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Blasting and Painting


Procedure For Piping Work

TABLE OF CONTENT
1. SCOPE 1

2.CODE OF SPECIFICATION APPLICABLE 1

3. RESPONSIBILITY AND AUTHORITY 1

4. MATERIALS 1
5
2-5
5. PROCEDURE 2-4
6
6.MIXING OF PAINT 5
6
7.REPAIR OF PAINTING 5
6
8.INSPECTION AND TEST 5
6-7
9.REPORTING 6-7

10.PAINTING PRODUCT DATA & SAFETY SHEETS (MSDS) 7-120


8-55

11.EQUIPMENT CALIBRATION & CERTIFICATE 121-124


56-59

12.CERTIFICATE OF NACE COATING 60


125 -127
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Blasting and Painting


Procedure For Piping Work
1. SCOPE
This procedure describes the painting work of Piping for SCOT PHOENIX PROJECT ensure the works is carried out in
accordance with project specification consistent with good engineering practice and in compliance with engineering standard
practice and code

2. CODE OF SPECIFICATION APPLICABLE


2.1 PROTECTIVE COATINGS FOR ONSHORE AND OFFSHORE FACILITIES (DEP 30.48.00.31-Gen.)
Painting and Coating for SCOT PHOENIX PROJECT
2.2 SSPC‐SP10/ISO 8501‐1 Sa 2 ½ : Near white blast cleaning
2.3 SSPC‐PA2: Measurement of dry coating thickness with magnetic gauges
3. RESPONSIBILITY AND AUTHORITY
3.1 ABB shall have responsibility and authority for direction and control of painting work including all necessary
provisions such as required materials, equipment and inspection
3.2 The Subcontractor shall perform the painting work activities and shall provide all required inspection
and control required for execution of painting work.
3.3 Inspection shall be performed by the ABB quality control inspector, and the
3.4 The ABB Inspection results must be documented on the proper Paint Inspection Report, and be signed
- The ABB quality control inspector.& The Third Party by Manufacturer
- The WTL representative.
4. MATERIALS
4.1 Blast Material : The blasting material is sand blast
4.2 Paints Coat Manufacturer System:
• GALBON S-HB • SILBON HB-CUI
• EPICON F-HS • UMEGUARD SX-HS
• UNY MARINE HS • SILBON HB-CUI
• EPICON T-800 HS-GF
• SILICON AS
4.3 The painting method must be according to the Chugoku Protective Coatings recommendation.
4.4 Recommendations regarding mixing, mix ratio, working pot life, method of application, thinning and etc must be
according to Chugoku Protective Coatings
4.5 All paint shall be kept covered to prevent contamination by dust, dirt or rain.
4.6 The compressed air supply for spray painting shall be free of water and oil.Water traps must be kept empty.
4.7 Painting materials and thinners shall be stored in a proper ventilated roomwhich provides protection from sparks,
naked flames, directs sunlight, excessiveheat, and rain water.
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Blasting and Painting


Procedure For Piping Work

5. Procedure
5.1 SUFACE PREPARATION & APPLYING
5.1.1 Surface preparation shall be applied by sand blasting shall be as specification in the above applicable
specification and standard and point manufacturing data profile of sand blasting to be 50-75 microns unless specified
otherwise by painting supplier.
5.1.2 Rust, oil, grease, dust, stain and other extraneous matter shall be removed from the surfaces to be painted.
In the event that no surface preparation isspecified for given area, it shall be understood that all oil, grease, dirt, loose paint,
and any other contaminants which are detrimental coating system shall be removed prior to painting application.
5.1.3 The surface preparation shall be performed in accordance with the surface preparation system as per table no.1.
Paint shall be applied only on surfaces
5.1.4 Surface defects revealed by the blast cleaning process, should be ground,filled or treated in the appropriate manner.

Note : Primer should be applied within 4-6 hours after blasting for near white (Sa 2.5) blast cleaner surface shall be
primed within 2 hours. If exceed the specified time sweep blasting shall be under taken. or depend
on manufacturer recommend.
Table 1 Surface Preparation to Paint Manufacturer‟s Requirements

SSPC Near white metal cleaning Criteria of Surface Preparation

SP10 Near white metal cleaning Very thorough blast cleaning. Mill scale,
Rust and foreign matters shell be
remove to extent that the only traces
remaining are slight stains in the form of
spots of stripes.
SP6 Commercial blast cleaning Thorough blast cleaning. Almost all mill
Scale, rust and foreign matters shell be
Removed.
SP3 Power tool cleaning Removing rust, loose mill scale and
loose paint by using hand tools sand,
grind, chip or others.
SP2 Hand tool cleaning Removing loose rust, loose mill scale
and loose paint by using hand tools to
sand, scrape, brush, chip or otherwise.
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Blasting and Painting


Procedure For Piping Work

5.1.5 Applying Paint coats :


• Roller application of primer coat is not acceptable.
• Wet or raising day and strong wind the painting work is prohibited.
• The temperature of the substrate shall be at least 3°C above the dew point or
• Paint must be applied without interruption to all surfaces between corners, seamsor other surface breaks.
• Use brush or roller to apply stripe coating to welding seams, corners, edges andrestricted aces areas.
• No laps will be permitted except at such surface breaks.
• Special precautions shall be taken with spray applications to prevent drifting or
spreading of airborne material, which might damage adjacent equipment, materials or property.
• Spray nozzles shall be held perpendicular and sufficiently close to the surface being painted to avoid excessive
loss of material in to the air, evaporation of volatile paint solvent sand dry over‐spray from angle application.
• Nozzles of air spray equipment shall be of proper size and type for the paint being in each case.
Air delivered to the spray nozzle must be dry and of sufficient and suitable pressure for the proper
application of the paint used.
• Let the paint dry to minimum “dry to recoat time” as outlined in the technical data sheet before applying
the second and third coats and also before handling and transportation.
• Dry film thickness (DFT) to be measured between each coat to ensure correct thickness has been applied with repairs
conducted if required to meet specification as specified in DEP 30.48.00.31-Gen. outlined in table 2 below
• Wet film thickness measurement shall be carried out regularly after apply each coat of paint, ensure
coating thicknessmet with specification
• Before handling or transporting painted components, ensure the paint surface is sufficiently dry; the
drying time of paint shall follow the manufacturer‟s recommendation.
• Sub sequent Coating of paint shall be applied after acceptance of dry film thickness of the previewer layer.
• To minimize inter coat contamination succeeding coats shall be applied with minimum time lapse consistent
with paper drying tine and work schedules
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Blasting and Painting


Procedure For Piping Work
Table 2 – Painting Application
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Blasting and Painting


Procedure For Piping Work
Table 2 – Painting Application
6

Blasting and Painting


Procedure For Piping Work
6. MIXING OF PAINT
The mixing of the paint shall be in accordance with the paint manufacturer‟s recommendations & as per attached
technical data sheets
6.1 A clean container should be used for each of different paint
6.2 Before decanting the paint containers, ensure that the kind of paints meets the clients specification
(as outlined in table 2).
6.3 The paint containers should be opened just before use. Paint containers opened must be used up within
a short period of time.
6.4 The paint containers should be mixed in a properly ventilated area thatprovides protection from sparks, naked flames,
excessive heat, rain water, oil, fat,grease, dirt, dust and contaminants during use.
6.5 After opening the containers, the paint should be stirred well fo homogenizing.
6.6 If the use of thinners is necessary, only the type and mixture as per paint ‟s recommendation manufacturer
should be used.
6.7 Should the paint system require one or more components for mixing or preparation, then the portions shall be
in accordance with the paint manufacturer‟recommendations

7. REPAIR OF PAINTING
7.1 Painting damaged by handling, welding, oxy cutting or by other mean shall be repaired. surface preparation
as table1 Surface Preparation to Paint Manufacturer‟s Requirements SP3 power tool cleaning
and re‐coat as for new paint .
7.2 The repair of the damaged portion shall be performed by using the same paint as originally used.
7.3 The demand area surface preparation shall be done by using power wire brushing in lien of blasting remove
contamination and irregularity.
7.4 The previously applied paint shall be feathered back 50 mm. per coat to allow the correct application and
built up the required report.

8. INSPECTION AND TEST


8.1 Surface Preparation: Surface preparation shall be visually checked to meet the requirements specified in
table 1 and the anchor profile shall be measured using comparison gauge
8.2 Before apply paint,
• Check temperature, relative humidity & determine dew point of working environment, using the
substrate shall be Sling hygrometers.
• Check temperature, relative humidity & determine dew point of working environment, using the
substrate shall be Sling hygrometers.
• Surface temperature check by Surface magnetic thermometer.
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Blasting and Painting


Procedure For Piping Work
8.3 Materials: Prior to application, painting materials shall be verified against the material certificate issued
by the paint manufacturer.The condition of paintingmaterials shall be visually checked before use.
8.4 Dilution: Dilution should be according manufacturer recommend.
8.5 Painted surface should be finished fine and smoothly.
8.6 Drying duration: Drying duration and dryness of previous paint film shall be checked before subsequent coating.
8.7 Dry Film Thickness (DFT): Dry film thickness shall be measured by electromagnetic coating.
• The DFT of completed coating system shall be equal to or greater than the specified nominal dry film thickness
(NDFT) thickness gauge for each coat applied to ensure compliance in accordance with table 2.
8.8 Individual coat and complete coating system shall be visual inspected. Coated surface shall be free of
damage runs and sags , Pin holes , voids bubbles , Mud cracking and solvent retention.

9. REPORTING
Painting report shall be recorded in form which form shall be attached
- Form : Painting Inspection Record. ( FM-PP-020 ) Or Vendor’s from

10. PAINTING PRODUCT DATA & SAFETY SHEETS (MSDS)


Painting Production data and MSDS will be submitted by painting suppliers (Under Project Approved Vendor List)
shall be posted at shop accordingly and submit to WTL/SCOT for review by batch number
Pate 7 of 60 8

PAINTING INSPECTION
REPORT
PROJECT No. : REPORT No. :
PROJECT TITLE : DATE :
CLIENT : Page :

Surface Preparation : WEATHER CONDITION


Surface Profile : TIME : 8.30 10.00 11.45 13.45 15.00 16.00
Abrasive Used : DRY TEMP C
Application : WET TEMP C
RELATIVE HUMIDITE %
SURFACE STEEL TEMP C
Mfr'Brand name :
Primer coat 1st : SPECCIFIED
Intermediate 2 nd : - PRIMER Microns
Finish coat 3 rd : - INTER MEDIATED - Microns
FINISH - Microns
Batch No. : TOTAL D.F.T 75 Microns
No.OF COAT
Dry Film Thicknees (Microns) Average
No. Item Painted Dwg. 1 2 3 4 5 6 7 8 DFT.

TOTAL
ABB WTL SCOT
NAME _________________________ NAME _________________________ NAME ______________________________
SIGN. _________________________ SIGN. _________________________ SIGN. ______________________________
DATE _________________________ DATE _________________________ DATE ______________________________

FM-PP-020
Pate 8 of 60 9

PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LC1-N : Un-Insulated Carbon Steel, Serviced temp. (-35)o C < Temp. < 120o C

SURFACE PREPARATION SSPC-SP10 (Near-white metal)


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat GALBON S-HB
[ Inorganic zinc silicate, high build type ]
Dry Film Thickness 75 Microns
Painting Interval Min. 14 Hrs. @Temp. 30o C
Max. 180 Days @Temp. 30o C
2nd Coat EPICON F-HS
[High-solid Low VOC andepoxy polyamide with micaceous iron oxide]
Dry Film Thickness 125 Microns
Painting Interval Min. 8 Hrs. @Temp. 30o C
Max. - Days
3rd Coat UNY MARINE HS
[Acrylic aliphatic polyurethane paint (non yellowing), high solid]
Dry Film Thickness 50 Microns
Painting Interval Min. 2 Hrs. @Temp. 30o C
Max. - Days
4th Coat UNY MARINE HS
[Acrylic aliphatic polyurethane paint (non yellowing), high solid]
Dry Film Thickness 50 Microns
Painting Interval Min. 2 Hrs. @Temp. 30o C
Max. - Days
Total Dry Film Thickness 300 mm

MKT-F-04-1-01/06/60
Pate 9 of 60 10
8

No.TH 6250
Jan' 20
GALBON S-HB
GALBON S-HB, is an inorganic zinc coating based on ethyl silicate and zinc dust type II per ASTM D-520.
It has zinc content by weight in dry film 86% comform to SSPC Paint No.20 Level 1 and ISO 12944-5. It gives
protection against corrosion prolonged weather resistance, good abrasion.
It also has continuous dry heat resistance up to 400°C and peak at 540°C for 1 hour.

TECHNICAL DATA
Type : Inorganic zinc silicate , high-build type
Recommended Use : As a protective coating outside of tank , pipe, steel structure, etc.
Mixing Ratio : Base : Zinc dust = 30 : 70 (by weight)
Colour : Grey
Flash Point : Base 14.5°C
VOC : 491 [g/litre] EPA method-24
Solid by Volume : 60.0 ± 2%
Coverage (Theoretical) : 0.08 - 0.14 l/m2 ; 12.0 - 7.06 m2/l
Wet Film Thickness : 3.33 - 5.67 mils ; 83 - 142 microns
Dry Film Thickness : 2.00 - 3.40 mils ; 50 - 85 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 75 microns) : Surface Dry 30 mins. 20 mins. 10 mins. 5 mins.
: Hard Dry 5 hrs. 4 hrs. 3 hrs. 2 hrs.
Painting Interval : Minimum 32 hrs. 20 hrs. 14 hrs. 6 hrs.
(at D.F.T. 75 microns) : Maximum 180 days 180 days 180 days 180 days
Pot Life : 10 hrs. 7 hrs. 5 hrs. 3 hrs.
Thinner : CMP-61
Method of Application : Airless spray, Brush is recommended for small touch up area.
Conditions of Application : Temperature 5 - 50°C
Humidity 50 - 95 % RH
For Airless spray
Tip No. GRACO 419 , 519
Paint output pressure 9.8 MPa.
Viscosity 10-12 sec (Ford Cup No.4)
Thinning 0 - 5% by volume
Surface preparation : Surfaces must be clean and dry ,remove dirt, dust, oil and all other
contaminants that could interfere with adhesion of the next coat.
Steel : Recommend Blast cleaning to Sa 2½ (ISO 8501-1)
Anchor profile 30-65 µm are recommended for the highest performance.
Preceding Coats : Cerabond 2000
Subsequent Coats : Epicon series, Umeguard series , Silicon series, etc
Packaging : Two pack product : 3.8 Litres / Gallon
Shelf life at 25°C : Base 6 months , Zinc dust 12 months , In unopened container

Note ; 1.Dry film thickness in excess of 5.0 mils (125 microns) is not recommended
2.Before apply the next coat the paint film of GALBON S-HB must dry clean and free of zinc salts, etc.
3. Mist coat is required to minimize topcoat bubbling, thinning 30-40% is recommended.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : GALBON S-HB, BASE
Color : Milky White
Product No. : TH 6250
Product Type : Ethyl Silicate Resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 2 Highly Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 3 Causes mild skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Specific target organ toxicity (single exposure) 3 May cause respiratory irritation drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 Respiratory, Liver , Kidney , Central Nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H303 : May be harmful if swallowed
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness
H373 : May cause damage to organs through prolonged or repeated exposure
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT
H402 : Harmful to aquatic life
H412 : Harmful to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS

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PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Xylene 1330-20-7 2-5
2 Ethylbenzene 100-41-4 0.1 - 0.3
3 1-Methoxy-2-Propanol. 107-98-2 20 - 30
4 Ethyl Silicate 78-10-4 30 - 40
5 Ethanol. 74-17-5 5 - 10

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.

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Keep patient warm and at rest. Do not induce vomitting.


4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).

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Clean preferably with a detergent - avoid use of solvents


6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

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Exposure Limits ACGIH TLV


Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
Ethylbenzene 20 mg/m3 -
1-Methoxy-2-Propanol. 560 mg/m3 375 mg/m3
Ethyl Silicate Limit 1920 mg/m3
Ethanol. Limit 1920 mg/m3

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.13 - 1.14
Colour : Milky White
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 14.5°C
10. STABILITY AND REACTIVITY
Reactivity : No information available

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Stability : Stable under recommended storage and handling conditions


Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat
1-Methoxy-2-Propanol. 4016 mg/kg,Rat >13300 mg/kg,Rabbit 54,6 mg/l,Rat
Ethyl Silicate 6270 mg/kg,Rat 5860 mg/kg,Rabbit 10-16 mg/l,Rat
Ethanol. >2000 mg/kg,Rat >2000 mg/kg,Rabbit >8000 mg/l,Rat
Skin corrosion/irritation:
Conclusion/Summary on mixture : No specific data.

Serious eye damage/irritation:


Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.
Potential acute health effects
Inhalation : Exposure to vapours may cause a health hazard.

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Version 2G - Revision Date 7/06/2019

Serious effects may be delayed following exposure.


Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available
1-Methoxy-2-Propanol. EC50/48h 23300 mg/l (Daphnia magna), LC50/96h 6812 mg/l (Leuciscus Idus), IC50 - Not available
Ethyl Silicate EC50/48h >75 mg/l (Daphnia magna), LC50/96h >245 mg/l (Brachydanio rerio), IC50 - Not available
Ethanol. EC50/24h >100mg/l (Daphnia magna), LC50 - Not available, IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.

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Version 2G - Revision Date 7/06/2019

Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group II II II
Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

Page 8 / 8
19

No.TH 5422H
Jan' 20
EPICON F-HS
EPICON F-HS, based on a combination of epoxy resin, polyamide curing agent and micaceous iron oxide.
It has excellent weather resistance and physical properties such as hardness, abrasion resistance.
It has excellent compatibility with almost type of the subsequent coat and excellent resistance to oil,
seawater, freshwater and chemicals such as weak acid or weak alkali.

TECHNICAL DATA
Type : High-solid Low VOC and epoxy polyamide with micaceous iron oxide
Recommended Use : As a heavy duty coat for bridge, plants, external tank, steel structures, etc.
Mixing Ratio : Base : Hardener = 70 : 30 (by volume) ; 85 : 15 (by weight)
Colour : Light Grey , Dark Grey
Flash Point : Base = 23°C Hardener = 27°C
VOC : 230 [g/litre] EPA method-24
Solid by Volume : 85.0 ± 2%
Coverage (Theoretical) : 0.06 - 0.18 l/m2 ; 17.0 - 5.67 m2/l
Wet Film Thickness : 2.35 - 7.06 mils ; 59 - 176 microns
Dry Film Thickness : 2.00 - 6.00 mils ; 50 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 100 microns) : Surface Dry 3.5 hrs. 2.5 hrs. 1.5 hrs. 1 hr.
: Hard Dry 20 hrs. 16 hrs. 14 hrs. 12 hrs.
Painting Interval : Minimum 18 hrs. 12 hrs. 8 hrs. 6 hrs.
(at D.F.T. 100 microns) : Maximum - - - -
Pot Life : 20 hrs. 15 hrs. 12 hrs. 10 hrs.
Thinner : CMP-31
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 415 , 417
Paint output pressure 14.7 - 17.7 MPa.
Viscosity 1.5 - 2.0 Pa.s
Thinning 0 - 15% by volume
Preceding coats : Zinc Rich Primer coating such as , Epicon Zinc HB-2 , Galbon S-HB , etc.
Subsequent coats : Wide range of any coating such as , Epoxy , Polyurethane , etc.
Packaging : Two pack product : 3.785 Litres / Gallon , 15.14 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container
Note ; As nature of Epoxy coating EPICON F-HS can not avoid chalking and fading on UV exposure.
Before the next coat is applied the surface must clean and dry, remove dirt, dust, oil and all other contaminants.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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Version No.02 - Revision Date 23/06/2019

SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : EPICON F-HS, BASE
Product No. : TH 5422H
Product Type : Epoxy Resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Specific target organ toxicity (single exposure) 3 May cause respiratory irritation drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 Respiratory, Liver , Kidney , Central nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H303 : May be harmful if swallowed
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness
H373 : May cause damage to organs through prolonged or repeated exposure
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT
H402 : Harmful to aquatic life
H412 : Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

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P233 : Keep container tightly closed.


P261 : Avoid breathing dust/vapours
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Xylene 1330-20-7 5 - 10
2 Epoxy Resin Mwt 700-1000 25036-25-3 30 - 35
3 MIBK 108-10-1 5 - 10

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects

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Version No.02 - Revision Date 23/06/2019

Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.

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See Section 8 for information on appropriate personal protective equipment.


See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV


Substance name STEL-15 min.ave Long term-TWA-8hr

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Version No.02 - Revision Date 23/06/2019

Xylene 150 ppm. 100 ppm.


MIBK 75 ppm. 50 ppm.
Epoxy Resin Mwt 700-1000 - -

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 2.10 - 2.15
Colour : Light Grey , Dark Grey
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 23°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.

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Version No.02 - Revision Date 23/06/2019

Conditions to avoid ; Heat, flames and sparks


Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
MIBK 2080 mg/kg,Rat >2000 mg/kg,Rabbit 8,2-16,4 mg/l,Rat
Epoxy Resin Mwt 700- 1000 >2000 mg/kg,Rat 2000 mg/kg,Rabbit Not available

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.

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Version No.02 - Revision Date 23/06/2019

Skin contact : May cause skin irritation.


: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
MIBK EC50/48h 170 mg/l (Daphnia magna), LC50/96h 505 mg/l (Pimephales promelas), IC50/16h >100 mg/l
(Scenedesmus subspicatus)
Epoxy Resin Mwt 700- 1000 EC50/48h >100 mg/l (Daphnia magna), LC50/96h >100 mg/l (Leuciscus idus), IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:

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Version No.02 - Revision Date 23/06/2019

Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

Page 8 / 8
28

No.TH 5512
Jan' 20
UNY MARINE HS
UNY MARINE HS, based on acrylic polyol and non-yellowing polyisocyanates resin , has excellent
gloss retention, durability and chemical resistance, etc . It is suitable for protection of tank , tower, bridge
and other steel structures.

TECHNICAL DATA
Type : Acrylic aliphatic polyurethane paint (non yellowing), high solid
Recommended Use : Finish coat of Epoxy system for bridge, chemical plant oil tank
and steel structures, etc.
Mixing Ratio : Base : Hardener = 80 : 20 (by volume) , 5 : 1 (by weight)
Colour : White , as specified
Flash Point : Base = 23.5°C Hardener = 29°C
VOC : 430 [g/litre] EPA method-24
Solid by Volume : 61.0 ± 2%
Coverage (Theoretical) : 0.07 - 0.12 l/m2 ; 15.3 - 8.1 m2/l
Wet Film Thickness : 2.62 - 4.92 mils ; 66 - 123 microns
Dry Film Thickness : 1.60 - 3.00 mils ; 40 - 75 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 40 microns) : Surface Dry 2 hrs. 1 hr. 30 mins. 15 mins.
: Hard Dry 14 hrs. 8 hrs. 7 hrs. 4 hrs.
Painting Interval : Minimum 6 hrs. 4 hrs. 2 hrs. 1 hr.
(at D.F.T. 40 microns) : Maximum - - - -
Pot Life : 8 hrs. 7 hrs. 6 hrs. 4 hrs.
Thinner : CMP-41
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 5°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 715 , 813
Paint output pressure 12 - 15 MPa.
Viscosity 25 - 35 sec (Ford Cup No.4)
Thinning 0 - 15 % by volume
Preceding coats : Epicon HB-CL, Epicon HB-NP, Epicon Undercoat , Epicon F-HS ,
Umeguard HS , Umeguard HS Silver, Univan HS , etc.
Subsequent coats : -
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
29

Version 1G - Revision Date 7/08/2016

SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : UNY MARINE HS , BASE
Product No. : TH 5512
Product Type : Polyurethane resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION OF MIXTURE Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Respiratory sensitizer NC.
Skin sensitizer NC.
Germ cell mutagenicity NC.
Carcinogenicity NC.
Reproductive Toxicity NC.
Effects on or via lactation NC.
Specific target organ toxicity (single exposure) 1 (Respiratory, liver, central nervous system,kidney)
Specific target organ toxicity (repeated exposure) 1 (Respiratory, nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 2 Toxic to aquatic life
Long-term hazards to the aquatic 2 Toxic to aquatic life with long lasting effects
Hazard to the Ozone Layer NC.
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
CRITERIA
No. Substance name CAS No. W.t (%)
TLV LD50
1 Xylene 1330-20-7 10 - 15
2 Low Boiling point Naphtha 64742-95-6 0-2
3 Naphtha (Petroleum),Hydrotreated Heavy 64742-48-9 0-2
4 N-Butyl Acetate 123-86-4 5 - 10
5 Polymethyl Methacrylate 9011-14-7 35 - 55
6 Hydroxyphenyl-Benzotriazole Derivatives. 104810-48-2 0.1 - 1

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular

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or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.


Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations

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6.3. Methods and material for containment and cleaning up


Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.
Exposure Limits ACGIH TLV
Substance name STEL-15 min.ave Long term-TWA-8hr
Xylene 150 ppm 100 ppm
Low Boiling point Naphtha Limit 19 ppm
Naphtha (Petroleum),Hydrotreated Heavy Limit 197 ppm
N-Butyl Acetate 200 ppm 150 ppm
Polymethyl Methacrylate 150 ppm 100 ppm
Hydroxyphenyl-Benzotriazole Derivatives. N.A N.A

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.15 - 1.25
Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water
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Explosion limits : LEL% 1.8 : UEL% 12.3


Vapour pressure : 370 Pa at 20°C
Autoignition temperature : 296°C
Flash point : 23.5°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6,193 mg/l,Rat
Naphtha (Petroleum),Hydrotreated Heavy >5000 mg/kg,Rat >5000 mg/kg,Rabbit >5 mg/l,Rat
N-Butyl Acetate 10760 mg/kg,Rat 9683 mg/kg,Rabbit >20,0 mg/l,Rat
Polymethyl Methacrylate >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Hydroxyphenyl-Benzotriazole Derivatives. >5000 mg/kg,Rat >2000 mg/kg,Rat 5,8 mg/l,Rat
Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

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STOT - single exposure:


Conclusion/Summary on mixture : No specific data.

STOT - repeated exposure:


Conclusion/Summary on mixture : No specific data.
Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Low Boiling point Naphtha EC50/48h 3,2 mg/l (Daphnia Magna), LC50/96h 9,2 mg/l (Oncorhynchus mykiss), IC50 - Not available
Naphtha (Petroleum),Hydrotreated Heavy EC50/48h >1000 mg/l (Daphnia magna), LC50/96h >1000 mg/l (Oncorhynchus mykiss), IC50 - Not available
N-Butyl Acetate EC50/48h 44 mg/l (Daphnia magna), LC50/96h 18 mg/l (fish), IC50/72h 674,7 mg/l (Algae)
Polymethyl Methacrylate EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Hydroxyphenyl-Benzotriazole Derivatives. EC50/48h 4,0 mg/l (Daphnia magna), LC50/96h 2,8mg/l (Oncorhynchus mykiss), IC50 - Not available

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12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

Page 8 / 8
37

PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LC10-N/M : Insulated Carbon Steel, Serviced temp. 50o C < Temp. < 175o C

SURFACE PREPARATION SSPC-SP10 (Near-white metal)


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat EPICON T-800 HS-GF
[ Epoxy phenolic glassflake coating, high-build ]
Dry Film Thickness 125 Microns
Painting Interval Min. 14 Hrs. @Temp. 30o C
Max. 30 Days @Temp. 30o C
2nd Coat EPICON T-800 HS-GF
[ Epoxy phenolic glassflake coating, high-build ]
Dry Film Thickness 125 Microns
Painting Interval Min. 14 Hrs. @Temp. 30o C
Max. 30 Days @Temp. 30o C

Total Dry Film Thickness 250 mm

MKT-F-04-1-01/06/60
38

No.TH 6037C
Jan' 20
EPICON T-800 HS-GF
EPICON T-800 HS-GF is a high-build type epoxy phenolic glassflake coating.
It is suitable as a protective coating for piping and tank. It has the following adventages;
1. Excellent temperature resistance up to 230 °C
2. Excellent physical properties such as adhesion, toughness, abrasion resistance and
wet/dry cycling condition resistance.
3. Excellent thermal shock resistance.

TECHNICAL DATA
Type : Epoxy phenolic glassflake coating, high-build
Recommended Use : Tank outside, insulated pipe, other steel structures, etc.
Mixing Ratio : Base : Hardener = 86 : 14 (by volume) , 90 : 10 (by weight)
Colour : Grey , Light Grey , Reddish Brown
Flash Point : Base = 27°C Hardener = 33°C
VOC : 361 [g/litre] EPA method-24
Solid by Volume : 75.0 ± 2%
Coverage (Theoretical) : 0.13 - 0.20 l/m2 ; 7.50 - 5.00 m2/l
Wet Film Thickness : 5.33 - 8.00 mils ; 133 - 200 microns
Dry Film Thickness : 4.00 - 6.00 mils ; 100 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 150 microns) : Surface Dry 2.5 hrs. 1.5 hrs. 30 mins. 15 mins.
: Hard Dry 24 hrs. 12 hrs. 8 hrs. 6 hrs.
Painting Interval : Minimum 24 hrs. 16 hrs. 14 hrs. 8 hrs.
(at D.F.T. 150 microns) : Maximum 30 days. 30 days. 30 days. 30 days.
Pot Life : 7 hrs. 5 hrs. 3 hrs. 1.5 hrs.
Thinner : CMP-31
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 5°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 631 , 635
Paint output pressure 14.7 - 17.7 MPa.
Viscosity 1.0 - 1.5 Pa.s
Thinning 0 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to Sa 2½ (ISO 8501-1)
preparation Anchor profile 60-90 µm are recommended for the highest performance.
Preceding coats : -
Subsequent coats : Epicon T-800 HS-GF , etc.
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container
Note ; 1.Even if discoloration occures under the sunshine , this is not an indication of a change in film resistance to the cargo.
2.In confined spaces such as tank insides ventilation is required during application and curing to removed solvent vapour
and promote curing.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : EPICON T-800 HS-GF, BASE
Color : White , Light Grey , Reddish Brown
Product No. : TH 6037C
Product Type : Epoxy Phenolic Resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 1 Causes serious eye damage
Respiratory sensitizer NC.
Skin sensitizer NC.
Germ cell mutagenicity NC.
Carcinogenicity NC.
Reproductive Toxicity NC.
Effects on or via lactation NC.
Specific target organ toxicity (single exposure) 1 (Respiratory, liver, central nervous system,kidney)
Specific target organ toxicity (repeated exposure) 1 (Respiratory, nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 2 Toxic to aquatic life
Long-term hazards to the aquatic 2 Toxic to aquatic life with long lasting effects
Hazard to the Ozone Layer NC.
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT

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H412 : Harmful to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Xylene 1330-20-7 15 - 20
2 MIBK 108-10-1 3-5
3 Ethylbenzene 100-41-4 0.1 - 0.3
4 IBA 78-83-1 2-4
5 Silica Cristaline 14808-60-7 25 - 30
6 Epoxy Resin Mwt 700-1100. 25036-25-3 25 - 30

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.

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Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions

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Do not allow to enter drains or watercourses.


If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

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Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits EU TLV


Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
MIBK 416 mg/m3 208 mg/m3
Ethylbenzene 20 mg/m3 -
IBA - -
Silica Cristaline - -
Epoxy Resin Mwt 700-1100. - -

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.45 - 1.50
Colour : White , Light Grey
Odour : Smell of solvent
Solubility : Insoluble in water

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Explosion limits : LEL% 1.4 : UEL% 12.3


Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 427°C
Flash point : 27°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
MIBK 2080 mg/kg,Rat >2000 mg/kg,Rabbit 8,2-16,4 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat
IBA 2460 mg/kg,Rat 3400 mg/kg,Rabbit >24 mg/l,Rat
Silica Cristaline Not available. Not available. Not available.
Epoxy Resin Mwt 700-1100. >2000 mg/kg,Rat >2000 mg/kg,Rat Not available

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : Causes serious eye damage.
: Method: Additivity approach, no testdata available.
Respiratory or skin sensitization:
Conclusion/Summary on mixture : May cause an allergic skin reaction.
: Method: Concentration Limit, no testdata available.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:

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Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
MIBK EC50/48h 170 mg/l (Daphnia magna), LC50/96h 505 mg/l (Pimephales promelas), IC50/16h >100 mg/l (Scenedesmus subspicatus)
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available
IBA EC50/48h 1439 mg/l (Daphnia magna), LC50/96h 1430 mg/l (Pimephales promelas), IC50 1250 mg/l (Algae)

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Silica Cristaline EC50 - Not available, LC50 - Not available, IC50 - Not available
Epoxy Resin Mwt 700-1100 EC50/48h >100 mg/l (Daphnia magna), LC50/96h >100 mg/l (Leuciscus idus), IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LC11-N/M : Insulated Carbon Steel, Serviced temp. 175o C < Temp. < 595o C

SURFACE PREPARATION SSPC-SP10 (Near-white metal)


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat SILBON HB-CUI
[ High build Inorganic copolymer heat resistance ]
Dry Film Thickness 150 Microns
Painting Interval Min. 6 Hrs. @Temp. 30o C
Max. - Days
2nd Coat SILBON HB-CUI
[ High build Inorganic copolymer heat resistance ]
Dry Film Thickness 150 Microns
Painting Interval Min. 6 Hrs. @Temp. 30o C
Max. - Days

Total Dry Film Thickness 300 mm

MKT-F-04-1-01/06/60
48

No.TH 8009B
Jan' 20
SILBON HB-CUI
SILBON HB-CUI is based on Inorganic copolymer and metallic flake.
It is designed to provide anti-corrosion under insulation for pipe coating which is exposed to continuous
operating temperature -196°C to 650°C . It has the advantages as follow;
1. Excellent adhesion on steel and stainless steel.
2. Excellent anti-corrosion under insulation.
3. Film drying at ambient temperature.
4. Resistance to thermal shock and thermal cycling in service.
5. Prevent stress corrosion cracking.

TECHNICAL DATA
Type : High build Inorganic copolymer heat resistance
Recommended Use : Structure , Pipe , Corrosion under insulation
Mixing Ratio : Base : Accelerator = 100 : 1.8 (by weight)
Colour : Aluminium
Flash Point: Base 25°C Accelerator 90°C
VOC : 339 [g/litre] EPA Method 24
Solid by Volume : 75.0 ± 2%
Coverage (Theoretical) : 0.13 - 0.20 l/m2 ; 7.50 - 5.00 m2/l
Wet Film Thickness : 5.33 - 8.00 mils ; 133 - 200 microns
Dry Film Thickness : 4.00 - 6.00 mils ; 100 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 125 microns) : Surface Dry 4 hrs. 3 hrs. 2 hrs. 1 hr.
: Hard Dry 12 hrs. 8 hrs. 6 hrs. 5 hrs.
Painting Interval : Minimum 12 hrs. 8 hrs. 6 hrs. 5 hrs.
(at D.F.T. 125 microns) : Maximum
Pot Life : 12 hrs. 8 hrs. 5 hrs. 3 hrs.
Thinner : Silbon Thinner
Method of Application : Airless spray is recommended. Brush is used only for small area or touch up.
Roller is not recommended for high dry film thickness.
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85 % RH
For Airless spray :
Tip No. GRACO 417 , 419 , 421
Paint output pressure 11.7 - 14.7 MPa.
Thinning 5 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to SSPC-SP 10 , Sa 2½ (ISO 8501-1)
preparation Duplex stainless : Blast cleaning to SSPC-SP16
Anchor profile 30-65 µm are recommended for the highest performance.
Preceding coats : Galbon S-HB , Galbon S-HB PZ-L1 or direct to steel.
Subsequent coats : Silbon HB-CUI
Packaging : Two pack product per set ; 3.785 Litres / Gallon
Shelf life at 25°C : Base 12 months , Accelerator 12 months , In unopened container
Notes ; Surface preparation ; All surface to be coated should be clean, dry and free from contamination.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : SILBOND HB CUI ALUMINIUM , BASE
Product No. : TH 8009B
Product Type : Inorganic copolymer heat resistance.
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Specific target organ toxicity (single exposure) 3 (Respiratory tract irritation)
Specific target organ toxicity (repeated exposure) 2 (Respiratory, nervous system)
Acute hazards to the aquatic environment 2 Toxic to aquatic life
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H373 : May cause damage to organs through prolonged or repeated exposure.
ENVIRONMENT
H401 : Toxic to aquatic life.
PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P271 : Use only outdoors or in a well-ventilated area.
P280 : Wear protective gloves/protective clothing/eye protection.
P273 : Avoid release to the environment.
RESPONSE/FIRST AID MEASURES
P305+P351+P338 : IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
P304+P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 : Call a POISON CENTER/doctor if you feel unwell.
P302+P352 : IF ON SKIN: Wash with plenty of water/soap.

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P332+P313 : If skin irritation occurs: Get medical advice/ attention.


P370+P378 : In case of fire: Use water mist, carbon dioxide or alcohol-resistant foam to extinguish.
STORAGE
P403+P235 : Store in a well-ventilated place. Keep cool.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%)
1 Xylene 1330-20-7 25-35
2 Low Boiling point Naphtha 64742-95-6 1-5
3 Ethylbenzene 100-41-4 0.2 - 0.3

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion

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No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
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Smoking, eating and drinking should be prohibited in application area.


Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.
Exposure Limits ACGIH TLV
Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
Low Boiling point Naphtha Limit 125 mg/m3
Ethylbenzene 20 mg/m3 -

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.

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For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.30 - 1.40
Colour : Aluminium
Odour : Smell of Aromatic solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 370 Pa at 20°C
Autoignition temperature : 296°C
Flash point : 25°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6,193 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.

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: Method: Additivity approach, no testdata available.


Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.

STOT - repeated exposure:


Conclusion/Summary on mixture : No specific data.
Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards

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Developmental effects : No known significant effects or critical hazards


Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Low Boiling point Naphtha EC50/48h 3,2 mg/l (Daphnia Magna), LC50/96h 9,2 mg/l (Oncorhynchus mykiss), IC50 - Not available
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No No No
Marine pollutant - No -
15. REGULATORY INFORMATION
Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

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Version 1G - Revision Date 7/12/2017

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

Page 8 / 8
57

PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LS3-N/M : Un-Insulated Stainless Steel, Serviced temp. 200o C < Temp. < 450o C

SURFACE PREPARATION SSPC-SP11


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat SILBON HB-CUI
[ High build Inorganic copolymer heat resistance ]
Dry Film Thickness 150 Microns
Painting Interval Min. 6 Hrs. @Temp. 30o C
Max. - Days

Total Dry Film Thickness 150 mm

MKT-F-04-1-01/06/60
58

No.TH 8009B
Jan' 20
SILBON HB-CUI
SILBON HB-CUI is based on Inorganic copolymer and metallic flake.
It is designed to provide anti-corrosion under insulation for pipe coating which is exposed to continuous
operating temperature -196°C to 650°C . It has the advantages as follow;
1. Excellent adhesion on steel and stainless steel.
2. Excellent anti-corrosion under insulation.
3. Film drying at ambient temperature.
4. Resistance to thermal shock and thermal cycling in service.
5. Prevent stress corrosion cracking.

TECHNICAL DATA
Type : High build Inorganic copolymer heat resistance
Recommended Use : Structure , Pipe , Corrosion under insulation
Mixing Ratio : Base : Accelerator = 100 : 1.8 (by weight)
Colour : Aluminium
Flash Point: Base 25°C Accelerator 90°C
VOC : 339 [g/litre] EPA Method 24
Solid by Volume : 75.0 ± 2%
Coverage (Theoretical) : 0.13 - 0.20 l/m2 ; 7.50 - 5.00 m2/l
Wet Film Thickness : 5.33 - 8.00 mils ; 133 - 200 microns
Dry Film Thickness : 4.00 - 6.00 mils ; 100 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 125 microns) : Surface Dry 4 hrs. 3 hrs. 2 hrs. 1 hr.
: Hard Dry 12 hrs. 8 hrs. 6 hrs. 5 hrs.
Painting Interval : Minimum 12 hrs. 8 hrs. 6 hrs. 5 hrs.
(at D.F.T. 125 microns) : Maximum
Pot Life : 12 hrs. 8 hrs. 5 hrs. 3 hrs.
Thinner : Silbon Thinner
Method of Application : Airless spray is recommended. Brush is used only for small area or touch up.
Roller is not recommended for high dry film thickness.
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85 % RH
For Airless spray :
Tip No. GRACO 417 , 419 , 421
Paint output pressure 11.7 - 14.7 MPa.
Thinning 5 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to SSPC-SP 10 , Sa 2½ (ISO 8501-1)
preparation Duplex stainless : Blast cleaning to SSPC-SP16
Anchor profile 30-65 µm are recommended for the highest performance.
Preceding coats : Galbon S-HB , Galbon S-HB PZ-L1 or direct to steel.
Subsequent coats : Silbon HB-CUI
Packaging : Two pack product per set ; 3.785 Litres / Gallon
Shelf life at 25°C : Base 12 months , Accelerator 12 months , In unopened container
Notes ; Surface preparation ; All surface to be coated should be clean, dry and free from contamination.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
59

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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : SILBOND HB CUI ALUMINIUM , BASE
Product No. : TH 8009B
Product Type : Inorganic copolymer heat resistance.
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Specific target organ toxicity (single exposure) 3 (Respiratory tract irritation)
Specific target organ toxicity (repeated exposure) 2 (Respiratory, nervous system)
Acute hazards to the aquatic environment 2 Toxic to aquatic life
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H373 : May cause damage to organs through prolonged or repeated exposure.
ENVIRONMENT
H401 : Toxic to aquatic life.
PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P271 : Use only outdoors or in a well-ventilated area.
P280 : Wear protective gloves/protective clothing/eye protection.
P273 : Avoid release to the environment.
RESPONSE/FIRST AID MEASURES
P305+P351+P338 : IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
P304+P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 : Call a POISON CENTER/doctor if you feel unwell.
P302+P352 : IF ON SKIN: Wash with plenty of water/soap.

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P332+P313 : If skin irritation occurs: Get medical advice/ attention.


P370+P378 : In case of fire: Use water mist, carbon dioxide or alcohol-resistant foam to extinguish.
STORAGE
P403+P235 : Store in a well-ventilated place. Keep cool.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%)
1 Xylene 1330-20-7 25-35
2 Low Boiling point Naphtha 64742-95-6 1-5
3 Ethylbenzene 100-41-4 0.2 - 0.3

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion

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82
81
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No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
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Smoking, eating and drinking should be prohibited in application area.


Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.
Exposure Limits ACGIH TLV
Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
Low Boiling point Naphtha Limit 125 mg/m3
Ethylbenzene 20 mg/m3 -

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.

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For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.30 - 1.40
Colour : Aluminium
Odour : Smell of Aromatic solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 370 Pa at 20°C
Autoignition temperature : 296°C
Flash point : 25°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6,193 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.

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: Method: Additivity approach, no testdata available.


Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.

STOT - repeated exposure:


Conclusion/Summary on mixture : No specific data.
Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards

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Developmental effects : No known significant effects or critical hazards


Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Low Boiling point Naphtha EC50/48h 3,2 mg/l (Daphnia Magna), LC50/96h 9,2 mg/l (Oncorhynchus mykiss), IC50 - Not available
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No No No
Marine pollutant - No -
15. REGULATORY INFORMATION
Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

Page 7 / 8
66

Version 1G - Revision Date 7/12/2017

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

Page 8 / 8
67
91

PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LC3-N : Un-Insulated Carbon Steel, Serviced temp. 200o C < Temp. < 450o C

SURFACE PREPARATION SSPC-SP10 (Near-white metal)


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat SILBON HB-CUI
[ High build Inorganic copolymer heat resistance ]
Dry Film Thickness 150 Microns
Painting Interval Min. 6 Hrs. @Temp. 30o C
Max. - Days

Total Dry Film Thickness 150 mm

MKT-F-04-1-01/06/60
68
92

Version 1G - Revision Date 7/12/2017

SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : SILBOND HB CUI ALUMINIUM , BASE
Product No. : TH 8009B
Product Type : Inorganic copolymer heat resistance.
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Specific target organ toxicity (single exposure) 3 (Respiratory tract irritation)
Specific target organ toxicity (repeated exposure) 2 (Respiratory, nervous system)
Acute hazards to the aquatic environment 2 Toxic to aquatic life
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H373 : May cause damage to organs through prolonged or repeated exposure.
ENVIRONMENT
H401 : Toxic to aquatic life.
PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P271 : Use only outdoors or in a well-ventilated area.
P280 : Wear protective gloves/protective clothing/eye protection.
P273 : Avoid release to the environment.
RESPONSE/FIRST AID MEASURES
P305+P351+P338 : IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
P304+P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 : Call a POISON CENTER/doctor if you feel unwell.
P302+P352 : IF ON SKIN: Wash with plenty of water/soap.

Page 1 / 8
69

No.TH 8009B
Jan' 20
SILBON HB-CUI
SILBON HB-CUI is based on Inorganic copolymer and metallic flake.
It is designed to provide anti-corrosion under insulation for pipe coating which is exposed to continuous
operating temperature -196°C to 650°C . It has the advantages as follow;
1. Excellent adhesion on steel and stainless steel.
2. Excellent anti-corrosion under insulation.
3. Film drying at ambient temperature.
4. Resistance to thermal shock and thermal cycling in service.
5. Prevent stress corrosion cracking.

TECHNICAL DATA
Type : High build Inorganic copolymer heat resistance
Recommended Use : Structure , Pipe , Corrosion under insulation
Mixing Ratio : Base : Accelerator = 100 : 1.8 (by weight)
Colour : Aluminium
Flash Point: Base 25°C Accelerator 90°C
VOC : 339 [g/litre] EPA Method 24
Solid by Volume : 75.0 ± 2%
Coverage (Theoretical) : 0.13 - 0.20 l/m2 ; 7.50 - 5.00 m2/l
Wet Film Thickness : 5.33 - 8.00 mils ; 133 - 200 microns
Dry Film Thickness : 4.00 - 6.00 mils ; 100 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 125 microns) : Surface Dry 4 hrs. 3 hrs. 2 hrs. 1 hr.
: Hard Dry 12 hrs. 8 hrs. 6 hrs. 5 hrs.
Painting Interval : Minimum 12 hrs. 8 hrs. 6 hrs. 5 hrs.
(at D.F.T. 125 microns) : Maximum
Pot Life : 12 hrs. 8 hrs. 5 hrs. 3 hrs.
Thinner : Silbon Thinner
Method of Application : Airless spray is recommended. Brush is used only for small area or touch up.
Roller is not recommended for high dry film thickness.
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85 % RH
For Airless spray :
Tip No. GRACO 417 , 419 , 421
Paint output pressure 11.7 - 14.7 MPa.
Thinning 5 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to SSPC-SP 10 , Sa 2½ (ISO 8501-1)
preparation Duplex stainless : Blast cleaning to SSPC-SP16
Anchor profile 30-65 µm are recommended for the highest performance.
Preceding coats : Galbon S-HB , Galbon S-HB PZ-L1 or direct to steel.
Subsequent coats : Silbon HB-CUI
Packaging : Two pack product per set ; 3.785 Litres / Gallon
Shelf life at 25°C : Base 12 months , Accelerator 12 months , In unopened container
Notes ; Surface preparation ; All surface to be coated should be clean, dry and free from contamination.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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P332+P313 : If skin irritation occurs: Get medical advice/ attention.


P370+P378 : In case of fire: Use water mist, carbon dioxide or alcohol-resistant foam to extinguish.
STORAGE
P403+P235 : Store in a well-ventilated place. Keep cool.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%)
1 Xylene 1330-20-7 25-35
2 Low Boiling point Naphtha 64742-95-6 1-5
3 Ethylbenzene 100-41-4 0.2 - 0.3

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion

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No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
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Smoking, eating and drinking should be prohibited in application area.


Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.
Exposure Limits ACGIH TLV
Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
Low Boiling point Naphtha Limit 125 mg/m3
Ethylbenzene 20 mg/m3 -

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.

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For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.30 - 1.40
Colour : Aluminium
Odour : Smell of Aromatic solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 370 Pa at 20°C
Autoignition temperature : 296°C
Flash point : 25°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6,193 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.

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100
99
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: Method: Additivity approach, no testdata available.


Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.

STOT - repeated exposure:


Conclusion/Summary on mixture : No specific data.
Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards

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Developmental effects : No known significant effects or critical hazards


Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Low Boiling point Naphtha EC50/48h 3,2 mg/l (Daphnia Magna), LC50/96h 9,2 mg/l (Oncorhynchus mykiss), IC50 - Not available
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No No No
Marine pollutant - No -
15. REGULATORY INFORMATION
Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

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16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LS1/N : Un-Insulated Stainless Steel, Serviced temp. (-35)o C < Temp. < 120o C

SURFACE PREPARATION SSPC-SP11


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat UMEGUARD SX-HS
[ High-solid modified mastic Epoxy ]
Dry Film Thickness 100 Microns
Painting Interval Min. 6 Hrs. @Temp. 30o C
Max. - Days
2nd Coat UNY MARINE HS
[Acrylic aliphatic polyurethane paint (non yellowing), high solid]
Dry Film Thickness 50 Microns
Painting Interval Min. 2 Hrs. @Temp. 30o C
Max. - Days
3rd Coat UNY MARINE HS
[Acrylic aliphatic polyurethane paint (non yellowing), high solid]
Dry Film Thickness 50 Microns
Painting Interval Min. 2 Hrs. @Temp. 30o C
Max. - Days

Total Dry Film Thickness 200 mm

MKT-F-04-1-01/06/60
78

No.TH 6193S
Jan' 20
UMEGUARD SX-HS
UMEGUARD SX-HS is surface tolerant type modified epoxy paint.
It has the following adventages,
1 Excellent compatibility with almost all type of subsequent coat.
2 Excellent physical properties such as toughness , impact and abrasion resistance.
3 Excellent resistance to sea water and cathodic protection.
4 High solid high build and low VOC product.

TECHNICAL DATA
Type : High-solid modified anti-corrosive epoxy polyamide paint
Recommended Use : As surface tolerant primer of epoxy paint system for steel surface.
Mixing Ratio : Base : Hardener = 74 : 26 (by volume) ; 83 : 17 (by weight)
Colour : Black , Reddish Brown , Grey , Green.
Flash Point : Base = 23.5°C Hardener = 27°C
VOC : 232 [g/litre] EPA Method 24
Solid by Volume : 77.0 ± 2%
Coverage (Theoretical) : 0.13 - 0.26 l/m2 ; 7.70 - 3.85 m2/l
Wet Film Thickness : 5.19 - 10.39 mils ; 130 - 260 microns
Dry Film Thickness : 4.00 - 8.00 mils ; 100 - 200 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 150 microns) : Surface Dry 7 hrs. 3.5 hrs. 1.5 hrs. 45 mins.
: Hard Dry 28 hrs. 12 hrs. 6 hrs. 5 hrs.
Painting Interval : Minimum 28 hrs. 12 hrs. 6 hrs. 5 hrs.
(at D.F.T. 150 microns) : Maximum* - - - -
Pot Life : 5 hrs. 3 hrs. 1.5 hrs. 1 hr.
Thinner : CMP-31
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 5°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 517, 721
Paint output pressure 14.7 - 17.7 MPa.
Thinning 0 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to Sa 2½ (ISO 8501-1) , St-3
preparation Anchor profile 30-65 µm are recommended for the highest performance.
Preceding coats : NZ Primes S, Cerabond 2000, Epicon Zinc Rich Primer B-2, etc
Subsequent coats : Wide range of any coating such as , Epoxy , Polyurethane , etc.
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container
As nature of epoxy coatings UMEGUARD SX-HS can not avoid chalking yellowing and fading on sunlight exposure
Maximum recoat time is limited. The surface must have a clean, dry surface free of chalk, etc.
Safety period should be coated within 30 days interval.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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MATERIAL SAFETY DATA SHEET


1. PRODUCT AND COMPANY IDENTIFICATION
Product name : UMEGUARD SX-HS , BASE Product No. : 6193S
Manufacutrer / Supplier : TOA-Chugoku Paints Co.,Ltd
110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpokong Chachoengsao, 24180
Telephone no. 66 02 2602701-8 , 66 038 570498-9 Fax : 66 02 2602700 , 66 038 570500
In case of emergency : Telephone no. 66 02 2602701-8 , 66 038 570501
Material intended use : Coating: Solvent ( Refer to technical data sheet )
2. HARZARDS IDENTIFICATION

3. COMPOSITION / INFORMATION ON INGREDIENTS


This product contains the following hazardous ingredients
Ingredient name CAS No. EINECS No. % by weight Classification
Xylene 1330-20-7 215-535-7 3-5 R10
Xn; R20/21
Xi; R38
Butanone 78-93-3 201-159-0 1-2 F ; R11
Xi; R38
R66 , R67
n-butanol 71-36-3 200-751-6 1 R10
Xn; R22
Xi; R41 , R37/38
4-methylpentan-2-one 108-10-1 203-550-1 4-5 F; R11
Xn; R20
Xi; R36/37
R66
4. FIRST-AID MEASURES

First-aid measures
General : In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation : Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious, place in recovery position and seek medical advice.
Ingestion : If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.

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5. FIRE FIGHTING MEASURES


Extinguishing media : Recommended : alcohol-resistant foam, CO2, powders, water spray.
Do not use - water jet.
Recommendation : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Approprirate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


Personal precautions : Remove sauces of ignition and ventilation the area, avoid breathing vapour or mist.
Do not turn lights or unprotected electricalequipment on or off.
Spill : Contain and absorb spillage with non-combustible material e.g. sand, earth, vermiculite.
Place in closed container outside building and disposal according to local regulation.
Preferably clean with a detergent. Do not use solvents.
Do not allow spills to enter drains or watercauses.
If drain, lakes, river, or sewers are contimated , inform the appropriateauthorities in
accordance with local regulations.
Note : see section 8 for personal protective equipment and section 13 for waste disposal.

7. HANDLING AND STORAGE


Handling : This coating contains solvents. Solvent vapours are heavier than air and may spread along floors.
vapours may form explosive mixtures with air. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentrations higher than the occupational exposure limits.

In storage : Handle containers carefully to prevent damage and spillage.


Naked flames and smoking should not be permitted in storage areas. It is recommended that
fork lift trucks and electrical equipment are protected to the appropriate standard.

In use : Avoid skin and eye contact. Avoid inhalation of vapours and spray mists.

Observe label precaution. Put on appropriate personal protective equipment.

Smoking, eating and drinking should be prohibited in areas where this material is handled.

Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made
from the same material as the original one.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static and
antistatic footwear; floor should be conductive type.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapour in all case. In such
circumstances they should wear a compressed air-fed respirator during the spraying process
and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
Storage ; Store in accordance with local regulation. Observe label precautions. Store in a cool,
well ventilated area away from incompatible materials and sauce of heat and direct sunlight.

Keep away from ; oxidising agent, strong alkalis, strong acids.

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Storage Store on concrete or other impervious floor, preferably with bunding to contain any spillage.
Do not stack more than 3 pallets high.
Keep container tightly closed. Container that have been opened must be carefully resealed and
kept upright to prevent leakage.
Prevent unauthorised access.
This is highly flammable liquid. Refer to the requirements of local regulations for the storage
and handling regulations petaining to this material.

8. EXPOSURE CONTROL / PERSONAL PROTECTION


Engineering measures : Provide adequate ventilation. Where resonably practicable, this should be achived by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and solvent vapours below the occupational exposure limits (OEL)
suitable respirator must be worn.
Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Occupational Exposure Limits


Material
STEL-15 min.ave Long term-TWA-8hr
xylene 150 ppm 100 ppm
n-butanol 100 ppm 50 ppm
Butanone 899 mg/m3 600 mg/m3
4-methylpentan-2-one 300 ppm 200 ppm

Personal protection equipment


Respiratory Protection : Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered
if practical.
Eye Protection : Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of
liquids. Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection : Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection : Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

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9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state : ( ) Solid ( x ) Liquid Odour : Smell of solvent Density : 1.50 g/cm3
( ) Paste ( ) Powder Colour : Various Flash point : 23 °C
Solubility : Insoluble in water Explosion limits : LEL% 1.4 UEL% 12.3

Vapour pressure : 1940 Pa, 20 °C Autoignition temperature : 432 °C


10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see section 8). When exposed to high teemperatures may produce
hazardous decomposition products such as carbon monoxide, carbon dioxide, oxide of nitrogen ans smkoe.

Keep away from oxidising agents, strongly alkaline and strong acid materials in order to avoid possible exothermic reactions.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.

Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
Aquatic ecotoxicity
Material name Test Result Species Exposure
xylene Mortality Actute LC50 3300 to 4093 u/L Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
trout,donaldson-trout-
Oncorhynchus mykiss
4-methylpentan-2-one Mortality Actute LC50 53700 to Fish-Fathead minnow 96 hours
3320000 u/L Pimephales promelas
Butanone Intoxication Actute EC50 5091000 to Daphnia-Water flea 48 hours.
6440000 u/L Daphnia-Magna
Fresh water
Mortality Actute LC50 3220000 to Fish Fathead minnow 96 hours.
3320000 u/L Pimephales promelas
Fresh water
n-butanol Intoxication Actute LC50 198300 to Daphnia-Water flea- 48 hours.
2072000 u/L Fresh water Daphnia magna.
Mortality Actute LC50 2250000 u/L Fish - Bleak alburnus 96 hours
Marine water
Biodegradability
Ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily

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13. DISPOSAL CONSIDERATION


Method of disposal : Do not allow into drain or water courses. Wastes and empty containers should be disposal
of in accordance with regulations made under the Control of Pollution Act and the
Environmental Protection Act.

Using information provided in this data sheet advice should be obtained from the Waste
Regulation Authority, whether the special waste regulations apply.

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint
UN number : 1263
Class : 3
Packing group : III
Label :

Additional information
ADR / RID : Hazardous identification no. : 30
: Special provision : 640E
IMDG : Class : 3
Proper shipping name : Paint
Emergency schedules (EmS) : F-E, S-E
Marine pollutant : No

15. REGULATORY INFORMATION

The product complies with these local regulations.


EU regulations : The product is classified and labelled for supply in accordance with the Directive 1999/45/EC
as follows:
hazard symbol :

Harmful

Risk phrases : R10 Flammable


R20/21 Harmful by inhalation and in contact with skin
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.

Safety pharses : S23 Don not breathe vapour / spray.


S36/37 Wear suitable protective clothing and gloves.
S51 Use only in well-ventilated areas.

Contains : Xylene , Epoxy resin MW 700-1100 and MW <700

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16. OTHER INFORMATION


CEPE Classification : 1
Full text of R-pharses : R10 Flammable
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R36/37 Irritating to eyes and respiratory system.
R36/38: Irritating to eyes and skin.
R38 Irritaing to skin.
R50/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R66 Repeated exposure may cause skin dryness or cracking.

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Material Safety Data Sheet is required according to legislation.

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84

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MATERIAL SAFETY DATA SHEET


1. PRODUCT AND COMPANY IDENTIFICATION
Product name : UMEGUARD SX-HS , HARDENER Product No. : 6193S
Manufacutrer / Supplier : TOA-Chugoku Paints Co.,Ltd
110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpokong Chachoengsao, 24180
Telephone no. 66 02 2602701-8 , 66 038 570498-9 Fax : 66 02 2602700 , 66 038 570500
In case of emergency : Telephone no. 66 02 2602701-8 , 66 038 570501
Material intended use : Coating: Solvent ( Refer to technical data sheet )
2. HARZARDS IDENTIFICATION

3. COMPOSITION / INFORMATION ON INGREDIENTS


This product contains the following hazardous ingredients
Ingredient name CAS No. EC No. % by weight Classification
Xylene 1330-20-7 215-535-7 3 R10
Xn; R20/21
Xi; R38
n-butanol 71-36-3 200-751-6 9 R10
Xn; R22
Xi; R41 , R37/38
2,4,6 tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 1 Xn; R22
Xi; R36/38
4. FIRST-AID MEASURES
First-aid measures
General : In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation : Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious, place in recovery position and seek medical advice.
Ingestion : If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.

5. FIRE FIGHTING MEASURES


Extinguishing media : Recommended : alcohol-resistant foam, CO2, powders, water spray.
Do not use - water jet.
Recommendation : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Approprirate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire to sewers or waterways.

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6. ACCIDENTAL RELEASE MEASURES


Personal precautions : Remove sauces of ignition and ventilation the area, avoid breathing vapour or mist.
Do not turn lights or unprotected electricalequipment on or off.
Spill : Contain and absorb spillage with non-combustible material e.g. sand, earth, vermiculite.
Place in closed container outside building and disposal according to local regulation.
Preferably clean with a detergent. Do not use solvents.
Do not allow spills to enter drains or watercauses.
If drain, lakes, river, or sewers are contimated , inform the appropriateauthorities in
accordance with local regulations.
Note : see section 8 for personal protective equipment and section 13 for waste disposal.

7. HANDLING AND STORAGE


Handling : This coating contains solvents. Solvent vapours are heavier than air and may spread along floors.
vapours may form explosive mixtures with air. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentrations higher than the occupational exposure limits.

In storage : Handle containers carefully to prevent damage and spillage.


Naked flames and smoking should not be permitted in storage areas. It is recommended that
fork lift trucks and electrical equipment are protected to the appropriate standard.

In use : Avoid skin and eye contact. Avoid inhalation of vapours and spray mists.

Observe label precaution. Put on appropriate personal protective equipment.

Smoking, eating and drinking should be prohibited in areas where this material is handled.

Never use pressure to empty. Container is not a pressure vessel. Always keep in containers made
from the same material as the original one.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static and
antistatic footwear; floor should be conductive type.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapour in all case. In such
circumstances they should wear a compressed air-fed respirator during the spraying process
and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
Storage ; Store in accordance with local regulation. Observe label precautions. Store in a cool,
well ventilated area away from incompatible materials and sauce of heat and direct sunlight.

Keep away from ; oxidising agent, strong alkalis, strong acids.


Store on concrete or other impervious floor, preferably with bunding to contain any spillage.
Do not stack more than 3 pallets high.
Keep container tightly closed. Container that have been opened must be carefully resealed and
kept upright to prevent leakage.
Prevent unauthorised access.
This is highly flammable liquid. Refer to the requirements of local regulations for the storage
and handling regulations petaining to this material.

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8. EXPOSURE CONTROL / PERSONAL PROTECTION


Engineering measures : Provide adequate ventilation. Where resonably practicable, this should be achived by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and solvent vapours below the occupational exposure limits (OEL)
suitable respirator must be worn.
Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Occupational Exposure Limits


Material
STEL-15 min.ave Long term-TWA-8hr
xylene 150 ppm 100 ppm
n-butanol 100 ppm 50 ppm

Personal protection equipment


Respiratory Protection : Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered
if practical.
Eye Protection : Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of
liquids. Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection : Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection : Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state : ( ) Solid ( x ) Liquid Odour : Smell of solvent Density : 0.91 g/cm3
( ) Paste ( ) Powder Colour : Yellowish Clear Flash point : 27 °C
Solubility : Insoluble in water Explosion limits : LEL% 1.4 UEL% 12.3

Vapour pressure : 4200 Pa, 20 °C Autoignition temperature : 343 °C


10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see section 8). When exposed to high teemperatures may produce
hazardous decomposition products such as carbon monoxide, carbon dioxide, oxide of nitrogen ans smkoe.

Keep away from oxidising agents, strongly alkaline and strong acid materials in order to avoid possible exothermic reactions.

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11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.

Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
Aquatic ecotoxicity
Material name Test Result Species Exposure
xylene Mortality Actute LC50 3300 to 4093 u/L Fish-Rainbow 96 hours.
Fresh water trout,donaldson-trout-
Oncorhynchus mykiss
trout,donaldson-trout-
Oncorhynchus mykiss
n-butanol Intoxication Actute LC50 198300 to Daphnia-Water flea- 48 hours.
2072000 u/L Fresh water Daphnia magna.
Mortality Actute LC50 2250000 u/L Fish - Bleak alburnus 96 hours
Marine water
Biodegradability
Ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily

13. DISPOSAL CONSIDERATION


Method of disposal : Do not allow into drain or water courses. Wastes and empty containers should be disposal
of in accordance with regulations made under the Control of Pollution Act and the
Environmental Protection Act.

Using information provided in this data sheet advice should be obtained from the Waste
Regulation Authority, whether the special waste regulations apply.

Page 4 / 6
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14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint
UN number : 1263
Class : 3
Packing group : III
Label :

Additional information
ADR / RID : Hazardous identification no. : 30
: Special provision : 640E
IMDG : Class : 3
Proper shipping name : Paint
Emergency schedules (EmS) : F-E, S-E
Marine pollutant : No

15. REGULATORY INFORMATION

The product complies with these local regulations.


EU regulations : The product is classified and labelled for supply in accordance with the Directive 1999/45/EC
as follows:
hazard symbol :

Harmful

Risk phrases : R10 Flammable


R20 Harmful by inhalation.
R41 Risk of serious damage to eyes.
R38 Irritaing to skin.
R43 May cause sensitisation by skin contact.

Safety pharses : S23 Do not breathe vapour / spray


S24 Avoid contact with skin
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S37/39 Wear suitable gloves and eye/face protection.
S51 Use only in well-ventilated areas.

Contains : Xylene

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16. OTHER INFORMATION


CEPE Classification : 1
Full text of R-pharses : R10 Flammable
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R37/38 Irritating to respiratory system and skin.
R38 Irritaing to skin.
R41 Risk of serious damage to eyes.

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Material Safety Data Sheet is required according to legislation.

Page 6 / 6
91

No.TH 5512
Jan' 20
UNY MARINE HS
UNY MARINE HS, based on acrylic polyol and non-yellowing polyisocyanates resin , has excellent
gloss retention, durability and chemical resistance, etc . It is suitable for protection of tank , tower, bridge
and other steel structures.

TECHNICAL DATA
Type : Acrylic aliphatic polyurethane paint (non yellowing), high solid
Recommended Use : Finish coat of Epoxy system for bridge, chemical plant oil tank
and steel structures, etc.
Mixing Ratio : Base : Hardener = 80 : 20 (by volume) , 5 : 1 (by weight)
Colour : White , as specified
Flash Point : Base = 23.5°C Hardener = 29°C
VOC : 430 [g/litre] EPA method-24
Solid by Volume : 61.0 ± 2%
Coverage (Theoretical) : 0.07 - 0.12 l/m2 ; 15.3 - 8.1 m2/l
Wet Film Thickness : 2.62 - 4.92 mils ; 66 - 123 microns
Dry Film Thickness : 1.60 - 3.00 mils ; 40 - 75 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 40 microns) : Surface Dry 2 hrs. 1 hr. 30 mins. 15 mins.
: Hard Dry 14 hrs. 8 hrs. 7 hrs. 4 hrs.
Painting Interval : Minimum 6 hrs. 4 hrs. 2 hrs. 1 hr.
(at D.F.T. 40 microns) : Maximum - - - -
Pot Life : 8 hrs. 7 hrs. 6 hrs. 4 hrs.
Thinner : CMP-41
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 5°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 715 , 813
Paint output pressure 12 - 15 MPa.
Viscosity 25 - 35 sec (Ford Cup No.4)
Thinning 0 - 15 % by volume
Preceding coats : Epicon HB-CL, Epicon HB-NP, Epicon Undercoat , Epicon F-HS ,
Umeguard HS , Umeguard HS Silver, Univan HS , etc.
Subsequent coats : -
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
92

No.TH 5512
ม.ค. 63
ยูนิ มารีน เอชเอส
ยูนิ มารีน เอชเอส ประกอบด้วยเรซิ�น อะคริลิค โพลิออล และไอโซไซยาเนตชนิดไม่ขึ�นเหลืองให้คุณสมบัติที�ดีเลิศในด้านคง
ความเงา ทนทาน ต่อสารเคมี ช่วยปกป้องโครงสร้างเหล็กต่างๆ จากแสงอุลตร้าไวโอเล็ต (U.V. PROTECTION) ดังนั�นจึง
เหมาะสําหรับ สะพาน ถังนํ�ามัน โรงงานเคมีและโครงสร้างเหล็กอื�นๆ
ข้อมูลทางเทคนิค
ชนิด : อะคริลิค อะลิฟาติค โพลียูรีเทน (ไม่เหลือง) ชนิดเนื�อสีสูง
การใช้งาน : ใช้เป็นสีทับหน้าในระบบ "อีพอกซี" ที�มีความเงางามเหมาะสําหรับงานสะพาน
ถังนํ�ามันและโครงสร้างเหล็กอื�นๆ
อัตรส่วนผสม : เนื�อสี : นํ�ายา = 80 : 20 (โดยปริมาตร) , 5 : 1 (โดยนํ�าหนัก)
สี : ขาว ,ตามที�ระบุ
จุดวาบไฟ : เนื�อสี 23.5 องศาเซลเซียส นํ�ายา 29 องศาเซลเซียส
ปริมาณสารอินทรีย์ระเหย : 430 [กรัม/ลิตร]
เนื�อสีโดยปริมาตร : 61.0 ± 2%
การปกคลุมพื�นผิวโดยทฤษฏี : 0.07 - 0.12 ลิตร / ต.ร.ม. : 15.3 - 8.1 ต.ร.ม. / ลิตร
ความหนาฟิล์มเมื�อเปียก : 2.62 - 4.92 มิล : 66 - 123 ไมครอน
ความหนาฟิล์มเมื�อแห้ง : 1.60 - 3.00 มิล : 40 - 75 ไมครอน
ระยะเวลาแห้ง : อุณหภูมิ 10°C 20°C 30°C 40°C
ที�ความหนา 40 ไมครอน : แห้งผิว 2 ชั�วโมง 1 ชั�วโมง 30 นาที 15 นาที
: แห้งแข็ง 14 ชั�วโมง 8 ชั�วโมง 7 ชั�วโมง 4 ชั�วโมง
ระยะเวลาแห้งก่อนทาสีทับ : อย่างน้อย 6 ชั�วโมง 4 ชั�วโมง 2 ชั�วโมง 1 ชั�วโมง
ที�ความหนา 40 ไมครอน : อย่างมาก - - - -
อายุการใช้งานหลังผสม : 8 ชั�วโมง 7 ชั�วโมง 6 ชั�วโมง 4 ชั�วโมง
ทินเนอร์ : CMP-41
วิธีใช้งาน : เครื�องพ่นไร้อากาศ , แปรง , ลูกกลิ�ง
ข้อแนะนําการปฎิบัติงาน : อุณหภูมิ อย่างน้อย 5 องศาเซลเซียส
ความชื�นสัมพัทธ์ อย่างมาก 85%
สําหรับเครื�องพ่นไร้อากาศ
ขนาดหัวพ่นกราโค 715 , 813
ความดันที�เครื�องพ่น 12 - 15 เมกาปาสกาล
ความหนืด 25 - 35 วินาที (ถ้วยฟอร์ด เบอร์ 4)
การเจือจาง 0 - 15 % โดยปริมาตร
สีชั�นก่อนทาสีนี� : อิพิคอน เอชบี-ซีแอล, อิพิคอน เอชบี-เอ็นพี, อิพิคอน อันเดอร์โค้ท, อิพิคอน เอฟ-เอชเอส
ยูมิการ์ด เอชเอส, ยูนิแวน เอชเอส, อื�นๆตามที�ระบุในระบบสี
ทาทับด้วยสี : -
ประเภทการบรรจุ : 2 ส่วนผสม ที�ขนาดบรรจุ 3.785 ลิตร/ชุดแกลลอน , 18.925 ลิตร/ชุดถัง
อายุการเก็บที� 25°C : เนื�อสี 24 เดือน , นํ�ายา 24 เดือน ภายในภาชนะที�ไม่ถูกเปิด

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
93

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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : UNY MARINE HS , BASE
Product No. : TH 5512
Product Type : Polyurethane resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION OF MIXTURE Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Respiratory sensitizer NC.
Skin sensitizer NC.
Germ cell mutagenicity NC.
Carcinogenicity NC.
Reproductive Toxicity NC.
Effects on or via lactation NC.
Specific target organ toxicity (single exposure) 1 (Respiratory, liver, central nervous system,kidney)
Specific target organ toxicity (repeated exposure) 1 (Respiratory, nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 2 Toxic to aquatic life
Long-term hazards to the aquatic 2 Toxic to aquatic life with long lasting effects
Hazard to the Ozone Layer NC.
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
CRITERIA
No. Substance name CAS No. W.t (%)
TLV LD50
1 Xylene 1330-20-7 10 - 15
2 Low Boiling point Naphtha 64742-95-6 0-2
3 Naphtha (Petroleum),Hydrotreated Heavy 64742-48-9 0-2
4 N-Butyl Acetate 123-86-4 5 - 10
5 Polymethyl Methacrylate 9011-14-7 35 - 55
6 Hydroxyphenyl-Benzotriazole Derivatives. 104810-48-2 0.1 - 1

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular

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or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.


Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations

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6.3. Methods and material for containment and cleaning up


Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.
Exposure Limits ACGIH TLV
Substance name STEL-15 min.ave Long term-TWA-8hr
Xylene 150 ppm 100 ppm
Low Boiling point Naphtha Limit 19 ppm
Naphtha (Petroleum),Hydrotreated Heavy Limit 197 ppm
N-Butyl Acetate 200 ppm 150 ppm
Polymethyl Methacrylate 150 ppm 100 ppm
Hydroxyphenyl-Benzotriazole Derivatives. N.A N.A

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.15 - 1.25
Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water
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Explosion limits : LEL% 1.8 : UEL% 12.3


Vapour pressure : 370 Pa at 20°C
Autoignition temperature : 296°C
Flash point : 23.5°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6,193 mg/l,Rat
Naphtha (Petroleum),Hydrotreated Heavy >5000 mg/kg,Rat >5000 mg/kg,Rabbit >5 mg/l,Rat
N-Butyl Acetate 10760 mg/kg,Rat 9683 mg/kg,Rabbit >20,0 mg/l,Rat
Polymethyl Methacrylate >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Hydroxyphenyl-Benzotriazole Derivatives. >5000 mg/kg,Rat >2000 mg/kg,Rat 5,8 mg/l,Rat
Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

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STOT - single exposure:


Conclusion/Summary on mixture : No specific data.

STOT - repeated exposure:


Conclusion/Summary on mixture : No specific data.
Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Low Boiling point Naphtha EC50/48h 3,2 mg/l (Daphnia Magna), LC50/96h 9,2 mg/l (Oncorhynchus mykiss), IC50 - Not available
Naphtha (Petroleum),Hydrotreated Heavy EC50/48h >1000 mg/l (Daphnia magna), LC50/96h >1000 mg/l (Oncorhynchus mykiss), IC50 - Not available
N-Butyl Acetate EC50/48h 44 mg/l (Daphnia magna), LC50/96h 18 mg/l (fish), IC50/72h 674,7 mg/l (Algae)
Polymethyl Methacrylate EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Hydroxyphenyl-Benzotriazole Derivatives. EC50/48h 4,0 mg/l (Daphnia magna), LC50/96h 2,8mg/l (Oncorhynchus mykiss), IC50 - Not available

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12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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PAINTING PROCEDURE
Steel Service and Construction
for The Shell Company of Thailand : SCOT Phoenix Project
Painting System LC2-N/M : Un-Insulated Carbon Steel, Serviced temp. 120o C < Temp. < 200o C

SURFACE PREPARATION SSPC-SP10 (Near-white metal)


The surface should be free from dirt, dust, oil,
grease, rust and etc. before paint.
Should be not over 4-6 hrs.
1st Coat GALBON S-HB
[ Inorganic zinc silicate, high build type ]
Dry Film Thickness 80 Microns
Painting Interval Min. 14 Hrs. @Temp. 30o C
Max. 180 Days @Temp. 30o C
2nd Coat SILICON AS
[ Silicone resin heat resisting paint ]
Dry Film Thickness 35 Microns
Painting Interval Min. 5 Hrs. @Temp. 30o C
Max. - Days
3rd Coat SILICON AS
[ Silicone resin heat resisting paint ]
Dry Film Thickness 35 Microns
Painting Interval Min. 5 Hrs. @Temp. 30o C
Max. - Days
Total Dry Film Thickness 150 mm

MKT-F-04-1-01/06/60
102

No.TH 6250
Jan' 20
GALBON S-HB
GALBON S-HB, is an inorganic zinc coating based on ethyl silicate and zinc dust type II per ASTM D-520.
It has zinc content by weight in dry film 86% comform to SSPC Paint No.20 Level 1 and ISO 12944-5. It gives
protection against corrosion prolonged weather resistance, good abrasion.
It also has continuous dry heat resistance up to 400°C and peak at 540°C for 1 hour.

TECHNICAL DATA
Type : Inorganic zinc silicate , high-build type
Recommended Use : As a protective coating outside of tank , pipe, steel structure, etc.
Mixing Ratio : Base : Zinc dust = 30 : 70 (by weight)
Colour : Grey
Flash Point : Base 14.5°C
VOC : 491 [g/litre] EPA method-24
Solid by Volume : 60.0 ± 2%
Coverage (Theoretical) : 0.08 - 0.14 l/m2 ; 12.0 - 7.06 m2/l
Wet Film Thickness : 3.33 - 5.67 mils ; 83 - 142 microns
Dry Film Thickness : 2.00 - 3.40 mils ; 50 - 85 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 75 microns) : Surface Dry 30 mins. 20 mins. 10 mins. 5 mins.
: Hard Dry 5 hrs. 4 hrs. 3 hrs. 2 hrs.
Painting Interval : Minimum 32 hrs. 20 hrs. 14 hrs. 6 hrs.
(at D.F.T. 75 microns) : Maximum 180 days 180 days 180 days 180 days
Pot Life : 10 hrs. 7 hrs. 5 hrs. 3 hrs.
Thinner : CMP-61
Method of Application : Airless spray, Brush is recommended for small touch up area.
Conditions of Application : Temperature 5 - 50°C
Humidity 50 - 95 % RH
For Airless spray
Tip No. GRACO 419 , 519
Paint output pressure 9.8 MPa.
Viscosity 10-12 sec (Ford Cup No.4)
Thinning 0 - 5% by volume
Surface preparation : Surfaces must be clean and dry ,remove dirt, dust, oil and all other
contaminants that could interfere with adhesion of the next coat.
Steel : Recommend Blast cleaning to Sa 2½ (ISO 8501-1)
Anchor profile 30-65 µm are recommended for the highest performance.
Preceding Coats : Cerabond 2000
Subsequent Coats : Epicon series, Umeguard series , Silicon series, etc
Packaging : Two pack product : 3.8 Litres / Gallon
Shelf life at 25°C : Base 6 months , Zinc dust 12 months , In unopened container

Note ; 1.Dry film thickness in excess of 5.0 mils (125 microns) is not recommended
2.Before apply the next coat the paint film of GALBON S-HB must dry clean and free of zinc salts, etc.
3. Mist coat is required to minimize topcoat bubbling, thinning 30-40% is recommended.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
103

No.TH 6250
ม.ค. 63
กัลบอน เอส-เอชบี
กัลบอน เอส-เอชบี เป็ นสีประเภทอินออกานิคซิงค์ ซึง่ ประกอบด้วยเอทิล ซิลเิ กตและผงซิงค์ทม่ี คี ณ
ุ ลักษณะตาม ASTM D520
ชนิดที่ 2, ฟิ ลม์ สีเมือ่ แห้งมีปริมาณผงสังกะสี 86% ,มีคณ
ุ สมบัตติ ามคุณลักษณะของ SSPC Paint 20 ระดับ 2 และ ISO 12944-5
ให้คณ ุ สมบัตติ า้ นทานการผุกร่อน ทนต่อสภาวะอากาศได้ยาวนาน ทนต่อสารละลาย น้ ามัน ทนต่อสภาวะอากาศได้ยาวนาน
ทนการขูดขีดได้ดเี ยีย่ มทาให้เกิดเสียหายน้อยเมือ่ มีการเคลือ่ นย้าย
ฟิ ลม์ สีทนต่อความร้อนแห้งแบบต่อเนื่องได้ถงึ 400°C และสามารถทนความร้อนได้สงู ในช่วงเวลา 1 ชัวโมงที่ ่ 540°C
ข้อมูลทางเทคนิ ค
ชนิด : อินออกานิคซิงค์ เอทิลซิลเิ กต ชนิดฟิ ลม์ หนา
การใช้งาน : โครงสร้างเหล็กทัวไป ่ สะพาน ท่อ ซัพพอร์ต และ แทงค์ภายนอก
อัตรส่วนผสม : เนื้อสี : ผงซิงค์ = 30 : 70 (โดยน้ าหนัก)
สี : เทา
จุดวาบไฟ : เนื้อสี 14.5 องศาเซลเซียส
ปริมาณสารอินทรียร์ ะเหย : 491 [กรัม/ลิตร]
เนื้อสีโดยปริมาตร : 60.0 ± 2%
การปกคลุมพืน้ ผิวโดยทฤษฏี : 0.08 - 0.14 ลิตร / ต.ร.ม. : 12.0 - 7.06 ต.ร.ม. / ลิตร
ความหนาฟิ ลม์ เมือ่ เปี ยก : 3.33 - 5.67 มิล : 83 - 142 ไมครอน
ความหนาฟิ ลม์ เมือ่ แห้ง : 2.00 - 3.40 มิล : 50 - 85 ไมครอน
ระยะเวลาแห้ง : อุณหภูม ิ 10°C 20°C 30°C 40°C
ทีค่ วามหนา 75 ไมครอน : แห้งผิว 30 นาที 20 นาที 10 นาที 5 นาที
: แห้งแข็ง 5 ชัวโมง
่ 4 ชัวโมง
่ 3 ชัวโมง
่ 2 ชัวโมง

ระยะเวลาแห้งก่อนทาสีทบั : อย่างน้อย 32 ชัวโมง
่ 20 ชัวโมง
่ 14 ชัวโมง ่ 6 ชัวโมง

ทีค่ วามหนา 75 ไมครอน : อย่างมาก 180 วัน 180 วัน 180 วัน 180 วัน
อายุการใช้งานหลังผสม : 10 ชัวโมง่ 7 ชัวโมง
่ 5 ชัวโมง่ 3 ชัวโมง่
ทินเนอร์ : CMP-61
วิธใี ช้งาน : เครือ่ งพ่นไร้อากาศ , แปรงสาหรับพืน้ ทีข่ นาดเล็ก
ข้อแนะนาการปฎิบตั งิ าน : อุณหภูม ิ อย่างน้อย 5 - 50 องศาเซลเซียส
ความชืน้ สัมพัทธ์ อย่างมาก 50 - 95 %
สาหรับเครือ่ งพ่นไร้อากาศ
ขนาดหัวพ่นกราโค 419 , 519
ความดันทีเ่ ครือ่ งพ่น 9.8 เมกาปาสกาล
ความหนืด 10 - 12 วินาที (ถ้วยฟอร์ด เบอร์ 4)
การเจือจาง 0 - 5 % โดยปริมาตร
แนะนาการเตรียมพืน้ ผิว : เหล็ก : โดยการพ่นทาความสะอาดให้ได้เกรดระดับ Sa 2½ (ISO 8501-1)
เพือ่ ประสิทธิภาพสูงสุด แนะนา ทีค่ วามหยาบ 30 - 65 ไมครอน
สีชนั ้ ก่อนทาสีน้ี : เซราบอนด์ 2000
ทาทับด้วยสี : อิพคิ อน ซีรย่ี ์ , ยูมกิ าร์ด ซีรย่ี ์ , ซิลคิ อน ซีรย่ี ์, อื่นๆตามทีร่ ะบุในระบบสี
ประเภทการบรรจุ : 2 ส่วนผสม ทีข่ นาดบรรจุ 3.8 ลิตร/ชุดแกลลอน
อายุการเก็บที่ 25°C : เนื้อสี 6 เดือน , ผงซิงค์ 12 เดือน ภายในภาชนะทีไ่ ม่ถกู เปิ ด
ไม่แนะนาให้มคี วามหนาฟิ ลม์ เกิน 125 ไมครอน การทา Mist coat เพือ่ ลดการเกิดฟองของสีชนถั ั ้ ดไป แนะนาให้ผสมทินเนอร์ท่ี 30-40%
พืน้ ผิวก่อนทาสีชนถั
ั ้ ดไปบนฟิ ลม์ สีตอ้ งไม่มสี นิม สะอาด แห้ง ไม่มคี ราบเกลือ ฝุ่นผง น้ ามัน บนพืน้ ผิว
The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : GALBON S-HB, BASE
Color : Milky White
Product No. : TH 6250
Product Type : Ethyl Silicate Resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 2 Highly Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 3 Causes mild skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Specific target organ toxicity (single exposure) 3 May cause respiratory irritation drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 Respiratory, Liver , Kidney , Central Nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H303 : May be harmful if swallowed
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness
H373 : May cause damage to organs through prolonged or repeated exposure
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT
H402 : Harmful to aquatic life
H412 : Harmful to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS

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PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Xylene 1330-20-7 2-5
2 Ethylbenzene 100-41-4 0.1 - 0.3
3 1-Methoxy-2-Propanol. 107-98-2 20 - 30
4 Ethyl Silicate 78-10-4 30 - 40
5 Ethanol. 74-17-5 5 - 10

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.

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Keep patient warm and at rest. Do not induce vomitting.


4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).

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Clean preferably with a detergent - avoid use of solvents


6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

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Exposure Limits ACGIH TLV


Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
Ethylbenzene 20 mg/m3 -
1-Methoxy-2-Propanol. 560 mg/m3 375 mg/m3
Ethyl Silicate Limit 1920 mg/m3
Ethanol. Limit 1920 mg/m3

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.13 - 1.14
Colour : Milky White
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 14.5°C
10. STABILITY AND REACTIVITY
Reactivity : No information available

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Stability : Stable under recommended storage and handling conditions


Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat
1-Methoxy-2-Propanol. 4016 mg/kg,Rat >13300 mg/kg,Rabbit 54,6 mg/l,Rat
Ethyl Silicate 6270 mg/kg,Rat 5860 mg/kg,Rabbit 10-16 mg/l,Rat
Ethanol. >2000 mg/kg,Rat >2000 mg/kg,Rabbit >8000 mg/l,Rat
Skin corrosion/irritation:
Conclusion/Summary on mixture : No specific data.

Serious eye damage/irritation:


Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.
Potential acute health effects
Inhalation : Exposure to vapours may cause a health hazard.

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Serious effects may be delayed following exposure.


Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available
1-Methoxy-2-Propanol. EC50/48h 23300 mg/l (Daphnia magna), LC50/96h 6812 mg/l (Leuciscus Idus), IC50 - Not available
Ethyl Silicate EC50/48h >75 mg/l (Daphnia magna), LC50/96h >245 mg/l (Brachydanio rerio), IC50 - Not available
Ethanol. EC50/24h >100mg/l (Daphnia magna), LC50 - Not available, IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.

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Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group II II II
Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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No.TH 8026
Jan' 20
SILICON AS
SILICON AS as based on silicone acrylic resin, has excellent heat-resistance and weathering resistance.
It has the following advantages :-
1. It has excellent heat resistance up to 260°C
2. It has excellent adhesion property.
3. It has excellent weathering resistance.

TECHNICAL DATA
Type : Silicone resin heat resisting paint
Recommended Use : Boiler, Cylinder of engine, the inside of the exhaust pipe,
Radiator Stove, Oil burner, steam pipe, etc.
Colour : White , Grey , As specified.
Flash Point : 27°C
VOC : 540 [g/litre] EPA Method-24
Solid by Volume : 37.0 ± 2%
Coverage (Theoretical) : 0.08 - 0.14 l/m2 ; 12.3 - 7.4 m2/l
Wet Film Thickness : 3.24 - 5.41 mils ; 81 - 135 microns
Dry Film Thickness : 1.20 - 2.00 mils ; 30 - 50 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 30 microns) : Surface Dry 50 mins. 30 mins. 20 mins. 10 mins.
: Hard Dry 8 hrs. 5 hrs. 3 hrs. 1.5 hrs.
Painting Interval : Minimum 12 hrs. 8 hrs. 5 hrs. 2.5 hrs.
(at D.F.T. 30 microns) : Maximum - - - -
Thinner : CMP-91
Method of Application : Airless spray , Brush
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 415
Paint output pressure 8.8 - 11.8 MPa.
Viscosity 25 - 30 sec (Ford Cup No.4 )
Thinning 0 - 15 % by volume
Preceding coats : Galbon S-HB , Galbon S-HB 100 , etc.
Subsequent coats :
Packaging : One pack product ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : In unopened container 24 months

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
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SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : SILICON AS
Product No. : TH 8026
Product Type : Silicon Acrylic resin paint
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Respiratory sensitizer NC.
Skin sensitizer NC.
Germ cell mutagenicity NC.
Carcinogenicity NC.
Reproductive Toxicity NC.
Effects on or via lactation NC.
Specific target organ toxicity (single exposure) 1 (Respiratory, liver, central nervous system,kidney)
Specific target organ toxicity (repeated exposure) 1 (Respiratory, nervous system)
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 2 Toxic to aquatic life
Long-term hazards to the aquatic 2 Toxic to aquatic life with long lasting effects
Hazard to the Ozone Layer NC.
GHS LABEL ELEMENTS
Pictograms

Signal word : Danger


HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H312 : Harmful in contact with skin.
H332 : Harmful if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H304 : May be fatal if swallowed and enters airways.
ENVIRONMENT
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES


P304+P340+P310 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+P310+P330+P331 : IF SWALLOWED: Immediately call doctor/physician. Rinse mouth. Do Not induce vomit.
P305+P351+P338+P337+P313 : IF IN EYES: Rinse cautiously with water for several minutes.
P303+P361+P352 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P302+P333+P313 : IF ON SKIN : If skin irritation or rash occurs: Get medical advice/attention.
P314 : Get medical advice/attention if you feel unwell.
P363 : Wash contaminated clothing before reuse.
P391 : Collect spillage.

STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Specific of chemical material : Mixture
CRITERIA
No. Substance name CAS No. W.t (%)
TLV LD50
1 Xylene 1330-20-7 25-50
2 Low Boiling point Naphtha 64742-95-6 5-10
3 Ethylbenzene 100-41-4 0.25 - 0.5

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.

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Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
Inhalation
No specific data
Skin contact
Adverse symptoms may include the following: irritation, redness
Eye contact
Adverse symptoms may include the following: irritation, watering, redness
Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed
The exposed person may need to be kept under medical surveillance for 48 hours
Specific treatments
No specific treatment

5. FIRE FIGHTING MEASURES


Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons :
Water jet zinc dust containing product should not be extinguished with water.
Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Approprirate breathing apparatus may be required.
5.3. Advice for firefighters
: Cool closed containers exposed to fire with water.
Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or watercourses.
If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations
6.3. Methods and material for containment and cleaning up

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Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents
6.4. Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or water courses.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Isolate from sources of heat, sparks and open flame.
Avoid skin and eye contact.
Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
Avoid inhalation of dust from sanding.
Smoking, eating and drinking should be prohibited in application area.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
Observe label precautions.
Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition.
No smoking.
Prevent unauthorised access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.
Exposure Limits ACGIH TLV
Substance name STEL-15 min.ave Long term-TWA-8hr
3
Xylene 441 mg/m 220 mg/m3
Low Boiling point Naphtha Limit 125 mg/m3
Ethylbenzene 20 mg/m3 -

ACGIH (American Conference of Governmental Industrial Hygienist)


TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.20 - 1.35
Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 370 Pa at 20°C

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Autoignition temperature : 296°C


Flash point : 27°C

10. STABILITY AND REACTIVITY


Reactivity : No information available
Stability : Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions : When exposed to high temperatures may produce
Hazardous polymerization : None under normal processing.
Conditions to avoid ; Heat, flames and sparks
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smkoe.

11. TOXICOLOGICAL INFORMATION


There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation


Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6,193 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17,8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:


Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:


Conclusion/Summary on mixture : No specific data.

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STOT - repeated exposure:


Conclusion/Summary on mixture : No specific data.
Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects


Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics


Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h
Low Boiling point Naphtha EC50/48h 3,2 mg/l (Daphnia Magna), LC50/96h 9,2 mg/l (Oncorhynchus mykiss), IC50 - Not available
Ethylbenzene EC50/48h 1,8-2,4 mg/l (Daphnia magna), LC50/96h 12,1 mg/l (Pimephales promelas), IC50 - Not available

12.2 Mobility in soil


Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

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13. DISPOSAL CONSIDERATIONS


Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION


Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA


UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III


Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION


Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION


The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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Blasting and Painting


Procedure For Piping Work
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11. EQUIPMENT CALIBRATION & CERTIFICATE


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