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Rare-earth element

The rare-earth elements (REE), also called the rare-earth metals Rare-earth elements
or (in context) rare-earth oxides, or the lanthanides[1] (though in the periodic table
yttrium and scandium are usually included as rare-earths) are a set of
17 nearly-indistinguishable lustrous silvery-white soft heavy
metals.[2] Scandium and yttrium are considered rare-earth elements
because they tend to occur in the same ore deposits as the
lanthanides and exhibit similar chemical properties, but have
different electronic and magnetic properties.[3][4]

These metals tarnish slowly in air at room temperature and react


slowly with cold water to form hydroxides, liberating hydrogen.
They react with steam to form oxides, and at elevated temperature
(400°C) ignite spontaneously.

These elements and their compounds have no biological function.


The water-soluble compounds are mildly to moderately toxic, but
the insoluble ones are not.[5] Rare-earth ore (shown with a 19 mm
diameter US 1 cent coin for size
Compounds containing rare earths have diverse applications in comparison)
electrical and electronic components, lasers, glass, magnetic
materials, and industrial processes.

Despite their name, rare-earth elements are relatively plentiful in


Earth's crust, with cerium being the 25th most abundant element
at 68 parts per million, more abundant than copper. All isotopes of
promethium are radioactive, and it does not occur naturally in the
earth's crust, except for a trace amount generated by spontaneous
fission of uranium 238. They are often found in minerals with Refined rare-earth oxides are heavy
thorium, and less commonly uranium. Because of their gritty powders usually brown or black,
geochemical properties, rare-earth elements are typically dispersed but can be lighter colors as shown
and not often found concentrated in rare-earth minerals. here.
Consequently, economically exploitable ore deposits are sparse Legend:
(i.e. "rare").[6] The first rare-earth mineral discovered (1787) was gadolinium · praseodymium · cerium
samarium · lanthanum
gadolinite, a black mineral composed of cerium, yttrium, iron,
neodymium
silicon, and other elements. This mineral was extracted from a
mine in the village of Ytterby in Sweden; four of the rare-earth
elements bear names derived from this single location.

Contents
List
Discovery and early history
Spectroscopic identification
Early classification
Light versus heavy classification
Origin
Geological distribution
Geochemistry applications
Production
China
Outside China
Other sources
Methods
Properties
Uses
Environmental considerations
Recycling and reusing REEs
Impact of REE contamination
Remediation after pollution
Geo-political considerations
See also
References
External links

List
A table listing the 17 rare-earth elements, their atomic number and symbol, the etymology of their names,
and their main uses (see also Applications of lanthanides) is provided here. Some of the rare-earth elements
are named after the scientists who discovered them, or elucidated their elemental properties, and some after
the geographical locations where discovered.
Overview of rare-earth metal properties

Abundance[7][8]
Z Symbol Name Etymology Selected applications
(ppm[a])
Light aluminium-scandium alloys for
from Latin aerospace components, additive in
21 Sc Scandium Scandia metal-halide lamps and mercury-vapor 22
(Scandinavia). lamps,[9] radioactive tracing agent in oil
refineries
Yttrium aluminium garnet (YAG) laser,
yttrium vanadate (YVO4) as host for
europium in television red phosphor,
YBCO high-temperature
superconductors, yttria-stabilized zirconia
(YSZ) (used in tooth crowns; as
refractory material - in metal alloys used
in jet engines, and coatings of engines
and industrial gas turbines;
electroceramics - for measuring oxygen
after the
and pH of hot water solutions, i.e. in fuel
village of
cells; ceramic electrolyte - used in solid
Ytterby,
oxide fuel cell; jewelry - for its hardness
Sweden,
39 Y Yttrium and optical properties; do-it-yourself high 33
where the first
temperature ceramics and cements
rare earth ore
based on water), yttrium iron garnet (YIG)
was
discovered. microwave filters,[9] energy-efficient light
bulbs (part of triphosphor white phosphor
coating in fluorescent tubes, CFLs and
CCFLs, and yellow phosphor coating in
white LEDs),[10] spark plugs, gas
mantles, additive to steel, aluminium and
magnesium alloys, cancer treatments,
camera and refractive telescope lenses
(due to high refractive index and very low
thermal expansion), battery cathodes
(LYP)
from the High refractive index and alkali-resistant
Greek glass, flint, hydrogen storage, battery-
57 La Lanthanum "lanthanein", electrodes, camera and refractive 39
meaning to be telescope lenses, fluid catalytic cracking
hidden. catalyst for oil refineries
Chemical oxidizing agent, polishing
after the dwarf
powder, yellow colors in glass and
planet Ceres,
ceramics, catalyst for self-cleaning
named after
58 Ce Cerium ovens, fluid catalytic cracking catalyst 66.5
the Roman
for oil refineries, ferrocerium flints for
goddess of
lighters, robust intrinsically hydrophobic
agriculture.
coatings for turbine blades[11]

from the Rare-earth magnets, lasers, core material


Greek for carbon arc lighting, colorant in
"prasios", glasses and enamels, additive in
59 Pr Praseodymium meaning leek- didymium glass used in welding 9.2
green, and goggles,[9] ferrocerium firesteel (flint)
"didymos", products, single mode fiber optical
meaning twin. amplifiers (as a dopant of fluoride glass)
60 Nd Neodymium from the Rare-earth magnets, lasers, violet colors 41.5
Greek "neos", in glass and ceramics, didymium glass,
meaning new, ceramic capacitors, electric motors of
and electric automobiles
"didymos",
meaning twin.
after the Titan
Prometheus,
61 Pm Promethium who brought Nuclear batteries, luminous paint 1 × 10−15 [12][b]
fire to
mortals.
after mine
Rare-earth magnets, lasers, neutron
official, Vasili
62 Sm Samarium capture, masers, control rods of nuclear 7.05
Samarsky-
reactors
Bykhovets.
after the Red and blue phosphors, lasers,
63 Eu Europium continent of mercury-vapor lamps, fluorescent lamps, 2
Europe. NMR relaxation agent
High refractive index glass or garnets,
lasers, X-ray tubes, Bubble (computer)
memories, neutron capture, MRI contrast
agent, NMR relaxation agent, steel and
after Johan chromium alloys additive, magnetic
Gadolin refrigeration (using significant
(1760–1852), magnetocaloric effect), positron emission
64 Gd Gadolinium 6.2
to honor his tomography scintillator detectors,
investigation substrate for magneto-optical films, high
of rare earths. performance high temperature
superconductors, ceramic electrolyte
used in solid oxide fuel cells, oxygen
detectors, possibly in catalytic
conversion of automobile fumes.
Additive in Neodymium based magnets,
after the green phosphors, lasers, fluorescent
village of lamps (as part of the white triband
65 Tb Terbium 1.2
Ytterby, phosphor coating), magnetostrictive
Sweden. alloys such as terfenol-D, naval sonar
systems, stabilizer of fuel cells
from the
Greek Additive in Neodymium based magnets,
66 Dy Dysprosium "dysprositos", lasers, magnetostrictive alloys such as 5.2
meaning hard terfenol-D, hard disk drives
to get.
after
Stockholm (in
Latin,
Lasers, wavelength calibration standards
67 Ho Holmium "Holmia"), 1.3
for optical spectrophotometers, magnets
native city of
one of its
discoverers.
after the
village of Infrared lasers, vanadium steel, fiber-
68 Er Erbium 3.5
Ytterby, optic technology
Sweden.
after the
mythological Portable X-ray machines, metal-halide
69 Tm Thulium 0.52
northern land lamps, lasers
of Thule.
after the Infrared lasers, chemical reducing agent,
village of decoy flares, stainless steel, stress
70 Yb Ytterbium 3.2
Ytterby, gauges, nuclear medicine, monitoring
Sweden. earthquakes
71 Lu Lutetium after Lutetia, Positron emission tomography – PET 0.8
the city that scan detectors, high-refractive-index
glass, lutetium tantalate hosts for
later became phosphors, catalyst used in refineries,
Paris. LED light bulb

a. Parts per million in earth's crust, e.g. Pb=13 ppm


b. No stable isotopes occurring in nature.

Discovery and early history


Rare earths were mainly discovered as components of minerals. Ytterbium was found in the "ytterbite"
(renamed to gadolinite in 1800). It was discovered by Lieutenant Carl Axel Arrhenius in 1787 at a quarry
in the village of Ytterby, Sweden.[13] Arrhenius's "ytterbite" reached Johan Gadolin, a Royal Academy of
Turku professor, and his analysis yielded an unknown oxide ("earth"), which he called yttria. Anders
Gustav Ekeberg isolated beryllium from the gadolinite but failed to recognize other elements in the ore.
After this discovery in 1794, a mineral from Bastnäs near Riddarhyttan, Sweden, which was believed to be
an iron–tungsten mineral, was re-examined by Jöns Jacob Berzelius and Wilhelm Hisinger. In 1803 they
obtained a white oxide and called it ceria. Martin Heinrich Klaproth independently discovered the same
oxide and called it ochroia. It took another 30 years for researchers to determine that other elements were
contained in the two ores ceria and yttria (the similarity of the rare-earth metals' chemical properties made
their separation difficult).

In 1839 Carl Gustav Mosander, an assistant of Berzelius, separated ceria by heating the nitrate and
dissolving the product in nitric acid. He called the oxide of the soluble salt lanthana. It took him three more
years to separate the lanthana further into didymia and pure lanthana. Didymia, although not further
separable by Mosander's techniques, was in fact still a mixture of oxides.

In 1842 Mosander also separated the yttria into three oxides: pure yttria, terbia and erbia (all the names are
derived from the town name "Ytterby"). The earth giving pink salts he called terbium; the one that yielded
yellow peroxide he called erbium.

So in 1842 the number of known rare-earth elements had reached six: yttrium, cerium, lanthanum,
didymium, erbium and terbium.

Nils Johan Berlin and Marc Delafontaine tried also to separate the crude yttria and found the same
substances that Mosander obtained, but Berlin named (1860) the substance giving pink salts erbium, and
Delafontaine named the substance with the yellow peroxide terbium. This confusion led to several false
claims of new elements, such as the mosandrium of J. Lawrence Smith, or the philippium and decipium of
Delafontaine. Due to the difficulty in separating the metals (and determining the separation is complete), the
total number of false discoveries was dozens,[14][15] with some putting the total number of discoveries at
over a hundred.[16]

Spectroscopic identification

There were no further discoveries for 30 years, and the element didymium was listed in the periodic table of
elements with a molecular mass of 138. In 1879 Delafontaine used the new physical process of optical
flame spectroscopy and found several new spectral lines in didymia. Also in 1879, the new element
samarium was isolated by Paul Émile Lecoq de Boisbaudran from the mineral samarskite.

The samaria earth was further separated by Lecoq de Boisbaudran in 1886, and a similar result was
obtained by Jean Charles Galissard de Marignac by direct isolation from samarskite. They named the
element gadolinium after Johan Gadolin, and its oxide was named "gadolinia".
Further spectroscopic analysis between 1886 and 1901 of samaria, yttria, and samarskite by William
Crookes, Lecoq de Boisbaudran and Eugène-Anatole Demarçay yielded several new spectroscopic lines
that indicated the existence of an unknown element. The fractional crystallization of the oxides then yielded
europium in 1901.

In 1839 the third source for rare earths became available. This is a mineral similar to gadolinite,
uranotantalum (now called "samarskite"). This mineral from Miass in the southern Ural Mountains was
documented by Gustav Rose. The Russian chemist R. Harmann proposed that a new element he called
"ilmenium" should be present in this mineral, but later, Christian Wilhelm Blomstrand, Galissard de
Marignac, and Heinrich Rose found only tantalum and niobium (columbium) in it.

The exact number of rare-earth elements that existed was highly unclear, and a maximum number of 25
was estimated. The use of X-ray spectra (obtained by X-ray crystallography) by Henry Gwyn Jeffreys
Moseley made it possible to assign atomic numbers to the elements. Moseley found that the exact number
of lanthanides had to be 15, and that element 61 had yet to be discovered.

Using these facts about atomic numbers from X-ray crystallography, Moseley also showed that hafnium
(element 72) would not be a rare-earth element. Moseley was killed in World War I in 1915, years before
hafnium was discovered. Hence, the claim of Georges Urbain that he had discovered element 72 was
untrue. Hafnium is an element that lies in the periodic table immediately below zirconium, and hafnium and
zirconium are very similar in their chemical and physical properties.

During the 1940s, Frank Spedding and others in the United States (during the Manhattan Project)
developed chemical ion-exchange procedures for separating and purifying the rare-earth elements. This
method was first applied to the actinides for separating plutonium-239 and neptunium from uranium,
thorium, actinium, and the other actinides in the materials produced in nuclear reactors. Plutonium-239 was
very desirable because it is a fissile material.

The principal sources of rare-earth elements are the minerals bastnäsite, monazite, and loparite and the
lateritic ion-adsorption clays. Despite their high relative abundance, rare-earth minerals are more difficult to
mine and extract than equivalent sources of transition metals (due in part to their similar chemical
properties), making the rare-earth elements relatively expensive. Their industrial use was very limited until
efficient separation techniques were developed, such as ion exchange, fractional crystallization and liquid–
liquid extraction during the late 1950s and early 1960s.[17]

Some ilmenite concentrates contain small amounts of scandium and other rare-earth elements, which could
be analysed by XRF.[18]

Early classification

Before the time that ion-exchange methods and elution were available, the separation of the rare earths was
primarily achieved by repeated precipitation or crystallization. In those days, the first separation was into
two main groups, the cerium earths (scandium, lanthanum, cerium, praseodymium, neodymium, and
samarium) and the yttrium earths (yttrium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium).
Europium, gadolinium, and terbium were either considered as a separate group of rare-earth elements (the
terbium group), or europium was included in the cerium group, and gadolinium and terbium were included
in the yttrium group. The reason for this division arose from the difference in solubility of rare-earth double
sulfates with sodium and potassium. The sodium double sulfates of the cerium group are poorly soluble,
those of the terbium group slightly, and those of the yttrium group are very soluble.[19] Sometimes, the
yttrium group was further split into the erbium group (dysprosium, holmium, erbium, and thulium) and the
ytterbium group (ytterbium and lutetium), but today the main grouping is between the cerium and the
yttrium groups.[20] Today, the rare-earth elements are classified as light or heavy rare-earth elements, rather
than in cerium and yttrium groups.

Light versus heavy classification

The classification of rare-earth elements is inconsistent between authors.[21] The most common distinction
between rare-earth elements is made by atomic numbers; those with low atomic numbers are referred to as
light rare-earth elements (LREE), those with high atomic numbers are the heavy rare-earth elements
(HREE), and those that fall in between are typically referred to as the middle rare-earth elements
(MREE).[22] Commonly, rare-earth elements with atomic numbers 57 to 61 (lanthanum to promethium) are
classified as light and those with atomic numbers 62 and greater are classified as heavy-rare earth
elements.[23] Increasing atomic numbers between light and heavy rare-earth elements and decreasing
atomic radii throughout the series causes chemical variations.[23] Europium is exempt of this classification
as it has two valence states: Eu2+ and Eu3+.[23] Yttrium is grouped as heavy rare-earth element due to
chemical similarities.[24] The break between the two groups is sometimes put elsewhere, such as between
elements 63 (europium) and 64 (gadolinium).[25] The actual metallic densities of these two groups overlap,
with the "light" group having densities from 6.145 (lanthanum) to 7.26 (promethium) or 7.52 (samarium)
g/cc, and the "heavy" group from 6.965 (ytterbium) to 9.32 (thulium), as well as including yttrium at 4.47.
Europium has a density of 5.24.

Origin
Rare-earth elements, except scandium, are heavier than iron and thus are produced by supernova
nucleosynthesis or by the s-process in asymptotic giant branch stars. In nature, spontaneous fission of
uranium-238 produces trace amounts of radioactive promethium, but most promethium is synthetically
produced in nuclear reactors.

Due to their chemical similarity, the concentrations of rare earths in rocks are only slowly changed by
geochemical processes, making their proportions useful for geochronology and dating fossils.

Geological distribution
As seen in the chart to the right, rare-earth elements are found on earth at similar concentrations to many
common transition metals. The most abundant rare-earth element is cerium, which is actually the 25th most
abundant element in Earth's crust, having 68 parts per million (about as common as copper). The exception
is the highly unstable and radioactive promethium "rare earth" is quite scarce. The longest-lived isotope of
promethium has a half-life of 17.7 years, so the element exists in nature in only negligible amounts
(approximately 572 g in the entire Earth's crust).[26] Promethium is one of the two elements that do not
have stable (non-radioactive) isotopes and are followed by (i.e. with higher atomic number) stable elements
(the other being technetium).

The rare-earth elements are often found together. During the sequential accretion of the Earth, the dense
rare-earth elements were incorporated into the deeper portions of the planet. Early differentiation of molten
material largely incorporated the rare-earths into mantle rocks.[27] The high field strength and large ionic
radii of rare-earths make them incompatible with the crystal lattices of most rock-forming minerals, so REE
will undergo strong partitioning into a melt phase if one is present.[27] REE are chemically very similar and
have always been difficult to separate, but a gradual decrease in ionic radius from light REE (LREE) to
heavy REE (HREE), called lanthanide contraction, can produce a broad separation between light and
heavy REE. The larger ionic
radii of LREE make them
generally more incompatible
than HREE in rock-forming
minerals, and will partition more
strongly into a melt phase, while
HREE may prefer to remain in
the crystalline residue,
particularly if it contains HREE-
compatible minerals like
garnet. [27][28] The result is that
all magma formed from partial
melting will always have greater
concentrations of LREE than
HREE, and individual minerals
may be dominated by either
HREE or LREE, depending on
which range of ionic radii best
fits the crystal lattice.[27] Abundance of elements in Earth's crust per million Si atoms (y axis is
logarithmic)
Among the anhydrous rare-earth
phosphates, it is the tetragonal
mineral xenotime that incorporates yttrium and the HREE, whereas the monoclinic monazite phase
incorporates cerium and the LREE preferentially. The smaller size of the HREE allows greater solid
solubility in the rock-forming minerals that make up Earth's mantle, and thus yttrium and the HREE show
less enrichment in Earth's crust relative to chondritic abundance than does cerium and the LREE. This has
economic consequences: large ore bodies of LREE are known around the world and are being exploited.
Ore bodies for HREE are more rare, smaller, and less concentrated. Most of the current supply of HREE
originates in the "ion-absorption clay" ores of Southern China. Some versions provide concentrates
containing about 65% yttrium oxide, with the HREE being present in ratios reflecting the Oddo–Harkins
rule: even-numbered REE at abundances of about 5% each, and odd-numbered REE at abundances of
about 1% each. Similar compositions are found in xenotime or gadolinite.[29]

Well-known minerals containing yttrium, and other HREE, include gadolinite, xenotime, samarskite,
euxenite, fergusonite, yttrotantalite, yttrotungstite, yttrofluorite (a variety of fluorite), thalenite, yttrialite.
Small amounts occur in zircon, which derives its typical yellow fluorescence from some of the
accompanying HREE. The zirconium mineral eudialyte, such as is found in southern Greenland, contains
small but potentially useful amounts of yttrium. Of the above yttrium minerals, most played a part in
providing research quantities of lanthanides during the discovery days. Xenotime is occasionally recovered
as a byproduct of heavy-sand processing, but is not as abundant as the similarly recovered monazite (which
typically contains a few percent of yttrium). Uranium ores from Ontario have occasionally yielded yttrium
as a byproduct.[29]

Well-known minerals containing cerium, and other LREE, include bastnäsite, monazite, allanite, loparite,
ancylite, parisite, lanthanite, chevkinite, cerite, stillwellite, britholite, fluocerite, and cerianite. Monazite
(marine sands from Brazil, India, or Australia; rock from South Africa), bastnäsite (from Mountain Pass
rare earth mine, or several localities in China), and loparite (Kola Peninsula, Russia) have been the principal
ores of cerium and the light lanthanides.[29]

Enriched deposits of rare-earth elements at the surface of the Earth, carbonatites and pegmatites, are related
to alkaline plutonism, an uncommon kind of magmatism that occurs in tectonic settings where there is
rifting or that are near subduction zones.[28] In a rift setting, the alkaline magma is produced by very small
degrees of partial melting (<1%) of garnet peridotite in the upper mantle (200 to 600 km depth).[28] This
melt becomes enriched in incompatible elements, like the rare-earth elements, by leaching them out of the
crystalline residue. The resultant magma rises as a diapir, or diatreme, along pre-existing fractures, and can
be emplaced deep in the crust, or erupted at the surface. Typical REE enriched deposits types forming in rift
settings are carbonatites, and A- and M-Type granitoids.[27][28] Near subduction zones, partial melting of
the subducting plate within the asthenosphere (80 to 200 km depth) produces a volatile-rich magma (high
concentrations of CO2 and water), with high concentrations of alkaline elements, and high element mobility
that the rare-earths are strongly partitioned into.[27] This melt may also rise along pre-existing fractures, and
be emplaced in the crust above the subducting slab or erupted at the surface. REE enriched deposits
forming from these melts are typically S-Type granitoids.[27][28]

Alkaline magmas enriched with rare-earth elements include carbonatites, peralkaline granites (pegmatites),
and nepheline syenite. Carbonatites crystallize from CO2 -rich fluids, which can be produced by partial
melting of hydrous-carbonated lherzolite to produce a CO2 -rich primary magma, by fractional
crystallization of an alkaline primary magma, or by separation of a CO2 -rich immiscible liquid from.[27][28]
These liquids are most commonly forming in association with very deep Precambrian Cratons, like the ones
found in Africa and the Canadian Shield.[27] Ferrocarbonatites are the most common type of carbonatite to
be enriched in REE, and are often emplaced as late-stage, brecciated pipes at the core of igneous
complexes; they consist of fine-grained calcite and hematite, sometimes with significant concentrations of
ankerite and minor concentrations of siderite.[27][28] Large carbonatite deposits enriched in rare-earth
elements include Mount Weld in Australia, Thor Lake in Canada, Zandkopsdrift in South Africa, and
Mountain Pass in the USA.[28] Peralkaline granites (A-Type granitoids) have very high concentrations of
alkaline elements and very low concentrations of phosphorus; they are deposited at moderate depths in
extensional zones, often as igneous ring complexes, or as pipes, massive bodies, and lenses.[27][28] These
fluids have very low viscosities and high element mobility, which allows for crystallization of large grains,
despite a relatively short crystallization time upon emplacement; their large grain size is why these deposits
are commonly referred to as pegmatites.[28] Economically viable pegmatites are divided into Lithium-
Cesium-Tantalum (LCT) and Niobium-Yttrium-Fluorine (NYF) types; NYF types are enriched in rare-
earth minerals. Examples of rare-earth pegmatite deposits include Strange Lake in Canada, and Khaladean-
Buregtey in Mongolia.[28] Nepheline syenite (M-Type granitoids) deposits are 90% feldspar and
feldspathoid minerals, and are deposited in small, circular massifs. They contain high concentrations of
rare-earth-bearing accessory minerals.[27][28] For the most part these deposits are small but important
examples include Illimaussaq-Kvanefeld in Greenland, and Lovozera in Russia.[28]

Rare-earth elements can also be enriched in deposits by secondary alteration either by interactions with
hydrothermal fluids or meteoric water or by erosion and transport of resistate REE-bearing minerals.
Argillization of primary minerals enriches insoluble elements by leaching out silica and other soluble
elements, recrystallizing feldspar into clay minerals such kaolinite, halloysite and montmorillonite. In
tropical regions where precipitation is high, weathering forms a thick argillized regolith, this process is
called supergene enrichment and produces laterite deposits; heavy rare-earth elements are incorporated into
the residual clay by absorption. This kind of deposit is only mined for REE in Southern China, where the
majority of global heavy rare-earth element production occurs. REE-laterites do form elsewhere, including
over the carbonatite at Mount Weld in Australia. REE may also by extracted from placer deposits if the
sedimentary parent lithology contained REE-bearing, heavy resistate minerals.[28]

In 2011, Yasuhiro Kato, a geologist at the University of Tokyo who led a study of Pacific Ocean seabed
mud, published results indicating the mud could hold rich concentrations of rare-earth minerals. The
deposits, studied at 78 sites, came from "[h]ot plumes from hydrothermal vents pull[ing] these materials out
of seawater and deposit[ing] them on the seafloor, bit by bit, over tens of millions of years. One square
patch of metal-rich mud 2.3 kilometers wide might contain enough rare earths to meet most of the global
demand for a year, Japanese geologists report in Nature Geoscience." "I believe that rare[-]earth resources
undersea are much more promising than on-land resources," said Kato. "[C]oncentrations of rare earths
were comparable to those found in clays mined in China. Some deposits contained twice as much heavy
rare earths such as dysprosium, a component of magnets in hybrid car motors."[29][30]

Geochemistry applications

The application of rare-earth elements to geology is important to understanding the petrological processes
of igneous, sedimentary and metamorphic rock formation. In geochemistry, rare-earth elements can be used
to infer the petrological mechanisms that have affected a rock due to the subtle atomic size differences
between the elements, which causes preferential fractionation of some rare earths relative to others
depending on the processes at work.[22]

In geochemistry, rare-earth elements are typically presented in normalized "spider" diagrams, in which
concentration of rare-earth elements are normalized to a reference standard and are then expressed as the
logarithm to the base 10 of the value. Commonly, the rare-earth elements are normalized to chondritic
meteorites, as these are believed to be the closest representation of unfractionated solar system material.
However, other normalizing standards can be applied depending on the purpose of the study. Normalization
to a standard reference value, especially of a material believed to be unfractionated, allows the observed
abundances to be compared to initial abundances of the element.[22] Normalization also removes the
pronounced 'zig-zag' pattern caused by the differences in abundance between even and odd atomic
numbers. The trends that are observed in "spider" diagrams are typically referred to as "patterns", which
may be diagnostic of petrological processes that have affected the material of interest.[22]

The rare-earth elements patterns observed in igneous rocks are primarily a function of the chemistry of the
source where the rock came from, as well as the fractionation history the rock has undergone.[22]
Fractionation is in turn a function of the partition coefficients of each element. Partition coefficients are
responsible for the fractionation of a trace elements (including rare-earth elements) into the liquid phase (the
melt/magma) into the solid phase (the mineral). If an element preferentially remains in the solid phase it is
termed ‘compatible’, and it preferentially partitions into the melt phase it is described as ‘incompatible’.[22]
Each element has a different partition coefficient, and therefore fractionates into solid and liquid phases
distinctly. These concepts are also applicable to metamorphic and sedimentary petrology.

In igneous rocks, particularly in felsic melts, the following observations apply: anomalies in europium are
dominated by the crystallization of feldspars. Hornblende, controls the enrichment of MREE compared to
LREE and HREE. Depletion of LREE relative to HREE may be due to the crystallization of olivine,
orthopyroxene, and clinopyroxene. On the other hand, depletion of HREE relative to LREE may be due to
the presence of garnet, as garnet preferentially incorporates HREE into its crystal structure. The presence of
zircon may also cause a similar effect.[22]

In sedimentary rocks, rare-earth elements in clastic sediments are a representation provenance. The rare-
earth element concentrations are not typically affected by sea and river waters, as rare-earth elements are
insoluble and thus have very low concentrations in these fluids. As a result, when a sediment is transported,
rare-earth element concentrations are unaffected by the fluid and instead the rock retains the rare-earth
element concentration from its source.[22]

Sea and river waters typically have low rare-earth element concentrations. However, aqueous geochemistry
is still very important. In oceans, rare-earth elements reflect input from rivers, hydrothermal vents, and
aeolian sources;[22] this is important in the investigation of ocean mixing and circulation.[24]

Rare-earth elements are also useful for dating rocks, as some radioactive isotopes display long half-lives. Of
particular interest are the 138 La-138 Ce, 147 Sm-143 Nd, and 176 Lu-176 Hf systems.[24]
Production
Until 1948, most of the world's rare earths were
sourced from placer sand deposits in India and
Brazil. Through the 1950s, South Africa was the
world's rare-earth source, from a monazite-rich
reef at the Steenkampskraal mine in Western Cape
province.[31] Through the 1960s until the 1980s,
the Mountain Pass rare earth mine in California
made the United States the leading producer.
Today, the Indian and South African deposits still
produce some rare-earth concentrates, but they are
dwarfed by the scale of Chinese production. In
Global production 1950–2000
2017, China produced 81% of the world's rare-
earth supply, mostly in Inner Mongolia,[6][32]
although it had only 36.7% of reserves. Australia was the second and only other major producer with 15%
of world production.[33] All of the world's heavy rare earths (such as dysprosium) come from Chinese rare-
earth sources such as the polymetallic Bayan Obo deposit.[32][34] The Browns Range mine, located
160 km south east of Halls Creek in northern Western Australia, is currently under development and is
positioned to become the first significant dysprosium producer outside of China.[35]

Increased demand has strained supply, and there is growing concern that the world may soon face a
shortage of the rare earths.[36] In several years from 2009 worldwide demand for rare-earth elements is
expected to exceed supply by 40,000 tonnes annually unless major new sources are developed.[37] In 2013,
it was stated that the demand for REEs would increase due to the dependence of the EU on these elements,
the fact that rare earth elements cannot be substituted by other elements and that REEs have a low recycling
rate. Furthermore, due to the increased demand and low supply, future prices are expected to increase and
there is a chance that countries other than China will open REE mines.[38] REE is increasing in demand
due to the fact that they are essential for new and innovative technology that is being created. These new
products that need REEs to be produced are high technology equipment such as smart phones, digital
cameras, computer parts, semiconductors, etc. In addition, these elements are more prevalent in the
following industries: renewable energy technology, military equipment, glass making, and metallurgy.[39]

China

These concerns have intensified due to the actions of China, the predominant supplier.[40] Specifically,
China has announced regulations on exports and a crackdown on smuggling.[41] On September 1, 2009,
China announced plans to reduce its export quota to 35,000 tons per year in 2010–2015 to conserve scarce
resources and protect the environment.[42] On October 19, 2010, China Daily, citing an unnamed Ministry
of Commerce official, reported that China will "further reduce quotas for rare-earth exports by 30 percent at
most next year to protect the precious metals from over-exploitation."[43] The government in Beijing further
increased its control by forcing smaller, independent miners to merge into state-owned corporations or face
closure. At the end of 2010, China announced that the first round of export quotas in 2011 for rare earths
would be 14,446 tons, which was a 35% decrease from the previous first round of quotas in 2010.[44]
China announced further export quotas on 14 July 2011 for the second half of the year with total allocation
at 30,184 tons with total production capped at 93,800 tonnes.[45] In September 2011, China announced the
halt in production of three of its eight major rare-earth mines, responsible for almost 40% of China's total
rare-earth production.[46] In March 2012, the US, EU, and Japan confronted China at WTO about these
export and production restrictions. China responded with claims that the restrictions had environmental
protection in mind.[47][48] In August 2012, China announced a further 20% reduction in production.[49]
The United States, Japan, and the European Union filed a joint lawsuit with the World Trade Organization
in 2012 against China, arguing that China should not be able to deny such important exports.[48]

In response to the opening of new mines in other countries (Lynas in Australia and Molycorp in the United
States), prices of rare earths dropped.[50] The price of dysprosium oxide was 994 USD/kg in 2011, but
dropped to US$265/kg by 2014.[51]

On August 29, 2014, the WTO ruled that China had broken free-trade agreements, and the WTO said in
the summary of key findings that "the overall effect of the foreign and domestic restrictions is to encourage
domestic extraction and secure preferential use of those materials by Chinese manufacturers." China
declared that it would implement the ruling on September 26, 2014, but would need some time to do so. By
January 5, 2015, China had lifted all quotas from the export of rare earths, but export licences will still be
required.[52]

In 2019, China supplied between 85% and 95% of the global demand for the 17 rare earth powders, half of
them sourced from Myanmar.[53] After the 2021 military coup in that country, future supplies of critical
ores were possibly constrained. Additionally, it was speculated that the PRC could again reduce rare earth
exports to counter-act economic sanctions imposed by the US and EU countries. Rare earth metals serve as
crucial materials for EV-manufacturing and high-tech military applications.[54]

Outside China

As a result of the increased demand and tightening restrictions on exports of the metals from China, some
countries are stockpiling rare-earth resources.[55] Searches for alternative sources in Australia, Brazil,
Canada, South Africa, Tanzania, Greenland, and the United States are ongoing.[56] Mines in these
countries were closed when China undercut world prices in the 1990s, and it will take a few years to restart
production as there are many barriers to entry.[41] One example is the Mountain Pass mine in California,
which announced its resumption of operations on a start-up basis on August 27, 2012.[32][57] Other
significant sites under development outside China include Steenkampskraal in South Africa, the world's
highest grade rare earths and thorium mine, which is gearing to go back into production. Over 80% of the
infrastructure is already complete.[58] Other mines include the Nolans Project in Central Australia, the
Bokan Mountain project in Alaska, the remote Hoidas Lake project in northern Canada,[59] and the Mount
Weld project in Australia.[32][57][60] The Hoidas Lake project has the potential to supply about 10% of the
$1 billion of REE consumption that occurs in North America every year.[61] Vietnam signed an agreement
in October 2010 to supply Japan with rare earths[62] from its northwestern Lai Châu Province.[63]

In the US, NioCorp Development Ltd has launched a long-shot effort to secure $1.1 billion[64] toward
opening a niobium, scandium, and titanium mine at its Elk Creek site in southeast Nebraska[65] which may
be able to produce as much as 7200 tonnes of ferro niobium and 95 tonnes of scandium trioxide
annually.[66]

Also under consideration for mining are sites such as Thor Lake in the Northwest Territories, and various
locations in Vietnam.[32][37][67] Additionally, in 2010, a large deposit of rare-earth minerals was discovered
in Kvanefjeld in southern Greenland.[68] Pre-feasibility drilling at this site has confirmed significant
quantities of black lujavrite, which contains about 1% rare-earth oxides (REO).[69] The European Union
has urged Greenland to restrict Chinese development of rare-earth projects there, but as of early 2013, the
government of Greenland has said that it has no plans to impose such restrictions.[70] Many Danish
politicians have expressed concerns that other nations, including China, could gain influence in thinly
populated Greenland, given the number of foreign workers and investment that could come from Chinese
companies in the near future because of the law passed December 2012.[71]
In central Spain, Ciudad Real Province, the proposed rare-earth mining project 'Matamulas' may provide,
according to its developers, up to 2,100 Tn/year (33% of the annual UE demand). However, this project
has been suspended by regional authorities due to social and environmental concerns.[72]

Adding to potential mine sites, ASX listed Peak Resources announced in February 2012, that their
Tanzanian-based Ngualla project contained not only the 6th largest deposit by tonnage outside of China,
but also the highest grade of rare-earth elements of the 6.[73]

North Korea has been reported to have exported rare-earth ore to China, about US$1.88 million worth
during May and June 2014.[74][75]

In May 2012, researchers from two universities in Japan announced that they had discovered rare earths in
Ehime Prefecture, Japan.[76]

Malaysian refining plans

In early 2011, Australian mining company Lynas was reported to be "hurrying to finish" a US$230 million
rare-earth refinery on the eastern coast of Peninsular Malaysia's industrial port of Kuantan. The plant would
refine ore — lanthanides concentrate from the Mount Weld mine in Australia. The ore would be trucked to
Fremantle and transported by container ship to Kuantan. Within two years, Lynas was said to expect the
refinery to be able to meet nearly a third of the world's demand for rare-earth materials, not counting
China.[77] The Kuantan development brought renewed attention to the Malaysian town of Bukit Merah in
Perak, where a rare-earth mine operated by a Mitsubishi Chemical subsidiary, Asian Rare Earth, closed in
1994 and left continuing environmental and health concerns.[78][79] In mid-2011, after protests, Malaysian
government restrictions on the Lynas plant were announced. At that time, citing subscription-only Dow
Jones Newswire reports, a Barrons report said the Lynas investment was $730 million, and the projected
share of the global market it would fill put at "about a sixth."[80] An independent review initiated by the
Malaysian Government, and conducted by the International Atomic Energy Agency (IAEA) in 2011 to
address concerns of radioactive hazards, found no non-compliance with international radiation safety
standards.[81]

However, the Malaysian authorities confirmed that as of October 2011, Lynas was not given any permit to
import any rare-earth ore into Malaysia. On February 2, 2012, the Malaysian AELB (Atomic Energy
Licensing Board) recommended that Lynas be issued a temporary operating license subject to meeting a
number of conditions. On 2 September 2014, Lynas was issued a 2-year full operating stage license by the
AELB.[82]

Other sources

Mine tailings

Significant quantities of rare-earth oxides are found in tailings accumulated from 50 years of uranium ore,
shale and loparite mining at Sillamäe, Estonia.[83] Due to the rising prices of rare earths, extraction of these
oxides has become economically viable. The country currently exports around 3,000 tonnes per year,
representing around 2% of world production.[84] Similar resources are suspected in the western United
States, where gold rush-era mines are believed to have discarded large amounts of rare earths, because they
had no value at the time.[85]

Ocean mining
In January 2013 a Japanese deep-sea research vessel obtained seven deep-sea mud core samples from the
Pacific Ocean seafloor at 5,600 to 5,800 meters depth, approximately 250 kilometres (160 mi) south of the
island of Minami-Tori-Shima.[86] The research team found a mud layer 2 to 4 meters beneath the seabed
with concentrations of up to 0.66% rare-earth oxides. A potential deposit might compare in grade with the
ion-absorption-type deposits in southern China that provide the bulk of Chinese REO mine production,
which grade in the range of 0.05% to 0.5% REO.[87][88]

Waste

Another recently developed source of rare earths is electronic waste and other wastes that have significant
rare-earth components.[89] Advances in recycling technology have made extraction of rare earths from
these materials less expensive.[90] Recycling plants operate in Japan, where an estimated 300,000 tons of
rare earths are found in unused electronics.[91] In France, the Rhodia group is setting up two factories, in
La Rochelle and Saint-Fons, that will produce 200 tons of rare earths a year from used fluorescent lamps,
magnets and batteries.[92][93] Coal and coal by-products are a potential source of critical elements including
rare earth elements (REE) with estimated amounts in the range of 50 million metric tons.[94]

Methods

One study mixed fly ash with carbon black and then sent a 1-second current pulse through the mixture,
heating it to 3,000 °C (5,430 °F). The fly ash contains microscopic bits of glass that encapsulate the metals.
The heats shatters the glass, exposing the rare earths. Flash heating also converts phosphates into oxides,
which are more soluble and extractable. Using hydrochloric acid at concentrations less than 1% of
conventional methods, the process extracted twice as much material.[95]

Properties
According to chemistry professor Andrea Sella, rare-earth elements differ from other elements, in that when
looked at analytically, they are virtually inseparable, having almost the same chemical properties. However,
in terms of their electronic and magnetic properties, each one occupies a unique technological niche that
nothing else can.[3] For example, "the rare-earth elements praseodymium (Pr) and neodymium (Nd) can
both be embedded inside glass and they completely cut out the glare from the flame when one is doing
glass-blowing."[3]

Uses
The uses, applications, and demand for rare-earth elements has expanded over the years. Globally, most
REEs are used for catalysts and magnets.[96] In USA, more than half of REEs are used for catalysts, and
ceramics, glass and polishing are also main uses.[97]

Other important uses of rare-earth elements are applicable to the production of high-performance magnets,
alloys, glasses, and electronics. Ce and La are important as catalysts, and are used for petroleum refining
and as diesel additives. Nd is important in magnet production in traditional and low-carbon technologies.
Rare-earth elements in this category are used in the electric motors of hybrid and electric vehicles,
generators in wind turbines, hard disc drives, portable electronics, microphones, speakers.

Ce, La and Nd are important in alloy making, and in the production of fuel cells and nickel-metal hydride
batteries. Ce, Ga and Nd are important in electronics and are used in the production of LCD and plasma
screens, fiber optics, lasers,[98] as well as in medical imaging. Additional uses for rare-earth elements are as
tracers in medical applications, fertilizers, and in water treatment.[24]

REEs have been used in agriculture to increase plant growth,


productivity, and stress resistance seemingly without negative effects
for human and animal consumption. REEs are used in agriculture
through REE-enriched fertilizers which is a widely used practice in
China.[99] In addition, REEs are feed additives for livestock which has
resulted in increased production such as larger animals and a higher
production of eggs and dairy products. However, this practice has
resulted in REE bio-accumulation within livestock and has impacted
vegetation and algae growth in these agricultural areas.[100]
Additionally while no ill effects have been observed at current low
concentrations the effects over the long term and with accumulation Global REE consumption,
over time are unknown prompting some calls for more research into 2015[96]
their possible effects.[99][101]
Catalysts, 24% (24%)
Given the limited supply, industries directly compete with each other Magnets, 23% (23%)
for resources, e.g. the electronics sector is in direct competition with Polishing, 12% (12%)
renewable energy use in windfarms, solar panels and batteries.[102] "other", 9% (9%)
Metallurgy, 8% (8%)
Environmental considerations Batteries, 8% (8%)
Glass, 7% (7%)
REEs are naturally found in very low concentration in the Ceramics, 6% (6%)
environment. Mines are often in countries where environmental and Phosphors and pigments, 3%
social standards are very low, leading to human rights violations, (3%)
deforestation and contamination of land and water.[102][103]

Near mining and industrial sites, the concentrations of REEs can rise
to many times the normal background levels. Once in the environment,
REEs can leach into the soil where their transport is determined by
numerous factors such as erosion, weathering, pH, precipitation,
ground water, etc. Acting much like metals, they can speciate
depending on the soil condition being either motile or adsorbed to soil
particles. Depending on their bio-availability, REEs can be absorbed
into plants and later consumed by humans and animals. The mining of
REEs, use of REE-enriched fertilizers, and the production of
phosphorus fertilizers all contribute to REE contamination.[104]
Furthermore, strong acids are used during the extraction process of
REEs, which can then leach out in to the environment and be
transported through water bodies and result in the acidification of US consumption of REE,
aquatic environments. Another additive of REE mining that 2018[97]
contributes to REE environmental contamination is cerium oxide
Catalysts, 60% (60%)
(CeO2 ), which is produced during the combustion of diesel and
Ceramics and glass, 15%
released as exhaust, contributing heavily to soil and water (15%)
contamination.[100] Polishing, 10% (10%)
"other", 5% (5%)
Mining, refining, and recycling of rare earths have serious
environmental consequences if not properly managed. Low-level Metallurgy, 10% (10%)
radioactive tailings resulting from the occurrence of thorium and
uranium in rare-earth element ores present a potential hazard[105] and
improper handling of these substances can result in extensive environmental damage. In May 2010, China
announced a major, five-month crackdown on illegal mining in
order to protect the environment and its resources. This campaign is
expected to be concentrated in the South,[106] where mines –
commonly small, rural, and illegal operations – are particularly
prone to releasing toxic waste into the general water
supply.[32][107] However, even the major operation in Baotou, in
Inner Mongolia, where much of the world's rare-earth supply is
refined, has caused major environmental damage.[108] China's
Ministry of Industry and Information Technology estimated that False-color satellite image of the
cleanup costs in Jiangxi province at $5.5 billion.[103] Bayan Obo Mining District, 2006

It is, however, possible to filter out and recover any rare earth
elements that flow out with the wastewater from mining facilities. However, such filtering and recovery
equipment may not always be present on the outlets carrying the wastewater.[109][110][111]

Recycling and reusing REEs

Literature published in 2004 suggests that, along with previously established pollution mitigation, a more
circular supply chain would help mitigate some of the pollution at the extraction point. This means
recycling and reusing REEs that are already in use or reaching the end of their life cycle.[101] A study
published in 2014 suggests a method to recycle REEs from waste nickel-metal hydride batteries,
demonstrating a recovery rate of 95.16%.[112] Rare-earth elements could also be recovered from industrial
wastes with practical potential to reduce environmental and health impacts from mining, waste-generation
and imports if known and experimental processes are scaled up.[113][114] A study suggests that "fulfillment
of the circular economy approach could reduce up to 200 times the impact in the climate change category
and up to 70 times the cost due to the REE mining."[115] In most of the reported studies reviewed by a
scientific review, "secondary waste is subjected to chemical and or bioleaching followed by solvent
extraction processes for clean separation of REEs."[116]

Impact of REE contamination

On vegetation

The mining of REEs has caused the contamination of soil and water around production areas, which has
impacted vegetation in these areas by decreasing chlorophyll production which affects photosynthesis and
inhibits the growth of the plants.[100] However, the impact of REE contamination on vegetation is
dependent on the plants present in the contaminated environment: some plants retain and absorb REEs and
some don't. Also, the ability for the vegetation to intake the REE is dependent on the type of REE present
in the soil, hence there are a multitude of factors that influence this process.[117] Agricultural plants are the
main type of vegetation affected by REE contamination in the environment, the two plants with a higher
chance of absorbing and storing REEs being apples and beets.[104] Furthermore, there is a possibility that
REEs can leach out into aquatic environments and be absorbed by aquatic vegetation, which can then bio-
accumulate and potentially enter the human food-chain if livestock or humans choose to eat the vegetation.
An example of this situation was the case of the water hyacinth (Eichhornia crassipes) in China, where the
water was contaminated due to a REE-enriched fertilizer being used in a nearby agricultural area. The
aquatic environment became contaminated with cerium and resulted in the water hyacinth becoming three
times more concentrated in cerium than its surrounding water.[117]
On human health

REEs are a large group with many different properties and levels in the environment. Because of this, and
limited research, it has been difficult to determine safe levels of exposure for humans.[118] A number of
studies have focused on risk assessment based on routes of exposure and divergence from background
levels related to nearby agriculture, mining, and industry.[119][120] It has been demonstrated that numerous
REEs have toxic properties and are present in the environment or in work places. Exposure to these can
lead to a wide range of negative health outcomes such as cancer, respiratory issues, dental loss, and even
death.[38] However REEs are numerous and present in many different forms and at different levels of
toxicity, making it difficult to give blanket warnings on cancer risk and toxicity as some of these are
harmless while others pose a risk.[118][120][119]

What toxicity is shown appears to be at very high levels of exposure through ingestion of contaminated
food and water, through inhalation of dust/smoke particles either as an occupational hazard or due to
proximity to contaminated sites such as mines and cities. Therefore, the main issues that these residents
would face is bioaccumulation of REEs and the impact on their respiratory system but overall, there can be
other possible short term and long-term health effects.[121][100] It was found that people living near mines
in China had many times the levels of REEs in their blood, urine, bone and hair compared to controls far
from mining sites. This higher level was related to the high levels of REEs present in the vegetables they
cultivated, the soil, and the water from the wells, indicating that the high levels were caused by the nearby
mine.[119][120] While REE levels varied between men and women, the group most at risk were children
because REEs can impact the neurological development of children, affecting their IQ and potentially
causing memory loss.[122]

The rare earth mining and smelting process can release airborne fluoride which will associate with total
suspended particles (TSP) to form aerosols that can enter human respiratory systems and cause damage and
respiratory diseases. Research from Baotou, China shows that the fluoride concentration in air near REE
mines is higher than the limit value from WHO, which can affect the surrounding environment and become
a risk to those that live or work nearby.[123]

Residents blamed a rare-earth refinery at Bukit Merah for birth defects and eight leukemia cases within five
years in a community of 11,000 — after many years with no leukemia cases. Seven of the leukemia victims
died. Osamu Shimizu, a director of Asian Rare Earth, said "the company might have sold a few bags of
calcium phosphate fertilizer on a trial basis as it sought to market byproducts; calcium phosphate is not
radioactive or dangerous" in reply to a former resident of Bukit Merah who said that "The cows that ate the
grass [grown with the fertilizer] all died."[124] Malaysia's Supreme Court ruled on 23 December 1993 that
there was no evidence that the local chemical joint venture Asian Rare Earth was contaminating the local
environment.[125]

On animal health

Experiments exposing rats to various cerium compounds have found accumulation primarily in the lungs
and liver. This resulted in various negative health outcomes associated with those organs.[126] REEs have
been added to feed in livestock to increase their body mass and increase milk production.[126] They are
most commonly used to increase the body mass of pigs, and it was discovered that REEs increase the
digestibility and nutrient use of pigs' digestive systems.[126] Studies point to a dose response when
considering toxicity versus positive effects. While small doses from the environment or with proper
administration seem to have no ill effects, larger doses have been shown to have negative effects
specifically in the organs where they accumulate.[126] The process of mining REEs in China has resulted in
soil and water contamination in certain areas, which when transported into aquatic bodies could potentially
bio-accumulate within aquatic biota. Furthermore, in some cases animals that live in the REE-contaminated
areas have been diagnosed with organ or system problems.[100] REEs have been used in freshwater fish
farming because it protects the fish from possible diseases.[126] One main reason why they have been
avidly used in animal livestock feeding is that they have had better results than inorganic livestock feed
enhancers.[127]

Remediation after pollution

After the 1982 Bukit Merah radioactive pollution, the mine in Malaysia has been the focus of a US$100
million cleanup that is proceeding in 2011. After having accomplished the hilltop entombment of 11,000
truckloads of radioactively contaminated material, the project is expected to entail in summer, 2011, the
removal of "more than 80,000 steel barrels of radioactive waste to the hilltop repository."[79]

In May 2011, after the Fukushima Daiichi nuclear disaster, widespread protests took place in Kuantan over
the Lynas refinery and radioactive waste from it. The ore to be processed has very low levels of thorium,
and Lynas founder and chief executive Nicholas Curtis said "There is absolutely no risk to public health."
T. Jayabalan, a doctor who says he has been monitoring and treating patients affected by the Mitsubishi
plant, "is wary of Lynas's assurances. The argument that low levels of thorium in the ore make it safer
doesn't make sense, he says, because radiation exposure is cumulative."[124] Construction of the facility has
been halted until an independent United Nations IAEA panel investigation is completed, which is expected
by the end of June 2011.[128] New restrictions were announced by the Malaysian government in late
June.[80]

IAEA panel investigation is completed and no construction has been halted. Lynas is on budget and on
schedule to start producing 2011. The IAEA report has concluded in a report issued on Thursday June
2011 said it did not find any instance of "any non-compliance with international radiation safety standards"
in the project.[129]

If the proper safety standards are followed, REE mining is relatively low impact. Molycorp (before going
bankrupt) often exceeded environmental regulations to improve public image.[130]

In Greenland there is a significant dispute on whether to start a new rare earth mine in Kvanefjeld due to
environmental concerns.[131]

Geo-political considerations
China has officially cited resource depletion and environmental
concerns as the reasons for a nationwide crackdown on its rare-
earth mineral production sector.[46] However, non-environmental
motives have also been imputed to China's rare-earth policy.[108]
According to The Economist, "Slashing their exports of rare-earth
metals… is all about moving Chinese manufacturers up the supply
chain, so they can sell valuable finished goods to the world rather
than lowly raw materials."[132] Furthermore, China currently has
an effective monopoly on the world's REE Value Chain.[133] (all Global rare-earth-oxide production
the refineries and processing plants that transform the raw ore into trends, 1956-2008 (USGS)
valuable elements[134]). In the words of Deng Xiaoping, a Chinese
politician from the late 1970s to the late 1980s, "The Middle East
has oil; we have rare earths ... it is of extremely important strategic significance; we must be sure to handle
the rare earth issue properly and make the fullest use of our country's advantage in rare earth
resources."[135]
One possible example of market control is the division of General Motors that deals with miniaturized
magnet research, which shut down its US office and moved its entire staff to China in 2006[136] (China's
export quota only applies to the metal but not products made from these metals such as magnets).

It was reported,[137] but officially denied,[138] that China instituted an export ban on shipments of rare-
earth oxides (but not alloys) to Japan on 22 September 2010, in response to the detainment of a Chinese
fishing boat captain by the Japanese Coast Guard.[139][48] On September 2, 2010, a few days before the
fishing boat incident, The Economist reported that "China...in July announced the latest in a series of
annual export reductions, this time by 40% to precisely 30,258 tonnes."[140][48]

The United States Department of Energy in its 2010 Critical Materials Strategy report identified dysprosium
as the element that was most critical in terms of import reliance.[141]

A 2011 report "China's Rare-Earth Industry", issued by the US Geological Survey and US Department of
the Interior, outlines industry trends within China and examines national policies that may guide the future
of the country's production. The report notes that China's lead in the production of rare-earth minerals has
accelerated over the past two decades. In 1990, China accounted for only 27% of such minerals. In 2009,
world production was 132,000 metric tons; China produced 129,000 of those tons. According to the report,
recent patterns suggest that China will slow the export of such materials to the world: "Owing to the
increase in domestic demand, the Government has gradually reduced the export quota during the past
several years." In 2006, China allowed 47 domestic rare-earth producers and traders and 12 Sino-foreign
rare-earth producers to export. Controls have since tightened annually; by 2011, only 22 domestic rare-earth
producers and traders and 9 Sino-foreign rare-earth producers were authorized. The government's future
policies will likely keep in place strict controls: "According to China's draft rare-earth development plan,
annual rare-earth production may be limited to between 130,000 and 140,000 [metric tons] during the
period from 2009 to 2015. The export quota for rare-earth products may be about 35,000 [metric tons] and
the Government may allow 20 domestic rare-earth producers and traders to export rare earths."[142]

The United States Geological Survey is actively surveying southern Afghanistan for rare-earth deposits
under the protection of United States military forces. Since 2009 the USGS has conducted remote sensing
surveys as well as fieldwork to verify Soviet claims that volcanic rocks containing rare-earth metals exist in
Helmand Province near the village of Khanashin. The USGS study team has located a sizable area of rocks
in the center of an extinct volcano containing light rare-earth elements including cerium and neodymium. It
has mapped 1.3 million metric tons of desirable rock, or about ten years of supply at current demand levels.
The Pentagon has estimated its value at about $7.4 billion.[143]

It has been argued that the geopolitical importance of rare earths has been exaggerated in the literature on
the geopolitics of renewable energy, underestimating the power of economic incentives for expanded
production.[144][145] This especially concerns neodymium. Due to its role in permanent magnets used for
wind turbines, it has been argued that neodymium will be one of the main objects of geopolitical
competition in a world running on renewable energy. But this perspective has been criticised for failing to
recognise that most wind turbines have gears and do not use permanent magnets.[145]

See also
Rare-earth mineral
Rare-earth magnet
List of elements facing shortage
Material passport: lists used materials in products
Digital Product Passport: renewed in function of the Circular Economy Action Plan
Pensana Salt End
References
1. The 1985 International Union of Pure and Applied Chemistry "Red Book" (p. 45)
recommends that lanthanoid is used rather than lanthanide. The ending "-ide" normally
indicates a negative ion. However, owing to wide current usage, "lanthanide" is still allowed
and is roughly analogous to rare earth element.
2. N. G. Connelly and T. Damhus, ed. (2005). Nomenclature of Inorganic Chemistry: IUPAC
Recommendations 2005 (https://web.archive.org/web/20080527204340/http://www.iupac.or
g/publications/books/rbook/Red_Book_2005.pdf) (PDF). With R. M. Hartshorn and A. T.
Hutton. Cambridge: RSC Publishing. ISBN 978-0-85404-438-2. Archived from the original (h
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External links
Media related to Rare earth elements at Wikimedia Commons
External media
Audio
"Rare Earths: The Hidden Cost
to Their Magic" (https://www.scienc
ehistory.org/distillations/podcast/rar
e-earths-the-hidden-cost-to-their-m
agic), Distillations Podcast and
transcript, Episode 242, June 25,
2019, Science History Institute
Video
“10 ways rare earth elements
make life better” (https://www.scienc
ehistory.org/rare-earth-elements-pr
oject), animation, Science History
Institute
Rare Earth Elements: The
Intersection of Science and Society
(https://www.youtube.com/watch?v=
aglMNj4hld0), presentation and
discussion led by Ira Flatow,
Science History Institute,
September 24, 2019

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