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Chem Q3
Chem Q3
MASS – measure of the quantity of the matter (kg) PRECISION - measures how close results are to one
WEIGHT – force that gravity exerts on an object (N) another
23
6.02 x 10 - 2 sig figs
ex. Express 1.0 gallon in milliliters.
100.000 - 6 sig figs
4𝑞𝑡 1𝐿 1000 𝑚𝐿 3
1.0 gal ( 1𝑔𝑎𝑙 )( 1.06 𝑞𝑡 )( 1𝐿
) = 3. 8 𝑥 10 𝑚𝐿
150000 - 1 sig figs
3
28,317 𝑐𝑚 3
1.0 gal ( ) = 3. 8 𝑥 10 𝑚𝐿
4. Any zero after a nonzero number is significant 7.4805 𝑔𝑎𝑙
1. Binary (M+NM)
- Ide: Two elements
- Fe2+ (Fer OUS) = Iron (II)
- Ate: Three or more elements
- Fe3+ (Fe RIC) = Iron (III)
Ex.
Ide Ate
CaC2 CaCo3
Kl KlO3
FeS FeSO4
How to name?
Ex.
1. Hydrates
- Combination of Polyatomic ( 3 or more), Molecular mass and its covalent compound
Binary (2) ion, and hydrate
- Uses Greek prefixes
Ex.
1. Na2CO3 5H2O
= Sodium Carbonate Pentahydrate
2. C9(ClO3) 7H2O
= Calcium Chlorate Heptahydrate
3. LiHCO3 9H2O
= Lithium carbonate or Bi Carbonate
Nonahydrate
Percent composition
Chemical Reaction and Equations - Describe the composition by mass of various
substances
Reaction: A process where a substance - Formula:
𝑝𝑎𝑟𝑡
x 100% = percent composition
𝑤ℎ𝑜𝑙𝑒
interacts with one another producing a
chemical change
Equation: Representation of chemical
reaction, symbols and formulas. Expression of
chemical reaction.
Symbols: Atoms and elements
Formulas: Compounds
Empirical formula
Subscript – H2O
- the simplest whole number ratio of atoms
Coefficient - 2 H2O
present in a compound
Rule: never change the subscript, only
coefficient
A simple rhyme for a simple formula by Joel S. Compressibility - very compressible
Thomspon
Volume and Shape - assumes the shape and volume
Percent to mass
of the container
Mass to mole
Divide by small Molecular Motion - free motion; forming
Multiply ‘til whole homogeneous mixture with one another
6.85 𝑔 𝐻
760 mmHg 760 torr
6.85% H, → 1 𝑔/𝑚𝑜𝑙 𝐻
= 6.80 mol/2.74 = 2.5 x 2 = 5
14.7 psi (pounds per square inch)
43.84 𝑔 𝑂
43.84% O, → 16 𝑔/𝑚𝑜𝑙 𝑂
= 2.74 mol/2.74 = 1 x 2 = 2
𝑁
kPa = 2
𝑚
empirical formula: C3H5O2 ratio: 3:5:2
ex. Adipic acid, the molar mass is 146g/mol Temperature (T) - always use absolute temperature
(K) when working with gasses.
3(12g)+5(1g)+2(16g)=73 g/mol
146 𝑔/𝑚𝑜𝑙
= 2 mol (then divide to the ratio of the Amount (n) - SI unit (mol) since we can’t count
73𝑔
molecules, we convert measured mass (kg) to the
empirical formula)
number of moles (n) using the molecular formula
3x2=6 weight of the gas.
5 x 2 = 10
GAS LAWS
2x2=4
A. Boyle's Law - states that a gas's pressure and
Molecular formula: C6H10O4
volume are inversely proportional. If the
A. Kinetic Molecular Theory volume increases, the pressure decreases.
- Robert Boyle - 1600s.
- have no volume
- are in constant, random, straight-line motion.
- don’t attract/repel each other
B. Characteristics of Gases
Formula: P1V2 = P2V2
- gases expand to fill any container
- gases are fluids (no attraction)
- gases have very low densities
- can be compressed (no volume)
- undergo diffusion and effusion (random ex. A sample of oxygen gas has a volume of 150 mL
motion) when its pressure is 0.947 atm. What will the volume
of the gas at a pressure of 0.987 atm if the
C. Properties of Gases
temperature does not change?
Density - low and highly variable based on T and P
P1 = 0.947 atm ex. At a constant volume, a gas has a pressure of 2.50
V1 = 150 mL atm at 32°C. Find the new pressure if temperature
P2 = 0.987 atm increases to 55°C.
V2 = ?
P1 =2.50 atm
𝑃1𝑉1 𝑃2𝑉2 𝑃1𝑉1
= → = 𝑉2
𝑃2 𝑃2 𝑃2 T1 = 32°C + 273 = 305 K
𝑃1𝑉1 𝑃2𝑉2
𝑇1
= 𝑇2
→ P1V1T2 = P2V2T1
𝑉1 𝑉2
Formula:
𝑇1
= 𝑇2
3
ex. A gas occupies 7.84 𝑐𝑚 at 71.8 kPa & 25°C. Find its
volume at STP
3
V1 = 7.84 𝑐𝑚
P1 = 71.8 kPa
T1 = 25°C + 273 = 298 K
V2 = ?
3
ex. A gas occupies 473 𝑐𝑚 at 36°C . Find its volume at P2 = 101.325 kPa
94°C. T2 = 273 K
𝑃1𝑉1 𝑃2𝑉2
V1 = 473 𝑐𝑚
3
𝑇1
= 𝑇2
3
V2 = (71.8 kPa)(7.84 𝑐𝑚 )(273 K)/(101.325 kPa)(298 K) =
T1 = 36°C + 273 = 309 K 3
5.09 𝑐𝑚
V2 = ?
𝑉1 𝑉2
𝑛1
= 𝑛2
= 0.225 mol - 0.176 mol = 0.049 mol Obey Always Only at very
PV=nRT low P and
high T
F. Dalton’s Law of Partial Pressure - the total Molecular Zero Small but
amount of pressure of a mixture in a given volume nonzero
volume equates to the sum of the partial
pressures of each gas in the mixture. Molecular Zero Small
attractions
𝑃𝑡𝑜𝑡𝑎𝑙 = 𝑃1 + 𝑃2 + 𝑃3 +... + 𝑃𝑛
Molecular Zero Small
ex. A sample of exhaled air contains four gasses with repulsions
the following partial pressures: 𝑁2(563 mm Hg), 𝑂2(118
mm Hg), 𝐶𝑂2(30 mm Hg) and 𝐻2𝑂 (50 mm Hg). What
The Development of the Atomic Theory
is the total pressure of the sample?
ATOMS- the building blocks of all substances and
𝑃𝑡𝑜𝑡𝑎𝑙 = 563 + 118 + 30 +... + 50
materials in the universe.
𝑃𝑡𝑜𝑡𝑎𝑙 = 761 𝑚𝑚 𝐻𝑔
𝑃𝑉 = 𝑛𝑅𝑇
𝑃𝑉 𝑛𝑅𝑇
𝑉
= 𝑉
● R = 0.08206 L⋅atm/mol⋅K
3 DEMOCRITUS
● R = 8.315 𝑑𝑚 ⋅kPa/mol⋅K
3
- A pupil of Leucippus.
ex. A 75 g 𝑂2 gas occupies 10.12 𝑐𝑚 at 25 °C.
- They believed that materials could be broken
Find its pressure. down into smaller pieces. However, there will
3
V = 10.12 𝑐𝑚 = 0.01012L → kaya naging 0.01012 come a point beyond which the particles can
3 no longer be divided.
kasi cinonvert 𝑐𝑚 to liters which is (10.12 x
1000) - He called the tiny particles ATOMOS
P=?
DEMOCRITUS' ATOMIC THEORY
T = 25°C = 298 K
- Atoms of each element are distinct in shape
mass = 75 g and size.
If 12 grams of magnesium is used instead, neutron in 1932. He found that the particle was
electrically neutral and its mass was
magnesium + oxygen = magnesium oxide approximately the same as that of the proton.
12 g 8g 20 g DALTON'S MODEL
8 grams of oxygen is needed to completely react with - He pictured an atom as a tiny indestructible,
magnesium. indivisible sphere with mass.
THOMSON'S MODEL
LAW OF MULTIPLE PROPORTIONS - states that when - He proposed the raisin- bread model of the
two elements combine to form more than one atom.
compound, the mass of one element which - He said that the negatively charged
combined with a fixed mass of the other is a ratio of embedded electrons were in a positively
small whole numbers. charged mass similar to the way raisins are
embedded in bread.
- The negative charge of the electrons and the
LAW OF CONSERVATION OF MASS - states that during positive charge of the sphere cancel each
all chemical reactions, the mass of the atoms other out to form neutral atoms.
involved does not change. This means that matter
RUTHERFORD'S MODEL
can neither be created nor destroyed but is only
transformed. - Ernest Rutherford proposed the nuclear
model of the atom.
- He won a Nobel prize in 1908 for his discovery
of the nucleus. The nucleus is a tiny, positive,
central core of the atom where its mass is
concentrated.
- The electrons in the atom revolve around the
nucleus.
BOHR'S MODEL
+
z always equal to proton (𝑃 )
1. How many protons are there in atoms
𝑐
A (𝑛 + 𝑝) to get 𝑛 (A-P)
0
of oxygen-18?
2. How many neutrons are there in
(-) nagdadagdag (+) nagbibigay
atoms of oxygen-18?
3. What is the mass number of
oxygen-18
1. The bottom-left number is the atomic number.
Therefore, all atoms of oxygen-18 have eight protons.
2. The top-left number is the mass number.
mass number = number of protons + number of
neutrons.
18 = 8 + number of neutrons
= 10 ( kaya naging ten kasi sinubract ung mass
number sa number of protons)
All atoms of oxygen-18 contain 10 neutrons