Test ID : 499

GREEN PARK INTERNATIONAL SENIOR SECONDARY SCHOOL, NAMAKKAL

XII (CBSE) PRE-BOARD EXAMINATION (CHEMISTRY - ANSWER KEY) - 26.02.24
Choose the correct answer : 100 x 4 = 400
1. 4) Vitamin B12 8. 4) Formation of an azeotropic mixture
Solution : Solution :
Only vitamin B12 of B group can be stored in Azeotropic mixture is formed by non-ideal
our body. solutions
2. 1) HCHO 9. 3) [Co(en)2(NO2)Cl]Br
Solution : Solution :
H2 O+ Ambidentate ligand ‘NO2’ will show linkage
CH3MgCl + HCHO  → C2H5OH
o
1 alcohol is obtained by action of RMgX on isomerism
HCHO [Co(en)2(NO2)Cl]Br & [Co(en)2(ONO)Cl]Br
3. 4) Sodium bi-carbonate are linage isomers
Solution : 10. 2) t 32g e1g
Solution :
If ∆o < P ⇒ it form high spin complex
eg

4. 3) PhCHOHCH3 t2g
Solution :
⇒ d4 configuration is t 32g e1g
Alcohol with α-H and β-CH3 group will give
iodoform test. 11. 3) Ti < V < Cr < Mn : increasing melting point
5. 3) 4 Solution :
Solution : Correct order of melting point is
Ti < V < Cr > Mn
12. 1) Copper liberates hydrogen from acids
Solution :
Copper has more SRP and it does not liberate
6. 3) 2- bromopentane H2 gas from acids
Solution : 13. 4) Group 12
Br Solution :
| Zn, Cd, Hg have lowest melting point due to
CH 3 − CH 2 − CH 2 − CH − CH 3
weak metallic bonding
Optically active
14. 2) All the ions are coloured
7. 1) Acetone-chloroform
Solution :
Solution :
Ions with unpaired electrons and splitting of
Acetone and chloroform show negative
d-orbitals only show colour property
deviation from Raoult’s law.
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15. 2) zero 21. 3) NH2
Solution : Solution :
From units of rate constant Presence of electron releasing group at para
Mol 1–n
= mol 1 position increases the basic strength of aniline
1–n=1⇒n=0 22. 3) C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH
16. 2) mechanism of reaction as well as relative Solution :
variation of rate with concentration of + I, effect
Basic strength ∝
reactants Involvement of lp
Solution : in conjugation
Order of reaction depends on experimental 23. 4) Hoffmann bromamide reaction
rate law which is determined from mechanism Solution :
of reaction (or) by verifying change in relative O
rate w.r.t concentration of reactants ||
Br2
CH3 − C − NH 2 
4NaOH→ CH3 – NH2 + Na2CO3
17. 2) bar min–1, bar–1/2 min–1
+ 2NaBr + 2H2O
Solution :
3/2
Hoffmann bromamide reaction
r = K. PCH 3 OCH 3
24. 2) Alkane nitriles
–1
Units of r = bar min Solution :
bar SnCl2
Units of K = min–1 = bar–1/2 min–1 R – CN 
HCl
→ R – CHO
bar 3/ 2
25. 1) propane< popanal <propanone < propanol <
18. 2) 271.6 S cm2 mol–1
propanoic acid
Solution :
Solution :
Λ omCaCl2 = λ om(Ca 2 + ) + 2λ om(Cl− ) Boiling point α Intermolecular attractions
= 119 + 2 x 76.3 26. 4) NH2-NH2/ethylene glycol and KOH
2 –1
= 271.6 S cm mol Solution :
19. 2) –1.37V Wolf Kishner reduction is carried with
Solution : NH2-NH2/ethylene glycol and KOH
Given : SHE acts as cathode electrode 27. 2) Nucleophilic addition

E ocell = E oH + / H − E anode
o Solution :
2
The addition of HCN to carbonyl compounds
1.37 = 0 - E oanode is an example of Nucleophilic addition
E oanodeelectrode = –1.37 V 28. 1) adipic acid
Solution :
20. 3) complete the circuit to complete the reaction
Solution :
Salt bridge is used to complete the circuit and
maintain electrical neutrality of electrolytic
solutions
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29. 3) (CH3)3CCHO 37. 3) (CH3)3N
Solution : Solution :
Aldehydes without α-hydrogens can give 3o-amine does not react with Hinsberg reagent
cannizzaro’s reactions 38. 2) On reaction with ice cold nitrous acid
30. 3) Resonance stabilization of their conjugate arylamines produce phenol
base with equivalent structures
Solution :
Solution :
O O O
R C H+
R C R C
O H O O
31. 4) Cu2O
Solution :
CH3CHO + 2Cu2+ + 5OH− → CH3COO− +
Cu2O + 3H2O
39. 4) N-methylprop-2-en-1-amine
32. 4) CH3 – CH = CH – CH2 – CH2 – CHO
Solution :
Solution :
DIBAL – H convert cyanide to aldehyde CH2 = CH – CH2 – NH – CH3
without effecting unsaturated >C=C< bond 3 2 1
DIBAL − H
CH3CH=CHCH2CH2CN  → N-methyl prop-2-en-1-amine
H2O
40. 2) Ethylmethylamine
CH3CH=CHCH2CH2CHO
33. 3) I2 and NaOH solution Solution :
Solution : 2o-amine react with benzene sulphonyl
In Haloform reaction, >C=C< bond is chloride gives sulphonamide that is insoluble
unaffected. in alkali
34. 4) Benzophenone 41. 1) Isobutyl amine
Solution : Solution :
Aldehydes and simple methyl ketone can react 1° amines with 1o-α-carbon only can be
with NaHSO3.
prepared by Gabriel synthesis from
35. 2) two molecule of acetone corresponding 1o-alkyl halide.
Solution :

36. 4) III >I >II > IV

Solution :
Reactivity of aldehyde > ketone
− I, − M
Reactivity α effects
+ I, + M
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NH2 47. 2) 0.59 V
Br Solution :
42. 3) E ocell = E ocathode − E anode
o

= 0.4 – (–0.25)
CH3
= 0.34 + 0.25
Solution : = 0.59 V
NH2 NHCOCH3 NHCOCH3 48. 2) specific conductance decreases, molar
Br conductance increase
(CH3CO)2O Br2
CH3COOH Solution :
Upon dilution, specific conductance decreases
CH3 CH3 CH3
due to decrease in number of ions per unit
H3O+
volume but molar conductance increases due
NH2
to increase in mobility of ions
Br
49. 2) 23.2 S cm2 mole–1
Solution :
CH3 cell constant
K=
R
43. 4) b > a > c > d
K x1000 Cell constant x 1000
Solution : Λm = =
M MxR
o-methyl aniline is less basic than aniline due
0.367 x1000
to steric inhibition of protonation but m- and Λm = = 23.2Scm 2 mol −1
0.5 x 31.6
p-isomers are more basic than aniline due to
+I effect and hyper conjugation effect 50. 1) 2 × 10–4

44. 3) Eexternal > Ecell Solution :

−∆x −(0.38 − 0.50)
Solution : r= =
∆t 10 x 60
If Eexternal > Ecell, the cell works as electrolytic
+0.12
cell = = 2 x 10–4 M s–1
600
45. 1) Zero
51. 3) mol–2 L2 s–1
Solution :
Solution :
Both SRP and SOP of hydrogen electrode is
Order n = 3
taken as zero. It is a reference electrode
Units of K = mol1–n Litn–1 sec–1
46. 3) C
= mol–2 lit2 sec–1
Solution :
52. 2) molecularity of a reaction
1
Reactivity of metal ∝ Solution :
SRP
Conceptual
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53. 3) 99.9% 61. 4) 4KCN.Fe(CN)2
Solution : Solution :
t99.9% = 10t1/2 = 10 x 10 = 100 min 4KCN.Fe(CN)2 exist as K4[Fe(CN)6] and it is
54. 3) is independent of initial concentration a coordinate compound.
Solution : 62. 2) two N and four O
For first order reaction Solution :
0.693
t1/2 =
K

63. 4) trans-[CoCl2(en)2]+
55. 2)
Solution :
Trans : [COCl2(en)2]+ is not optically active
due to presence of plane of symmetry
Solution :
64. 1) sp3d2
Concentration of reactant decreases and
concentration of products increases Solution :
exponentially with time. High spin complex K3[CoF6] do not proxide
56. 3) k[A][B] inner vacant ‘d’ orbitals for hybridization

Solution : ∴ Its hybridization is sp3d2

From slow step ⇒ r ∝ [A] [B] 65. 1) [Cr(H2O)6]3+

Solution :
⇒ r = K.[A][B]
Paramagnetic nature ∝ number of unpaired
57. 4) Disproportionation
electrons
Solution :
+ 2+
[Cr(H2O)6]3+ ⇒ n = 3
2Cu → Cu + Cu
[Fe(CN)6]4– ⇒ n = 0
58. 1) Sc
[Fe(CN)6]3– ⇒ n = 1
Solution :
[Cu(H2O)6]2+ ⇒ n = 1
Sc show only +3 oxidation state.
66. 2) 2
59. 1) Ce
Solution :
Solution :
Primary valency = oxidation number of central
Ce+4 exist due to stable inert gas configuration
metal
60. 2) E⁰ Mn3+/Mn2+ is more positive than
67. 1) 6, 3, 6, 0
Fe3+/Fe2+
Solution :
Solution :
Co-ordination number = 6
Ce(OH)3 is more basic than Lu(OH)3
Oxidation number = 3
Zn & Hf have same radii
d-electrons = 6
Lanthanides are not easy to separate
Unpaired d-electrons = 0
 6 Test ID : 499
–
68. 1) two Cl satisfy primary valency while one 73. 1) molality
Cl– satisfy both primary and secondary Solution :
valency
∆Tb = Kb.m
Solution :
[Co(NH3)5Cl]Cl2 ∆Tb
⇒ = molality
According to Werner’s theory, two Cl– satisfy Kb
primary valency while one Cl– satisfy both 74. 4) Non-solubility of resulting haloalkanes
primary and secondary valency
Solution :
69. 3) 400
In Lucas test, turbidity appears due to Non-
Solution :
solubility of resulting haloalkanes
0.2
ppm = x106 75. 2) Swarts synthesis
500
2000 Solution :
= = 400 ppm
5 The Synthesis of Alkyl Fluoride is best
70. 1) 4.0× 10−4 accomplished by Swarts synthesis
Solution : R – X + AgF ∆
→ R – F + AgX
According to Henry’s law and Dalton’s law.
76. 3) CH3CHO
KH - χN2 = p. YN2 per one mole of solvent
Solution :
105. χN2 = 5 x 0.8
HBr aq.NaOH
C2H4 → CH3CH2Br  →
χN2 = 4 x 10–5 per one mole of H2O
2
NaOH/I
χN2 = 4 x 10–5 x 10 CH3CH2OH → CH3CHO (Z)
NaOH/I2
= 4 x 10–4 per 10 moles of H2O → CHI3 + HCOO–
∆
71. 1) Increases with increase in temperature 77. 3) C2H5COOH
Solution :
Solution :
1
Solubility ∝ SOCl2 KCN
T C2H5OH  → CH3CH2Cl  →
pyridine
1
Solubility ∝ H 2O/H +
KH CH3CH2CN  → CH3CH2COOH
KH ∝ T 78. 1) Pentan-1-ol
72. 2) A – ii, B – iii, C – iv, D – i Solution :
Solution :
Column I Column II
A π ii CRT 79. 3) ZnO + benzene
Lowering in vapour Solution :
B p0 - ps iii
pressure
No. of gram mole of
C m iv
solute per Kg solvent
n w W
D i ×
N m M
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80. 2) o-Hydroxybenzoic acid Lone pair electrons of ‘N’ readily react with
Solution : AlCl3 and do not undergo Friedal-craft
reaction
88. 2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A)
Solution :
Foul smelling compound is isocyanide
89. 1) Both (A) and (R) are true and the (R) is a
81. 3) Hydrogen bonds correct explanation of the (A)
Solution : Solution :
In α-helix, hydrogen bonds are present The boiling points of aldehydes and ketones
between –NH group of one amino acid residue are higher than hydrocarbons and ethers of
to the >C= O group of another amino acid comparable molecular masses.
residue. There is a weak molecular association in
82. 1) IV III V I II aldehydes and ketones arising out of the
Solution : dipole-dipole interactions.
Option (1) is correct match. 90. 4) Both (A) and (R) are false
83. 1) Both (A) and (R) are true and the (R) is a Solution :
correct explanation of the (A) Deoxyribose is a carbohydrate.
Solution : All carbohydrates cannot fit into the general
3+ 4+ formula Cx(H2O)y.
Ce is more stable than Ce and therefore
Ce4+ is oxidizing agent and reduces to Ce3+ 91. 2) Both (A) and (R) are true but (R) is not a
84. 3) (A) is true but the (R) is false correct explanation of the (A)
Solution : Solution :
Non-ionisable groups are known as secondary 1
Solubility ∝
valencies Vander Waal forces
85. 2) Both (A) and (R) are true but (R) is not a 92. 1) Both (A) and (R) are true and the (R) is a
correct explanation of the (A) correct explanation of the (A)
Solution : Solution :
Limiting molar conductivity of weak
electrolyte cannot be determined because it
does not give straight line in graph.
86. 3) (A) is true but the (R) is false 93. 1) Both (A) and (R) are true and the (R) is a
Solution : correct explanation of the (A)
Catalyst decreases the activation energy Solution :
87. 2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A)
Solution :
 8 Test ID : 499
94. 2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A)
Solution :
Aniline reacts with bromine water to form 2,
4, 6-tribromo aniline because of its high
reactivity towards electrophilic substitution
98.
reaction.
95. 1) Both (A) and (R) are true and the (R) is a
correct explanation of the (A)
Solution :
99.
2FeCl2 + 4H2O → 2Fe(OH)2 + 4HCl
96. 3) (A) is true but the (R) is false
100. 3)
Solution :
On dilution inter ionic interaction decreases
97. 1) Both (A) and (R) are true and the (R) is a
correct explanation of the (A)
Solution :
r = K[ester][H2O]
Here [H2O] is constant
∴ r = K1 [ester]
It is pseudo first order reaction
2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A)
Solution :
Separation of Zr and Hf is difficult due to
same size and chemical properties
1) Both (A) and (R) are true and the (R) is a
correct explanation of the (A)
Solution :
Complexes with more than one kind of ligands
are known as heteroleptic complexes.
(A) is true but the (R) is false
Solution :
Central atoms involve in d2sp3 hybridization