2025 Jee Main 3_gen 2_paper

JEE Main – 3 (GEN 2) | JEE - 2025
Date: 16/10/2023 Maximum Marks: 300
Timing: 4:00 PM to 7:00 PM Duration : 3.0 Hours
General Instructions
1. The test is of 3 hours duration and the maximum marks is 300.
2. The question paper consists of 3 Parts (Part I: Physics, Part II: Chemistry, Part III: Mathematics). Each Part
has two sections (Section 1 & Section 2).
3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.
4. Section 2 contains 10 Numerical Value Type Questions Out of which ONLY 5 (any) questions have to be
attempted. You will NOT be allowed to attempt the sixth question. If you wish to attempt any other
question apart from the five already attempted, then you will have to delete any one response from the
five previously answered and then proceed to answer the new one.
The answer to each question should be rounded off to the nearest integer.
5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc. inside the examination room/hall.
6. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
Marking Scheme
1. Section – 1: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.
2. Section – 2: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.
Name of the Candidate (In CAPITALS) :
Roll Number :
OMR Bar Code Number :
Candidate's Signature : Invigilator's Signature
Syllabus:
Physics: Kinematics of a Particle, Motion in Two Dimensions
Chemistry: Atomic Structure, Periodic Classification, Chemical Bonding - I
Mathematics: Trigonometry, Sequence and Series
Vidyamandir Classes: Innovating For Your Success
PART I: PHYSICS MARKS: 100

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. A boat is to go straight across a stream that is flowing at 5.0 km/h to east. The
boatman knows that his speed with respect to water is 10 km/h. The angle at
which he must head the boat, and his speed relative to the shore will be:
(A) 10 km/h at 0° (B) 5 3 km/h 60°
(C) 10 3 km/h at 30° (D) 5 3 km/h at 30°
2. A bird flies for 4 sec from t  0 with a velocity of | t  2 | m/s in a straight line, where t  time in
seconds. It covers a distance of:
(A) 2m (B) 4m (C) 6m (D) 8m
3. A particle P is moving in a circle of radius ‘a’ with a uniform speed v. C is the centre of the circle and AB
is a diameter. When passing through B the angular velcoity of P about A and C are in the ratio:
(A) 1:1 (B) 1:2 (C) 2:1 (D) 1:3
SPACE FOR ROUGH WORK
Code A | Page 2 JEE Main - 3 GEN-2 | JEE 2025

4. You calculate that to throw an object vertically to a height h it needs to be launched with an initial upward
velocity v0 , assuming no air resistance. The dashed lines in figure show the motion according to this
calculation. Which of the velocity-time graphs shows the motion of an object tossed with initial upward v1
that will also rise to height h, but this time with air resistance?
(A) (B) (C) (D)
5. Graph of (1/ v) vs x for a particle under rectilinear motion is as shown,

where v is velocity and x is position. The time taken by particle to move
from x  4 m to x  12 m is:
16
(A) sec (B) 10 sec
3
(C) 8 sec (D) 12 sec
6. A stone is dropped from the top of a tall cliff and n seconds later another stone is thrown vertically
downwards with a velocity u. Then the second stone overtake the first, below the top of the cliff at a
distance given by:
2 2
g  n( gn / 2  u )  g  n( gn  u / 2) 
(A) (B)
2  ( gn  u )  2  ( gn  u ) 
2 2
 ( gn  u )   n ( gn  2u ) 
(C) g  (D) 2g  
 ( gn  u / 2)   2 gn  u 

7. The acceleration due to of gravity can be measured by projecting a body upward and measuring the time
that it takes to pass two given lines in both directions (upward motion and downward motion). If the time
the body takes to pass a horizontal line A in both direction (from A1 to A2 ) is TA , and the time to go by a
second line B in both directions is (from B1 to B2 ) TB , then assuming that the acceleration due to gravity
to be constant, its value is:
8h 8h
(A) (B)
TA2  TB2 TA2  TB2
8h 8hTATB
(C) (D)
TA2TB2 TA2TB2
8. A particle is projected from a point O with a velocity u in a direction making an angle  upward with the
horizontal. At P it is moving at right angles to its initial direction. Its velocity at P is:
(A) u tan  (B) u cot  (C) ucosec  (D) u sec 
9. A man is riding on a horse. He is trying to jump the gap between two

symmetrical ramps of snow separated by a distance W as shown in
the figure. He launches off the first ramp with a speed VL . The man
and the horse have a total mass m and their size is small as compared
to W. The value of initial launch speed VL which will put the horse
exactly at the peak of the second ramp is:
Wg Wg
(A) (B)
sin  cos  sin( / 2)  cos( / 2)
Wg 2Wg
(C) (D)
2sin  cos  sin  cos 

10. Jai is standing on the top of a building of height 25 m he wants to throw his gun to Veeru who stands on
top of another building of height 20 m at distance 15 m from first building. For which horizontal speed of
projection, it is possible:
(A) 5 ms 1 (B) 10 ms 1 (C) 15 ms 1 (D) 20 ms 1
11. An astronaut on a strange planet observes that he can jump a maximum horizontal distance of 2m, if his
initial speed is 6 m/s. What is the acceleration due to gravity of the planet?
(A) 3 m/s 2 (B) 9 m/s 2 (C) 18 m/s 2 (D) 36 m/s 2
12. Two projectiles are projected with velocity v A , vB at angles  A (from

horizontal) and  B (from vertical) as shown in the figure below, such that
v A  vB but having same horizontal component of velocity. Which of the
following cannot be correct?
(A) TA  TB (B) H A  HB
(C) RA  RB (D) RB  RA
13. The equation of the path of the projectile is y  0.5 x  0.04 x 2 . The initial speed of the projectile is:
(A) 10 m/s (B) 15 m/s (C) 12.5 m/s (D) 25 m/s
14. A particle is projected from a horizontal plane ( x-z plane such that its velocity vector at time is given by

V  a iˆ  (b  ct ) ˆj . Its range on the horizontal plane is given by:
2bc ba 3ba 2ab
(A) (B) (C) (D)
c c c c

15. Trajectory of particle in a projectile motion is given as y  x  x 2 / 80 . Here, x and y are in metres and
considered along horizontal and vertical direction respectively ( g  10 m/s 2 ) . For this projectile motion:
(A) Angle of projection is 45°
(B) Angle of velocity with horizontal after 4s is tan 1 (1/ 2)
(C) Maximum height is 80 m
(D) Horizontal range is 20 m
16. A shot is fired at angle  to the horizontal such that it strikes the hill while moving horizontally. Find
initial angle of projection  .
2 3 3 2
(A) tan   (B) tan   (C) tan   (D) tan  
5 8 2 3
17. A ball thrown down the incline strikes at a point on the incline 25 m
below the horizontal as shown in the figure. If the ball rises to a
maximum height of 20 m above the point of projection, the angle of
projection  (with horizontal x-axis) is:
4 3
(A) tan 1 (B) tan 1
3 4
3 2
(C) tan 1 (D) tan 1
2 3

18. A body is thrown with velocity 20 m/s at an angle of 60° with the horizontal. Find the time gap between
the two positions of body where velocity of body makes an angle of 30° with horizontal. [ g  10 m/s 2 ]
(A) 1.15 sec. (B) 0.95 sec. (C) 1 sec. (D) 1.5 sec.
19. At the same instant two boys throw balls A and B from the
positions shown with a speed v0 and kv0 respectively, where k is
a constant. For what value of k, balls with collide? Relevant data
are available in figure.
cos 2 sin 2
(A) (B)
cos 1 cos 1
tan 2 sin 2
(C) (D)
tan 1 sin 1
20. Two swimmers start swimming perpendicular to river flow with different constant speeds at the same time.
After reaching the opposite bank they have to walk back to reach the point exactly opposite to the starting
point at the same time. Assume constant walking speed for both the swimmers.
(A) Swimmer with greater speed in water will have to walk slowly
(B) Swimmer with smaller speed in water will have to walk back slowly
(C) Both the swimmers will have to walk back with the same speed
(D) It is not possible for both swimmer to reach the starting point simultaneously

SECTION-2
Section 2 contains 10 Numerical Value Type Questions Out of which ONLY 5 (any) questions have to be
attempted. The answer to each question should be rounded off to the nearest integer.
1. To man running at a speed of 5 m/sec, the rain drops appear to be falling at an angle of 45° from the
vertical. If the rain drops are actually falling vertically downwards, then velocity of rain in m/sec is:
2. Raindrops are falling vertically with a velocity of 10 m/s. To a cyclist moving on a straight road the
raindrops appear to be coming with a velocity of 20 m/s. The velocity of cyclist is 2 x 3 , then x is ___.
3. A ball is thrown vertically upwards from the ground. It crosses a point at the height of 25 m twice at an
interval of 4 sec. The ball was thrown with the velocity of:
4. The drawing shows velocity (v) versus time (t) graphs for two cyclists moving along the same straight
segment of a highway from the same point. The second cyclist starts moving at t  3 min. What time do
the two cyclists meet?

5. Particle projected from tower of height 10 m as shown in figure. Find the time (in sec) after which particle
will hit the ground.
6. A particle is thrown horizotnally from the top of a tall tower with a speed of 10 m/s. If radius of curvature
of path followed is 4 2k m at t = 1 sec, then find the value of k.
7. A car, moving with a speed of 50 km h 1 , can be stopped by brakes in minimum 6 m distance. If the
same car is moving at a speed of 100 km h 1 , the minimum stopping distance is:
8. A particle at a height ‘h’ from the ground is projected with an angle 30° from the horizontal, it strikes the
ground making angles 45° with horizontal. It is again projected from the same point with the same speed
but with an angle of 60° with horizontal. The angle it makes with horizontal when it strikes the ground is
  tan 1 ( k ) , thenk is:

9. In the griven figure, the angle of inclination of the inclined plane is 30°. A particle is projected with
horizontal velocity v0 from height H. Find the horizontal velocity v0 (in m/s) so that the particle hits the
inclined plane perpendicularly. Given, H  4 m , g  10m / s 2
10. At t  0 a projectile is fired from a point O (taken as origin) on the ground with a speed of 50 m/s at an
angle of 53° with the horizontal. It just passes two points A and B each at heigth 75 m above horizontal as
shown.
The horizontal separation between the points A and B is:

PART II: CHEMISTRY MARKS: 100
SECTION-1
1. If ionisation energy of a hydrogen atom is 13.6eV, IE of Be3 will be:

(A) 13.6eV (B) 10.1eV (C) 217.6eV (D) 122.4eV
2. Match the Column-I (Elements) with Column-II (Configuration of elements).

Column-I Column-II
(P) The third alkali metal (I) 1s2 2s2 2p6 3s2 3p5
(Q) The second transition element (II) 1s2 2s 2 2p6 3s2 3p6 3d10 4s2 4p6
(R) The fourth noble gas element (III) 1s2 2s2 2p6 3s 2 3p6 3d2 4s 2
(S) The second halogen element (IV) 1s2 2s2 2p6 3s2 3p6 4s1
Codes:
(A) (P)-(II); (Q)-(I); (R)-(III); (S)-(IV) (B) (P)-(I); (Q)-(IV); (R)-(III); (S)-(II)
(C) (P)-(IV); (Q)-(III); (R)-(II); (S)-(I) (D) (P)-(I); (Q)-(II); (R)-(III); (S)-(IV)
3. Which of the following graphs correspond to wave function plot of an atomic orbital for which
n  2, l  0, m  0 ?
(A) (B) (C) (D)

4. Correct order of electronegativity of N, P, C and Si is:
(A) N < P < C < Si (B) N > C > Si > P (C) N = P > C = Si (D) N > C > P > Si
5. In which of the following species p - d bond is present?

(A) SiH4 (B) CS2 (C) CO2 (D) SO2Cl2
6. The orbitals which are involved in hybridisation of central atom in CHCl3 are:
(A) 2s-orbital only (B) 2p-orbitals only
(C) 3d and 3d orbitals only (D) 2s and 2p-orbitals only
z2 x 2  y2
10 2 6
7. Configuration of Br  is [Ar]3d 4s 4p . The electronic configuration of Br 2 would be identical with
the element:
(A) Se (B) As (C) Ga (D) Ge
8. Which pair of molecules contains only polar species?

(A) CO2 and H2O (B) BF3 and PCl3
(C) SO2 and SCl2 (D) CS2 and SO3
9. An electron is moving with a kinetic energy of 4.55 1025 J. What will be de-Broglie wavelength for this
electron? [Given : h  6.626 1034 J - sec, me  9.11031 kg]
(A) 5.28 107 m (B) 7.28 107 m (C) 2 1010 m (D) 3 105 m
10. The I.P1, I.P2 , I.P3 , I.P4 and I.P5 of an element are 7.1, 14.3, 34.5, 46.8, 162.2 eV respectively. The
element is likely to be: [Given : I.P is ionisation potential]
(A) Na (B) Si (C) F (D) Ca

11. Select the incorrect statement about CH4 :
(A) All the hybrid orbitals of carbon are equivalent
(B) All the hybrid orbitals of carbon have 25% s-character
(C) All the hybrid orbitals of carbon are projected at the four vertices of a regular tetrahedral
(D) All the H – C – H bond angles are less than 109°28’
12. The wavelength (in nm) of the radiations emitted, when in a hydrogen atom electron falls from infinity to
ground state is: (R H  1.097  107 m 1 )
(A) 9.1108 (B) 192 (C) 406 (D) 91
13. Select the process in which least magnitude of enthalpy change is associated:
(A)  F (g)
F(g)  (B)  O  (g)
O(g) 
(C)  Cl (g)
Cl(g)  (D)  S (g)
S(g) 
3
14. In a molecule ABx E y ( sp d - hybridisation of A) have “T” shape geometry. What will be the geometry of
molecule if A form ABy E x type molecule? [E : Lone pairs, A – B : Bond pair]

(A) “T” shape (B) See-saw
(C) Trigonal bipyramidal (D) Linear

15. Order of lattice energies of given metal oxides is:
MgO Na 2O Al2 O3
(A) MgO  Na 2O  Al2O3 (B) Na 2O  MgO  Al2O3
(C) Al2O3  Na 2O  MgO (D) Al2O3  MgO  Na 2O
16. In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have
the same energy in the absence of magnetic and electric fields?
(1) n  1,   0, m  0 (2) n  2,   0, m  0 (3) n  2,   1, m  1
(4) n  3,   2, m  0 (5) n  3,   2, m  1
(A) (1) and (2) (B) (2) and (3) (C) (3) and (4) (D) (4) and (5)
3 2 
17. The ionic radii (in Å) of N , O and F are respectively:
(A) 1.71, 1.40 and 1.36 (B) 1.71, 1.36 and 1.40
(C) 1.36, 1.40 and 1.71 (D) 1.36, 1.71 and 1.40
18. The bond order of NO bond in nitrate ion (NO3 ) is:

(A) 1.5 (B) 1.25 (C) 1.33 (D) 1.75
19. The compound which contains ionic, coordinate and covalent bonds is :
(A) CH 4 (B) B2 H 6 (C) NH4 Cl (D) KCl
20. The number of waves made by an electron in one complete revolution in 5th Bohr orbit is:
(A) 6 (B) 3 (C) 5 (D) 4

SECTION-2
1. Total number of bonds in BrF5 which are at an angle of 90° from each other is _______.

2. The value of orbital angular momentum of electron in a 2p orbital multiplied by 8 2   is ______.
h
[Given h is Planck’s constant]
3. Ratio of  - bonds and  - bonds in a benzene molecule is _______.
4. The number of pairs in which size of the first element or ion is higher as compared to the second out of
following pairs is _______.
     
(O, S), (He, Ne), (Kr, Ne), (Na, Na ), (Cl, Cl ), (I , Cl ), (Li, Na), (Li , Na )
5. The number of species in which the central atom has a hybridization of sp3d is _______.
H 2O, XeF4 , XeOF4 , PF5 , ClF3 , XeF2 , XeO2 F2

6. Two elements A and B have the following electronic configurations:
A  1s2 2s 2 2p6 3s2 3p6 4s2
B  1s2 2s2 2p6 3s2 3p3
If expected compound formed by A and B is Ax By , then the sum of x and y is _______.
7. The number of species which have square pyramidal type structure out of the following is _______.
NF3 , SF4 , IF5 , XeOF4 , IO3 , XeF5 , XeF5 , XeO3
8. The total number of sp3 hybrid orbitals in the following molecule is _______.
CH3  CH 2  CH  CH  CH 2  CH 3
9. How many of the following species do not exist?

Li 2 , BF63 , Ne2 , AlF63 , NCl5 , Be 2 , B22
10. The number of electrons in Cr  Z  24  , having n  l  3

1.
PART III: MATHEMATICS MARKS: 100
SECTION-1
3
1. If sec   tan   , then the value of sin  is:
2
12 5 2 6
(A) (B) (C) (D)
13 13 13 13
1
2. The most general solution of tan   1 and cos    is:
2
3 5
(A) n  , nI (B) n  (1) n , nI
4 4
5 
(C) 2n  , n  I (D) n  (1) n , n  I
4 4
1 1 1
3. Sum of the series S  1  (1  2)  (1  2  3)  (1  2  3  4)  .... upto 40 terms is:
2 3 4
(A) 428 (B) 432 (C) 430 (D) 420
4. Consider the ten numbers ar , ar 2 , ar 3 ,....ar10 . If their sum is 18 and the sum of their reciprocals is 6,
then the product of these ten numbers is:
(A) 81 (B) 243 (C) 343 (D) 324

5. If     90 the maximum value of sin .sin  is:
1 3
(A) 1 (B) (C) (D) 2
2 2
6. If 13  23  33  ...  n3  2025 , then the value of n is:

(A) 8 (B) 9 (C) 10 (D) 11
a b c d
7. If a, b, c and d are positive real number, then    belongs to the interval.
b c d a
(A) [2, ) (B) [3, ) (C) [4, ) (D) (, 4)
8. Let a1 , a2 , a3 , ……. be in A.P. and h1, h2 , h3 , …… in H.P. If a1  2  h1 & a30  25  h30 then
a7 h24  a14  a17 
(A) 50 (B) 77 (C) 200 (D) 400
9. If 2 sin 2   3cos  , where   [0, 2 ] , then the sum of all the possible values of  is:
(A)  (B) 3 (C) 2 (D) 4
1 1 1 1
10. x2  x4  x8 16
 x ....  ......( x  0, x  1)
1
(A) x2 (B) x x (C) x (D)
x

1 1 1
11. If S denotes the sum of infinite terms and S n denotes the sum of n terms of the series 1     ... ,
2 4 8
1
such that S  S n  , then the least value of n is:
1000
(A) 8 (B) 9 (C) 10 (D) 11
12. If sin   cos   1 , then the value of |cos 2 | is:
1 3
(A) 1 (B) 0 (C) (D)
2 2
13. If p and q are positive real numbers such that p 2  q 2  1 , then the maximum value of p + q is ……...
1 1
(A) 2 (B) (C) (D) 2
2 2
1 1 1
14. The sum of n terms of the series 1    ...  is:
1 2 1 2  3 1  2  3  ...  n
n 2n n 2n
(A) (B) (C) (D)
n 1 n 1 2n  1 2n  1
15. The sum of first 20 terms of 0.7 + 0.77 + 0.777 + … is:
7 7
(A) (179  1020 ) (B) (99  10 20 )
81 9
7 7
(C) (179  1020 ) (D) (99  10 20 )
81 9

3 5 7
16. The sum of first n terms of 2  2   ... is :
1 1  2 2 12  22  32
6n 2 6n 6(2n  1) 3(n 2  1)
(A) (B) (C) (D)
n 1 n 1 n 1 n 1
tan x tan y tan z 38
17. If   , x  y  z   and tan 2 x  tan 2 y  tan 2 z  then K =
2 3 5 K
(A) 2 (B) 1 (C) 3 (D) 5
18. If the nth terms of two series 3 + 10 + 17 + …. and 63 + 65 + 67 + …. are equal, then n = ……
(A) 9 (B) 11 (C) 13 (D) 19
19. The value of cos10  cos30  cos50  cos 70 is:

1 1 3 3
(A) (B) (C) (D)
8 16 8 16
20. The sum of 20 terms of a series of which every even term is 2 times the term before it, and every odd term
is 3 times the term before it, the first term being unity is:
 2  10  3  10  3  10  2  10
(A)   (6  1) (B)   (6  1) (C)   (6  1) (D)   (6  1)
7 7 5 5

SECTION-2
1. If a, b, c, d, e are in A.P., then the value of (a  e)  4(b  d )  6c is _______.
2. In a certain A.P., 5 times the 5th term is equal to 8 times the 8th term. Then its 13th term is _______.
H H
3. If H is the harmonic mean between P and Q, then the value of  is _______.
P Q
    
4. If sin 1 sin 2  cos 1 cos 2  1  0 where 1  2  (0, 2 ) then value of 1  tan 1   1  tan 2 
 4  4 
is _______.
1 1
5. If tan A  and tan B  then tan(2A + B) is _______.
2 3

S3
6. If sum of n, 2n, 3n terms of an A.P. are S1, S2 , S3 , respectively then find the value of .
S2  S1
7. If f k ( x)  k (sin k x  cos k x) , where x  R, k  1 , then 9 f 4 ( x)  4 f6 ( x) is equal to_______.
1
8. If the sum of first n natural numbers is times the sum of its squares, then the value of n is _____.
5
9. The maximum value of log 2  5(2sin x  cos x)  11 is ______.

 
1 1 44
10. If the sum of infinite terms of the series 3  (3  d )  (3  2d ) 2  .... is , then the value of d
4 4 9
is_______.
  End of 2025 | JEE Main - 3 GEN 2   

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JEE Main – 3 (GEN 2) | JEE - 2025

Date: 16/10/2023 Maximum Marks: 300

Timing: 4:00 PM to 7:00 PM Duration : 3.0 Hours

Name of the Candidate (In CAPITALS) :

OMR Bar Code Number :

Candidate's Signature : Invigilator's Signature

PART I: PHYSICS MARKS: 100

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Code A | Page 2 JEE Main - 3 GEN-2 | JEE 2025

(A) (B) (C) (D)

5. Graph of (1/ v) vs x for a particle under rectilinear motion is as shown,

Code A | Page 3 JEE Main - 3 GEN-2 | JEE 2025

9. A man is riding on a horse. He is trying to jump the gap between two

Code A | Page 4 JEE Main - 3 GEN-2 | JEE 2025

12. Two projectiles are projected with velocity v A , vB at angles  A (from

Code A | Page 5 JEE Main - 3 GEN-2 | JEE 2025

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inclined plane perpendicularly. Given, H  4 m , g  10m / s 2

The horizontal separation between the points A and B is:

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PART II: CHEMISTRY MARKS: 100

1. If ionisation energy of a hydrogen atom is 13.6eV, IE of Be3 will be:

2. Match the Column-I (Elements) with Column-II (Configuration of elements).

(A) (B) (C) (D)

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5. In which of the following species p - d bond is present?

8. Which pair of molecules contains only polar species?

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(A) 9.1108 (B) 192 (C) 406 (D) 91

molecule if A form ABy E x type molecule? [E : Lone pairs, A – B : Bond pair]

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Code A | Page 13 JEE Main - 3 GEN-2 | JEE 2025

18. The bond order of NO bond in nitrate ion (NO3 ) is:

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3. Ratio of  - bonds and  - bonds in a benzene molecule is _______.

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9. How many of the following species do not exist?

10. The number of electrons in Cr  Z  24  , having n  l  3

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PART III: MATHEMATICS MARKS: 100

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6. If 13  23  33  ...  n3  2025 , then the value of n is:

Code A | Page 18 JEE Main - 3 GEN-2 | JEE 2025

12. If sin   cos   1 , then the value of |cos 2 | is:

Code A | Page 19 JEE Main - 3 GEN-2 | JEE 2025

19. The value of cos10  cos30  cos50  cos 70 is:

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7. If f k ( x)  k (sin k x  cos k x) , where x  R, k  1 , then 9 f 4 ( x)  4 f6 ( x) is equal to_______.

9. The maximum value of log 2  5(2sin x  cos x)  11 is ______.