II. CHEMICAL BONDS AND POLARITY I. NUCLEOSYNTHESIS AND THE ATOM The elements of the periodic table can be split into The natural elements primarily were formed from three basic parts: three primary processes: (1) The Big Bang 1. METALS – shiny, ductile, malleable, good Nucleosynthesis, (2) Stellar Nucleosynthesis, and (3) conductors of heat and electricity, &c. Big Bang Nucleosynthesis. Heavier natural elements 2. NON-METALS – complete opposite of metals were formed from the continuous process of nuclear when it comes to properties fusion. 3. METALLOIDS – has properties that lie between Big Bang Nucleosynthesis: Hydrogen, Helium, metallic and non-metallic Lithium and Beryllium. The proofs of the Big Bang The metalloid elements form a stair-like pattern in phenomenon are (1) Cosmic Microwave Background, the periodic table—B, Si, Ge, As, Sb, Te, and At. The (2) Redshift of visible galaxies, and (3) steady elements to the right of the metalloids plus Hydrogen are acceleration of the Universe’s expansion. the non-metals, While all elements to the left of the Stellar Nucleosynthesis (Low Mass): Hydrogen and metalloids except Hydrogen are the metals. Helium to Carbon, Nitrogen and Oxygen The type of element between atoms in a molecule Stellar Nucleosynthesis (Big Mass): Hydrogen and dictates what type of chemical bond occurs between Helium all the way to Iron them. Supernova Nucleosynthesis: All natural elements 1. IONIC BOND: occurs between a metal and non- heavier than Iron metal All matter in the Universe are made up of small 2. COVALENT BOND: occurs between non-metals indivisible particles called the atom. An atom has four only basic parts: (1) the center called nucleus where the (2) Furthermore, covalent bonds can be classified into positively charged proton and the (3) neutron, which two types: has no charge, can be found. Outside the vicinity of the 1. POLAR Covalent bond: has unequal distribution nucleus lie the negatively charged (4) electrons. of electrons in an atom. Examples are water, ammonia, Elements can be written by using the electron hydrochloric acid, hydrofluoric acid A 2. NON-POLAR Covalent bond: have equal or notation Z X , where X is the element symbol, Z is the atomic number and A is the mass number. The atomic symmetrical distribution of electrons, thus giving it no number represents the total number of protons in an dipoles charges. Examples are: oil, hydrocarbons like atom’s nucleus which also dictates the chemical Methane, Ethane, Propane, Butane properties of an element, while the mass number Covalent substances of different polarities are not represents an atom’s total sum of protons and neutrons. miscible or will not mix together. Polar substances are Electrons are found outside the nucleus in areas miscible with polar substances only, and non-polar called energy levels. Inside these energy levels are the substances are miscible to non-polar substances only. orbitals—sharp (s), principal (p), diffuse (d), and The forces that occur between individual molecules fundamental (f). in a substance are called Intermolecular Forces of Attraction (IMFA). These forces affect a substance’s boiling point, melting point, vapor pressure, viscosity, volatility, solubility, and surface tension. Strong IMFA increases the boiling point, melting point, viscosity and surface tension in a substance, while weak IMFA increases a substance’s vapor pressure, volatility, and solubility. There are five main types of IMFA. From strongest to weakest, these are: (1) Ion-Ion Interaction, (2) Ion- Dipole Interaction, (3) Dipole-Dipole Interaction, (4) Each electron in an atom has its own unique set of Hydrogen Bonding, and (5) London Dispersion Forces. quantum numbers. These are (1) the principal quantum III. BIOLOGICAL MACROMOLECULES number (n), azimuthal quantum number (l), magnetic 1. CARBOHYDRATES: The primary source of energy number (ml) and spin quantum number (ms). for our body. These include sugars and starches. PRINCIPAL Q.N. n = 1 to 7 Carbohydrates are found in table sugar, bread, rice, flour, AZIMUTHAL Q.N. ls = 0, lp = 1, ld =2, lf = 3 etc. MAGNETIC Q.N. s = 0 2. LIPIDS: Serves as the energy storage of our body. p = -1,0,+1 Lipids also make up the cell membrane. Lipids can be d = -2,-1,0,+1,+2 found in oils, waxes, fats and steroids. Common medicine, technology, engineering, cuisine, and many examples are cooking oil, butter, lard, and margarine. more. 3. PROTEINS: Also known as the building blocks of These useful consumer products are classified into: life, proteins are used in diverse functions in our bodies. 1. ACTIVE INGREDIENTS: are chemical The enzymes used in digestion, and the keratin in our compounds that have direct effects on our bodies once hair, skin, and nails are some examples of proteins. applied or consumed. These are found in medicine and 4. NUCLEIC ACIDS: Are the carriers of genetic various food products. information in our cells. These make up our DNA 2. FOOD ADDITIVES: are used for enhancing the (deoxyribonucleic acid) and RNA (ribonucleic acid). flavor of food. Examples of these are sugar, salt, Nucleic acids are A (Adenine), T (Thymine), C monosodium glutamate (MSG), etc. (Cytosine), G (Guanine) and U (Uracil). 3. COSMETICS: are used for beautification and IV. RATE OF REACTION hygiene. These chemical compounds can be found in The rate of chemical reactions between substances various beauty products, perfumes, and other personal can be affected by the following factors: items. 1. TEMPERATURE: Higher temperature increases 4. CLEANING AGENTS: are used for cleaning the rate of reaction, while lower temperatures decreases and disinfecting our surroundings. Examples of these are it. alcohols, bleach (sodium hypochlorite), baking soda 2. CONCENTRATION: Increasing the (sodium bicarbonate), muriatic acid (hydrochloric acid), concentration of the substances to be reacted also and many more. increases the rate of reaction due to the higher possibility of collisions between molecules. 3. SURFACE AREA: A higher surface area increases the rate of reaction. This is the reason why powdered or pulverized substances dissolves better in liquids than large chunks of materials. 4. PRESENCE OF A CATALYST: A catalyst is a substance that increases the rate of reaction by lowering that reaction’s activation energy. If a catalyst is present in a chemical reaction, that reaction will definitely happen faster. A catalyst will remain unchanged after a chemical reaction. V. ENERGY RESOURCES Energy is extremely important to our everyday lives. We use it in cooking, appliances, transportation, and many more functions. Humanity harness energy from various sources collectively known as Energy Resources. Energy resources can be split into two types: Renewable and Non-Renewable. 1. RENEWABLE: Can be replaced by natural processes and can be reused multiple times. Renewable resources do little to no damage to the environment. Examples of renewable resources are solar, geothermal, hydroelectric, biomass, and wind energy. 2. NON-RENEWABLE: Cannot be easily replaced by natural means. These also cannot be reused nor recycled, and they also cause harm to the environment because of their polluting methods of acquisition and by- products. Examples of non-renewable resources are coal, petroleum, nuclear energy, natural gas, and fossil fuels. Energy is harnessed through turbines or combustion engines. VI. CONSUMER PRODUCTS Chemistry is useful in our everyday lives. Discoveries made by various chemists through history are now utilized in various purposes from health and