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Chemstry Anual Exam Detailed Answer
Chemstry Anual Exam Detailed Answer
3. At constant temperature, different gases have different KH value. What does this statement
suggest?
Ans: Henry’s constant KH is function of nature of gas (different gas will have different solubility)
Ans: FeO/ K2O solid catalyst in the manufacturing of Ammonia by Haber’s process.
Ans: Helium
Ans: methoxyethane
13. Aldehydes are more reactive than ketones towards Nucleophilic addition reaction. Give reason.
Ans: Due to steric hindrance of alkyl groups and decreased electrophilicity of carbonyl carbon due to
(+I) inductive effect
PART-B
Z M
Ans: d
a3 N A
d a3 N A
M
Z
160.4
40.1g / mol
4
17. Define molarity [M]. How does molarity vary with temperature?
As temperature increases molarity decreases. Temperature and molarity are inversely proportional.
19. What is molar conductance? How is it related to concentration “C” molm-3 and conductivity
“K” Sm-1?
Ans: it is the conductance due to all the ions produced by 1 mol of an electrolyte in given volume of
solution
ᴧm= K/C
20. What is the role of coke in the extraction of zinc from zinc oxide? Write the chemical equation.
21. How do xenon fluorides react with fluoride ion donor like NaF? Give equation.
Ans: xenon fluorides react with fluoride ion donors to form fluroanions
Ans:
NaNO2 HCl
23. Complete the equation. _____ HNO2 H3CN2Cl
H 2O
CH3OH ____ HCl
NaNO2 HCl
Ans: CH3 NH 2 HNO2 H3CN2Cl
H 2O
CH3OH N2 HCl
Ans: Drugs which reduce pain without causing impairment of consciousness. Example for narcotic
analgesic is Morphine
Ans: calcium and magnesium ions present in hard water forms insoluble calcium and magnesium
soaps and seperates out from water and form scum.
Ans: Lowers the melting point of the mix and increases conductivity.
NO thus formed is recycled and aqueous HNO3 can be further concentrated by distillatin upto 68%
by mass. Further it can concentrated upto 98% by dehydration with conc. H2SO4.
Ans: H2SO3
Ans: 2NaHSO3
n(n 2)
5(5 2)
5.9 BM
31. Write the balanced chemical equations in the manufacture of K2Cr2O7 from chromite ore.
Ans: (i) Potassium dichromate is generally prepared from iron chromite ore.
The fusion of chromite ore (FeCr2O4) with sodium or potassium carbonate in presence of air.
The yellow solution of sodium chromate is filtered and acidified with sulphuric acid to give a
solution from which orange sodium dichromate, Na2Cr2O7. 2H2O can be crystallized.
2 Na2CrO4 2 H Na2Cr2O7 2 Na H 2O
Sodium dichromate is more soluble than potassium dichromate. The latter is therefore, prepared by
treating the solution of sodium dichromate with potassium chloride. Orange crystals of potassium
dichromate crystallise out.
Na2Cr2O7 2 KCl K 2Cr2O7 2 NaCl
Hybridisation: sp3d2
Geometry: octahedral
Magnetic behaviour: paramagnetic
Packing efficiency in simple cubic structure: In simple cubic, atoms are located only on the corners
of the cube. Hence the particles touches each other along the edges. Let the edge length of cube be 'a'
and 'r' is the radius of sphere.
37. a) On dissolving 3.46 g of non- volatile solute in 100 g of water, the boiling point of solution was
raised to that of pure water by 0.12 K. Calculate the molar mass of non-volatile solute. (Given:
Kb of water = 0.51 K Kg mol-1).
kb wB 1000
Ans: M B
Tb WA
HKS P U COLLEGE, HASSAN CREATIVE P U COLLEGE, KARKALA CREATIVE P U COLLEGE UDUPI
0.51 3.46 1000
0.12 100
17.646
147.05 g / mol
0.12
b) What type of deviation from Raoult’s law is observed when equal volume of ethanol and
acetone are mixed? Mention the reason for it.
Ans: Shows positive deviations because in pure ethanol molecules are hydrogen bonded. On adding
acetone, its molecules get in between the ethanol molecules and break hydrogen bonds between
them.
38. a) Calculate the value of ΔG0 at 298 K for the cell reaction.
+2
Mg(s) +Cu(aq) Mg(aq)
+2
+Cu(s)
40. a) What is effective collision? Write any two factors responsible for effective collision.
Ans: Collision between activated molecules having proper orientation.
1. Activation energy 2. Proper orientation
b) Show that half-life period of a first order reaction is independent of initial concentration of
the reacting species.
Ans: The rate equation for a reaction of first order is expressed as:
2.303 R0
k log
t R
When t t 1 , R
R0
2 2
On substituting these values, we get
2.303 R 0
t1 log
2 k R 0
2
2.303
t1 log 2
2 k
2.303 0.3010
t1
2 k
0.693
t1
2 k
41. a) Give any three differences between Lyophilic Colloid and Lyophobic Colloid.
Ans:
Lyophilic sols Lyophobic sols.
1. Prepared easily by directly mixing 1. Cannot be prepared directly prepared
with the liquid dispersion medium by special methods only.
5. Viscosity is much higher than that 5. Viscosity is almost the same as that
of dispersion medium dispersion of medium
b) Write the expression of Freundlich adsorption isotherm. In this isotherm, what is the value
of “1/n” to show that adsorption is independent of pressure.
x 1
Ans: kp n
m
Value of 1/n = 0
43. a) Write three steps involved in the mechanism of acid catalyzed dehydration of ethanol to
ethene.
Ans: Mechanism: The mechanism of dehydration of ethanol involves the following steps:
Step 2: Formation of carbocation: It is the slowest step and hence, the rate determining step of the reaction.
45. a) How does formaldehyde reacts with concentrated alkali on heating? Name this reaction.
Ans:
Cannizzaro reaction.
46. a) What type of carboxylic acids undergo Hell- Volhard- Zelinsky (HVZ) reaction. Explain this
reaction with example
Ans: Carboxylic acid containing alpha hydrogen will undergo HVZ reaction.
b) Among formic acid and acetic acid, which is weaker acid and why?
Ans: Acetic acid. Because of due to +I effect of CH3.
49. a) What are fibrous protein? Name the protein present in hair.
Ans: These are the fiber like structure held together by hydrogen and Disulphide bonds.
Ex: Keratin
b) Mention two hormones which regulates the glucose level in the blood.
Ans: Glucagon, Insulin
c) Write the name of the nitrogeneous base present only in DNA, but not in RNA.
Ans: Thymine
50. a) Name the two monomers present in Nylon – 6, 6.
Ans: Hexamethylenediamine and Adipic acid
b) Explain vulcanization of rubber.
Ans: Heating the natural rubber with calculated amount of sulphur at temperature range between
373 -415 K.
c) Write the name of the biodegradable polymer used in manufacture of orthopaedic devices.
Ans: PHB
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