3/17/24, 1:33 PM Which one of the following reactions of Xenon compounds is not feasible?

(A) $Xe{{O}_{3}}+6HF\\to Xe{{F}_{6}}+3{{H}_{2}}O$…

Which one of the following reactions of Xenon compounds is not feasible?

(A) XeO3 + 6H F → XeF6 + 3H2 O

(B) 3XeF4 + 6H2 O → 2Xe + XeO3 + 12H F + 1.5O2

(C) 2XeF2 + 2H2 O → 2Xe + 4H F + O2

(D) XeF6 + RbF → Rb [XeF7 ]

CBSE Chemistry Grade 12 Inert Gases

Last updated date: 16th Mar 2024 • Total views: 369.6k • Views today: 8.69k

Answer Verified

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Hint: The irreversible reactions will be feasible than that of reversible ones. The formation of stable products in a reaction is what we call as
feasible ones. One observation can be made that in the given equations, three of them are about reacting xenon fluorides and one is about
xenon oxide.

Complete step by step solution:

Firstly, let us discuss xenon and its compounds. Xenon is an atom in the modern periodic table having atomic number as 54 with symbol Xe. It
is a noble gas found in trace amounts in earth’s crust. It is generally unreactive, but can undergo some chemical reactions to form some

compounds. The three commonly known fluorides of xenon are XeF2 , XeF4 and XeF6 . Whereas, the three oxides known are XeO3 ,

XeO 4 and XeO2 . According to the illustration given, we need to see which reaction would not be possible. Thus, we need to see that the

reactions are reversible or irreversible simply.

Xenon fluorides- These compounds of xenon can be obtained under appropriate conditions when we react with fluorine with xenon directly.
For example,

N ickel−tube

Xe + F2 −−−−−−−→ XeF2 and similarly, other fluorides are formed.

673K

-All the Xenon fluorides are the powerful fluorinating agents and can be readily hydrolysed by the traces of water. Thus,

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2XeF2 + 2H2 O → 2Xe + 4H F + O 2 is feasible. Centres

-Xenon hexafluoride acts as a Lewis acid when bound to a fluoride ion. Thus, it would form a salt when added to rubidium fluoride to give a
complex as rubidium heptafluoroxenonate.

Hence, XeF6 + RbF → Rb [XeF7 ] is feasible.

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3/17/24, 1:33 PM Which one of the following reactions of Xenon compounds is not feasible?(A) $Xe{{O}_{3}}+6HF\\to Xe{{F}_{6}}+3{{H}_{2}}O$…

-The oxides of xenon are obtained from the other compounds of xenon i.e. xenon fluorides. Hydrolysis of xenon fluorides (XeF4 or XeF6 )
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results in the formation Courses
of xenon oxides. Thus, Free study Offline
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Answer
3XeF4 + 6H2 O → 2Xe + XeO 3 + 12H F + 1.5O 2
Study Materials Sample Papersis feasible. Previous Year Question Papers Exam Info Syllabus

-Now, as we know that the xenon fluorides easily hydrolysed to give xenon oxides. But the vice versa reaction is impossible as xenon

fluorides will again reverse the reaction to give xenon oxides. Thus, XeO3 + 6H F → XeF6 + 3H2 O is not feasible.

Therefore, option (A) is correct.

Note: Xenon does not react with oxygen directly to give xenon oxides. Always xenon oxides are formed from the hydrolysis of xenon
fluorides. So, do note that the vice versa reaction would never be possible as the stability of reaction and reversibility matters.

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