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Chemical Principles 8th Edition

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Chapter 07 - Acids and Bases
1. For the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak acid), the equilibrium
constant expression is
a.

b.

c.

d. K = [H+][NO2–]
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | solutions of a weak acid or
base

2. Identify the Brønsted acids and bases in the following equation (A = Brønsted acid, B = Brønsted base).
HPO42– + HSO4– H2PO4– + SO42–
a. A B B A
b. B A A B
c. A B A B
d. B B A A
e. B A B A
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

3. The equilibrium constant for the reaction


A– + H+ HA
is called
a. Kb

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Chapter 07 - Acids and Bases
b.

c. KwKa
d.

e. Ka
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | solutions of a weak acid or
base

4. According to the Brønsted-Lowry definition, an acid is


a. a substance that can donate a proton to another species.
b. a substance that increases the hydroxide ion concentration in a solution.
c. a substance that can accept a proton from another species in solution.
d. an electron pair acceptor.
e. a substance that increases the hydrogen ion concentration in a solution.
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

5. Which of the following reactions is associated with the definition of Ka?


a. [Al(OH2)6]3+ Al(OH)(OH2)52+ + H+
b. CN– + H+ HCN
c. OCl– + H2O HOCl + OH–
d. Al3+ + 6H2O Al(OH2)63+
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | solutions of a weak acid or
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Chapter 07 - Acids and Bases
base

6. Which of the following is a conjugate acid-base pair?


a. H3O+/OH–
b. N2H5+/N2H4
c. Mg2+/Mg(OH)2
d. HCl/OCl–
e. H2SO4/SO42–
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: True
TOPICS: 7.1
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

7. Which of the following represents a conjugate acid-base pair?


a. H2PO4– and PO43–
b. HNO3 and NO3–
c. HCl and NaOH
d. HSO4– and SO32–
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

8. Which of the following does not represent a conjugate acid-base pair?


a. H3O+ and H2O
b. HCN and NH3
c. HF and F–
d. C5H5NH+ and C5H5N
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: easy
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Chapter 07 - Acids and Bases
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

9. Which of the following species is not amphoteric?


a. H2PO4–
b. HPO42–
c. H2O
d. HSO4–
e. All of these are amphoteric.
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

10. The hydrogen sulfate or bisulfate ion HSO4– can act as either an acid or a base in water solution. In which
of the following equations does HSO4– act as an acid?
a. HSO4– + H2O → SO42– + H3O+
b. HSO4– + H2O → H2SO4 + OH–
c. HSO4– + H3O+ → SO3 + 2H2O
d. HSO4– + OH– → H2SO4 + O2–
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
7.2
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

11. Which of the following is the equilibrium constant expression for the dissociation of the weak acid HOCl?
a.

b. K = [H+][OCl–]
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Chapter 07 - Acids and Bases
c.

d.

e. none of these
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.1
7.2
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | solutions of a weak acid or
base

12. The strong acid HA is added to water. Which of the following is the strongest base in the system?
a. A–
b. HA
c. H3O+
d. H2A–
e. H2O
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.1
7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

13. The conjugate base of a weak acid is


a. a strong base.
b. a strong acid.
c. a weak base.
d. a weak acid.
e. none of these
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
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Chapter 07 - Acids and Bases
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

14. The following acids are listed in order of decreasing acid strength in water.
HI > HNO2 > CH3COOH > HClO > HCN
According to Brønsted-Lowry theory, which of the following ions is the weakest base?
a. ClO–
b. NO2–
c. CH3COO–
d. I–
e. CN–
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

15. Given that the Ka for HOCl is 3.5 × 10–8, calculate the K value for the reaction of HOCl with OH–.
a. 3.5 × 10–22
b. 3.5 × 10–8
c. 2.9 × 10–7
d. 3.5 × 106
e. none of these
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

16. In deciding which of two acids is the stronger, one must know
a. the pH of each acid solution only.
b. the concentration of each acid solution only.
c. the equilibrium constant of each acid only.
d. all of the these.
e. both the concentration and the equilibrium constant of each acid.
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Chapter 07 - Acids and Bases
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

17. Which reaction does not proceed far to the right?


a. HCN + OH– → H2O + CN–
b. HCl + H2O → H3O+ + Cl–
c.
d. H3O+ + OH– → 2H2O
e.
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

18. The acids HC2H3O2 and HF are both weak, but HF is a stronger acid than HC2H3O2. HCl is a strong
acid. Order the following according to base strength.
a. Cl– > F– > C2H3O2– > H2O
b. C2H3O2– > F– > H2O > Cl–
c. C2H3O2– > F– > Cl– > H2O
d. F– > C2H3O2– > H2O > Cl–
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

The following three equations represent equilibria that lie far to the right.
HNO3(aq) + CN–(aq) HCN(aq) + NO3–(aq)

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Chapter 07 - Acids and Bases
HCN(aq) + OH–(aq) H2O(l) + CN–(aq)
H2O(l) + CH3O–(aq) CH3OH(aq) + OH–(aq)
19. Identify the strongest acid.
a. HNO3
b. HCN
c. OH–
d. H2O
e. CH3OH
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

20. Identify the strongest base.


a. CH3OH
b. CH3O–
c. H2O
d. NO3–
e. CN–
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.2
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

21. At a particular temperature, the ion-product constant of water, Kw, is 1.7 × 10–14. What is the pH of pure
water at this temperature?
a. 6.73
b. 7.00
c. 7.12
d. 6.77
e. 6.88
ANSWER: e
POINTS: 1
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Chapter 07 - Acids and Bases
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.2
7.3
KEYWORDS: acids and bases | general chemistry | self-ionization of water | self-ionization of water and
pH

22. For a neutral solution, it must be true that


a. pH = 7.00.
b. [H+] = [OH–].
c. [H2O] = 1 × 10–14
d. [H+] = 0 M.
e. At least two of these must be true.
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | self-ionization of water | self-ionization of water and
pH

23. Calculate [H+] in a solution that has a pH of 9.4.


a. 1 × 10–1 M
b. 3 × 10–5 M
c. 9 M
d. 5 M
e. 4 × 10–10 M
ANSWER: e
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: True
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

24. Find the pH of a solution at 25°C in which [OH–] = 2.5 × 10–9 M.


a. 6.50
b. 8.60
c. 7.40
d. 2.50
e. 5.40
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Chapter 07 - Acids and Bases
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

25. As water is heated, its pH decreases. This means that


a. [OH–] > [H+].
b. [H+] > [OH–].
c. the water is no longer neutral.
d. Two of these are correct.
e. None of these is correct.
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | self-ionization of water | self-ionization of water and
pH

26. The pH of a solution is raised from 3 to 5. Which statement is false?


a. The final [OH–] (at pH = 5) is 10–9 M.
b. The [H+] decreases by a factor of 20.
c. The initial solution could be 0.001 M HNO3.
d. The pOH decreases from 11 to 9.
e. The initial [H+] (at pH = 3) is 10–3 M.
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

27. Solid calcium hydroxide is dissolved in water until the pH of the solution is 10.94. What is the hydroxide
ion concentration [OH–] of the solution?
a. 3.06 M
b. 1.1 ×10–11 M
c. 1.0 ×10–14 M

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Chapter 07 - Acids and Bases
d. 8.7 ×10–4 M
e. none of these
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

28. In pure liquid ammonia, the equilibrium concentrations of both NH4+ and NH2– are 3 × 10–14 M. Which of
the following equations always holds for liquid ammonia solutions?
a. pNH4+ = log [pNH4+]
b. pNH4+ = 27.0
c. pNH4+ – pNH2– = 13.5
d. pNH4+ = 27.0 – pNH2–
e. pNH4+ + pNH2– = 13.5
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.3
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

29. Which of the following indicates the most acidic solution?


a. pOH = 5.9
b. [H+] = 0.3 M
c. [H+] = 1.0 × 10–4 M
d. [OH–] = 0.5 M
e. pH = 1.2
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.3
KEYWORDS: acids and bases | general chemistry | solutions of a strong acid or base

30. HCl gas is in a 1.21-L cylinder at 0.870 atm and 28.0° C. This gas is dissolved in 750.0 mL of
water. Calculate the pH of this solution (assume no volume change).

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Chapter 07 - Acids and Bases
a. 0.950
b. 2.52
c. 1.25
d. 1.37
e. none of these
ANSWER: c
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.3
7.4
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

31. Calculate the pH of a 1.8 M solution of HNO3.


a. –0.59
b. –0.26
c. 14.26
d. 13.74
e. 0.26
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: True
TOPICS: 7.4
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

32. Calculate the pH of a 0.040 M perchloric acid (HClO4) solution.


a. 1.40
b. 2.10
c. 12.60
d. 11.90
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.4
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

33. Calculate the pH of a solution made by mixing equal volumes of a solution of HCl with a pH of 1.52 and a
solution of HNO3 with a pH of 2.44. (Assume the volumes are additive.)
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Chapter 07 - Acids and Bases
a. 3.97
b. 1.98
c. 2.44
d. 1.77
e. 1.47
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.4
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

34. What concentration of HF (Ka = 7.2 × 10–4) has the same pH as that of 0.070 M HCl?
a. 6.8 M
b. 5.0× 10–6 M
c. 1.0 × 10–2 M
d. 0.070 M
e. 0.15 M
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.4
7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

35. The pH of a 0.6 M solution of a weak acid is 4.0. What percent of the acid has ionized?
a. 0.02%
b. 7%
c. 4%
d. 0.06%
e. 2%
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | solutions of a weak acid or
base

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Chapter 07 - Acids and Bases
36. Calculate the pH of the following aqueous solutions. Choose your answer from the given pH ranges.

0.1 M NaCN (pKa for HCN = 9.31)


a. pH 11.00–14.00
b. pH 3.00–5.99
c. pH 0.00–2.99
d. pH 6.00–8.99
e. pH 9.00–10.99
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

37. For nitrous acid, HNO2, Ka = 4.0 × 10–4. Calculate the pH of 0.33 M HNO2.
a. 2.92
b. 1.94
c. 3.40
d. 0.48
e. 4.36
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

38. A monoprotic weak acid, when dissolved in water, is 0.92% dissociated and produces a solution with pH =
3.42. Calculate Ka for the acid.
a. 1.4 × 10–7
b. 2.8 × 10–3
c. 3.5 × 10–6
d. We need to know the initial concentration of the acid.
e. none of these
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
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Chapter 07 - Acids and Bases
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

39. The pH of a 0.010 M weak acid solution is 5.28. Calculate Ka for this acid.
a. 1.9×10–9
b. 2.8×10–9
c. 5.3×10–6
d. 3.6×10–16
e. 5.3×10–8
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.5
KEYWORDS: general chemistry | acids and bases | solutions of a weak acid or base | acid-ionization
equilibria | experimental determination of Ka

40. How many moles of benzoic acid, a monoprotic acid with Ka = 6.4 × 10–5, must be dissolved in 500. mL of
H2O to produce a solution with pH = 2.50?
a. 1.6 × 10–1
b. 2.0 × 10–2
c. 7.8 × 10–2
d. 0.50
e. none of these
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

41. Calculate [H+] in a 0.026 M solution of HCN, Ka = 6.2 ×10–10.


a. 6.5 ×10–7 M
b. 2.5 ×10–9 M
c. 6.2 ×10–10 M
d. 4.0 ×10–6 M

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Chapter 07 - Acids and Bases
e. 1.5 ×10–4 M
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.5
KEYWORDS: general chemistry |acids and bases |solutions of a weak acid or base |acid-ionization
equilibria |calculations with Ka

42. In a solution prepared by dissolving 0.100 mol of propionic acid in enough water to make 1.00 L of
solution, the pH is observed to be 1.35. What is Ka for propionic acid (HC3H5O2)?
a. 4.5 × 10–2
b. 2.0 × 10–2
c. 5.0 × 10–12
d. 3.6 × 10–2
e. none of these
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

43. The pH of a 0.100 M solution of an aqueous weak acid (HA) is 3.20. What is Ka for the
weak acid?
a. 4.0 × 10–6
b. 6.3 × 10–4
c. 7.2 × 10–5
d. 3.2
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

44. The pH of a 0.14 M solution of a weak monoprotic acid, HA, is 2.89. Calculate Ka for this acid.
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Chapter 07 - Acids and Bases
a. 1.7 × 10–6
b. 1.2 × 10–5
c. 7.7–10
d. 1.4–4
e. 1.3–3
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.5
KEYWORDS: general chemistry | acids and bases | solutions of a weak acid or base | acid-ionization
equilibria | experimental determination of Ka

45. The pH of a solution made of 0.100 mol of a weak monoprotic acid HA in 1.000 L of solution is
1.470. Calculate Ka for this acid.
a. 29.5
b. 0
c. 0.100
d. 0.0174
e. 0.0339
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

46. A 0.050 M aqueous solution of a weak monoprotic acid is 1.2% ionized at equilibrium at 25° C. Calculate
Ka for this acid.
a. 7.3 × 10–33
b. 29
c. 3.4 × 10–2
d. 6.4 × 10–8
e. none of these
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False

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Chapter 07 - Acids and Bases
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

47. If an acid, HA, is 10.0% dissociated in a 1.0 M solution, what is Ka for this acid?
a. 6.3 × 10–2
b. 9.1 × 10–2
c. 8.1 × 10–1
d. 1.1 × 10–2
e. none of these
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

48. A 2.5 M solution of a weak acid is 0.52% ionized. What is Ka for this acid?
a. 1.3 × 10–2
b. 6.8 × 10–5
c. 0.11
d. 1.1 × 10–5
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

49. Calculate the pH of a 0.10 M solution of HOCl, Ka = 3.5 × 10–8.


a. 8.46
b. 4.23
c. 1.00
d. 3.73
e. 3.23
ANSWER: b

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Chapter 07 - Acids and Bases
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

50. Calculate the pOH of a 0.74 M solution of acetic acid (Ka = 1.8 × 10–5) at 25°C.
a. 2.77
b. 9.26
c. 4.88
d. 11.56
e. 2.44
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

51. The pKa of HOCl is 7.5. Calculate the pH of a 0.5 M solution of HOCl.
a. 0.3
b. 6.5
c. 7.5
d. 10.1
e. 3.9
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

52. How much water should be added to 10.0 mL of 12.0 M HCl so that it has the same pH as 0.90 M acetic
acid (Ka = 1.8 × 10–5)? (Assume the volumes are additive.)
a. 30 mL
b. 3 L
c. 30 L
d. 300 L
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Chapter 07 - Acids and Bases
e. 300 mL
ANSWER: c
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

53. A 0.240 M solution of the salt NaA has pH = 8.40. Calculate Ka for the acid HA.
a. 2.63 × 10–11
b. 3.80 × 10–4
c. 1.05 × 10–5
d. 6.60 × 10–17
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | experimental determination of Ka | general
chemistry | solutions of a weak acid or base

54. Calculate the pH of a solution made by a mixture of the following acids: 0.40 M HC2H3O2 (Ka = 1.8 × 10–
5
), 0.10 M HOCl (Ka = 3.5 × 10–8), and 0.20 M HCN (Ka = 6.2 × 10–10).
a. 2.57
b. 3.92
c. 4.95
d. 4.23
e. 3.49
ANSWER: a
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.5
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

55. Which of the following reactions is associated with the definition of Kb?
a. [Al(OH2)6]3+ Al(OH)(OH2)52+ + H+
Copyright Cengage Learning. Powered by Cognero. Page 20
Chapter 07 - Acids and Bases
b. OCl– + H2O HOCl + OH–
c. Al3+ + 6H2O Al(OH2)63+
d. CN– + H+ HCN
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

56. Which of the following reactions is associated with the definition of Kb?
a. CN– + H+ HCN
b. Cr3+ + 6H2O Cr(OH2)63+
c. Zn(OH2)62+ [Zn(OH2)5OH]+ + H+
d. F– + H2O HF + OH–
e. none of these
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

57. Calculate the pH of a 0.02 M solution of KOH.


a. 1.7
b. We cannot calculate the answer unless a volume is given.
c. 12.3
d. 2.0
e. 12.0
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

58. Which of the following aqueous solutions will have the highest pH?
For NH3, Kb = 1.8 × 10–5; for C2H3O2–, Kb = 5.6 × 10–10.
Copyright Cengage Learning. Powered by Cognero. Page 21
Chapter 07 - Acids and Bases
a. 2.0 M NH3
b. 2.0 M HCl
c. 2.0 M NaOH
d. 2.0 M HC2H3O2
e. All these solutions will have the same pH.
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

59. Calculate the pH of the following aqueous solutions. Choose your answer from the given pH ranges.

0.1 M methylamine (pKb = 3.36)


a. pH 11.00–14.00
b. pH 6.00–8.99
c. pH 3.00–5.99
d. pH 0.00–2.99
e. pH 9.00–10.99
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

60. Calculate the pOH of a 0.10 M solution of Ba(OH)2.


a. 13.30
b. 0.70
c. 13.00
d. 1.00
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base
Copyright Cengage Learning. Powered by Cognero. Page 22
Chapter 07 - Acids and Bases

61. What is the equilibrium constant for the following reaction?


NH4+ + OH– NH3 + H2O
a.

b.

c.

d.

e.

ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

62. What is [OH–] in a 0.50 M pyridine (C5H5N; Kb = 1.7 × 10–9) solution?


a. 1.8 × 10–9 M
b. 2.9 × 10–5 M
c. 0.50 M
d. 3.3 × 10–10 M
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

63. Calculate the pH of a 5.0 M solution of aniline (C6H5NH2; Kb = 3.8 × 10–10).


a. 9.64

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Chapter 07 - Acids and Bases
b. 9.30
c. 4.36
d. –0.070
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

64. Calculate the percentage of pyridine (C5H5N) that forms pyridinium ion, C5H5NH+, in a 0.10 M aqueous
solution of pyridine (Kb = 1.7 × 10–9).
a. 0.77%
b. 0.060%
c. 0.0060%
d. 1.6%
e. 0.013%
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

65. Calculate the pH of a 0.048 M solution of KOH.


a. 12.68
b. 11.32
c. 1.32
d. 2.68
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

66. A 2.98-g sample of NaOH(s) is added to enough water to make 300.0 mL of solution at 25°C. What is the
Copyright Cengage Learning. Powered by Cognero. Page 24
Chapter 07 - Acids and Bases
pH of this solution?
a. 10.40
b. 0.60
c. 13.40
d. 15.00
e. 12.35
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.6
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

67. Calculate the pH of a solution made by mixing equal volumes of a solution of NaOH with a pH of 11.40 and
a solution of KOH with a pH of 10.30. (Assume the volumes are additive.)
a. 11.13
b. 1.10
c. 10.85
d. 21.70
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

68. Calculate the pH of a solution that is 7.22 × 10–4 M C6H5NH2. Kb is 3.8 × 10–10.
a. 6.28
b. 7.72
c. 6.50
d. 7.50
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

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Chapter 07 - Acids and Bases
69. Calculate the pH of a 0.50 M NH3 (Kb = 1.8 × 10–5) solution.
a. 4.78
b. 2.52
c. 7.00
d. 13.72
e. none of these
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

70. Consider two separate solutions of equal concentration. The first solution contains sodium hydroxide, and
the second solution contains barium hydroxide. Which solution has the lower pH?
a. The barium hydroxide solution.
b. The sodium hydroxide solution.
c. We need to know the concentrations to answer this question.
d. The pH's of the two solutions are equal.
e. We need to know the volumes to answer this question.
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

71. The pH of a 2.1 × 10–3 M solution of a weak base is 9.87. Calculate Kb for this base.
a. 2.6 × 10–6
b. 1.2 × 10–4
c. 6.4 × 10–8
d. 8.7 × 10–18
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
Copyright Cengage Learning. Powered by Cognero. Page 26
Chapter 07 - Acids and Bases
base

72. The pH of a 0.124 M solution of a weak base is 10.89 at 25°C. Calculate the pH of a 0.0470 M solution of
the base at 25°C.
a. 10.68
b. 11.31
c. 4.13
d. 3.32
e. 10.47
ANSWER: a
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: True
TOPICS: 7.6
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

73. The conjugate acid and conjugate base of bicarbonate ion, HCO3–, are, respectively,
a. H3O+ and OH–
b. H2CO3 and OH–
c. H3O+ and CO32–
d. H2CO3 and CO32–
e. CO32– and OH–
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | polyprotic acids | solutions
of a weak acid or base

74. The dihydrogenphosphate ion, H2PO4–, has both a conjugate acid and a conjugate base. These are,
respectively,
a. H2PO4– and HPO42–
b. HPO42– and H3PO4
c. HPO42– and PO43–
d. H3PO4 and PO43–
e. H3PO4 and HPO42–
ANSWER: e

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Chapter 07 - Acids and Bases
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | polyprotic acids | solutions
of a weak acid or base

75. A 0.10-mol sample of a diprotic acid, H2A, is dissolved in 250 mL of water. Ka1 for this acid is 1.0 × 10–5
and Ka2 is 1.0 × 10–10. Calculate the concentration of A2– in this solution.
a. 2.0 × 10–3 M
b. 4.0 × 10–6 M
c. 0.40 M
d. 1.0 × 10–10 M
e. 1.0 × 10–5 M
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | polyprotic acids | solutions
of a weak acid or base

Calculate the pH of the following aqueous solutions. Choose your answer from the given pH ranges.

76. 1.0 × 10–12 M HCl


a. pH 3.00–5.99
b. pH 11.00–14.00
c. pH 0.00–2.99
d. pH 9.00–10.99
e. pH 6.00–8.99
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

77. 0.5 M NaHCO3 (pKa1 = 6.37; pKa2 = 10.25)


a. pH 6.00–8.99
b. pH 11.00–14.00
c. pH 9.00–10.99
Copyright Cengage Learning. Powered by Cognero. Page 28
Chapter 07 - Acids and Bases
d. pH 0.00–2.99
e. pH 3.00–5.99
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

78. Which of the following species is present in the greatest concentration in a 0.100 M H2SO4 solution in H2O?
a. H2SO4
b. H3O+
c. All species are in equilibrium and therefore have the same concentration.
d. HSO4–
e. SO42–
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | polyprotic acids | solutions
of a weak acid or base

79. What is the pH in a solution of 1.0 M H2A (Ka1 = 1.0 × 10–6; Ka2 = 1.0 × 10–10)?
a. 8.00
b. 3.00
c. 2.00
d. 13.00
e. 5.00
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.7
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | polyprotic acids | solutions
of a weak acid or base

80. Calculate the pH of a 0.05 M solution of ascorbic acid (Ka1 = 7.9 × 10–5; Ka2 = 1.6 × 10–12).
a. 5.4
Copyright Cengage Learning. Powered by Cognero. Page 29
Chapter 07 - Acids and Bases
b. 3.1
c. 6.5
d. 1.3
e. 2.7
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-ionization equilibria | acids and bases | general chemistry | polyprotic acids | solutions
of a weak acid or base

81. Calculate [H+] in a 1.0 M solution of Na2CO3 (for H2CO3, Ka1 = 4.3 × 10–7 and Ka2 = 5.6 × 10–11).
a. 6.6 × 10–4 M
b. 7.5 × 10–13 M
c. 7.5 × 10–6 M
d. 1.3 × 10–2 M
e. none of these
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | solutions of a
weak acid or base

82. Of the bases NaOH, H2O, CN–, SO42–, and HPO42–, which is the weakest? (Ka for HCN is 6.2 × 10–10; Ka
for HSO4– is 1.2 × 10–2; and Ka3 for H3PO4, is 4.8 × 10–13)
a. CN–
b. HPO42–
c. SO42–
d. NaOH
e. H2O
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
Copyright Cengage Learning. Powered by Cognero. Page 30
Chapter 07 - Acids and Bases
7.8
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

83. HOAc Ka = 1.8 ×10–5


H2CO3 Ka1 = 4.3 × 10–7, Ka2 = 5.6 × 10–11
Which of the following 0.01 M solutions has the highest pH?
a. HOAc
b. NaHCO3
c. H2CO3
d. NaOAc
e. Na2CO3
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.7
7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

84. If Ka for HCN is 6.2 × 10–10, what is Kb for CN–?


Note: CN– + H2O HCN + OH–
a. 6.2 × 10–24
b. 6.2 × 104
c. 1.6 × 10–5
d. 1.6 × 1023
e. none of these
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

85. If you know Kb for ammonia, NH3, you can calculate the equilibrium constant Ka for the reaction
NH4+ NH3 + H+
by which of the following equations?
a. Ka = KwKb
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Chapter 07 - Acids and Bases
b. Ka = 1/Kb
c. Ka = Kb/Kw
d. Ka = Kw/Kb
ANSWER: d
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acids and bases | base-ionization equilibria | general chemistry | solutions of a weak acid or
base

86. If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic?
solid potassium chloride (KCl)
a. acidic
b. neutral
c. basic
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

87. If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic?
solid ammonium nitrate (NH4NO3)
a. basic
b. neutral
c. acidic
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

88. What is the pH of a 0.2 M solution of NH4Cl? Kb for NH3 is 1.8 × 10–5.
a. 5.0
b. 11.3
c. 2.7
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Chapter 07 - Acids and Bases
d. 7.0
e. 9.0
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

89. Which of the species below, when dissolved in H2O, will not produce a basic solution?
a. Ba(OH)2
b. NH3
c. SO2
d. BaO
e. none of these; that is, they all will produce a basic solution
ANSWER: c
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base concepts | acids and bases | Brønsted-Lowry concept of acids and bases | general
chemistry

90. If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic?
solid sodium cyanide (NaCN)
a. neutral
b. basic
c. acidic
ANSWER: b
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

91. If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic?
solid sodium bicarbonate (NaHCO3)
a. basic
b. neutral
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Chapter 07 - Acids and Bases
c. acidic
ANSWER: a
POINTS: 1
DIFFICULTY: easy
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

92. If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic?
solid ammonium fluoride (NH4F)
For NH3, Kb = 1.8 × 10–5; for HF, Ka = 7.2 × 10–4.
a. neutral
b. basic
c. acidic
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

93. In which of the following are the species listed in order of increasing pH? (Ka for HC2H3O2 is 1.80 × 10–5,
and Ka for NH4+ is 5.56 × 10–10).
a. HNO3, NH4Cl, KCl, NaC2H3O2, KOH
b. NH4Cl, HNO3, KCl, KOH, NaC2H3O2
c. KCl, NH4Cl, HNO3, KOH, NaC2H3O2
d. HNO3, KCl, NH4Cl, KOH, NaC2H3O2
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

Calculate the pH of the following aqueous solutions. Choose your answer from the given pH ranges.

94. 1.0 M NaHSO4 (pKa for HSO4– = 1.92)


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Chapter 07 - Acids and Bases
a. pH 9.00–10.99
b. pH 3.00–5.99
c. pH 6.00–8.99
d. pH 11.00–14.00
e. pH 0.00–2.99
ANSWER: e
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

95. 0.5 M NH4F (pKb for NH3 = 4.74, pKa for HF = 3.14)
a. pH 11.00–14.00
b. pH 0.00–2.99
c. pH 3.00–5.99
d. pH 6.00–8.99
e. pH 9.00–10.99
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

96. The salt BX, when dissolved in water, produces an acidic solution. Which of the following could be true?
a. HX is a weak acid.
b. The cation B+ is a weak acid.
c. HX is a strong acid.
d. All of these could be true.
e. Both HX and the cation B+ are weak acids.
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

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Chapter 07 - Acids and Bases
97. Calculate the pH of a 0.21 M solution of NaA (Ka for HA is 2.1 × 10–4) at 25°C.
a. 11.82
b. 5.50
c. 8.50
d. 3.00
e. 2.18
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

98. The sodium salt, NaA, of a weak acid is dissolved in water; no other substance is added. Which of these
statements (to a close approximation) is true?
a. [H+] = [A–]
b. [A–] = [OH–]
c. [HA] = [OH–]
d. [H+] = [OH–]
e. none of these
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

99. What is the [H3O+] of a 0.14 M solution of NH4Cl in H2O at 25°C? (Kb for NH3 = 1.8 × 10–5)
a. 1.1 × 10–9 M
b. 8.8–6 M
c. 2.5–6 M
d. 7.8–9 M
e. 1.6–3 M
ANSWER: b
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: True
Copyright Cengage Learning. Powered by Cognero. Page 36
Chapter 07 - Acids and Bases
TOPICS: 7.8
KEYWORDS: general chemistry | acids and bases | solutions of a weak acid or base | acid-base properties
of salt solutions

100. Calculate the pH of a 0.005 M solution of potassium oxide, K2O.


a. 2.3
b. 11.7
c. 7.0
d. 12.0
e. 2.0
ANSWER: d
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

101. Calculate the pH of a 0.30 M solution of NH4Cl. (Kb for NH3 = 1.8 × 10–5)
a. 3.33
b. 11.67
c. 4.89
d. 9.11
e. 7.00
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

102. Calculate the pH of 0.10 M NH4CN. (Kb for NH3 = 1.8 × 10–5; Ka for HCN = 6.2 × 10–10)
a. 5.79
b. 8.21
c. 8.87
d. 5.13
e. 9.23
ANSWER: e
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
Copyright Cengage Learning. Powered by Cognero. Page 37
Chapter 07 - Acids and Bases
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

103. Arrange the following 0.10 M solutions from lowest to highest pH: NaF, NaC2H3O2, C5H5NHCl, KOH,
HCN. (Ka for HCN is 6.2 × 10–10; Ka for HF is 7.2 × 10–4; Ka for HC2H3O2 is 1.8 × 10–5; and Kb for C5H5N is
1.7 × 10–9)
a. C5H5NHCl, HCN, NaF, NaC2H3O2, KOH
b. NaF, NaC2H3O2, HCN, C5H5NHCl, KOH
c. KOH, NaC2H3O2, NaF, HCN, C5H5NHCl
d. HCN, C5H5NHCl, NaF, NaC2H3O2, KOH
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid and base strength | acids and bases | general chemistry | relative strengths of acids and
bases

104. Calculate the pH of a 2.0 × 10–5 M solution of HOC6H5. (Ka = 1.6 × 10–10)
a. 6.94
b. 6.75
c. 7.06
d. 7.25
e. none of these
ANSWER: a
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.9
KEYWORDS: acid-ionization equilibria | acids and bases | calculations with Ka | general chemistry |
solutions of a weak acid or base

105. Calculate [H+] in a 1.2 × 10–5 M solution of NH4Cl. (Kb for NH3 = 1.8 × 10–5)
a. 1.5 × 10–5 M
b. 8.2 × 10–8 M
c. 1.3 × 10–7 M
d. 1.2 × 10–5 M

Copyright Cengage Learning. Powered by Cognero. Page 38


Chapter 07 - Acids and Bases
e. 7.7 × 10–8 M
ANSWER: c
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.9
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | solutions of a
weak acid or base

106. Calculate the [H+] in a 2.0 × 10–6 M solution of NaC2H3O2.(Ka for HC2H3O2 = 1.8 × 10–5)
a. 6.0 × 10–6 M
b. 1.7 × 10–9 M
c. 3.4 × 10–8 M
d. 1.1 × 10–7 M
e. 9.6 × 10–8 M
ANSWER: e
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.9
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | solutions of a
weak acid or base

107. Calculate the pH of a 2.0 × 10–3 M solution of KClO2. Ka for HClO2 = 1.2 × 10–2
a. 7.24
b. 7.03
c. 6.97
d. 7.39
e. 6.61
ANSWER: b
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.9
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

108. Calculate [H+] in a 0.40 M solution of NaH2PO4. (For H3PO4, Ka1 = 7.5 × 10–3, Ka2 = 6.2 × 10–8, Ka3 =
4.8 × 10–13)

Copyright Cengage Learning. Powered by Cognero. Page 39


Chapter 07 - Acids and Bases
a. 1.6 × 10–4 M
b. 2.5 × 10–4 M
c. 0.40 M
d. 3.9 × 10–11 M
e. 2.2 × 10–5 M
ANSWER: e
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.9
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | solutions of a
weak acid or base

109. Calculate the pH of a 1.5 × 10–7 M solution of HCl.


a. 7.18
b. 7.00
c. 7.30
d. 6.82
e. 6.70
ANSWER: e
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.10
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

110. Calculate the pH of a 2.0 × 10–8 M solution of HNO3.


a. 7.70
b. 6.96
c. 7.00
d. 6.30
e. 7.04
ANSWER: b
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.10
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

111. Calculate [OH–] in a 4.0 × 10–8 M solution of NaOH.


Copyright Cengage Learning. Powered by Cognero. Page 40
Chapter 07 - Acids and Bases
a. 8.2 × 10–8 M
b. 6.7 × 10–6 M
c. 2.5 × 10–7 M
d. 4.0 × 10–8 M
e. 1.2 × 10–7 M
ANSWER: e
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.10
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

112. Calculate the pH of a 2.0 × 10–7 M solution of Ca(OH)2.


a. 6.62
b. 7.30
c. 6.37
d. 7.38
e. 7.63
ANSWER: e
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.10
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

113. True or False? The pH of a strong acid solution is always lower than the pH of a weak acid solution. If
this is true, explain why and include an example with calculations. If it is false, explain why and include a
counterexample with calculations.
ANSWER: False. See Sections 7.4 and 7.5 of Zumdahl, Chemical Principles.
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.1
7.2
7.3
7.4
7.5
KEYWORDS: acids and bases | general chemistry

114. A solution is made by mixing equal volumes of 0.20 M HCN (Ka = 6.2 × 10–10) and 0.20 M NH3 (Kb = 1.8
× 10–5). Determine the pH of the solution.
Copyright Cengage Learning. Powered by Cognero. Page 41
Chapter 07 - Acids and Bases
ANSWER: 9.22
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.5
7.6
7.11
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

115. Explain why the pH of an aqueous solution of NaHCO3 is independent of concentration.


ANSWER: See Section 7.7 of Zumdahl, Chemical Principles.
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | pH of a salt
solution | solutions of a weak acid or base

116. Provide an example of a salt that is acidic, a salt that is basic, and a salt that is neutral when dissolved in
water. Provide chemical equations for each of these to support your answer.
ANSWER: See Section 7.8 of Zumdahl, Chemical Principles.
POINTS: 1
DIFFICULTY: moderate
HAS VARIABLES: False
TOPICS: 7.8
KEYWORDS: acid-base properties of salt solutions | acids and bases | general chemistry | prediction of salt
solution acid-base properties | solutions of a weak acid or base

117. Determine the pH of a solution made by adding 1.0 × 10–7 mol of HCl to 1.0 L of solution.
ANSWER: 6.80
POINTS: 1
DIFFICULTY: difficult
HAS VARIABLES: False
TOPICS: 7.10
KEYWORDS: acids and bases | general chemistry | pH of a solution | solutions of a strong acid or base

118. You have at your disposal 100.00 mL of 0.650 M HCl and 500.00 mL of 0.300 M NaOH. How many mL
of the base have to be added to the full volume of the acid to reach a pH of 1.90?
a. 20.4 mL
b. 43.3 mL
c. 10.2 mL

Copyright Cengage Learning. Powered by Cognero. Page 42


Chapter 07 - Acids and Bases
d. 433 mL
e. 204 mL
ANSWER: e
POINTS: 1
HAS VARIABLES: False

119. If solid sodium cyanide (NaCN) is dissolved in pure water, will the solution be acidic, neutral, or basic?
a. acidic
b. neutral
c. basic
ANSWER: c
POINTS: 1
HAS VARIABLES: False

120. Which of the following statements is true for polyprotic acids?


a. The values of Ka1 and Ka2 are dependent on the concentration of the acid.
b. Ka2 Ka1
c. Ka1 Ka2
d. pKa1 pKa2
e. C and D
ANSWER: c
POINTS: 1
HAS VARIABLES: False

121. Calcium carbonate is used in many antacid tablets because it reacts with HCl, the primary acid in the
stomach, to produce water, calcium chloride, and carbon dioxide. At 37°C and 760 torr, what volume of CO2 is
produced when a person consumes an antacid tablet containing 500.0 mg of CaCO3 to eliminate excess stomach
acid? Assume acid is in excess of the carbonate. (R = 0.08206 L.atm/K. mol)
a. 17 ml
b. 30 ml
c. 1300 ml
d. 130 ml
e. 150 ml
ANSWER: d
POINTS: 1
HAS VARIABLES: False

122. Which of the following is true of Arrhenius concept of acids and bases?
a. Acids produce hydroxide ions in aqueous solution and bases produce hydrogen ions.
b. Acids and bases are proton (H+) donors.

Copyright Cengage Learning. Powered by Cognero. Page 43


Chapter 07 - Acids and Bases
c. Acids are proton (H+) acceptors and bases are proton donors.
d. Acids produce hydrogen ions in aqueous solution and bases produce hydroxide ions.
e. Acids are electron donors and bases are electron acceptors.
ANSWER: d
POINTS: 1
DIFFICULTY: Easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: general chemistry

123. Identify the hydronium ion among the following ions.


a. H3O+
b. H3O-
c. H2O2+
d. H2O2-
e. H3O2+
ANSWER: a
POINTS: 1
DIFFICULTY: Easy
HAS VARIABLES: False
TOPICS: 7.1
KEYWORDS: general chemistry

124. Which of the following statements is/are true of HCl solution?


1. A 1.0 M HCl solution contains H+ and Cl− ions rather than HCl molecules.
2. A 1.0 M HCl solution contains 6.02 × 10−23 HCl molecules and no ions.
3. In 1.0 M HCl, water produces less than 10−7 M H+ ions.
a. 1 only
b. 2 only
c. 3 only
d. 1 and 2
e. 1 and 3
ANSWER: e
POINTS: 1
DIFFICULTY: Easy
HAS VARIABLES: False
TOPICS: 7.4
KEYWORDS: general chemistry

125. A _____ can furnish more than one proton per molecule and it always dissociates in a stepwise manner,
Copyright Cengage Learning. Powered by Cognero. Page 44
Chapter 07 - Acids and Bases
one proton at a time.
a. polyprotic acid
b. lysergic acid
c. lysergic base
d. monoprotic acid
e. polyprotic base
ANSWER: a
POINTS: 1
DIFFICULTY: Easy
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: general chemistry

126. Determine the pH of a 7.5 M H3PO4 ( ) solution.


a. 0.63
b. 1.02
c. 0.89
d. 0.41
e. 1.84
ANSWER: a
POINTS: 1
DIFFICULTY: Difficult
HAS VARIABLES: False
TOPICS: 7.7
KEYWORDS: general chemistry

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145 Feb
12617 Zegler S 65
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2571.
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2636 Smith Jas 2F June 29
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798 Turner H, Colored 2 I Apr 29
204 Weeks Nathan 2F Mar 28
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Total 17.

OHIO.
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3932 Almond A
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122 Oct
10425 Adams I
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91 Oct
10874 Allen James C
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24 Oct
11198 Andermill John
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12495 Allen J W, Cor 1G 65
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45 Mar
188 Baiel W T, S’t 64
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207
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691
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Beeman 125 May
829
Richard E 1
Biddinger M, 94 May
861
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952 Branigan 82 May
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70 May
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1602 Boman John 2C
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19 June
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135 June
1937 Brooks J
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1970 Bothin W J
F 15
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1993
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105 June
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2067 Brookheart W
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2170 Berry J C
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2264 Beers A
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2292 Burnham W Art 1K
21
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2415 Bird I
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21 June
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39 June
2599 Broughfman I
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2696 Brandon John
F 30
92 July
3053 Barnes V H
H 9
23 July
3245 Brown Charles
D 13
111 July
3299 Burns M G
B 13
July
3608 Brackneck H Cav 7A
19
July
3656 Bogart John 9G
20
July
3706 Bontrell C 6G
21
45 July
3756 Butch O
I 22
51 July
3831 Bowman S
K 23
4073 Brockway M Art 2D July
27
11 July
4279 Boyle W H
H 30
125 Aug
4684 Britton B H
H 4
45 Aug
4968 Berdy M J
D 7
126 Aug
5138 Buckle J J
E 9
Aug
5219 Brabham Geo Cav 9B
10
Aug
5498 Baldwin Geo “ 9G
13
Bonestine W H, 107 Aug
5653
Cor I 14
121 Aug
5656 Burna J M
K 14
19 Aug
5758 Balmet J
I 15
10 Aug
5771 Brutch E Cav
I 15
123 Aug
5819 Bond S T
B 16
130 Aug
5825 Boyle H
B 16
61 Aug
5937 Bower F
I 17
31 Aug
5985 Birch L T
H 17
104 Aug
6008 Bowman A
E 17
July
6020 Bright N 6E
17
111 Aug
6152 Brown G S
F 18
6839 Baren T J, Cor 89 Aug
A 25
26 Aug
7280 Barrett S C
F 30
70 Aug
7283 Bell A
B 30
121 Sept
7484 Baxter P D
D 1
14 Sept
7490 Brenning C
G 1
26 Sept
7529 Brown W
G 1
33 Sept
7806 Bear E
A 4
54 Sept
7983 Bender C
C 6
110 Sept
7993 Brown M, Cor
F 6
31 Sept
7994 Barnes T S
B 6
135 Sept
8365 Benear W A
F 10
135 Sept
8376 Barston G H
F 10
60 Sept
8476 Brenner N
F 11
36 Sept
8496 Barnes A
G 11
Sept
8508 Blythe C 1 I
12
65 Sept
8509 Brinhomer J
C 12
41 Sept
8676 Brown H H
A 13
8693 Bell James 135 Sept
B 14
126 Sept
8872 Buckley J G
A 15
Sept
8939 Blessing C 9F
16
94 Sept
9287 Baker W C
- 19
135 Sept
9446 Brookover Geo
B 21
122 Sept
9473 Briace J R
C 21
101 Sept
9625 Bradley A
A 24
72 Sept
9679 Blackman S
G 24
14 Sept
9897 Birchfield Eli
- 27
34 Sept
9949 Beant H T
D 28
43 Oct
10120 Brewer D C
K 1
21 Oct
10199 Brown E N
E 2
20 Oct
10281 Brum W H, S’t
B 4
17 Oct
10591 Briggs F
G 10
153 Oct
11072 Baymher L G
A 17
112 Oct
11307 Boles G
H 22
11 Oct
11308 Bunker J 64
K 22
12 Oct
11313 Burns M
K 22

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