10/19/23, 12:43 PM How Boiling point varies with Vapor Pressure - Antonie Equation - Pharma Engineering

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The most basic thing that many engineers were aware of that is Boiling point varies with Vapour pressure, and i'll bet you that many of
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For that you should be aware of some damn basic things like what does exactly Vapour pressure, Boiling point means. May 26 2023

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What is Vapour Pressure ? 2 Good morning everyone....!!!Hope e
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Vapour Pressure means the pressure exerted by the vapour on the surface of liquid at equilibrium, Usually vapour wont have any
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Vapour pressures, the vapour pressure is the property of solvents, every solvent will have their respective vapour pressures.
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Boiling point is nothing but a point of saturation where the vapour pressure of a solvent equals the atmospheric pressure, simply
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toluene is a solvent, whose boiling point is 110.6°C, and at that boiling point the vapour pressure of toluene will be 760 torr, [Dont get Good day everyone ......!!Hope every
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confused Torr means mmHg only]. And same is the case with every solvents boiling point.
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Right now, you got a clear idea of the Vapour Pressure & Boiling point, So now i'll start my show about describing the relation ship Estimation of Oxygen Depletion
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between Vapour Pressure and Boiling point, the only relation that describes the relation between these two parameters is Antonie
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By using Antonie equation we can calculate the boiling point of solvent at different pressures, it also means that the boiling point of 9 Extinguishers Requirement

solvents will decrease with Vacuum, and we can calculate it theoretically. In fact, this is the first calculation that i've learned after
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Log P = A - B / ( T + C ),

Type Here...
A, B, C are Antonie Constants,

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P is Vapour Pressure, T is Boiling point.

Just remember one thing, while selecting the Antonie constants, there are many set of constants available, and they will vary with the Training on Process Engin
units of Pressure that you choose.

So, by now, if you are new to this calculation, this known equation will look something special to you,

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And here vacuum should be NLT 650 mmHg at the end of distillation, so now just try to calculate the boiling point at 650 mmHg,
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For that you need to know the Antonie constants of Toluene,

Antonie constants data here

A = 6.95, B = 1344.8, C = 219.482,

the Vacuum should be NLT 650 mmHg, so the pressure should be P = 760 - 650 = 110 mmHg.

Log (110 ) = 6.95 - 1344.8 / ( T + 219.482 )

Solving for T, T = 54.4°C. Pharma Engineering need auth

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So, this means at 650 mmHg the boiling point of Toluene will be 54.4°C, which means it came down from 110.6°C to 54.4°C.
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10/19/23, 12:43 PM How Boiling point varies with Vapor Pressure - Antonie Equation - Pharma Engineering

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KANDIPALLI SATISH 8 FEBRUARY 2017 AT 22:22

Good

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1. UNKNOWN 29 MARCH 2017 AT 18:00

how you calculated T value?

2. AJAY KUMAR AUTHOR 30 MARCH 2017 AT 06:27

if you know the vapour pressure just insert in Antonie equation, and solve for T, that's it....!!!

Regards,
PHARMA ENGINEERING

Reply

RAVI KUMAR 10 NOVEMBER 2017 AT 10:15

thanks for ur valuable post.

Reply

UNKNOWN 13 NOVEMBER 2017 AT 18:45

Dear Ajay,
For selection of P value, do we have to substract required Vacuum (i.e.,650mmHg in case you have considered) from
760 mmHg or the atmospheric pressure at the given location (for example ~720mmHg in Hyderabad)??
Thanks

Reply

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1. AJAY KUMAR AUTHOR 13 NOVEMBER 2017 AT 21:27

Dear Khan,

correct, you need to subtract from atnospheric pressure, i.e., 760 mmHg.
Leave a message
Regards,
AJAY K

2. UNKNOWN 13 NOVEMBER 2017 AT 21:35

Atmospheric pressure varies with sea level.Then, how do we consider that?

3. AJAY KUMAR AUTHOR 14 NOVEMBER 2017 AT 06:08

Dear Khan,

please go through the post, and try to calculate the atmospheric pressure at different
locations based on height of sea level. Casually i've mentioned atmospheric pressure i.e.,
760mmHg.

Regards,
AJAY K

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KEDAR 29 APRIL 2019 AT 22:11

Hello this is kedar,

How you find T value is 54.4,

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10/19/23, 12:43 PM How Boiling point varies with Vapor Pressure - Antonie Equation - Pharma Engineering
By calculating the equation T value comes minus 874.96
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Pls varifie the euation i;e log (110)=(6.95-1344.8)/(T+219.482)
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KEDAR 29 APRIL 2019 AT 22:16

Hello this is kedar,

How you calculate log110= (6.95-1344.8)/(T+219.482)
Its comes in minus value ,
But not 54.4
Pls check & reply.

Reply

Replies

1. AJAY KUMAR AUTHOR 30 APRIL 2019 AT 05:59

Hii Kedar,

You read the equation wrong, its Log(110) = 6.95 - (1344.8/(T+219.482)).

Now once try repeating the calculation, you will get it.

Best Regards,
AJAY K

Reply

KEDAR 1 MAY 2019 AT 09:19

Hello this is kedar,

Antonie constant are always same, if we take pressure unit is mmhg then its value is constant ? If we take pressure
unit is kg/cm2 then whats it value ?pls reply.

Reply

Replies

1. AJAY KUMAR AUTHOR 1 MAY 2019 AT 12:33

Hii Kedar,

The constants will surely vary based on the units of pressure and temperature,
As we are much familiar with mmHg and C, i've given those.

Regards,
AJAY K

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UNKNOWN 25 SEPTEMBER 2019 AT 22:38

Hi
This Rachit
How we find out the values of A,B,C for different types of solvents
please suggest.

Reply

Replies

1. AJAY KUMAR AUTHOR 27 SEPTEMBER 2019 AT 16:02

Hii Rachit,

Pl click on the link provided, 'ANTONIE CONSTANTS DATA HERE'.

Regards.

Reply

UNKNOWN 1 JUNE 2020 AT 17:33

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