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MODULE 10
a. Define acid, salt, pOH, Alkalies, base, pH, and dissociation constant of water
b. State the formula of pH
c. State the formula of pOH
d. Calculate the pH of a specified solution
Lesson Outline:
MODULE 10: ACID, BASES, SALTS and pH
10.1 Acid, Base and Salts
10.2 Calculating pH and pOH
REFERENCES:
Book:
Mackay, K. M., Mackay, R. A., Henderson, W., (2002). Introduction to Modern Inorganic
Chemistry 6th edition. Nelson Thomas Ltd
Online References:
Khan Academy. Acids, Bases, pH and Buffers.
https://www.khanacademy.org/science/biology/water-acids-and-bases/acids-bases-and-
ph/a/acids-bases-ph-and-
bufffers#:~:text=Anything%20below%207.0%20is%20acidic,pH%20values%20of%20commo
n%20substances.
Science Learning Hub. Acids and bases-introduction.
https://www.sciencelearn.org.nz/resources/3019-acids-and-bases-introduction
https://www.chem.purdue.edu/gchelp/howtosolveit/Equilibrium/Calculating_pHandpOH.htm#:
~:text=To%20calculate%20the%20pH%20of,%5BH3O%2B%5D.
10. Solve for the pOH of calcium carbonate solution with 0.234 M.
ACID
An ACID is a substance that produces hydrogen (H+) ions when it is added to water.
It is capable of donating a proton or hydrogen ion to another substance. Thus, acids
are proton donors or electron acceptors. In a compound they all contain at least
one H (hydrogen).
Examples:
PROPERTIES OF ACIDS
1. Acids taste sour. Acid comes from the Latin “acere”, which means “sour”.
2. Acids can change litmus paper from blue to red.
3. Acids react with bases to form salts and water.
4. Acids can release H2 upon reaction with an active metal.
5. Acids are corrosive.
CLASSIFICATION OF ACIDS
A. STRONG ACIDS
- They break down completely to give off many H+ ions in their
aqueous states.
Examples:
B. WEAK ACIDS
- They partially break down, give less number of H+ in the
aqueous states.
Examples:
BASE
A BASE is a substance that neutralizes acids. When bases are added to water,
they split to form hydroxide ions, written as OH-. They are proton acceptors and
electron pair donors.
PROPERTIES OF BASES
1. Bases taste bitter.
2. Bases are slippery or soapy to touch.
3. Bases can change litmus paper from red to blue.
4. Bases react with acids to form salts and water.
5. Bases in their aqueous solutions conduct electric current.
CLASSIFICATION OF BASES
A. STRONG BASES
- They can release hydroxyl ions in maximum amounts.
Examples:
B. WEAK BASES
- They can release hydroxyl ions in less amounts.
Examples:
• NH3 – Ammonia
• CH3NH2 – Methylamine
• C5H5N – Pyridine
• NH4OH – Ammonium Hydroxide
SALTS
A SALT is formed when acid reacts with base. It is composed of a positively
charged ion (Cation) and negatively charged ion (Anion).
PROPERTIES OF SALTS
CLASSIFICATION OF SALTS
A. NORMAL SALTS
- The hydrogen ions of the acids are completely replaced by
metallic ions.
Examples:
B. ACID SALTS
- The salt still has hydrogen atoms from an acid which can be
further replaced by metallic ions.
Examples:
C. BASIC SALT
- The salt contains hydrogen together with metallic ions and
negative ions from an acid.
Examples:
• Acids have a pH below 7. The more H+ ions, the more acidic it is and the
lower the pH will be.
• Bases have a pH above 7.
• pH 7 is said to be neutral – this means it is WATER.
• pH value can be less than 0 for very strong acids.
• pH value that is greater than 14 for very strong bases.
CALCULATING PH
To calculate the pH of an aqueous solution you need to know the concentration of the
hydronium ion in moles per liter (molarity). The pH is then calculated using the expression:
pH = - log [H3O+].
Example:
1. Find the pH of a 0.0025 M HCl solution. The HCl is a strong acid and is 100%
ionized in water. The hydronium ion concentration is 0.0025 M.
Solution:
pH = - log (0.0025)
= - ( - 2.60)
= 2.60
CALCULATING pOH
To calculate the pOH of a solution you need to know the concentration of the
hydroxide ion in moles per liter (molarity). The pOH is then calculated using the
expression:
1. What is the pOH of a solution that has a hydroxide ion concentration of 4.82 x
10-5 M?
Solution:
10. Solve for the pOH of calcium carbonate solution with 0.234 M.