue of Hazardous Chemicals : Listed

The components of this product are reported in the following inventories:

TCSI : On the inventory, or in compliance with the inventory

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941146

TSCA : All substances listed as active on the TSCA inventory

AICS : On the inventory, or in compliance with the inventory

DSL : All components of this product are on the Canadian DSL

ENCS : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

16. OTHER INFORMATION

Further information
Date format : dd/mm/yyyy

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No
Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines
Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity
Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

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SAFETY DATA SHEET Revision Date: 11/15/2021

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SDS Number: R0001171
SULPHAMIC ACID Version: 1.4

941146

Sources of key data used to compile the Safety Data Sheet

Key literature references and sources of data
SOLENIS Internal data
SOLENIS internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for
labelling (GHS) and transport.

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text. This SDS has been prepared by
the Solenis Environmental Health and Safety Department.

CN / EN

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