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Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 1 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
that exceeds U.S. output, according to a survey conducted Sand; still used as blasting abrasive media in the Middle
by the U.S. Geological Survey (USGS). East, it produces high levels of dust and contains high level
It is produced by processing beach sand and grading to of contaminants such as chloride; It generally does not
exact specifications. Due to its low free silica, garnet produce a good surface profile as other abrasives. More
abrasive is widely used in sand/grit blasting and now importantly, its use is banned in most industrial countries
widely popular for water jet cutting. Garnet is cost effective, due to its connection with silicosis, a lung disease caused
environmentally and operator friendly, alternative to silica by inhaling dust that contains silica, which is found in high
sands and minerals slags and will provide a class Sa3 White level in sand. Sand is found in huge quantities in Egypt and
Metal surface finish. Garnet particles are dense, hard and the studied samples were collected from Ismailia and
sharp and free of heavy metals or toxic components. The Salhyea which has a good reserve utilized by private sector
low friability of garnet permits recycling up to 5 times and for construction projects.
the relatively high density ensures fast blasting speeds White sand; Zafarana white silica ore reserves are huge
(Dev International abrasive - www.indiamart.com). [3] and exceed billions of tons and the deposit has little or no
The United States is the world's largest consumer of overburden and it’s exposed in extensive areas. Many
industrial garnet, accounting for 25% to 35% of global active quarries operated by public and private sector firms
consumption as per (Ronald F. Balazik, 1997); [4] the are operating in Abu Darag and Wadi Dakhal near Zafarana
consumption of industrial garnet in U.S. was estimated on the Red Sea coast. The sand mainly composed of SiO2
about 65,000 tons in 1997. which ranging from 99.2 to 99.5 % (Gaber M. AW, 2012). [5]
Garnet occurs worldwide in many rock types, Ilmenite ore occurs with huge reserve in Wadi Abu
principally gneisses and schists, other sources include Ghalaga in the south part of the Eastern Desert, the area
contact metamorphic rocks, crystalline limestone, comprises the Eastern portion of Hamata sheet, 30 km of
pegmatite and serpentinites. Additionally, garnet is found Red Sea and 100 km south Marsa Alam, the ore deposits of
near veins formed at high temperatures. Alluvial garnet is Wadi Abu Ghalaga includes two main parts, the eastern
associated with heavy mineral sand and gravel deposits in part composed of metavolcanics and the Western part
many parts of the world. composed of ilmenite deposit surrounded by gabbroic
In addition to the United States, significant quantities of rocks, the specific gravity ranging from 3.8 to 4.4 gm/cm³
industrial grade garnet are mined in several countries (Mahmoud Ibrahim, 2011). [6]
abroad. The most significant foreign producers are Ilmenite grains were found on the Al Aresh Beach and
Australia, India and China; other producers include the Rashied area along sea coast in black sand, meanwhile the
Czech Republic, Pakistan, Russia, Turkey and the Ukraine. Egyptian Nuclear Materials Authority separate the grains of
Estimates of total output by all producers’ worldwide range ilmenite and garnet to be utilized in industrial work.
from 180,000 tons to 250,000 tons, but probably is not
much greater than 200,000 tons. Total global supply is EXPERIMENTAL
roughly divided among markets as follows: blasting media, Forty samples of blasting abrasive nonmetallic ores were
45%; water filtration, 25%; abrasive powders, 10%; water collected from different brand names and subjected to
jet cutting, 10%; and other uses, 10%. many tests to assessment the physical and chemical
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 2 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
Table 3: Physical Properties Standard of Natural Ores Used as Abrasive Media (SSPC-Vol. 1, 2003) [7]
Hardness Shape Specific Gravity Free Silica Degree of Dust Reuse Color
sand silica 5 Rounded 2-3 90 + high Poor white
sand heavy mineral 5 –7 Rounded 3-4 <5 medium Good variable
Flint 6.5-7 angular 2-3 90 + medium Good grey- white
Garnet 7–8 angular 4 nil low Good 5 pink
Ilmenite 7 angular 4.4 < 30 medium Good black
Zircon 7.5 cubic 4.5 nil low Good white
properties comparing with standard of metal surface using these tools Bronze cylinder, Balance, Oven. The
preparation requirements procedure to determine the free flow as follows:
Weigh a 50 gram of abrasive into the bronze cylinder
Chemical Analysis with the solid cap on the bottom end. Fill the cylinder with
The chemical analysis for different abrasive media includes water and allow the abrasive to soak for 1 hour. Screw the
sand, garnet, ilmenite and white sand was carried out to hole bearing cap onto the top end of the cylinder, invert,
determine the major constituents which affect the hardness remove the solid cap and allow the water to drain through
and specific gravity, also to check the presence of the holes. Place the cylinder in horizontal position in an
detrimental matters and corrosion constituents and oven at 120°C for 3 hours, then cooled to room
adhesion impairing contaminants. temperature and inclined the cylinder to an angle 75° so
the abrasive can flow freely by gravity. The abrasive shall
Physical Properties be collected and weighted to determine compliance with
There are many physical properties shall be characterize the original weight (Military specification, 1997). [13]
the blasting abrasive media to achieve the required surface
preparation of metallic surface, a numerous of standard 4. Conductivity
state the range of physical properties as illustrated in Table The conductivity shall be less than 290 micro Siemens per
2 and Table 3. square centimeter (micromhos/cm) as per MIL-A-2226 2B,
1993 [14] and shall be less than 150 µS/cm² as per
1. Particle Size Distribution Petroleum companies painting specifications and shall be
Grain size distribution plays an important role in the use of measured in accordance to ASTM D 4940, 1998 [15] and (ISO
blasting abrasive grains as an abrasive media to clean the 11127-6, 1993). [16]
rusted steel surface as per (B.S 410, 2000). [8] The
mechanical analysis was carried out by sieving method 5. Oil Content
with different screen size as per ISO 11127 -2, 1993 [9] and The oil content in the abrasive material shall be less than
Gamal El Din, 2012. [10] 0.030 % by weight.
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RESEARCH ARTICLE
Peak to trough
Table 4: Typical Surface Profile of Some Nonmetallic Abrasive Media (SSPC volume 1, 2003) [7]
Abrasive Media Maximum U. S Sieve Size Average Profile (mils) Average Profile (µm)
Garnet 30/60 1.97 – 2.95 50 -75
20/60 1.97- 3.54 50-90
20/40 2.95 – 3.93 75-100
12/40 3.93 – 5.90 100-150
Heavy mineral sand Medium-fine 2.6 – 2.1 66 – 53.4
Silica sand Medium 2.9 74
Flint shot Medium -fine 2.7 68.6
Ilmenite Medium 2.9 74
Table 5: Comparison of Salt Level from Wet and Dry Surface Cleaning Methods (JPCL, 2002)[19]
9. Free Silica abrasives media. The following testing carried out as per
A minimum of 99 percent of abrasive material shall flow international standard ASTM, B.S, ISO, SSPC and oil
from the test cylinder. company specifications ADMA-OPCO, SHELL, TOTAL FINA
ELF and AGIP as follows:
FIELD MECHANICAL TESTING
The field practical application and testing for different Measurement of Rust Grade of Metal Surfaces
types of nonmetallic ores utilized as blasting abrasive Rust grades of bare pipes are divided to 4 grades (A, B, C,
media for surface preparation and cleaning before applying D) according to degree of pitting in steel surfaces. The
protective coating for metallic surfaces were conducted in grade of rust need to define before start surface
PETROJET, Maidda yard and L and T Yard, Oman to preparation to determine the blasting method can be
evaluate the suitability and performance of many types of achieve the cleanliness and profile degrees.
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 4 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
Surface Cleanliness Degree In this study the Testex Tape method (D4417) is
The cleanliness degree achieved by blasting shall be at least probably the most common method used to determine
Sa 2½ according to ISO 8501-1, 1988. [20] Surface surface profile. The Tape has a compressible foam layer
Cleanliness involves determining how much of the original with a 2 mil (50 um) Mylar covering. The foam takes on the
mill scale, rust and paint have been removed from the shape of the profile and it is measured with a spring
surface as well as how much invisible surface micrometer. Since the foam is covered with 2 mils of Mylar,
contamination is present usually in the form of salts. this must be subtracted from the reading to get the surface
Surface preparation is probably the main cause of most profile (Tom Swan, 1960). [23]
paint failures because more than any other factor, it affects The photos show the difference in profile between
how well the paint sticks to the surface being painted. nonmetallic and metallic abrasive on metal surface Figure
2.
Surface Profile
The surface anchor is necessary for good bonding of steel Salt Level
surfaces and coating materials and shall be measured Chloride coming from the abrasive itself and may be
according to ISO 8503-2. [21] transferred to the structure surface. Over a period of time,
Surface profile is the determination of the roughness of moisture drawn through the coating to the area containing
the surface and for painting purposes involves depth of the the chloride may produce blistering and premature coating
profile, peak density and angularity of the profile. failure (Gay-Iynne, 1989). [24]
Most paint forms a mechanical bond with the steel and The coated surface shall be free of all hazard materials
generally surfaces that have roughness will supply the best “salt level” and shall be tested according to ISO 8502-6,
mechanical bonds. Also, when you put a profile on the 1992. [25]
surface, you increase the surface area, so the paint has
more surface area to adhere to. Different paints are made Dust Level
for different texture surfaces from smooth to rough. Dust level for coated surfaces shall be less than rate 2 as
There are currently four accepted ways to find surface per coating specifications and ISO 8502-3, 1992. [26]
profile and each one has advantages and disadvantages.
The First Three methods are detailed in ASTM-D- 4417, Abrasive Conductivity
1993 [22] "Standard Test Method for Field Measurement of The soluble salts such as sulfate or nitrate are considered
Surface Profile of Blast Cleaned Steel" less detrimental to steel surface than chloride; therefore, if
1. Surface Profile Visual Comparator (D4417 Method A) the conductivity comes primarily from sulfate, the
2. Surface Profile Gage - Profilometer (D4417 Method B) allowable level of conductivity would be much greater than
3. Press-o-film Testex® Tape (D4417 Method C) that for chloride. For example, the water jetting standard.
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 5 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
Table 6: Cleaning Rates and Abrasive Consumption of Blasting Abrasive Media (SSPC volume 1, 2003) [7]
Table 7: Application Parameters and Cost Comparison of Blast Abrasive Media (Garnet, Sand, Coal Slag), Applied for New Steel
with Light Rust (PCE, 1989) [27]
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 6 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
Table 8: Physical Properties of Egyptian Types of Natural Ores Used as Abrasive Media
Table 10: Average Results of Garnet Sieve Analysis for Grade 30/60
Table 11: Chemical Analyses of Egyptian Natural Ores Used as Abrasive Media
mean more or less presence of rust traces ”pitting” start to 4. Salt Contamination Level
appear. The grade of rust need to define before start The recent investigations shows that the mainly chlorides,
surface preparation to determine the blasting method can is critical to the performance of protective coatings, the
be achieve the cleanliness and profile degrees. small increase in salt content (+1 µg/cm²) heads to a 200 %
decrease in coating lifetime (JPCL, 2004). [31] Salt content is
2. Cleanliness Degree basically evaluated through the following three
The cleanliness degree achieved by blasting is Sa 2½ to Sa3 parameters: -specific electric conductivity (us/cm);
according to ISO 8501-1, 1988. [30] Volumetric concentration (ppm = ug/cm³); and -Surface
concentration (µg/cm²).
3. Surface Profile The coated surface shall be free of all hazard materials,
The surface profile or depth that the abrasive digs into the the results indicates that the salt level measured using SCM
surface is affected by the abrasive size, hardness and shape 00 is µm/cm² “ 0 - 5 mg/m²”.
and by distance from the blast nozzle to the surface (Gay-
Iynne, 1989). [24] The surface anchor is measured using the 5. Dust Level
Press-O-Film gauge and it’s necessary for bonding of Dust on blast cleaned steel surfaces may reduce the
primer with steel surfaces and polyethylene coating layers, adhesion of applied coatings and by absorbing moisture
the profile ranging from 65-80 µm as per ISO 8503 -2, may promote the corrosion of the blast cleaned steel.
1988. [21] Assess the quality of the dust on the tape by comparing
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 7 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
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Figure 11: Attach paper to substrate Figure 12: SCM salt tester
visually an area of the tape with equivalent sized areas of from contamination and the conductivity is ranging from
the pictorial reference shown in ISO 8502 – 3, 1992. [26] 10 to 15 ms/m (100 - 150 µS/cm) which comply with
coating specification requirements, (Total Fina Elf, 2002).
6. Abrasive Conductivity [32]
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[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 9 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in
RESEARCH ARTICLE
surface cleanliness - Part 6: Extraction of soluble 31. JPCL, February. Surface preparation standards for steel
contaminants for analysis - The Bresle method, 1995. substrates, page 51, 2004.
26. ISO 8502-3. Preparation of steel substrates before application 32. Total Fina Elf. External protection of off-shore and related
of paints and related Products - Tests for the assessment of structures and equipment by painting, page 11, 2002.
surface cleanliness - Part 3: Assessment of dust on steel
surfaces prepared for painting (pressure sensitive tape Acknowledgment
method), 1992. The authors would like to express his deeply thanks to
27. PCE, May. Economics of abrasive selection for shipyard use, PETROJET painting crew at Maadia yard and LARSEN and
page 28, 1989. TOUBRO LIMITED (L and T), Oman for helping to evaluate the
28. JPCL, January. On conductivity and chloride concentration, abrasive media and conduct the practical and field testing.
page 77, 2008.
29. Barton data sheet: Technical data sheet and physical
characteristics for Barton garnet abrasive, www.barton.com, Cite this article as: Mohamed A Wahab A Halim Gaber,
page 9/14. Ibrahim H Ibrahim. Geochemical and Mechanical Studies
30. ISO 8503-1. Preparation of steel substrates before application of Nonmetallic Ores Utilized as Blasting Abrasive Media
of paints and related products - Surface roughness for Surface Preparation of Metallic Surfaces. Inventi
characteristics of blast-cleaned steel substrates –Visual Rapid: Chemical Engineering, 2014(4):1-10, 2014.
assessment of surface cleanliness, 1988.
Inventi Rapid: Chemical Engineering Vol. 2014, Issue 4 10 2014 eche 14286, CCC: $10 © Inventi Journals (P) Ltd
[ISSN 2320-1053] Published on Web 01/10/2014, www.inventi.in