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SOLUTIONS
PHYSICS
7. Ans : (1)
SECTION A The number of electrons lost
1. Ans : (1) 3 × 10−7
n=
Charge is a scalar (or invariant) under rotation; 1.6 × 10−19
it is also invariant for frames of reference in rel- = 1.875 × 1012
ative motion. This is not always true for every ∆ m = 1.875 × 1012 × 9.1 × 10−31
scalar. For example, kinetic energy is a scalar ' 2 × 10−18 kg
under rotation, but is not invariant for frames of
reference in relative motion. 8. Ans : (2)
The force of interaction is
2. Ans : (1) kq2 F r2
2
The additive property of charge is not an ’obvi- F=
r2
⇒ q =
k
ous’ property. It is related to the fact that elec- q
n=
tric charge has no direction associated with it; e
charge is a scalar.
9. Ans : (1)
This is the ratio of electric force to the gravita-
3. Ans : (2)
tional force (at the same distance) between an
Conservation of total charge of an isolated sys-
electron and a proton.
tem is a property independent of the scalar na-
ture of charge. Conservation refers to invariance
10. Ans : (4)
in time in a given frame of reference.
kq 1 q 2
F21 = (r2 − r1 )
| r2 − r1 | 3
4. Ans : (4)
1 × q1 × q2
The electric field due to a discrete charge con- = (−2î + ĵ − 3k̂)
4πε0 | − 2î + ĵ − 3k̂|3
figuration is not defined at the locations of the
q 1 q 2 (−2î + ĵ − 3k̂)
discrete charges. For continuous volume charge = p
distribution, it is defined at any point in the dis- 56 14πε0
tribution. For a surface charge distribution, elec- 11. Ans : (4)
tric field is discontinuous across the surface. The force will be minimum when the interacting
charges are the least, which is equal to electronic
5. Ans : (1)
charge.
The overall charge of the universe remains con-
ke2
stant; however, the quantities of positively and F= ⇒ F = 2.3 × 10−24 N
r2
negatively charged particles may vary through
processes like pair production and pair anihila- 12. Ans : (2)
tion. Nevertheless, these quantities always re- The expansion of the soap bubble occurs, regard-
main equal at any given moment. less of the charge’s nature, as a result of the mu-
tual repulsion between the charges.
6. Ans : (3)
1
13. Ans : (2) is outside the charges on the line joining them
near the charge of smaller magnitude.
Since, A is in equilibrium,
ΣF = 0 ⇒ T AB =
K q(4 q) K q(2 q) 3K q2
+ =
20. Ans : (4)
(2 d )2 d2 d2 kq
E= (r2 − r1 ) = (5.4î − 7.2ĵ)
Since, C is in equilibrium ΣF = 0 |r2 − r1 |3
K q(4 q) K (2 q)(4 q) 9K q2
⇒ TBC = + = 21. Ans : (2)
(2 d )2 d2 d2
The net electric field will be equal to the electric
T AB 3K q2 / d 2 1
= = field due to the missing charge at the sixth ver-
TBC 9K q2 / d 2 3
tex.
14. Ans : (1) ⇒E=
kq
F (2a)2
In air tan θ =
mg
F /κ 22. Ans : (4)
In liquid tan θ = ρℓ
mg(1 − )
ρb
1
⇒κ= ρℓ = 2
1−
ρb
F=
2 kqq 0
y 24. Ans : (4)
a3 Work done by the electric field is equal to change
F∝y in kinetic energy of the charge.
2
rρ 1 2 d 1 qE 2
E inside = y= at ⇒ = t
3ϵ 0 2 2 2 m
√
29. Ans : (2) t=
md
The electric field at all points on the y− axis are qE
√
in the same direction. md mdv2
x = vt ⇒ L = v ⇒q=
qE EL2
30. Ans : (4)
39. Ans : (1)
31. Ans : (2) Since the resultant field is always in the positive
direction, a should be positive and b should be
32. Ans : (1) negative. The resultant field at a distance x from
Number of lines is proportional to the flux a is given by
through gaussian surface enclosing the charge kq kq
E= +
q x2 ( r − x)2
⇒ϕ=
ϵ0
40. Ans : (4)
33. Ans : (4) The electric field at S will not change by moving
mv2 λq the charge q inside the cavity.
=
r 2πϵ0 r
41. Ans : (1)
34. Ans : (1) 2 kλ
For circular motion mr ω2 = qE , but E =
The electron is to be considered as a projectile r
3
48. Ans : (1) 49. Ans : (1)
Kq2
K Cq 2 The electric field inside the inner shell is zero
Net force on + q = + p =0 and in between the shells and outside the outer
p 4 a2 2 2 a2
1
C=−
2 2 1
= −p shell, the field is proportional to
4 2 r2
CHEMISTRY
has to be dissolved.
SECTION A So, 1 molar is more concentrated than 1 molal.
4
azeotropic mixture is formed. 76. Ans(4)
1
700 ×
68. Ans(1)
χBenzene = ( ) (2 )
For more concentrated solution, vapour pressure 1 1
700 × + 600 ×
is very low and to prevent in-flow of pure wa- 2 2
ter though a semi permeable membrane, greater 700
= = 0.54
pressure has to applied than for a dilute solution. 1300
77. Ans(4)
69. Ans(1)
Osmotic pressure method has the advantage that
Hypotonic solution has low concentration and
even for very low concentration, large osmotic
water will flow into the cell leading to swelling
pressure is developed, which is easy to measure
of the cell.
(Elevation in the boiling point and depression in
freezing point have comparatively very low val-
70. Ans(1)
ues.)
M A RT02
Kb =
1000∆vap H 78. Ans(1)
∆T f = k f (1 − α + nα) × m
71. Ans(1)
= 1.86 × (1 − 0.3 + 2 × 0.3) × 0.2 = 0.48◦ C
Elevation in boiling point and depression in
freezing point depends upon the solvent chosen,
79. Ans(4)
because every solvent has a distinct k b &k f val-
neither association, nor dissociation
ues.
80. Ans(1)
72. Ans(2)
Here, for glucose Van’t Hoff factor is 1, so rela-
Reverse osmosis is a non-spontaneous process
tive lowering of vapour pressure will be the low-
and here solvent flows from high concentration
est and so vapour pressure will be the highest.
side to low concentration side when external
pressure is applied. 81. Ans(3)
Ptotal = P ◦A × χ A + PB◦
× χB
73. Ans(2) ◦ ◦
= P A × χ A + PB × χB = 220 − 110χB
Here, with increase in the number of parti- ( )
= P ◦A × 1 − χB + PB ◦
× χB
cles/ions per mole of substance chosen, more ◦ ◦ ◦
= P A − P A χB + P B × χB
will be the colligative property, more will be the ( ◦ )
= P ◦A + PB − P ◦A χB = 220 − 110χB
lowering of vapour pressure, for same molar so-
Comparing LHS and RHS, P ◦A = 220 torr
lutions. ( )
Again, PB◦ − P ◦A = 110
so, PB◦ = 110 + P ◦A = 110 + 220 = 330 torr
74. Ans(1)
Elevation in boiling point being a colligative
82. Ans(1) Mass of the substance in the first solution
property is directly proportional to the concen-
= 500 × 20% = 100g
tration of solute as well as the number of the
Mass of the substance in the second solution =
particle per molecule.
400 × 50% = 200g
Total mass of the substance
75. Ans(1)
( α) = (100 + 200)g = 300g
∆T f = k f 1 − α +
n
×m Total mass of the solution = (500 + 400)g
( α ) wB × 1000 = 900 g
= kf 1−α+ × So, percentage mass of the substance
n W m B × WA
( α ) 20 × 1000 300
= 0.69 = 5.12 × 1 − α + × = × 100 = 33.33%
2 94 × 1000 900
α 0.69 × 94
=> 1 + = = 0.633; 83. Ans(4)
2 5.12 × 20
α 0.1MCa (NO3 )2 and 0.1MNa2 SO4 has 0.3 molar
2
= 0.367; α = 0.734 = 73.4% ionic concentration each and so will be isotonic.
5
84. Ans(3) P0 − P P0 − 250 2
Here = χB ; = − − − −(1),
Here, Vant Hoff factor, P0 P0 7
i = 1 − α+ nα = 1 − 0.25 + 5 × 0.25 = 2 for the first solution; cross multiplying,
Ideal molar mass 7P0 − 1750 = 2P0 ; 5P0 = 1750;
i=2= ; so
Observed molar mass P0 = 350 torr
Ideal molar mass = 2× Observed molar mass. P0 − P 3
Again, = − − − −(2),
Or normal molar mass = 2× experimental molar P0 7
for the second solution.
mass
350 − P 3
= ; cross-multiplying,
350 7
85. Ans(4)
4 × 350
let the atomic mass of A and B are respectively 3 × 350 = 7 × 350 − 7P; = 200 torr
7
a &b. Then molar mass of AB2 and AB4 are re-
spectively a + 2 b and a + 4 b. 91. Ans(3)
All are correct
For solution of AB2 ,
WB ×1000
∆T B = k b × 92. Ans(1)
W m B × WA
required pressure > i MRT
1 × 1000
=> 2.55 = 5.1 × = 2 × 0.38× 0.082 × 300 > 18.696 atm
x × 20
5100
x= = 100 93. Ans(2)
2.55 × 20
M1 V1 + m 2 V2 = M3 V3 ; V1 + V2 = V3
For solution of AB4 ,
5V1 + 2V2 = 4 × 1 = 4
WB ×1000
∆T B = k b × V1 + V2 = 1 − − − − − (2);
W m B × WA
(2) × 5 = 5V1 + 5V2 = 5 − − − −−(3)
1 × 1000
=> 1.7 = 5.1 × ; 1
y × 20 (3) −(1) => 3V2 = 1; V2 = L
3
5100 ( )
y= = 150 1 2
1.7 × 20 V1 = 1 − L = L
3 3
then x = a + 2 b = 100 − − (1)
y = a + 4 b = 150 − −(2) 94. Ans(1)
( )
(2) −(1) = 2b = 50; b = 25 520 × χ A + 1000 × 1 − χ A = 760
Feeding this in (1), a + 50 = 100; 520χ A − 1000χ A = 760 − 1000;
so a = 50 480χ A = 240;
Atomic mass of a = 50 240 1
χA = = = 50% each A and B
480 2
SECTION B 95. Ans(1)
d × % mass value × 10
86. Ans(2) M=
W mB
for positive deviation all vapour pressure curves
1.26 × 70 × 10
are convex type. = = 14
63
6
= (1 − α + nα) k f × m Now, 1 − α + nα = 1 − α + 2α = 1 + α = 1.9
= (1 − 0.8 + 2 × 0.8) × 1.86 × 0.5 So, degree of ionization, α = 0.9
= 1.8 × 1.86 × 0.5 = 1.674K
So, freezing point = (273.15 − 1.674)K 99. Ans(3)
= 271.476 K Since evaporation tendency of a is more it will
evaporate at a faster rate than B. naturally the
98. Ans(2) mole fraction of A will be more in the vapour
Van’t Hoff factor, phase than in the liquid phase.
Observed colligative property
i= 100. Ans(3)
ideal colligative property
5.7 This liquid pair is showing positive deviation
= = 1. 9 from ideal behaviour; naturally A-B interactions
3.0
are weaker than A − A and B − B interactions.
7
BOTANY
SECTION A
101. (2) 108. (4) 115. (1) 122. (3) 129. (3)
102. (4) 109. (2) 116. (2) 123. (2) 130. (4)
103. (3) 110. (3) 117. (3) 124. (1) 131. (2)
104. (1) 111. (1) 118. (4) 125. (2) 132. (2)
105. (3) 112. (3) 119. (2) 126. (4) 133. (2)
106. (4) 113. (2) 120. (2) 127. (2) 134. (1)
107. (1) 114. (3) 121. (3) 128. (2) 135. (1)
SECTION B
136. (2) 139. (4) 142. (2) 145. (1) 148. (2)
137. (1) 140. (1) 143. (4) 146. (1) 149. (2)
138. (3) 141. (1) 144. (3) 147. (4) 150. (1)
ZOOLOGY
SECTION A
151. (2) 158. (4) 165. (3) 172. (4) 179. (2)
152. (3) 159. (3) 166. (3) 173. (4) 180. (3)
153. (2) 160. (2) 167. (3) 174. (3) 181. (4)
154. (3) 161. (3) 168. (3) 175. (4) 182. (4)
155. (3) 162. (2) 169. (3) 176. (1) 183. (4)
156. (1) 163. (4) 170. (2) 177. (1) 184. (3)
157. (2) 164. (4) 171. (4) 178. (1) 185. (2)
8
SECTION B
186. (3) 189. (2) 192. (1) 195. (2) 198. (3)
187. (3) 190. (1) 193. (2) 196. (4) 199. (1)
188. (4) 191. (4) 194. (2) 197. (1) 200. (4)