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  • Cbe 40 HW3

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    Huỳnh Huy Đắc
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    1) A gas is compressed adiabatically and reversibly from an initial state of 250K and 5MPa to a final pressure of 2.5MPa. Using energy, mass and entropy balances, the final temperature is calculated to be 299K. 2) Steam at 226.5K and 93bar is condensed reversibly to liquid water. The enthalpy change and entropy change for the process are calculated. 3) The enthalpy of vaporization at the normal boiling point is determined using data given for the enthalpy change of vaporization between two specified states.

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    CBE 40 HW3

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    1) A gas is compressed adiabatically and reversibly from an initial state of 250K and 5MPa to a final pressure of 2.5MPa. Using energy, mass and entropy balances, the final temperature is calculated to be 299K. 2) Steam at 226.5K and 93bar is condensed reversibly to liquid water. The enthalpy change and entropy change for the process are calculated. 3) The enthalpy of vaporization at the normal boiling point is determined using data given for the enthalpy change of vaporization between two specified states.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    1 views8 pages

    Cbe 40 HW3

    Uploaded by

    Huỳnh Huy Đắc
    1) A gas is compressed adiabatically and reversibly from an initial state of 250K and 5MPa to a final pressure of 2.5MPa. Using energy, mass and entropy balances, the final temperature is calculated to be 299K. 2) Steam at 226.5K and 93bar is condensed reversibly to liquid water. The enthalpy change and entropy change for the process are calculated. 3) The enthalpy of vaporization at the normal boiling point is determined using data given for the enthalpy change of vaporization between two specified states.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 8

    D

    Timpa
    GaT(k-T()pP.
    a
    di =

    B A
    P -
    ⑧

    pat-Apap.
    C
    dS =

    Pa ⑧

    is I,
    As van der Waal:

    P
    -E2E() b
    =

    H-H*) RTCZ-D+
    SE=x) PdV.
    -

    RTCz-D JE=T -bt a


    +
    =

    -
    RTCE-D JE 8EaK
    +

    Ri(zt
    = +

    ():RIEH-
    S-SFG=RIz +
    IEs () )al -

    =Rmz
    JE (Eb.- IjaY
    +

    =
    3

    R(z
    =
    RICK-B) (Y
    + -

    R(((1 2)) Rm(z


    =

    z3 az2+ z
    -

    =
    -

    2)
    1 0.
    + =
    +

    ATT 300KP:IOMPa
    =

    x +-=

    BiB Ai)) =

    -
    =

    AB,a0.2303;b 3.306
    =
    =

    AziB b ATT=200K iP=4MPa


    =

    I
    RI =A 0.3332;B 0.1036
    =

    0.1726
    =

    0.3782
    = =

    z3 -1.17262, 0.37062 0.8639


    =>
    +
    -

    0
    =

    =>
    I
    0.8136
    =

    - =2 -
    1103622 0.33327
    +
    -

    0.8345

    z 0.6961
    =

    =>

    sto-seat fabad3.323x
    --5.7089 mol
    AH=DH+ CH-HFG)+2P2- CH-HEG)+IPI
    =-3.3231x103-1.301x8+ 1.5967x183 =-3.0274x3
    AS ASEG +
    =

    (S-SIGtz-(S-SFG)+, IP,
    =- 5,
    7089-4.339 4339 +

    = -

    570895/molK
    H A DV
    =
    +

    =) 4 HAPV
    =

    V, = 2.0313x184ms/mol
    =
    =

    VaZzRt2 2.897x10-4 m4 mol


    =

    P2

    Al AH-PeVa+4, V,
    =

    =- 3,827x103-4x10X2.897x04,10x1042.0313
    x104)
    -2. 15x103
    ->
    Molar balance:

    =
    a 0 fNe-Ni 0
    =

    (NF+NE)1 (NF+N*), 0
    =>
    -

    Since NF atinitial is empty -> NF 0 =

    E(NF+NY1-(NY) i 0. =

    Energybalance
    at 0
    0
    at
    = = Uf-4i =

    = (NEUF+N*)1- INFUNEi
    0
    0 =

    = (NEUE+NEUE)f-(NEUE)i 0. =

    The gas uniformly distribute all over the tank


    UE h*f
    =>
    = Uf(NE+NI)f-NUFi 0
    NUE=OEME=hi
    = =

    UENE -
    Entropy balance:
    = S -

    S + Saen transfer
    =

    no heat

    Sf-Si
    =>

    Spen
    =

    v=hV

    H H PX
    -
    =
    =>

    =>
    H-UEEg H-HER = -
    PI

    UE, 4178.25645/mo) 05/mol-Goobar/Pata)


    - -
    => =

    squid
    no phase
    1.05362 mttmal
    x

    uE, 6859,25645/mal
    I
    -

    =>
    =

    X 0.05362m3/kmo) x2 0.10724m4kmol
    =
    =

    +f 226.5K, Pf=93bar.
    =
    ·
    Slowly Sgen 0
    => =

    isolated=> adiabatic
    closed system.

    T, 250K
    = T2 10k =

    P, 5MPa
    =
    P2 =?

    Mass balance:

    aN 0 N2 N, 0 =
    = = =

    Energy balanc
    1H UcU,
    =

    -fPdV
    =

    Entropy balance:

    DS Sn = -

    5 =
    st
    +
    0.
    =

    3
    5
    Sz = -39.4125/mol.k.
    =

    =>

    Atinitial T2 180k
    =

    =R1.68MPa
    =
    16.5bar
    =

    V2 0.8475 troll
    =

    =>

    x50mol 0.0412m
    At final
    =
    = 2.5MPa, T=299

    0.
    gH
    T 3
    -

    =
    =

    * FV -T5 -306.85
    = =

    e
    -

    E4 55
    307.57
    =
    - -
    =

    E-E
    x18.Olg/md E E 12.6 5/mol
    =
    -

    since itat the border


    b) of liquid and steam
    G
    => =
    or
    E-G 0 =

    c)

    Liquid Vapor
    55847214-2-(223,99 273) (10,9084l)
    = I IS" -
    =
    +

    E 805*md,10185/mo)
    =

    GV
    - -
    G=-135/mol

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