Q1 When carbon disulphide reacts with excess of chlorine in the presence of a lewis acid as a

catalyst ,the product obtained is a

(a) dihalide (b) trihalide (c) monohalide (d) tetrahalide

Qin the finkelstein rxn for the prepartion of iodoalkanes from alkyl chloride and bromide ,acetone is
used b/c

(a) NaIis soluble in acetone ,but NaBr and NaCl are not

(b) alkyl halides are soluble in acetone

(c) acetone is a universal solvent

(d) acetone catalysed the Rxn

Q3 which among the following is a geminal dihalide?

(a) Ethylene dihalide (b) ethylidene dihalide

(c) alkyl chloride (d) chloroethyne

Q4 sandmayers method of preparation of chlorobenzene proceeds through which of the following

mechanisms

(a) electrophilic substitution (b) nucleophilic substitution (c) free radical substitution (d) free
radical addition

Q5 IUPAC name of Chloral (C2HCl3O) is

(a) 2,2 -trichloro eth-1-enol

(b) 2,2,2-trichloroethanal

(c) 2,2-Dichloroethanoyl chloride

(d) None of the above

Q6 Which amog the following is allyl halide

(a) Chlorobenzene (b) 1-chlorocyclohex-1-ene (c) chloroethane (d) 3-chlorocyclohex-1-ene

Q7 the reagent used for the iodonation of benzenering in the presence of a halogen carrier (F.C.R) is

(a) HI (b) I2 (c) ICl (d) CuI

Q8 Neopentyl chloride is preferably prepared by free radical chlorination of neopentane because

(a) tert- free radical is formed (b) free radical do not undergo rearrangement

(c) Both a&b (d) none of the above

Q9 In the presence of two different β -hydrogens, the dehydrohalogenation of fluoroalkane would
yield

(a) Saytzeff Products (b) Hoffmann product (c) Markovnikov 's products (d0 None of the above

Q10 C6H5CH3 -----Cl2-----> X -----Aq KOH , HCl---------> Y ---Red P-----> Z , the product Z is

(a) C6H5COOH (b) CH3COOH (c) C6H5CH3 (d) C6H5COOK

Q11 A halogen used in potential blood a substitute in surgery is

(a) Bromine (b) Fluorine (c) Iodine (d) Chlorine

Q12 By the reaction of PCl5 on glycol, the productis

(a) ClCH2-CH2Cl (b) Cl2CH CH3 (b) POCl3 (d) Both a & c

Q13 The most common freons in industrial use is manufactured by

(a) Swart Rxn (b) Finkelstein Rxn (c) Fitting rxn (d) none of the above

Q14 Tetrachloromethane is a

(a) Ntiseptic drug (b) Insecticide (c) Degreasing agent (d) none of the above

Q15 Vinyl Chloride and propargyl chloride are respectively the chloro derivatives of

(a) alkene and alkyne (b) alkyne and alkene (c) alkane and alkene (d) alkene and alkane

Q16 Consider the Rxn :

CH3CH2CH2Br + NaCN ---------> CH3CH2CH2CN + NaBr , the Rxn will be faster in :

(a) Water (b) Ethanol (c) Methanol (d) N,N -dimethylformamide(DMF)

Q17 In an SN1 Rxn on chiral centres , there is :

(a) more inversion than retention leading to partial racemisation

(b) 100% retention

(c) 1005 inversion

(d) 100% racemisation