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HINT – SHEET
5 4πσd 2 4πσd 2
α m ix = α 1
3 or T∝ −
√ d
105. Ans ( 2 )
Energy supplied by heater = Energy absorbed 110. Ans ( 1 )
by system. If M is mass of water and W is Using, Dalton's law of partial pressures,
water equivalent of calorimeter, then P = P1 + P2 + P3
Pt = (M + W) SΔT nRT nRT nRT
= + +
90 × 10 × 60 V V V
⇒ = (360 + 40) × 1 × (Tf − Ti ) 3nRT
4.2 = ...(i)
Tf = 42.1°C V
1
106. Ans ( 2 ) Here, n = , T = 27°C = 27 + 273 = 300 K
2
As per Stefan's law, the thermal radiation emited V = 5 × 10–3 cc.
by all types of bodies is proportional to T. P = 7.48 × 105 N m–2
1016CMD303122077 HS-3/8
TARGET:PRE-MEDICAL 2023/06-03-2023
111. Ans ( 2 ) 116. Ans ( 1 )
If f is the degree of freedom of a gas molecule, If forces are applied simultaneously on body in
then same direction
Cp f +2 F = F1 + F2 (mean paralled arrangement)
Cv
= (
f
)
Keq. = K1 + K2 then Teq. decreases
Cp fA + 2 1 1 1
29 So = +
(
Cv
) =
22
= (
fA
)
Teq2 T12 T22
A
3 4
⇒ fA = 6 T1 T2 5
×
5
⇒ Teq . = =
Cp 30 fB + 2 √
−−−
T12
−−−−
+ T22 √
−
9
−−−−−
+
16
( ) = = ( ) 25 25
Cv B 21 fB
12
⇒ fB = 5 =
25
So A has one vibrational degree of freedom and 117. Ans ( 3 )
B has none π
x = 4 sin ωt + 3 sin(ωt + )
112. Ans ( 2 ) 3
π
16 16 1 a1 = 4; a2 = 3 and ϕ =
n1 = = 4 n2 = = 3
4 32 2 −−−−−−−−−−−−−−−−−
R = √a 21 a 22 2a 1 a 2 cos ϕ
4 × 52 R + 1 7 + +
2
×
2
R 47
γ mix = = −−−−−−−−−−−−−−−−−−−−
π
4 × 32 R + 1
×
5
R 29 = √ 42 + 32 + 2 ⋅ 4 ⋅ 3 cos( ) = √
−−
37
2 2 3
113. Ans ( 4 ) R≃6
P 1D 1 − γ
= P 2D 2 −γ
118. Ans ( 4 )
1 × d1 γ = 128 × (32d1)–γ
−
F = mg = 500
γ F = kx
1 1
= ( )
128 32 20
500 = k ( )
1 1 7 100
= ⇒γ= 50000
27 2 5γ 5 k= = 2500 N/m
20
114. Ans ( 4 ) −
m
−−
Q2 T2 T = 2π√
CoP = = k
w T1 − T2 −−
m
−−−
TH
=
10
=
10 2
−−
TL Time period of oscillation ∝ √ L
COP = −−−−
TH − TL T1 L/4 1 T
Qa 1 ∴ = √ = or T1 =
=
T L 2 2
W TH
1
TL
− T
Time taken to complete half the oscillation =
Qa 1 4
10
=
10
− 1
Total time period of oscillation
9 T T 3T
Qa = 9 × 10 = 90 J =
2
+
4
=
4
HS-4/8 1016CMD303122077
LEADER & ACHIEVER COURSE/PHASE-MLA,MLB,MLC,MLD,MLE & MAZA/06-03-2023
120. Ans ( 1 ) 125. Ans ( 4 )
Let they will be in phase after time 't'
then ϕ1 – ϕ2 = π
2π 2π 21
t− t=π ⇒ t= sec
T1 T2 8
121. Ans ( 2 ) No doppler's effect for observer D & B
Both the spring-mass system and torsional
pendulum have no dependence on gravitational
acceleration for their time periods. V ⃗ − V 0⃗
nA = n [ ]
122. Ans ( 2 ) V ⃗ − V s⃗
(Acceleration)max. = ω2a = 5π2 ...(i) 330 − 0
nA = 300 [ ] = 330 Hz
Velocity at y= 4 cm is, 330 − 30
v = ω√a 2
−−−−−−
− y2 = ω√a 2
−−−−
−
−−
2
4
= 3π
For C
−−−− −−
or ω a 2
√ − = 16 3π
2 2 2 330 − 0
Squaring, ω (a
– 16) = 9π ....(ii) nC = 300 [ ]
2 2
330 − (−30)
ω (a − 16) 9π 2 9 330 × 300
So, = =
= S = 275 Hz
ω2 a 5π 2 5 360
a2 − 16 9
or = 126. Ans ( 3 )
a 5
9 ± 41 λ
or a = = 5 or –3.2 cm = l2 − l1 = 59 − 19 = 40cm
10 2
∴ a = 5 cm Third resonance will be observed at
λ
From eqn.(i), ω2 × 5 = 5π2 or ω = π l3 = l2 +
2
= 59 + 40 = 99 cm
∴ T = 2 sec.
127. Ans ( 4 )
123. Ans ( 1 )
U = 5x(x – 4) 5v v v
= + 100 = 100 ⇒
dU 4ℓ ℓ 4ℓ
⇒F=– = – 10x + 20 Fundamental frequency of open end organ
dx
when a = 0 ⇒ x = 2m velocity is maximum v
pipe = 200 Hz
F = – 10x + 20 → SHM eqm 2ℓ
−−−
m −
−−
0.1
T = 2π √= 2π = π/5 sec √
128. Ans ( 4 )
k 10
1
124. Ans ( 4 ) f∝
ℓ
f1 ℓ2 440 ℓ − ℓ/5 440 4
= ⇒ = ⇒ =
f2 ℓ1 f2 ℓ f 5
f = 550
Change in frequency = f2 – f1 = 550 – 440 = 110Hz
129. Ans ( 4 )
At free end Δϕ = 0
As for wire f ∝ √
−−
T so 130. Ans ( 1 )
I ∝ x 20 and I ∝ f 2
f2nd case > f1st case
−−
T f −6 −−− In A x0A = 2x0 and f0A = f0
f1 √ 1 √ 225 15
= ⇒ = = In B x0B = x0 and f0B = 2f0
f2 −−
√ 2 T f +6 √
−−−
256 16
IA
f = 186 Hz ∴ = 1
IB
1016CMD303122077 HS-5/8
TARGET:PRE-MEDICAL 2023/06-03-2023
131. Ans ( 1 ) 137. Ans ( 1 )
t x λmT = constant
y = 4sin2π ( − ) cm
0.02 100 Tsun > Tarc > Tfilament
2πt 2πx λm sun < λm arc < λm filament
y = 4sin ( − )
0.02 100
2π 2π 138. Ans ( 1 )
ω= ⇒ 2πn = Adiabatic compression will increase temperature
0.02 0.02
1 and kinetic energy.
n= ⇒ n = 50 Hz
0.02
ω 2π 100 139. Ans ( 1 )
v= = ×
Graph is b/w P & T
k 0.02 2π
= 5000 cm/sec = 50 m/s (at constant volume as it is st. line having zero
134. Ans ( 2 ) intercept)
∴ V1 = V2 & V3 = V4
Also at constant pressure
V∝T
∴ T2 > T3 ⇒ V2 > V3
140. Ans ( 1 )
2x = Vt1 For an ideal gas PV = nRT
2y = Vt2 m
⇒ PV = RT
2(x + y) = V(t1 + t2) Mw
V (t 1 + t 2 ) d P Mw
⇒ PV = RT ⇒ d =
(x + y) = Mw RT
2
340 (1.5 + 3.5) d1 P1 T2
(x + y) = 850m So, = ×
2
=
d2 P2 T1
d1 P ′ 4T ′
135. Ans ( 3 ) = × = 2 : 1
d2 2P ′ T′
V = λf, as frequency does not change with medium.
350 3500
141. Ans ( 2 )
f= = ⇒ λ2 = 10λ1 3
λ1 λ2 ET = PV = 1.5 P V
2
SECTION-B Also, due to collision velocities of gas molecules changes.
142. Ans ( 1 )
136. Ans ( 2 )
dQ dT For A :
P = = kA ( )
dt dx PV = Constant
Initially, or P1V1 = P2V2
dQ V
∝ A {max. at sec A & min. at sec B} or P2 = P ) = 2P
dt (
V /2
At steady state, For B :
dQ
(
dt
) same for all section PVγ = Constant
Also, or P1Vγ1 = P2Vγ2
γ
dT 1 V γ
( ) ∝ {max. at sec B & min. at sec A} or P2 = P ( ) = 2 P
dt A V /2
P 2 )B 2γ P
& ( dT ) same for all section i.e. zero
(
∴ = = 2γ–1
dt (P 2 )A 2P
HS-6/8 1016CMD303122077
LEADER & ACHIEVER COURSE/PHASE-MLA,MLB,MLC,MLD,MLE & MAZA/06-03-2023
143. Ans ( 2 ) SUBJECT : CHEMISTRY
By FLOT :
dQ = dW + Δu SECTION-A
Also, in adiabatic process 151. Ans ( 2 )
(dQ = 0) dW = –Δu IUPAC name 3-Chloro benzaldehyde
if dW = +ve 152. Ans ( 4 )
then Δu = –ve π=6
144. Ans ( 2 ) 153. Ans ( 1 )
CnH2nO2 ester general formula
154. Ans ( 1 )
IUPAC name 2-Ethyl pent-4-enal
5
Ui =NRT and 155. Ans ( 1 )
2
5 3 (1) CH3–CH2–CHO
Uf = (N − n)RT + (2n)RT
2 2
V = constant ⇒ ΔW = 0 ⇒ ΔQ = dU (2)
ΔQ = Uf – Ui
5 3 5 156. Ans ( 3 )
= (N − n)RT + (2n)RT − NRT Two different groups at ortho position.
2 2 2
1 157. Ans ( 2 )
ΔQ = nRT
2
145. Ans ( 1 )
TV γ–1= K
∣dV ∣ V0 158. Ans ( 4 )
∣ ∣ = = tan θ
∣dT ∣ (γ − 1) T0
V0
⇒ γ = 1+
T0 tan θ SI = 2n
148. Ans ( 2 ) 159. Ans ( 1 )
200
ΔP in decibles = 10 log( )
20
= 10 db
150. Ans ( 3 ) 160. Ans ( 1 )
161. Ans ( 1 )
R–S
Spring P and Q, R and S are in parallel 162. Ans ( 3 )
then, x = k + k + 2k (For P, Q)
and y = k + k = 2k (For R, S)
POS present so optically inactive.
x and y both in series
1 1 1 1 163. Ans ( 3 )
∴ = + =
k′ x y k Chiral
m
−
−− −
m
−−
164. Ans ( 4 )
Time period T = 2π√ ′ = 2π√
k k Identical
1016CMD303122077 HS-7/8
TARGET:PRE-MEDICAL 2023/06-03-2023
165. Ans ( 4 ) 188. Ans ( 4 )
–CH3 don't form H-bonding +M +I
EAR reactivity ∝
167. Ans ( 4 ) −M − I
Reaction based
189. Ans ( 3 )
168. Ans ( 2 ) ℓp containing +M → O/P directing (if para occupied,
Reactivity ∝ leaving group tendency
then ortho major)
169. Ans ( 4 )
Only 4th option have α H 190. Ans ( 3 )
170. Ans ( 3 ) –charactertics reaction
191. Ans ( 4 )
171. Ans ( 2 )
Reaction c form propane
172. Ans ( 4 )
all catalyst are used in this process
173. Ans ( 4 )
Reaction proceed by SN2 192. Ans ( 3 )
176. Ans ( 4 )
HS-8/8 1016CMD303122077