(0999DJA161103230002) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

TEST # 02
(Academic Session : 2023 - 2024)
23-07-2023

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Unit Test # 02
ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. A B D A
Q. 5 6 7 8
SECTION-I (ii)
A. A,B A,B A,C A,D
Q. 9 10 11 12
SECTION-I (iii)
A. B D A,B C,D
Q. 13 14 15 16
SECTION-I (iv)
A. A B D B
Q. 1 2 3 4
SECTION-II
A. 4.50 1.33 to 1.34 30.00 2.00

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. D B A D
Q. 5 6 7 8
SECTION-I (ii)
A. A,B,C A,B,D A,B,C A,B
Q. 9 10 11 12
SECTION-I (iii)
A. A,B,C C A,C,D A,C
Q. 13 14 15 16
SECTION-I (iv)
A. C D A C
Q. 1 2 3 4
SECTION-II
A. 125.00 33.33 11.75 42.00

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. B D A C
Q. 5 6 7 8
SECTION-I (ii)
A. A,B,D B,C B,D A,C,D
Q. 9 10 11 12
SECTION-I (iii)
A. A,C B A,B,D A,B
Q. 13 14 15 16
SECTION-I (iv)
A. A C A C
Q. 1 2 3 4
SECTION-II
A. 1.00 3.00 17.00 9.00

0999DJA161103230002 HS-1/11
 Target : JEE (Main + Advanced) 2024/23-07-2023
HINT – SHEET
PART-1 : PHYSICS PART-1 : PHYSICS
SECTION-I (i) SECTION-I (ii)

1. Ans ( A ) 5. Ans ( A,B )

Since electric field due to an infinite plate is
uniform, thus both the balls will reach the ground
at same time and will have same velocity.
PART-1 : PHYSICS
kλ 1 1 −2√2kλ ^ SECTION-I (iii)
E1 = [ + ]( −j^) = j
(
a
) √ 2 √ 2 a 9. Ans ( B )
2
q 1 1 1
2kλ 1 1 ^ 4√2kλ ^ V = Vq + V−qin + Vqin = [ − + ]
E2 = [ + ]( ) i = i 4π∈0 r R 1 R 2
(
a
) √ 2 √ 2 a
2
10. Ans ( D )
3kλ 1 ^ 6√2kλ ^
1 Charge distribution on the inner surface : non uniform.
E3 = [ + ] (j ) = j
(
a
) √2 √2 a
2 11. Ans ( A,B )
4kλ 1 1 −8√2kλ ^
E4 = [ + ]( −i^) = i
(
a
) √ 2 √ 2 a
2

→ = −4√2 kλi^ + 4√2 kλj^

E net
a a
mg – qE = ma
2. Ans ( B ) qE
a=g–
Electric field inside every position of conductor m
is zero. (A) a = 2qE − g ⇒ A
′
m
q
3. Ans ( D ) same ⇒ a' = a
m
Vavg = slope of secent qE q ′E
(B) g − >g−
= tan45° m m′
qE q ′E
= 1 m/sec = <
m m′
4. Ans ( A ) 12. Ans ( C,D )
d 1 qE 2
= (g − )t
4 2 m
qE 2qE
⇒g− = −g
m m
3qE
= 2g
m
qE 2g
=
Vb sinθ = 10 m 3
20sinθ = 10 q ′E qE 2g
g − ′ = 2 (g − ) =
1 m m 3
sin θ = ′ ′
2 qE q q q
θ = 30° ⇒ = ⇒ =
m 3 m ′ 2m
HS-2/11 0999DJA161103230002
 Leader Test Series/Joint Package Course/23-07-2023
PART-1 : PHYSICS
SECTION-I (iv)

13. Ans ( A )
→v = 6i^ + (20 − 4t) ^j
time when vy = 0
20 – 4t = 0
t=5 2Kθ
T = 2 × t = 10 sec at x=0 : Enet = , so only option is (P)
ℓ2
20 − 4t
tan 53 = 15. Ans ( D )
6
4 20 − 4t
= Distribution of charge on different surfaces of
3 6
t = 3 sec
the plates have been shown.
R = vx × T
= 6 × 10 = 60 m
v2y 20 × 20 400 200
H= = = = = 50m
2×a 2×4 8 4
14. Ans ( B )
For (P) :
Take a point P on left most plate. The electric
field at P
Q−q q q q q (q − 2Q)
E= − + − + − =0
2A ε0 2A ε0 2A ε0 2A ε0 2A ε0 2A ε0
ρr (inside a conductor, E = 0)
For (Q) : Inside point E= , outside point
3ε0

E=
Kθ So, Q – q – q + 2Q = 0
r2 3Q
Or 2q = 3Q ⇒ q =
2
The charge appearing on outer surface of right
most plate
Kθ 3Q Q
For (R) : Einside = 0, Eoutside = = q − 2Q = − 2Q = −
r2 2 2
The charge on outer surface of left most plate
3Q Q
=Q−q =Q− =−
2 2
Charge appearing on middle plate is – q and +q
Kθ ℓ
For (S) : Enet = 2E cos α = 2 × ; 3Q 3Q
x + ℓ2
2
√ x 2 + ℓ2 i.e., − and +
2 2
2Kθℓ
Enet =
3/2
(x2 + ℓ2 )

0999DJA161103230002 HS-3/11
 Target : JEE (Main + Advanced) 2024/23-07-2023
16. Ans ( B ) 2. Ans ( 1.33 to 1.34 )
2 × 25 4
(P) Time of flight = ×
10 5
1
Range = Ux T + ax T 2
2
= (25 × ) (4) + 1 × (5)(4)2
3
5 2
u2 sin2 θ
(Q) Hmax =
2g
2 2
(25) (sin 53)
= = 20
2 × 10
At 3 th of Hmax speed of particle is given by
4
Consider a point on circumference at angular
V2 = 400 – 2 × 10 × ( 3 × 20) = 100
4
position θ .
V = 10 m/s
For surface to be equipotential net E.F. at A
2V 2 × 1010
Time difference = = = 2 sec should be perpendicular to A.
g 10
(R) →u. →v = 0 kP sin θ
= E sin θ
R3
t = 5 sec > Time of flight kP
E=
R3
So not possible 3. Ans ( 30.00 )
VA = VC
PART-1 : PHYSICS
so C = a + b
SECTION-II
1. Ans ( 4.50 ) 4. Ans ( 2.00 )

potential difference due to inner 10C charge

1 1
= K 10 ( − ) = 9 × 1010 (5)
.1 .2 Electric field due to element dx on origin
= 45 × 1010 = 4.5 × 1011 V
kλdx (−i^)
→= kλ0 x2 ^
dE = dx (−i )
potential difference due to outer charge = 0 x2 x2
1
{ k= }
4π∈0

dE = kλ0 dx
L

Electric field at origin E→ = ∫

^
kλ0 dx (−i )
0

E = kλ0 L
∴ p.d. = 4.5 × 1011 V
so α = 1, β = 1 ⇒ α + β = 2
HS-4/11 0999DJA161103230002
 Leader Test Series/Joint Package Course/23-07-2023
PART-2 : CHEMISTRY 6. Ans ( A,B,D )
d[H2 ] 1 d[NH3 ]
SECTION-I (i) =−1 =
3 dt 2 dt
1. Ans ( D )
−d[H2 ] 3 0.001 Kmole
In Mn+2, the number of unpaired electrons is 5. ∴ =
2
×
dt 17 hr
spin only magnetic moment = √ n (n + 2) B. M. 3 0.001
= × × 2 Kg/hr
√ 5 (5 + 2) = √35 B. M. 2 17

2. Ans ( B ) = 1.76 × 10 – 4 Kg/hr.

Electronic configuration of
Mn2+ : 1s22s22p63s23p63d5 7. Ans ( A,B,C )
max. number of electrons having (ml = – 1) is 5 V4+ ⇒ 4s° 3d1
(2p6→2e – , 3p6→2e – , 3d5→1e – )
ℓ=2
3. Ans ( A )
CH3CHO(g) → CH4(g) + CO(g) orbital angular momentum
t=0 80 0 0 h
= √ℓ(ℓ + 1)
t = 20min 80 – x x x 2π
h
(80 – x) + x + x = 120 ⇒ x = 40 = √2(n)
2π
t1/2 = 20min h
= √6
0.693 2π
K= = 3.465 × 10 – 2 min – 1
20 8. Ans ( A,B )
4. Ans ( D ) Fact
Li+2 → single electron : energy : 3s = 3p = 3d
PART-2 : CHEMISTRY
PART-2 : CHEMISTRY SECTION-I (iii)
SECTION-I (ii)
11. Ans ( A,C,D )
5. Ans ( A,B,C ) [A] Incorrect
(A) Enthalpy of reaction always depends on
EA –
physical state of reactants. −−
→ Be endothermic
(B) It is not necessory that it always increases with
increase in temperature. fully-filled orbitals
(C) ΔH is different between [Ea]f – [Ea]b not ratio. [B] Correct
(D) Catalyst decreases activation energy but do not
change ΔH. Since → He – is endothermic.

that's why He – → He is exothermic

[C] Incorrect
Li → Li2 − 2 exothermic
1s2 2s1 1s 2s (fully−filled)

[D] Incorrect
P → P – is slightly exothermic
Δ H = [Ea]f – [Ea]b
0999DJA161103230002 HS-5/11
 Target : JEE (Main + Advanced) 2024/23-07-2023
PART-2 : CHEMISTRY 14. Ans ( D )
SECTION-I (iv) [P] Ionisation energy → [3] HF > Zr [I.E.]
13. Ans ( C ) [Q] Radii → [1] Ne > Na+
(P) Ca [R] Electronegativity →
Belongs to 2nd group
[4] [He]2s22p4 > [He]2s2 2p3
Has lower size than Cs (across the period size
⇓ ⇓
decreases)
O [E.N.] > N[E.N.]
Have higher IE than Cs (as zeff increases
across the period) [S] Electron gain enthalpy → [2] S > O
(P) → 1, 3, 4 ↓
(Q) Ba [More space]
Belong to 2nd group PART-2 : CHEMISTRY
Has lower size than Cs (across the period size SECTION-II
decreases) have higher IE than Cs(as zeff 1. Ans ( 125.00 )
increases accross the period) 3 1
Δ H = Δ H1 × + Δ H2 ×
4 4
(Q) → 1, 3, 4 3 1
= 100 × + 200 × = 125 cal
(R) K 4 4

Belong to 1st group. 2. Ans ( 33.33 )

t1/2 V∞
Has lower size than cs (Top to bottom size t= . log
log 2 V∞ − Vt
increases ) 10 V∞
20 = . log
log 2 V ∞ − 25
Have higher IE than cs (top to bottom IE
decreases. ∴ V ∞ = 33.33 ml

(R) → 2, 3, 4 3. Ans ( 11.75 )

(S) Na Eab – Eaf = 4RT ; Af = 2 × Ab
Belong to 1st group −Eaf

K f = Af e RT ..........(1)
Has lower size than Cs (Top to bottom size −Eab
K b = Ab e RT ........(2)
increases)
Kf Af
Have higher IE than cs (Top to bottom IE Keq = = e
Kb Ab
decreases Keq = 2e4
(S) → 2, 3, 4 Δ ºG = – RTlnKeq= – 2500 × [4.7]

=11.75 kJ/mol
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4. Ans ( 42.00 ) 4. Ans ( C )
Z = 29 ⇒ copper 5log5 x.log5 x + xlog5 x = 1250

Cu29 = 1s2 2s2 2p6 3s2 3p6 3d10 4s1 ⇒ (5log5 x )

log5 x
+ xlog5 x = 1250
non directional orbitals = 1s2, 2s2, 3s2, 4s1
⇒ xlog5 x + xlog5 x = 1250 ⇒ 2.xlog5 x = 1250
Total 7e –
⇒ xlog5 x = 625 ⇒ log5 x(log5 x) = log5 625
So X = 7
⇒ (log5 x) (log5 x) = 4 ⇒ (log5 x)2 = 4
|m ℓ | = 1, m ℓ = ±1
1
⇒ log5x = 2 or log5x = – 2 ⇒ x = 25 or x =
25
Y=6 1
So, log25 ( ) = −1
25
X.Y = 7 × 6 = 42 PART-3 : MATHEMATICS
PART-3 : MATHEMATICS SECTION-I (ii)
SECTION-I (i) 5. Ans ( A,B,D )
1. Ans ( B ) e2x − 1 − 2x 2e2x − 2
ℓ1 = lim = lim =2
(4x − 1)3 ⎛ (
x
p
) ⎞⎛
x2 ⎞ x→0 x2 x→0 2x
3
lim ( )⎜
⎜ x
⎟⎜
⎟⎜
⎟
⎟ × 3p
x→0 x3 sin log(1 + x2
⎝ p ⎠⎝
3
) ⎠
sin 3x − 3x
ℓ2 = lim
3 x→0 x3
= 3p (loge4)
3 (cos 3x − 1) −3 sin 3x 9
2. Ans ( D ) = x→0
lim = =−
3x2 2x 2

1 + 2 + 3+. . . +n tan x (cos x − 1)

Tn = 1
1 + 23 + 33 +. . . +n3
3 ℓ3 = lim =−
x→0 x3 2
n(n + 1)
6. Ans ( B,C )
2 2 1 1
= = = 2[ −
sin−1 (sin x)
]
2 n(n + 1) n n+1
n(n + 1) A = lim
(
2
) x→0 cos−1 (cos x)

1 1 sin−1 (sin x) x
⇒ Sn = 2 [ − ] ∴ S∞ = 2 lim− = lim− = −1
1 n+1 x→0 cos−1 (cos x) x→0 −x

sin−1 (sin x) x
3. Ans ( A ) lim+ = lim+ =1
x→0 cos−1 (cos x) x→0 x
10n + 3.4n+2 + 5

P ut n = 1 = 101 + 3.41+2 + 5 ⇒ A does not exist

= 10 + 3.64 + 5 = 207
[|x|]
Which is divisible by 9 B = lim = 0 as [|x|] = 0 when x → 0.
x→0 x

0999DJA161103230002 HS-7/11
 Target : JEE (Main + Advanced) 2024/23-07-2023
7. Ans ( B,D ) 10. Ans ( B )
⎧ 0 0<x⩽ π
2
a (1 − rn )
⎪
⎪
⎪ Sn =
⎪
⎪
⎪
⎪
1−r
⎪
⎪
⎪
⎪
− cos x π
2
<x⩽π 4 1
cos x [cos x] = ⎨ for r = & a = 5; for r = & a = 20
3π
5 5
⎪
⎪ − cos x π<x< 2 n n
20 (1 − ( 15 )
⎪
⎪
⎪
⎪
⎪
⎪
5 (1 − ( 45 ) ) )
⎪
⎪ 3π > 24 > 24
⎪
⎩
0 2
⩽ x < 2π 1− 4
1− 1
5 5
n n
4 1 1 24
( ) < ⇒1−( ) >
5 25 5 25
2 log 5
n>
log 5 − log 4
n
1 1
⇒( ) < ⇒ 5n > 25
5 25
2 (1 − 0.3)
8. Ans ( A,C,D ) n> ⇒ n>2⇒ n≥3
1 − 0.3 − 2 × 0.3
T40 = 119 t50 = 101 n > 14
common term series = 5, 11, 17, ..., T'n
smallest value n = 3
T'n ≤ 101 ⇒ 5 + (n – 1) 6 ≤ 101 ⇒ n ≤ 17 11. Ans ( A,B,D )
⇒ n = 17
A = log2[log4(16log102 + 16log105)] – 1
= log2[log416] – 1 ⇒ log22 – 1 = 0
⇒ T'17 = 101 
 
⎛ ⎞
 


sum of all common terms = 17 (5 + 101) = 901


B = log 5⎷5⎷5 5 5 5 5⎟
⎜
⎜ ⎟
√ √ √ √

2 ⎝ ⎠

PART-3 : MATHEMATICS 3 7
√ 5 √5 = 5 4 , √ 5 √ 5 √5 = 5 8
SECTION-I (iii) 

15  31
9. Ans ( A,C ) √
5 √ 5 √ 5 √5 = 5 16 , ⎷
5√5√5√5√5 = 5 32
a 63
ar = 4 = 25 √
5√5...6times = 5 64 ,
1−r
63 127

1 4 1 5 5...7times = 5.5 64 = 5 64
√ √

r= , i.a = 20, a = 5.
5 5 (C) log410 + 1 = x + 1 = log440
log220 + 1 = y + 1 = log240
log58 + 1 = z + 1 = log540
1 1 1
⇒ + +
x+1 y+1 z+1
= log404 + log402 + log405 = 1
(D) (log210)(log280) – (log25)(log2160)
(1 + log25)(4 + log25) – (log25)(5 + log25)
=4
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12. Ans ( A,B ) PART-3 : MATHEMATICS
4 8
A = log2 log4 [ ( log 1610 + log 2510 )] − 1 SECTION-I (iv)
8 8
A = log2 log4 log 410 + log 2510
[ ( )] −1 13. Ans ( A )
A = log2 [log4 (8 × 2)] − 1 (P) a + b + c = 0 and a + c = 2b ⇒ b = 0
A = log2 2 log44 − 1
[ ]

A=0 In 17 terms of A.P., b is 9th (middle) term

B = (2q – P) ⇒ 8 (+)ve terms & 8(–)ve terms of equal

⎛  ⎞
 P
log ⎜
⎜
5 
5
√√√√5⎟
5 5 5 5

⎟
= log5 magnitude
⎷⎷ q
⎝ ⎠

(
127
) p ⇒ sum = 0
= log 5 64
= log5
q 1
2 ( a+2 )(
1
)
p 127 1 4a+5
⇒ = (Q) =
q 64 a2 1
+ 1
a+2 4a+5
⇒ p = 127, q = 64 7
a=
B = 2q – p ⇒ 2a2 – 5a – 7 = 0 {
2
a = −1
= 2 × 64 – 127
(R) S1 = α + β + γ + 2 = α ⇒ γ + 2 = –β
B=1
1 1 1
→C= + + ; A.P. ⇒ 2β = α + γ + 2 ⇒ 3β = α
x+1 y+1 z + 1
x = log10 20 8
4 , y = log2 log 5 = z S2 = αβ + β(γ + 2) + α(γ + 2) = β
1 1 1
C= + +
log10
4 +1 log20
2 +1 log85 +1 ⇒ 3β2 – β2 + 3β(–β) = β ⇒ β = –1,
1 1 1
C= + +
log10
4 + log44 log20
2 + log22 log85 + log55 0(rejected)
1 1 1
C= + +
log40
4 log40
2 log40
5 ⇒ α = –3 ⇒ γ = –1
4 2 5
log + log + log
C=
log40 ⇒ roots are –3,–1,1 (in order)
c=1 ∞
1 1
(S) ∑ (αr + β r ) = +
⇒D= ( log10 80 5 160
2 ) (log2 ) – (log2 ) (log2 ) r=0
1−α 1−β
D= ( 1+ log52 ) ( 4+ log52 ) – log52 ( 5+ log52 ) 2 − (α + β )
= =7
1 + αβ − (α + β)
D = (1 + t) (4 + t) – t (5 + t) {Let t = log52
D = t2 + 5t + 4 – 5t – t2
D=4
option - (A) BC2D = 1 × 12 × 4 = 4
option - (B) 2B + D = 2 × 1 + 4 = 6
option - (C) B + C + 4d = 1 + 1 + 4 × 4 = 18
option - (D) A2 + D + B = (O)2 + 4 + 1 = 5
option (A,B)
0999DJA161103230002 HS-9/11
 Target : JEE (Main + Advanced) 2024/23-07-2023
14. Ans ( C ) 16. Ans ( C )
2 − 102
(P) d = = −5
19 + 1

A17 = 102 + 17( – 5) = 17 (P)

A10 = 102 + 10( – 5) = 52

(Q) Pn = 1 ⋅ 31 ⋅ 5 + 3 ⋅ 51 ⋅ 7 +. . . + 1
(2n − 1) (2n + 1) (2n + 3)

1 1 1
Pn = ( − )
4 1⋅3 (2n + 1) (2n + 3)
(Q)
1
P∞ =
12
n i 2 n
(R) ∑ (∑ 1) = ∑ i2 = 385
i=1 j=1 i=1
n (n + 1) (2n + 1)
= 385 1/x
6 (R) x→0
lim ( 1 + x ln(1 + b2 )) = 2b sin2 θ, b > 0

⇒ n = 10 ⇒ 1 + b2 = 2b sin2 θ ⇒ b2 − 2b sin θ + 1 = 0

1/6 D ⩾ 0 ⇒ sin2 θ = 1 ⇒ sin θ = ±1

(S) (G1 G2 G3 G4 G5 G6 ) = √ 2×5
π 3π 5π
6 ⇒ θ=± , ,
2 2 2
∏ Gi = 103
i=1 ∴ Sum of all possible value of θ = 4 π
15. Ans ( A )
1 ∴k=4
(P) x = log π e + >2
logπ e
3 (S) for a limit of the function to exist α + β = 1
(Q) x = 3log10 a + < −6
log10 a
4 since function gain form of 1 ∞ we get α = – 3,
y = 4log10 b + >8⇒x<y
log10 b
β=4
(R) x = y
∴ (4β + 3α) = 7 ⇒ Q
(S) x = 2 − √3 + √3 − √2 + √2 − 1 = 1

y=3

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 Leader Test Series/Joint Package Course/23-07-2023
PART-3 : MATHEMATICS 3. Ans ( 17.00 )
n+1
SECTION-II tan (px) is discontinuous at points x = ( ) ,
2
1. Ans ( 1.00 ) ie. −7 −5 −3 −1 1 3 5 7
, , , , , , , , total 8 points
(ax + b) − √4 + sin x 2 2 2 2 2 2 2 2
27
Lim =
x→0 tan x 4 signum function in discontinuous at points where
As x → 0, Dr → 0 tan π x = 0

So, Nr → 0 for existence of limit. So ⇒ – 4, – 3, – 2, – 1, 0, ..........4

b−2=0 ⇒ b=2
total 9 points

(ax + 2) − √ 4 + sin x 27 0
4. Ans ( 9.00 )
Now, Lim = ( )
x→0 x 4 0 Let log2x = t
2
(ax + 2) − (4 + sin x) 27
Lim = 3 √t − t − 3 + 1 = 0
x→0 x ⋅ (ax + 2 + 4 + sin x)
√ 4
3 √t = t + 2
a2 x2 + 4ax − sin x
Lim ( ) = 27
x→0 x 9t = t2 + 4 + 4t
28
⇒ 4a − 1 = 27 ⇒ a = =7 t2 – 5t + 4 = 0
4

Hence, (a − 3b) = 7 − 3(2) = 1 Ans.

t = 1,4
log2x = 1,4
2. Ans ( 3.00 )
x = 2,16
For continuity at x = 1

8 = b2 – 3b + 10 ⇒ b2 – 3b + 2 = 0
Sum of all b's = 3

0999DJA161103230002 HS-11/11