Steam boiler

No 3
Flue gas 150 C
1100 C

Steam 100 C (x=100%)

Water 100 C
condenser T  25 oC
Liquid water 100 C

 kJ 
Wlost  SG .T  
 mol flue gas 

SG
Perlu karena pertanyaan Wlost per mol gas
ngas

Entropy generation di steam boiler :

SG  msteam S steam  ngas S gas
SG msteam
 Ssteam  S gas per mol gas
ngas ngas
 H v

Qrev
Recall S  S steam 
T Tsteam
Dari steam table Hv= 2676 – 419.1=2257 J/gram steam

H v 2257 kJ kJ
kg
S steam    6.048
Tsteam 100  273 K K . kg steam

cp

P2
S gas  dT  R ln per mol gas
T P1
T2 Cp
P2=P1 maka  S gas   dT
T1 T
T2  Cp 1
Karena punya data Cp/R maka ditulis: ΔSgas =R 
T1  R dT
T
Cp
Plug in =3.83 + 0.000551T dan integral dari 1100 C ke 150 C
R
kJ
 diperoleh ΔSgas =  41.835
K.mol gas
 msteam
Energy balance untuk dapatkan
ng

Energy dilepas gas=energy diterima steam

T2
T2 mg  CpdT

T1
 ngas CpdT  msteam HV  0  
T1 ng HV

Cp T2
 CpdT  R  R dT  R T1  3.83  0.000551T  dT
423
R   3.83  0.000551T  dT   34,159 J/mol
1373
Dari steam table Hv= 2676 – 419.1=2257 J/gram steam

T2
 CpdT   34,159  J / mol gas
ms T1 gram steam
    15.134
ng HV 2257 J / gram steam mol gas

mgas
Recall SG  Ssteam  S gas
ngas
J
 15.134  6.048  41.835  49.7
K .mol gas

kJ
Wlost  SG .T   49.7  25  273  14.8
mol gas
 Steam 100 C (x=100%)
condenser (b) Max work = ? Hitung Wideal
Liquid water 100 C

 kJ 
Wideal  H steam  T Ssteam  kg steam 
 
kJ
H steam condens  H v  2257
kg steam

HV 2257 kJ kJ
kg
S steam    6.048
Tsteam 100  273 K K .mol gas

Wideal  H steam  T S steam  per kg steam

kJ
 2257   25  273 6.048  453.6
kg.steam
Pertanyaan: Wmax per mol gas  perlu convert ini
 msteam produced= msteam condensed

m steam
Maka sama dengan kasus a  perhitungan Wlost 
ngas
m steam g steam
Recall rasio n  15.135
gas mol gas

 15.135 kg steam   kJ  kJ
Wideal per mol gas    
x 453.6   6.86
 1000 mol gas   kg.steam  mol gas