Calculations around the mixer (AMT001)

Volume of the tank: 80 m^3

80000 L

Area of the tank 10 m

Radius 1.7841241162 m
Concentration of
H2SO4 in the inlet
stream (C_A) 1641.8041217 g H2SO4/ L solution
Concentration of
H2SO4 in the exit
stream (C_out) 25.5 g H2SO4/ L solution
Concentration of H2O
in the inlet stream
(C_out) 104.80 g H2O/ L solution
Concentration of H2O
in the exit stream
(C_out) 986.10 g H2O/ L solution
mass of H2SO4 2040000 g
2040 kg
2.04 ton
4497.4248 lb

density of H2SO4 1.834 g/cm^3

1834 kg/m^3
molar mass of H2SO4 98.079 g/mol kg/kmol lb/lb-mol
liters of H2SO6 1112322.7917 cm^3
1112.32 L

density of H2O 1 g/cm^3

1000 kg/m^3
liters of water in the
exit stream 78887.68 L
mass of water in the
exit stream 78887.68 kg
78887677.208 g
78.89 ton
173917.35 lb
Water in the inlet
stream of the acid
solution 130212.77 g
130.21 kg
0.13 ton
287.07 lb
130.21 L
Pure water in the inlet
stream 78757.46 kg
78757464.44 g
78.76 ton

total mass of the

solution exit stream 178414.78 lb
80927.68 kg
80.93 ton
80927677.208 g

mass fraction of
H2SO4 in theexit
solution 2.5% wt H2SO4

The specific enthalpy

of the acid solution of
2.5% wt H2SO4 at Btu/lb-m solution
75°C 121 H2SO4

Heat capacity of the

ΔH of the acid inlet water (stream
solution (stream 10) 21588187.863 Btu 8) 0.8365
22757946303 J Molar mass of H2O 18.016
22757946.303 kJ 0.046431
Energy of water 3656784
ΔH of the acid
solution (stream 10) -
energy of water= 19101162.388 kJ
Calculations around the mixer (AMT001)
Assumptions: Ideal gas behaviour

References: Water ( 0°C, 1 atm, liquid)

Sulphuric acid (25°C, 1 atm, liquid)

(25°C, Liquid, 1 atm) (250°C, Liquid, 10 atm)

ΔH_a

(100°C, Liquid, 1 atm) ΔH_d

ΔH_b

(100°C, Vapor, 1 atm) (250°C, Vapor, 1 atm)

ΔH_c

ΔH_total = ΔH_a + ΔH_b + ΔH_c + ΔH_d

Water

ΔH_total = ∫24_25^100▒ 〖𝐶 _(𝑝(𝑙)) 𝑑𝑇 〗

+𝛥𝐻 ̂_𝑣+∫_100^250▒ 〖𝐶 _(𝑝(𝑣)) 𝑑𝑇+0 〗

= 48.40 kJ/mol

mass of water needed

to heat the acid
solution to 75°C
degrees 394662.30382 mol
molar mass of water
(steam) 18.016 g/mol
7110236.0655 g
7110.2360655 kg
7.1102360655 ton
Mass concentration
of H2SO4 in the inlet 94%

Density of the exit

acid solution 1011.60 kg/m^3
Mass flow rate of the
exit stream 80927.68 kg/hr

80.93 ton/hr

Volumetric flow rate 80 m^3/hr

F_w = 78.76 m^3/hr F_9 = 1.24 m^3 H2SO4 solution/hr

C_w = 1 kg H2O/ m^3 C_9, A = 1641.80 kg H2SO4/ m^3 solution
T_w = 25 °C C_9, W = 104.80 kg H2O/ m^3 solution
T_9 = 25 °C

F_10 = 7.11 m^3/hr

T= 250 °C

F_10 = 80 m^3 H2SO4 solution/hr

C_10, A = 25.50 kg H2SO4/ m^3 solution
C_10, W = 986.10 kg H2O/ m^3 solution
T_10 = 75 °C
kJ/mol reference used for this heat capacity was liquid water at 1 atm with temp. of 0 °C. Also water was going
g/mol
kJ/g
kJ

stream 6

Water (250°C, Vapour, 10 atm)

 heat exchanger

(25°C, Liquid, 1 atm)

stream 3
,
O4 solution/hr
/ m^3 solution
m^3 solution
0 °C. Also water was going from 0°C to 25°C