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Maths - Section A
1. Answer: A 2. Answer: B
Sol: Sol:
2a 2(a+1)
└ ┘
−−−−−−−−−−−−−−−−−−
9a2−16a(a + 1) ≥ 0 ; −2 >
Σ=56
3a
a+1
ℓ − 3d, ℓ − 2d, ℓ − d, ℓ
0 └
−−−−−−−−−−−−−−−−−
┘
Σ=112
a+1
>0 Now ℓ = a + (n – 1)d
31 = 11 + (n – 1) × 2
a+1
>0 n = 11
a∈ [−
16
7
, 0] ; a ∈ (−∞,−1)
∪ (2,∞)
af(k) > 0
⇒ (a + 1) (a − 1 − 3a + 4a) > 0
⇒ (a + 1) (2a + 1) > 0
−1
⇒a ∈ (−∞, ) ∪ (– 1, ∞)
2
a= −3
3. Answer: A 4. Answer: A
Sol: Sol:
Sm = m2 – 5m a = k2 + 1 ; d = 1
Sm–1 = (m–1)2
– 5(m–1)
Sm–1 = m2 + 1 – 2m – 5m
+5 and l = k2 + 1 + (2k)(1) = k2 + 2k + 1
S = [(k2 + 1) + (k2 + 2k + 1)]
2k+1
S = (2k + 1) (k2 + k + 1) = k3 + k3
+
2
= k3 + (k + 1)3 Ans.]
5. Answer: C 6. Answer: C
Sol: Sol:
4
5
√7
,
6
√7
,
7
√7
, ......
θ = nπ + 3π
√7 √7 √7 √7
cos θ = √2
1
= cos π
4
=
√7
θ = 3π
4
, 7π
4
&θ= π
4
, 7π
4
,n
∈I
7. Answer: D 8. Answer: B
Sol: Sol:
α ⋅ α
2
= a
2
⇒ α
3
= a
3
Dis. of x2 +px + 3q is p2 − 12q ≡ D1
Dis. of –x2 + rx + q is r2 + 4q ≡ D2
⇒ α = a
2 15
α + α =
4
Dis. of –x2 + sx − 2q is s2 − 8q ≡ D3
2
⇒ 4a + 4a − 15 = 0
Case 1 : If q < 0, then D1 > 0, D3 > 0
⇒ 4a
2
+ 10a − 4a − 15 = 0 and D2 may or may not be positive
⇒ (2a − 3)(2a + 5) = 0 Case 2 : If q > 0, then D2 > 0 and D1, D3
3 −5
may or may not be positive
⇒ a = or a =
2 2
Case 3 : If q = 0, then D1 ≥ 0, D2 ≥ 0
and D3 ≥ 0
Sol:
4 3 2
(x − 1) (x + x + x + x + 1) = (x − 1) ⋅ 0
5 5 5 5 5 5
x − 1 = 0 ⇒ x = 1 ⇒ α = β = γ = δ = 1
400
5
S = ∑ α(α )
S = ∑ α(1) = α + β + γ + δ
4 3 2
(x + x + x + x + 1) = 0
roots α, β, γ, δ
sum of roots
α + β + γ + δ = −1
S = −1
Sol:
9a –5 > 0
5
a >
9
–2(a+1) < 0
a+1 > 0
a > –1
D ≥ 0
a2 +2a+1 –9a + 5 ≥ 0
a2 –7a + 6 ≥ 0
(a–6)(a–1) ≥ 0
−2(a+1)
& < 0
2
a >– 1
Intersection of all (
5
9
, 1] ∪ [6, ∞)
Sol: Sol:
Since a, b, c ∈ R.
⇒K∈(0,1)
x2 − 11x + m = 0
3
11x
(2 ) 2
11x 2 11x
⇒ 2
+ 2 ⋅ 2 = (2 ) ⋅ 2 + 1
2
x2 − 14x + 2m = 0 3
t 2
⇒ + 4t = 2t + 1
4
α 2 − 14 α + 2m = 0 i.e. t1 t2 t3 = 4 ⇒ 2
11x1 11x2
⋅ 2
11x3
⋅ 2 = 4
− + − ⇒ 2
11(x1 +x2 +x3 )
= 2
2
_________________
2
⇒ 11 (x1 + x2 + x3 ) = 2 ⇒ x1 + x2 + x3 =
11
3 α − m = 0
⇒m = 3 α
α 2 − 11 α + 3 α = 0
α2 − 8 α = 0
α ( α − 8) = 0
α = 0 or α = 8
m=3α=0
m = 3 × 8 = 24
m = 0 or 24
Sol: Sol:
1 − cos
2
θ − 2 cos θ +
1
= 0 cot4x – 2(1 + cot2x) + a2 = 0
0
4
4 2 2
⇒ 4 cos θ + 8 cos θ − 5 =
2 ⇒cot x – 2 cot x + a –2=0
2 2 2
⇒ (2 cosθ -1)(2cosθ+5)
= 0 ⇒(cot x – 1) =3–a
to have atleast one solution
cos θ = (reject)
1
,
−5
3 – a2 ≥ 0
2 2
2
θ = 2nπ ± π
⇒a –3≤0
a ∈ [–√3, √3
]
3
integral values
– 1, 0, 1
∴sum = 0 Ans. ]
Sol:
∵θ∈ (0,
π
4
) ⇒ tan θ < 1 & cot θ > 1
∴ t1 = (1 − x)1−x, t2 = (1 − x)1 + y
t3 = (1 + y)1−x , t4 = (1 + y)1 + y
also t3 > t1
sin(2θ)
then we have to find
sin(2ϕ)
tan(θ+ϕ) a+b
=
tan(θ−ϕ) a−b
a c a + b c + d
∵ If = then =
b d a – b c – d
sin(θ+ϕ) sin(θ–ϕ)
+
cos(θ+ϕ) cos(θ–ϕ) 2a
⇒ =
sin(θ+ϕ) sin(θ–ϕ) 2b
–
cos(θ+ϕ) cos(θ−ϕ)
sin((θ+ϕ)+(θ−ϕ)) a
⇒ =
sin((θ+ϕ)–(θ−ϕ)) b
sin 2θ a
⇒ =
sin 2ϕ b
Sol: Sol:
−
(1+cos 2θ)(1+cos 4θ)(1+cos 8θ) 10π 3π 5π
π 2π π
(cos cos cos ) (sin sin sin )
cos 2θ.cos 4θ.cos 8θ 7 7 7 14 14 14
2 2 2
cos (π + θ) = –cos θ
2 cos θ.2 cos 2θ.2 cos 4θ
=
cos 2θ.cos 4θ.cos 8θ
−
8cosθ.cosθcos2θcos4θ π 2π 3π
= ∴ (cos . cos . cos )
cos 8θ 7 7 7
−
8cosθ sin 8θ
= .{ 3
}
cos 8θ 2 sinθ
7π 6π 7π 4π 7π 2π
{sin ( − ) . sin ( − ) sin ( − )}
tan 8θ 14 14 14 14 14 14
=
tanθ
⇒ + cos .cos π
7
2π
7
.cos 4π
7
− cos 3π
7
.cos 2π
7
.cos
π
⇒ 2 cos π
7
.cos 2π
7
.cos 4π
8π
=
2×sin
7 1
π
= −
3 4
2 .sin
7
Maths - Section B
1. Answer: 2 2. Answer: 0
Sol: Sol:
Given f (x)=4x 2
− 17x + λ = 0; λ ∈ R similar Let Ist term is A and Common difference
to is d.
f (x)=ax 2
+ bx + c= 0
∴ Tp =A + (p-1) d = a..... (i)
2
f (1)= 4 (1 ) − 17×1 + λ > 0 a−b
⇒ p − q = . .... (iv)
d
⇒ λ > 13
Subtracting (iii) from (ii) we get
(ii) Substitute x=2 in f(x) then ⇒ b - c = (q − 1 − r + 1) d
2
f (2) =4 × 2 −17 × 2 + λ< 0
⇒ b − c = (q − r) d
⇒ λ < 18
b−c
⇒ q − r = ..... (v)
d
⇒ λ > 15
⇒ c − a =(r − p) d
⇒ 15 < λ < 18
c−a
⇒ r − p = ..... (vi)
The integral values of λ = 16, 17 d
Now,
The total number of integral values are 2.
a (q - r) + b (r - p) + c (p - q)
= a (
b-c
d
) + b (
c-a
d
) + c (
a-b
d
) (From (iv),(v)
& (vi))
1
= [ab - ac + bc - ab + ca - bc]
d
1
= [0]
d
= 0
3. Answer: 1 4. Answer: 7
Sol:
tan 6°.tan 54°.tan 66° tan 18°.tan 42°.tan 78°
=( )( )
tan 54° tan 18
tan(3×6°) tan(18×3)
= .
tan 54° tan 18
=1
Sol:
tanx(sin2x+1)=sinx(2+tan x)
⇒ sin x
cos x
(sin 2x+1) = sin x (2+tan x)
⇒ sin x [
sin 2x+1
cos x
− (2 + tan x)] =0
cos x
− (2 +
sin x
cos x
)] =0
cos x cos x
sin x = 0
⇒sin 2x +
1 = 2 cos x + sin x
⇒sin 2x – sin x + 1 – 2 cos x =
0
⇒sin x (2 cos x – 1) – 1 (2 cos x –
1) = 0
sin x = 1, cos x =
1
tan x is not
2
± , 4π –
3
x = π, 2π, 3π, , 2π π π π
3 3 3
5. Answer: 0 6. Answer: 8
Sol: Sol:
∵ sin
π
n
+ sin
3π
n
+sin
5π
n
+ ……n terms Here Let N = 3
12
× 2
8
π 2π
α = ,β =
n n
Taking logarithm on both sides
π 2n−1 π 2π
sin( +( ) ) sin(n⋅ ) 12 8
n
2n 2 2n
⇒ log (N ) = log (3 × 2 )
= 2π
= 0 10 10
sin
2n
12 8
⇒ log10 (N ) = log10 3 + log10 2
⇒ log10 (N ) = 8. 1332
Final Answer:
7. Answer: 5 8. Answer: 4
Sol:
−λ
k+5
λ = log5 (log5 (3)) , 3 = 405
−λ 1
5 = = log3 5
log 3
5
k log 5
3
= 3 .3 = 405
k
⇒ 3 = 81
k = 4
Sol:
Given:
8
logx+
log(xy )
2 2
= 2
(logx) +(logy)
8
x
log( )
y
logy+ = 0
2 2
(logx) +(logy)
a 8b
⇒ a+ 2 2
+ 2 2
= 2
(a) +(b) (a) +(b)
.........................(1)
⇒ b+
2
8a
2
−
2
b
2
= 0 ........................
(a) +(b) (a) +(b)
(2)
Multiply eq(1) by a and eq(2) by b
a 8b
⇒ (a + + = 2) × a
2 2 2 2
(a) +(b) (a) +(b)
2
2 a 8 ab
⇒ a + + = 2a . . . . . . . . . . . . . . . . . . . . (3)
2 2 2 2
(a) +(b) (a) +(b)
8a b
⇒ (b + − = 0) × b
2 2 2 2
(a) +(b) (a) +(b)
2
2 8 ab b
⇒ b + − = 0 . . . . . . . . . . . . . . . . . . . . . (4)
2 2 2 2
(a) +(b) (a) +(b)
Eq (3) − (4)
2 2
2 a 8 ab 2 8 ab b
⇒ a + 2 2
+ 2 2
− b − 2 2
+ 2 2
= 2a − 0
(a) +(b) (a) +(b) (a) +(b) (a) +(b)
2 2
2 2 a +b
⇒ a − b + 2 2
= 2a
(a) +(b)
2 2
⇒ a − b + 1 = 2a
2 2
⇒ a − 2ab + 1 = b
2 2
⇒ (a − 1) = b
a 8b
⇒ (a + 2 2
+ 2 2
= 2) × b
(a) +(b) (a) +(b)
2
ab 8b
⇒ ab + 2 2
+ 2 2
= 2b . . . . . . . . . . . . . . . . . . . . (6)
(a) +(b) (a) +(b)
8a b
⇒ (b + 2 2
− 2 2
= 0) × a
(a) +(b) (a) +(b)
2
8a ab
⇒ ab + 2 2
− 2 2
= 0 . . . . . . . . . . . . . . . . . . . . . (7)
(a) +(b) (a) +(b)
Eq(6) + eq(7)
2 2
ab 8b 8a ab
⇒ ab + + + ab + − = 2b
2 2 2 2 2 2 2 2
(a) +(b) (a) +(b) (a) +(b) (a) +(b)
2 2
8a +8b
⇒ 2ab + 2 2
= 2b
(a) +(b)
⇒ 2ab + 8 = 2b
⇒ ab + 4 = b
⇒ b(1 − a) = 4
4
⇒ b = . . . . . . . . . . . . . . . . . . . . . . . (8)
1−a
When b = 1 − a
4
⇒ 1 − a =
1−a
2
⇒ (1 − a) = 4
2
⇒ 1 − 2a + a = 4
2
⇒ a − 2a − 3 = 0
2
⇒ a − 3a + a − 3 = 0
⇒ a(a − 3) + 1(a − 3) = 0
⇒ (a + 1)(a − 3) = 0
⇒ a = −1, 3
The values of (a, b) = (3, 2), (3, −2), (−1, 2), (−1, −2)
When a = −1
⇒ logx = −1
1
⇒ x =
10
When b = 2
⇒ logy = 2
2
⇒ y = 10 = 100
xy 100
⇒ = = 5
2 10×2
Final Answer:
Sol: Sol:
2sin2x + 5sinx – 3 = 0
2 2
x +15a 8 ax
logπ = logπ . . . . (1)
a−2 a−2
(2sinx-1)(sinx+3) = 0 2 2
⇒ x + 15a = 8 ax
sinx≤1)} 5 3
satisfies (1) hence a = 9
or a = 3
Possible Values of x in [0,3π] are
∴ x =9
∴ 5
5
is not possible (think!) ⇒ a = 3
substituting a = 3 in (2)
x
2
− 24x + 225 = 0 ⇒ x = 9 or x = 15
1. Answer: A 2. Answer: C
Sol: Sol:
friction is f
2
= μmg ⇒ 0. 4 × 2 × 9. 8
max
fmax = 7. 84N
√3
μ = F + mg
2
= 0.5 (F + 10√3)
To avoid slipping,
⇒ 10 = 0.5 (F + 10√3)
⇒ F = 20 – 10√3
⇒ F = 20 – 17.3 = 2.7 N
3. Answer: C 4. Answer: A
Sol: Sol:
Here the spring force has been ignored as The net applied force F on the block B
while considering the two system as a
= (force due to mass C − force due to
whole, it will be accounted as an internal
mass A)
force for the system.
= 20 − 6 = 14 N
Therefore, the acceleration of the system
will be: Here, F < fmax static friction comes into
play.
a= Total external
Total mass
force
m+M
= mF
m+M
5. Answer: B 6. Answer: B
Sol: Sol:
Case I
T1 = 2 mg
ma1 = 2mg − T1
⇒ a1 = g ↑
S1 = 5√3 t
S2 = 10√3 t
⇒ a2 = 2 g/3 ⏐
S2 – S1 = x ↓
⇒ y = 15t – 10t2 1
2 T3 = mg
2
15t−5t 1
⇒ =
√3
(10√3 t−5√3 t) ma3 = T3 − mg
t(15−5t)
1
⇒ =
5 √3 t √3 ⇒ a3 = 3g ↑
t = 2 sec.
Case IV :
T4 = mg
2 ma4 = 2mg − T4
⇒ a4 = g/2 ⏐
↓
7. Answer: A 8. Answer: B
Sol: Sol:
the velocity of P is vp = up + ap t
= 0 + a p t= ap t
l 8 10
t = = =
v0 cosβ v0 ×
4
5
v0
Similarly, the velocity of Q is v Q = aQ t
v P/ = ap t − aQ t
Q
1 2
l = v0 sinβt− × 10sinα. t
2
= (a − a )t
3 10 1 4 100
l = v0 × × − × 10× ×
5 v0 2 5 2 p Q
v0
l = 6 −
400
v0
2
Both the accelerations are different but
constant, but time increases. And hence
400
v0
2
= 5 as time increases the relative velocity
increases. So, at t > t , the 0
v0
2
= 80 relative velocity increases continuously.
v0 ≃ 9m/s
So, the correct answer is option 2.
Sol:
vD = 10+0
2
= 5m/sec ↓
so vB = 15 m/sec ↑
Since F net = 0
Tcos θ = W -1
T sin θ = P -2
-1
2 2
(Tcosθ) = W
-2
2 2
(Tsinθ) = P
α = 30°
mA +mB
=
Fcos 30°
1+2
=
F
2√3
N = 90N
∴ N = mAg + Fsinα = 9N
= 0.2 × 40
= 10 + F
f 'max = 8N
∴ Fmax = µN
So F = ma
= 1
(10 +
F
)
Maximum accelerating for a system
2 2
= 5 +
F
4
F 8 2
a = = = 2m/s
m 4
⇒ amax =
fmax
mB
F
5+
= 2
4
F = 3×(2.5+0.125F)
√3
⇒ 2
Sol:
200
× 9.8
= 9.8 m/s2
Vb = velocity of ball
Vc = velocity of car.
→ → →
( v bc ) = ( v b) − ( v c)
x x x
→
20cos60°= ( v b) – 30
x
→
( v b) = 40
x
→ →
( v bc ) = ( v b) – 30
y y
→
20 sin 60° = ( v b) –0
y
→
( v b) = 10√3
y
= =
y 10√3 √3
tanθ =
→ 40 4
( v b)
x
Sol: Sol:
ds ds
t = ∫ dt = ∫ = ∫
v−vcos 60° v
(v− )
2
2 2ℓ
= ∫ ds =
v v
v
× v = 12ℓ
x + v1 T = R =
2
(v2 sin α) (v2 cos α) When ball is moving upwards
g
A → B
⇒ x =
2
(v2 sin α) (v2 cos α) – v1T
v2 = u2–2gh
g
= 2
0 = u2–2gh
v2 sinα(v2 cosα − v1 )
h = ...(1)
2
g u
⇒ ⇒
2g
& ∵ v = u + at
(3)
2
= oxt ' +
1
2
g[t']
2
[s = h
2
, for half of
height & t' = time taken]
…(4)
2 h
⇒[t'] =
g
t2 = 2[t']2
⇒t = √2t' t' =
⇒
t
√2
√2
= t (1 +
1
)
√2
dropped down with acceleration due to The time taken by object P to cover 20 km
2 Where, u = 0, s =
1
2
at
2
1 2
⇒ h = (a + g)t
2 2s
t = √
a
(g+a)
and s = 20 km
2×2.7 5.4
= √ = √
(9.8+1.2) 11
2×20
t = √
40
= √0 .49 = 0 .7 s
= 1 hour
so, the correct answer is option 3.
Time taken by Q will be 1
2
hour, because
it started after 30 min.
The acceleration in Q,
2s 2×20
a = 2
=
2
t 1
( )
2
= 2 × 4 × 20
2
= 160 km /h
Physics - Section B
1. Answer: 5 2. Answer: 2
Sol: Sol:
aA = aB =
12g 9g
25 25
Hence N =
4mg
NBW = N sin 37
⇒NBC =
12mg
25
it must be divided by 5
So Answer is 5
×5 × 10 = 10aB
Relativeness of the motion of B with
40 − 10 = 10aB
respect to A
−2
⇒ aB = 3 ms −−→ −
→ −
→
VBA = VB − VA
−−→
VBA = −3 î − ĵ ......refer figure
3
OB = 10 ×
√10
OB = 3√10m
t = 3 sec
5. Answer: 5 6. Answer: 4
Sol:
1 g×16
3 = 4tanθ − 2
2 v cos2 θ
1 16 2
3 = 4tanθ − g (1 + tan θ)
2 2g×4
⇒ umin = √8g
Sol:
10 cos α+4
=
40
30
=
4
30 sinα − 9 = 40 cos α + 16
30 sinα − 40 cos α = 25
α −53° = 30°
α = 83°
α = 8 × 10 + 3
a=8
b=3
a − b = 8 −3 = 5
7. Answer: 4 8. Answer: 3
Sol: Sol:
F1 − F2 = (m1 + m2 )a
5 − 2 = (1 + 2)a
a = 1m/s
2
a
Now calculating f
F1 − f = M 1 a
5 − f = 1 × 1
f = 4N
blocks is 4N V R = V RM + V M
0
θ = 30
2h
t1 = √
g
2(H−h)
2 2
∣−−
→∣ ∣ −−→∣ t2 = √
Given ∣AC ∣ = ∣2 AB ∣ g
∣ ∣ ∣ ∣
⇒ ∣
ˆ∣ ∣ ˆ∣
∣4 î + (4x − 2) ĵ + 2k ∣ = 4∣ î + x ĵ + 3k ∣
2h 2(H−h)
t = √ + √
⇒ 16 + (4x − 2)
2 2 g g
+ 4= 4 (1 + x + 9)
⇒ 3x 2
− 3x − 3 = 0 For the time to be maximum, the
derivative of t wrt h should be 0.
⇒ x = 2, −
2
3
...(i) dt
= 0
dh
−
−→ −
−→
Angle between AB and AC is
Taking derivative of t with respect to h
−
−→ −
−→ −
−→ −
−→
AB .AC AB .AC g/2 −g/2
cos θ = = dt
∣−−
→ ∣∣−−
→∣ → ∣2 = +
∣−−
dh 2h 2(H−h)
∣AB ∣∣AC ∣ 2∣AB ∣ 2√ 2√
∣ ∣∣ ∣ ∣ ∣ g g
ˆ ˆ
( î +x ĵ +3k).(4 î +(4x−2) ĵ +2k) equating to the zero
11
14
=
2
2( î +x ĵ +3k̂)
g g g
0 = (√ − √ )
4 2h 2(H−h)
=
2
4+x(4x−2)+6 2x −x+5
=
2
2(1+x +9) x2 +10
g g
√ = √
2h 2(H−h)
2 2
⇒ 11 (x + 10) = 14 (2x − x + 5)
2
Squaring both the sides
⇒ 17x − 14x − 40 = 0
g g
=
⇒ x = 2, −
20
17
.......(ii) 2h 2(H−h)
(H − h) = h
H = 2h
H
= 2
h
1. Answer: B 2. Answer: A
Sol: Sol:
At constant volume, P ∝ T
P1> P2> T3
3. Answer: C 4. Answer: B
Sol: Sol:
gram
so, log V = log (
nR
) + log T
1 molecule of CH4 has mass = P
16 –23
= 2. 656 × 10
compare this with
23
6.022×10
y = mx + c
5. Answer: C 6. Answer: D
Sol: Sol:
4–methyl–6–nitro–3–oxohept–4–enal
7. Answer: D 8. Answer: A
Sol: Sol:
2
Ni2+ = [Ar]3d84s0
ΔHeg = − 90 − × 2 × 300 × 10−3 =
5
Cr3+ = [Ar]4s 0
3d
3
Unpaired electron = 3
Unpaired electron = 5
μ (magnetic moment) =
√5 (5 + 2) = √35 B. M.
Cu+ = [Ar]3d 10
4s
0
Unpaired electron = 0
Sol: Sol:
(1) B(OH)3 acidic and H3PO3 Seaborgium is the element having atomic
acidic no. 106 its symbol is Sg.
(2) B(OH)3 acidic and Al(OH)3 For Z = 106, Root of 1 - un, Root of 0 -
amphoteric nil
of 6 - hex + ium, IUPAC name =
Root
(3) NaOH basic and Ca(OH)2 unnilhexium
basic
Sol: Sol:
dAB = rA + rB − 0. 09[ΔEN] Mole of Zn = 9.81
65.3
= 0. 15 mol
= 0. 30 mol
difference between A and B and rA and rB
23
6.022×10
are respectively the atomic radii of A and Mole of O-atoms = 0.60 mol
B (half of bond lengths of A-A and B-B)
Zn Cr O
1.6 2.0
dAB = + − 0. 09(2. 8 − 2. 1) 0. 15 0. 30 0. 60
2 2
1 2 4
o
= 1. 737A
So, simplest formula = ZnCr 2 O4
Sol: Sol:
Sol: Sol:
1J = n×6.6×10
–34
×3×10
8
Option (C) is correct.
–10
4000×10
n = 2 x 1018 Photons
Sol: Sol:
2
Given, n
rn ∝
z
V1 = 75 ml ; V2 = 590 ml
= 98
Now, ⇒ 2πr3 = nλ
M1 = 1. 18 X 0. 49 / 98
2πr3
= 0. 0059 ⇒ λ =
3
Answer − 3
Ch i t S ti B
Chemistry - Section B
1. Answer: 9 2. Answer: 6
Sol: Sol:
Transition elements are De-broglie-wave length of electron:
Cr, Cu, Fe, Re, Ru, Rh, Co, Ni, Ag
−
⎧ ∵ e is accelerated
⎪
h
λc = ⎨ from rest
√2m(KE)
⎩
⎪
⇒ KE=q × V
h
λ =
√2mqv
−34
6.63×10
=
√2×1.6×10−19 ×9.1×10−31 ×40×103
−11
= 0.614 × 10 m
−12
= 6.16 × 10 m
Nearest integer = 6
OR
12.3
λ = Å
√V
12.3 −12
= = 6.15 × 10 m
200
Ans is 6
Sol: Sol:
5. Answer: 4 6. Answer: 3
Sol: Sol:
Homocyclic - cyclic compound do't have X5+ ion has five positive electron
have hetro-atom affinities.
EA1, EA2 are less when compared with
EA3,EA4,EA5 i.e 289.7, 270.9, 30.1, 17.9
and 8.3.
So, the expected number of electrons
in the outermost shell of X-atom is 3
Sol:
Electronegativity of F − Electronegativity
of Cl = 0. 208√BECl−F − √BECl−Cl BEF −F
Electronegativity of F − Electronegativity
of Cl = 0. 208√61 − √38 × 58
Electronegativity of Cl = (4 − 0.779)
eV = 3.220 eV
Answer: 3.22
Sol: Sol:
430.53 × 10
≃9%