万华化学工业涂料综合解决方案

Industrial coating solutions

Wanhua Chemical Group Co., Ltd.

Surface Material Business

Jeff Zhang 张振飞

Oct 23, 2014 Shanghai
 目录
万华化学集团股份有限公司、表面材料事业部

金属漆

木器漆

地坪漆
 盈利能力 Profitability

Net profit belonging to the parent company from 1999 to 2013

350,000 120%
归属于母公司净利润（万元 左轴） 增长率（百分比 右轴）
102% 289,134 100%
300,000
89%
80% 80%
250,000 Net profit grows annually by a compound
74% rate of 234,888
29.5 percent over the past 13 years from 60%
200,000 2001 to 2013. 53% 51% 53% 185,390
43%
The net profit of 2013 is 28.7 times that of 200134%
148,784150,974 153,021 40%
150,000 27%
21% 23%20%
106,638
100,000 82,596
1% 0%
61,763
50,000 40,350
-20%
15,433 23,228
2,628 4,980 10,073 -29%
0 -40%
1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013
Business Structure of Wanhua Chemical

Wanhua Chemical Group

Polyurethanes Petrochemicals and Specialty Chemicals

Monomers
PO New Materials Business
(TPU)
MDI MTBE
TDI TBA
Polyol Acrylic Acid (AA) ADI business
Derivatives Butyl Acrylate (BA) (HMDI, HDI, IPDI, trimer)
Ethyl Acrylate (EA)
EHA Surface Materials
… Business
（waterborne PU and
PA dispersions,
crosslinkers, thcikeners)

Total Capacity is 400Ktons Special Amines

(IPDA, HMDA, MDA,
MDBA, etc)
表面材料事业部

基本情况 Basic information

为客户提供基于万华上游原料的增值服务

表面材料事业部主要从事环保型水性表面材料的研
发、生产和销售，逐步形成了包括水性聚氨酯（PUD）、
水性丙烯酸（PA）、改性聚氨酯（PUA）、水性光固
化（UV）、水性双组份（2K）、流变助剂（HEUR和
HASE）在内的六大研发技术平台，产品应用于建筑涂
料、工业涂料、粘合剂、织物涂层、生态合成革、个人
护理等多个领域。
依托上游聚氨酯和丙烯酸酯原料优势，延伸产业
链，拟打造百亿产值绿色环保表面材料新业务，现已完
成60余款产品开发。
表面材料研发平台 R&D PLATFORM
 表面材料（Surface Materials）
建筑涂料 纺织&合成革
工业涂料 胶黏剂 个人护理
（Architectural （Textile & Artificial
（Industrial Coatings） （Adhesives） （Personal Care）
Coatings） Leather）
普通金属防腐树脂 水性鞋胶
内墙建筑乳液 织物印花 头发护理
（General industrial） （ Waterborne footwear
（Interior paints emulsion） （Textile pigment coatings） （Hair care）
Auto OEM adhesive）
水性家具胶
外墙建筑乳液 木器漆用树脂 织物涂层 指甲护理
（Waterborne furniture
（Exterior paints emulsion） （Wood coatings） （Textile coatings） （Fingernail care）
adhesive）
水性复合膜胶 水性合成革
底漆乳液 塑料涂层树脂 皮肤护理
（Waterborne （Waterborne artificial
（Primer emulsion） （Plastic coatings） （Skin care）
lamination adhesive） leather）
汽车内饰胶
分散剂 地坪用树脂 增稠剂 成膜剂
（Waterborne autom-
（ Dispersant） （ Floor coatings） （Thicker） （ Film former）
otive interior adhesive）

增稠剂 涂料玻璃树脂 增稠剂 交联剂 增稠剂

（Thicker） （Glass coatings） （Thicker） （Cross-linker） （Thicker）

打印油墨树脂 交联剂
（Printing inks） （Cross-linker）

电子器件树脂
（Electronic coatings）

PUD PUA PA emulsion 2K WB UV HEUR

聚氨酯分散体 聚氨酯/丙烯酸分散体 丙烯酸乳液 反应型树脂/固化剂 水性光固化 聚氨酯增稠剂
Domestic Presence of Surface Materials Business
表面材料事业部国内布局
成都工厂（2017-2018)
Chengdu plant (operation
in June 2017-2018)

6万吨/年
60kt/year

研发中心 R&D
center

烟台工厂
Yantai plant

6-10万吨/年
100kt/year

珠海工厂(2015)
Zhuhai plant (operation
In July 2015) 宁波工厂(2014)
Ningbo plant (operation
仓库 warehouse in June 2014)
10-20万吨/年
200kt/a 7-10万吨/年
150kt/a
广州商务技术服务中心
Commercial and technical 上海技术服务(operation
service center in July 2013)
Commercial and
technical service center
宁波5万吨水性装置
Ningbo Aqueous Dispersion Plant of 50,000 Tons Capacity
Products 金属涂料产品线

Type Product Solids, % MFFT, °C OH/NCO, % Performance Application

优异的耐水性，高性价比 临时防护
Wantipro® 0639 48±1 20 -
Excellent water resistance, high cost performance Temporary protective coating
高光泽和硬度，与颜料相容性优异 轻防腐涂料及零部件浸涂
PA Wantipro® 0612 43±1 37 -
High gloss and hardness, good compatability with pigment Light duty anticorrosion paint, dipping system
优异的防腐性，柔韧性 高性能轻防腐涂料
Wantipro® 0618 50±1 17 -
Excellent anti-corrosive property, good flexibility High perforamce light duty anticorrosion paint
高光泽，优异的耐性及重涂性 烤漆
Wantipro® 0676 47±1 41 1.3
High gloss, excellent chemical resistance, good recoatability Baking system
优异的耐候性，高光高硬 2K，工程机械，交通运输
Antkote® 2033 46±1 - 3.3
Excellent weatherability, high gloss and hardness 2K, Machinery/Transportation
OH-PA
优异的耐性 2K，工程机械，交通运输
Antkote® 2042 42±1 - 4.2
Excellent chemical resistance, high gloss and hardness 2K, Machinery/Transportation
优异的耐性和柔韧性，高光泽 烤漆
Antkote® 2043 44±1 - 4.2
Excellent chemical resistance and flexibility, high gloss Baking system
耐性优异、活化时间长 2K，工程机械，交通运输
Hardener Aquolin® 161 100 - 18.5
Excellent chemical resistance, long pot life 2K, Machinery/Transportation
Light duty anticorrosion system 轻防腐体系
O

Wantipro® C C O
H
C
H2
C O R Fe

Excellent adhesion on metal 优异的金属附着力

Excellent salt fog resistance 优异的耐盐雾性能
Higher高

轻防腐涂料及零部件浸涂
Light duty anticorrosion paint, dipping system
®
Wantipro
Wantipro®0612
0612
Hardness 硬度

高性能轻防腐涂料
High performance light duty anticorrosion paint
临时防护涂层
®
Temporary protective coating Wantipro
Wantipro®0618
0618
®
Wantipro
Wantipro®0639
0639

Salt fog resistanc 耐盐雾 Higher高

Wantipro® 0639

• Outstanding water resistance 卓越的耐水性

• Good salt water resistance 优异的耐盐水性
• Good stability 稳定性优异
物料 % 供应商
打浆
耐水，30天 耐盐水，12天 1 水 10 /
Water resistance, 30d Salt water resistance, 12d 2 OROTAN 731A 1 分散剂/Dow
3 CF-10 0.1 润湿剂/联合碳化
4 AMP-95 0.1 pH调节剂
6 Ti-pure 902+ 4 钛白粉/杜邦
7 沉淀硫酸钡（1250目） 10 填料/青岛林柯化工
8 铁钛 6 防锈填料/万达科技
9 云母粉CJ-A4 5 填料/滁绢
10 磷酸锌 2 防锈填料/广西化工研究院
11 Black 6 0.3 炭黑/德固赛
配漆
1 Wantipro® 0639 43 乳液/万华
2 AMP-95 0.2 pH调节剂
3 浆料 38.5 自制
Water line 4 Texanol 2.6 成膜助剂/Dow
水位线 5 Tego 1488 0.1 消泡剂/Tego
6 FA-179 0.5 防闪锈助剂/海明斯
7 水 14.8 /
8 VesmodyTM A401 0.3 增稠剂/万华
100

指标
1 pH 8.3
2 Visco, stomer, 25°C 89.2KU
Thickness of dry film, 40um, on tinplate
3 pH after RT 40 days 8.1
干膜厚度: 40um，马口铁 4 Visco, stomer, 25°C, RT 40d 86.5KU
drying: T=25C RH=55% 7day
养护条件：25C，RH=55%，7天
Wantipro® 0612

Execllent adhesion 优异的附着力

马口铁 Tinplate 碳钢 CRS 铝 Aluminum

Test method: GB/T 9286-1998, RT 7 days. 测试方法：GB/T 9286-1998, 制膜后，室温养护7天。PVC=16%。

Excellent chemical resistance 优异的化学耐性

5% salt water, 7d 5%H2SO4, 3d Water, 10d

5%盐水, 7d 5%硫酸, 3d 自来水, 10d
Test method: GB/T 9274, RT 7 days, thickness of dry film is 40um, on tinplate.PVC=16%。
测试方法：GB/T 9274, 将室温放置7d的漆膜(干膜厚40um, 马口铁)置于相应浓度的液体介质中。
Wantipro® 0612

Good salt fog resistance, 7D Excellent orientation of Al powder

7天耐盐雾性 优异的银粉定向

Wanripro® 0612 Competitor

Thickness of film 干膜厚: 80um

Aluminum phosphate 三聚磷酸铝: 5%
Zinc phosphate 磷酸锌: 5%
Titanium dioxide 钛白粉: 5%
Wantipro® 0612: For Dipping 用于浸涂

• Smooth surface, no sagging 外观无流挂点

• Good stability 稳定性好
• Salt fog resistance 一定的耐盐雾性
物料 % 供应商
1 水 9.2 去离子水
2 BYK-190 1 分散剂/毕克化学
3 AMP-95 0.3 pH调节剂
4 CF-10 0.1 润湿剂/联合碳化
5 HEUCOPHOS® ZMP 5 防锈填料/凯佰
6 拜尔乐4330 5 铁黑/拜耳乐
7 滑石粉 (1250目) 6 填料
8 Attagel 50 0.1 膨润土/美洋时代
9 Black 6 0.5 炭黑/德固赛
搅拌状态下依次加入, 研磨至细度20um以下
10 Wantipro® 0612 65 树脂/万华化学
11 二乙二醇丁醚 6.5 成膜助剂
12 Tego Foamex 1488 0.2 消泡剂/迪高
13 NALZIN® FA 179 0.3 防闪锈助剂/海明斯
TM
14 Vesmody A401 0.5 增稠剂/万华化学
15 VesmodyTM A801 0.3 增稠剂/万华化学

指标
1 Visco, 25°C, DIN4 68s
2 pH 8.1
工艺：浸涂后挂起表干10-20min, 然后80-100C 30min
施工粘度：17-25s (可根据所需膜厚及现场施工环境调节)
Wantipro® 0612: For Dipping 用于浸涂
Excellent stability 优异的稳定性
Wantipro® 0612 Competitor

Dilute to 20s, 50°C 3 weeks, no settling, no segmentation, no pig skin, no visco change. 开稀至20s，热储
存3周，无硬沉淀、浮白及返粗，粘度无明显变化。

Excellent compatibility 优异的相容性

Mixed with a commercial dipping paint, RT 7 days, the mix is stable, no visco change, and the gloss keeps the same.
与一市售浸涂漆混合，室温7天，混合液稳定，无粘度和光泽的变化。

相容性监测
20
光泽/粘度

15
光泽
粘度
10

5
一天 二天 三天 四天 五天 六天 七天
时间
Wantipro® 0612: For Dipping 用于浸涂

Salt fog resistance 24h 耐盐雾性24h

Wantipro® 0612 Competitor

Thickness 膜厚: 10um

Wantipro® 0618

Wantipro®技术 后交联技术
Wantipro® Technology Post self crosslink system

Wantipro®
Wantipro®0618
0618
••Better
Bettersalt
saltfog
fogresistance
resistanceand andchemical
chemicalresistance
resistance
••优异的耐盐雾及抗化学性
优异的耐盐雾及抗化学性
••Good
Goodbalance
balanceofofflexibility
flexibilityand
andhardness
hardness
••柔韧性和硬度的平衡
柔韧性和硬度的平衡

Performance of anticorrosion paint 防腐漆性能

Adhesion
Property Hardness Impact Flexibility Water resistence Salt water resistence,
(tinplate, crosshatch)
性能 硬度 1kg 耐冲击 柔韧性 耐水 3%NaCl 耐盐水
附着力（碳钢/马口铁）
Result
0-1 HB 100/100cm 0.5mm 15 d 10 d
结果

P/B=1 颜基比=1. Thickness of dry film干膜厚度: 40um. Drying conditions干燥条件: 7d, T=25C, RH=60%
Wantipro® 0618

Excellent salt fog resistance 240h 物料 % 供应商

浆料部分

优异的耐盐雾性能 240h 1
2
水
BYK-190
10.4
1.4 颜料分散剂/BYK
3 沉淀硫酸钡 4
4 滑石粉1250目 6
Wantipro® 0618 Competitor 5 Ti-Pure 902+ 6.5 钛白粉/Dupont
6 三聚磷酸铝AWP-II 6
7 磷酸锌 5
8 Tego 1488 0.05 消泡剂/Tego
39.35

配漆部分
1 Wantipro®0618 55 树脂/万华化学
2 氨水 1
3 浆料 39.3
4 DPnB 3.3 溶剂
5 Tego 1488 0.1 消泡剂/Tego
6 NALZIN® FA 179 0.5 防闪锈助剂/海明斯
7 VesmodyTM U604:水=1:2 0.9 增稠剂/万华化学
100.1

P/B=1 颜基比=1. Thickness of dry film干膜厚度: 40um. 指标

1 Visco 95KU
Drying conditions干燥条件: 7d, T=25C, RH=60%
Wantipro® 0618+Wantipro® 0612

Even better salt fog resistance 600h

更为优异的耐盐雾性能 600h

底漆：Wantipro ®
底漆：Wantipro®0618
0618
Excellent
Excellentanticorrosion
anticorrosionresistance
resistance
优异的防腐性
优异的防腐性
面漆：Wantipro ®
面漆：Wantipro®0612
0612
Higher
Higherhardness
hardness Wantipro® 0618 Primer: 50um, 80C 30min
较高的硬度
较高的硬度 Wantipro® 0612 white top, PVC=16%: 30um
RT 7d, 25C, 60%
WB industry baking paint 水性工业烤漆

Wantipro®
Wantipro®0676
0676
••Outstanding
Outstandingchemical resistance卓越的化学抗性
chemicalresistance 卓越的化学抗性
••High gloss >97%, varnish 清漆光泽高
High gloss >97%, varnish 清漆光泽高
••Good
Goodrecoatability, degree重涂性好
recoatability,00degree 重涂性好
••Excellent Flexibility, 0.5mm 优异的柔韧性
Excellent Flexibility, 0.5mm 优异的柔韧性
••Excellent
ExcellentImpact
Impactresistance
resistance>50/>50 kg·cm优异的冲击强度
>50/>50kg·cm 优异的冲击强度
项目Item 结果Result

Rub resistance to alcohol, ≥2000 times,

95%, 1kg 耐醇擦 no change 无变化
Rub resistance to MEK, ≥200 times,
1kg 耐MEK擦 slight gloss loss 轻微失光
Acid resistance, 24h, no change
H2SO4, 5% 耐酸 无变化
Alkali resistance, 12h no change, 24h little bubble, recoverable
NaOH, 5% 耐碱 12h 无变化, 24h 轻微起泡, 可恢复
Salt water resistance, 48h, no change
5%NaCl 耐盐水 无变化
Water resistance 48h, no change
耐水 无变化
Salt fog resistance
96h
耐盐雾

Thickness of dry film, 30um, according to GB/T9274

Wantipro® 0676

MEK rubbing Alcohol rubbing

物料 % 供应商
®
1 Wantipro 0676 78 树脂/烟台万华
2 DMEA 0.6 胺中和剂
TM
3 Butyl Cellosolve Solvent 7.9 助溶剂
4 BYK-024 0.3 消泡剂/BYK
5 Tego®AIREX 902W 0.2 消泡剂/迪高
6 CYMEL 325 12 交联剂/氢特
7 HALOX-515 1 防腐助剂/HALOX
100

指标
1 pH 8.5

100次，漆膜无变化 2000次，漆膜无变化 喷涂，室温干燥30分钟，140C 烘烤30分钟，隔天测试性能。

100 times, no change 2000 times, no change Spraying, RT 30min, 140oC 30min, test overnight
200次，漆膜有失光 测试方法：ASTM D5402-2006 (擦拭法)，500g载荷
200 times, slight gloss loss Test method: ASTM D5402-2006, load 500g
Wantipro® 0676+Antkote® 2033: wheel hub 轮毂
For wheel hub用于轮毂烤漆
• Good appearance and building up property 优异的外观和丰满度
• Excellent resistance 优异的抗性
• Good flexibility & recoatability 柔韧性及重涂性好

Wantipro® ®
Wantipro®0676
0676 +
Antkote
Antkote®2033
2033 = 1:1
Flexibility柔韧性
••Flexibility 柔韧性 ••Building
Buildingup property丰满度
upproperty 丰满度
Recoatability重涂性
••Recoatability 重涂性 ••Appearance 外观
Appearance 外观

Test on aluminum alloy wheel hub 在铝合金轮毂上实测

项目Item 结果Result
Salt fog resistance 240h, no bubble and rust
耐盐雾 无起泡无锈蚀
Acid resistance, 48h slight gloss loss
H2SO4, 0.1mol/L 耐酸 轻微失光
Alkali resistance, 24h, no change
NaOH, 0.1mol/L 耐碱 无变化
No. 93 gasoline resistance 48h, no change
耐93号汽油 无变化
Boiling water resistance 2h, no change
耐水煮 无变化
40°C water resistance 144h, no change
40°C 耐水 无变化
Wantipro® 0676+Antkote® 2033: wheel hub 轮毂
Good stability for aluminum paint 银粉漆优异的稳定性
Competitor Wantipro® 0676

RT 30 days, apply. The same appearance and performance.

国产铝银浆配漆，室温放置一个月，喷涂，漆膜外观及性能无变化。

Good recoatability 优异的重涂性

Interlayer adhesion, 0 class 二涂、三涂层间附着力均为零级。

WB industry baking paint 水性工业烤漆

Recipe for aluminum paint 银粉漆参考配方 Recipe for white paint 白漆参考配方
物料 % 供应商 物料 % 供应商
1 Wantipro® 0676 29 树脂/万华 1 BYK-2012 1.2 分散剂/BYK
2 DMEA 0.4 pH调节剂 2 水 6.1 /
3 Antkote® 2033 28 树脂/万华 3 Ti-Pure 902+ 22 钛白粉/Dupont
4 二丙二醇丁醚 4 助溶剂 研磨至细度15um以下
5 乙二醇丁醚 1.5 助溶剂 4 Wantipro® 0676 53 树脂/万华
6 异丁醇 1.5 助溶剂 5 DMEA 0.6 pH调节剂
7 BYK-346 0.3 润湿剂/BYK 6 CYMEL 325 8 交联剂/氰特
8 CYMEL 325 9 交联剂/氰特 7 二丙二醇丁醚 4 助溶剂
9 BYK-024 0.3 消泡剂/BYK 8 乙二醇丁醚 2 助溶剂
10 银粉浆 10 9 异丁醇 2 助溶剂
11 BYK-AQUATIX8421 3 排列助剂/BYK 10 BYK-346 0.3 润湿剂/BYK
12 水 13 11 BYK-024 0.3 消泡剂/BYK
100 12 FA-179 0.5 防闪锈助剂/海明斯
银粉浆配方
100
1 乙二醇丁醚 3.3 助溶剂
2 水 3.3 /
3 AMP-95 0.2 pH调节剂
4 BYK-192 0.5 分散剂/BYK
5 JNW 314 3.3 银粉/吉诺
Machinery and transport 工程机械及交通工具

抗性 硬度 外观 无法烘烤

羟基丙烯酸（组分A） 聚异氰酸酯（组分B）

O
H
O
H
OH
OH 交联反应

O
H
NCO

OH 固化

N
C
NCO
OH

O
O
H

O
H
=O
羟基反应团 异氰酸酯反应团
化学交联 –NH-C-O-
2K PU industry paint 双组分聚氨酯体系工业涂料

2K PU system 双组分聚氨酯体系

Antkote®
Antkote®2033
2033 Aquolin®
•Excellent
•Excellentultraviolet
ultravioletresistance
resistanceand
andweatherability
weatherability
Aquolin®161
161
优异的耐紫外和耐候性
优异的耐紫外和耐候性 •self-emulsion自乳化
•self-emulsion 自乳化
•Good •High
•High Functionality,100%
Functionality, 100%solid
solidcontent
content
•Goodappearance
appearanceandandbuilding
buildingup
upproperty
property 高官能度，100%固含
优异的外观
优异的外观 丰满 丰满 高官能度，100%固含
•High •Good
•Goodmiscibility
miscibilitywith
withWater-based
Water-basedsystem
system
•Highgloss
gloss>90%,
>90%,varnish
varnish 与水性体系互溶性好
清漆光泽高
清漆光泽高 与水性体系互溶性好
•Good
•GoodMechanical
Mechanicalresistance
resistanceand
andstability,
stability,
优异的机械稳定性能
优异的机械稳定性能
•Excellent
•ExcellentImpact
Impactresistance
resistance>100/100
>100/100kg·cm
kg·cm
优异的冲击强度
优异的冲击强度
•Outstanding
•Outstandingchemical
chemicalresistance
resistance
卓越的化学抗性
卓越的化学抗性
2K PU industry paint 双组分聚氨酯体系工业涂料
• Good appearance and building up property 优异的外观和丰满度
• Excellent resistance 优异的抗性
• Excellent ultraviolet resistance and weatherability 优异的耐紫外和耐候性
Recipe for 2K paint 2K面漆参考配方
物料 % 供应商

1 H2O 17.42 纯净水

2 BYK 190 7.5 BYK/分散剂
3 901W 0.08 TEGO/消泡剂
4 Ti-Pure R-706 75 钛白粉
配漆
1 Antkote® 2033 65 万华/树脂
2 DMEA 0.2 中和剂
3 BYK 346 0.5 润湿剂/毕克
4 BYK WS 0.4 流平剂/毕克
5 BYK 381 0.4 BYK/流平剂
不建议配方中添加防闪锈助剂FA179或者聚氨酯类
6 BYK 011 0.5 BYK/消泡剂 增稠剂，配方黏度可通过PH和助溶剂的含量来调
7 白浆 33 白浆 整。可添加沉淀硫酸钡、滑石粉、碳酸钙、磷酸
调整pH至8.5-9 100 锌、三聚磷酸铝等粉料，不建议添加ZMP，客户可
1 Aquolin® 161 20 万华/固化剂 根据实际需求，添加适当粉料。23℃条件下，活
化期>4h。
2 PGDA 8.6 溶剂
2K PU industry paint 双组分聚氨酯体系工业涂料

NCO/OH=1.5 ，表干30min+80℃/30min，膜厚=40-50um

执行标准
测 试 项目Item 数 值Value
Standard
活化时间 pot life h，23℃ ＞4
涂膜干燥条件 dry condition 80℃/30min
表干 touch dry/min 30 GB/T 1728 乙法
实干 hard dry/h 7 GB/T 1728 甲法
铅笔硬度 pencil hardness H GB 6739
光泽 gloss （60）% 77/87 GB 9754
附着力（adhesive force）CRS 0-1 GB/T 9286
柔韧性，mm 0.5 GB/T 1731
冲击 impact kg.cm, 1kg 100/100 GB 1732
耐水性 water resistance（23℃） ，h >72 GB 9274
耐碱（5%NaOH, 6h） 无变化

耐酸（5%H2SO4, 24h） 无变化

耐盐雾性 salt-fog resistance，h 144

耐UV UV resistance （1000小时） △E=1.5，失光率15%，无粉 GB/T 1766
化 No pulverization
2K PU industry paint 双组分聚氨酯体系工业涂料

不同产品耐UV测试对比

3
X-6
2.5
X-7
2 X-76

1.5 X-5

2033
1
2042
0.5

0
0 100 200 300 400 500 600

其中，X-5、X-6、X-7、X-76为市面竞品
2K PU industry paint 双组分聚氨酯体系工业涂料
物料 % 供应商

1 H2O 17.42 纯净水

2 BYK 190 7.5 BYK/分散剂
电机壳应用配方
3 901W 0.08 TEGO/消泡剂 Formulation of motor shell paint
4 Ti-Pure R-706 75 钛白粉
配漆
2 Antkote® 2033 60 中和剂

3 DMEA 0.2 树脂/万华

4 Tego Wet 270 0.2 润湿剂/迪高
5 BYK 346 0.5 润湿剂/毕克
6 BYK 333 0.5 流平剂/毕克

7 DPnB 5 助溶剂
8 钛白浆 15 白浆
9 黑浆 0.5 克莱恩
10 蓝浆 5.5 克莱恩
调整pH至8.5-9 100
1 Aquolin® 161 20 万华/固化剂
2 PGDA 8.6 溶剂
各类水性木器漆与溶剂型体系的对比

VOC
5
成本 QUV

硬度 化学抗性

堆叠性 平整度

透明度/
干燥
润湿性
丰满度

NC WB 1K WB 2K PU SB 2K PU (TDI) WB UV
Products for Wood Coatings 木器漆产品
Polymer
Application Product Feature
Type
Outstanding chemical resistance.
PA Lacper® 4501
Good sandability. Fast drying.
High hardness. Fast drying.
PA Lacper® 4316
Excellent sandability.
Furniture For white primer. Good whiteness, sandability,
PA Lacper® 4055
家具 and building up property.
Excellent building up. Good stackability.
PUD Lacper® 4210
Flexibility.
Excellent stackability. Low VOC needed.
PUA Lacper® 4221
High hardness and scratch resistance.
Good adhesion on Metal/Glass/SB paint/Plastic.
DIY PA Lacper® 4600
Exellent chemical resistance.
Wood Exterior Flexibility. Good early water whitening resistance.
木器漆 PA Lacper® 4055
户外 Durability against weather.
Window
Very low VOC needed. Flexibility. Good water resistance.
frame PUA Lacper® 4220
Durability against weather. Good stackability.
& Door
Floor Good adhesion on wood.
WB UV Urosin® 4632
地板 Compatible with pigment/dye. Re-emulsifiable.
For mat coating. Good chemical resistance.
Kitchen WB UV Urosin® 4617
High hardness. Dust free before UV curing.
Cabinet
For high gloss coating. Good chemical resistance.
橱柜 WB UV Urosin® 4695
High hardness.
Stain Very fine particle size.
PUD Leasys® 5530
插色 Good compatiblity with cosolvent/dye/pigment.
Hydrophilic Polyisocyanate Crosslinkers
亲水固化剂

Polymer Type Product Counterpart Feature

Hydrophilically modified
polyisocyanate
Aquolin® 161 Bayhydur 304 Polyether modified. Good chemical resistance.
based on HDI
聚醚改性亲水固化剂
Hydrophilically modified
polyisocyanate based on HDI Aquolin® 268 Bayhydur 2487/1 Sulfonate modified. Good water dispersability.
磺酸改性亲水固化剂
Hydrophilically modified
TDI free. Good drying. Could be used with Lacper® 4316
polyisocyanate based on MDI Aquolin® 296 NA
as isolation sealer.
亲水改性MDI基固化剂
万华水性单组份方案 Wanhua WB 1K system

万华水性2K方案 Wanhua WB 2K system

万华水性UV方案 Wanhua WB UV system

Wanhua WB 1K: Product

Product Type Solids, % MFFT, °C Performance

Lacper® 4210 PUD (Aliphatic) 40 44 Outstanding building up property, hand feeling, flexibility. For furniture.

Lacper® 4221 PUA (Aliphatic) 40 34 Excellent stackability, hardness, fast drying, low odour. For furniture.

Flexibility, Good early water whitening resistance, Durability against weather. Could be used
Lacper® 4055 Aqueous acrylic emulsion 45 29
in high PVC system. For furniture, DIY, exterior wood.

Lacper® 4316 Styrene-acrylate copolymer emulsion 40 60 Fast drying, hard, good sandability. For furniture, toy.

Water resistance, flexible, durability against weather, good adhesion on difficult sub. For
Lacper® 4400 Acrylic emulsion, self-crosslinking 40 40
furniture, window frame/door.

Lacper® 4501 Acrylic emulsion, self-crosslinking 40 32 Low VOC possible, chemical resistance. For furniture, DIY.

Lacper® 4560 Acrylic emulsion, self-crosslinking 45 34 Stackability, low VOC possible, chemical resistance. For furniture.

Leasys® 5530 PUD (Aliphatic) 35 <5 Fine particle size, good compatiblity with cosolvent/dye/pigment. For stain.
Wanhua WB PUD/PUA

Lacper® 4210: PUD Lacper® 4221: PUA

• Outstanding hand feeling and building up
property
• Flexibility
• Good adhesion on PU, PVC, Melamine,
plastic-wood, etc.
• Could be used as 2K with Aquolin® 268
• APEO, NMP and Organotin free
• High hardness and low cosolvent needed
• Flexibility
• Fast drying, outstanding stackability
• Could be used as 2K with Aquolin® 268
• APEO, NMP and Organotin free

Typical Properties Typical Properties

Viscosity (25°C), mPa·s 20-100 Viscosity (25°C), mPa·s 20-100
pH 7-9 pH 7-9
Non-volatile content, wt% 39-41 Non-volatile content, wt% 39-41
MFFT, °C 44 MFFT, °C 34
Pendulum hardness, koenig 71 Pendulum hardness, koenig 112
Pencil hardness B Pencil hardness HB
Impact resistance, cm 100 Impact resistance, cm 100
Flexibility, mm 0.5 Flexibility, mm 0.5
Wanhua WB PUD/PUA

Hardness
6
Flexibility 4 VOC
2
0
Building up property Sandability

Early water resistance Stackability

Lacper® 4221 Lacper® 4210

Wanhua WB 1K: Lacper® 4210
Lacper® 4210 could be used alone.
With Aquolin® 268, chemical resistance will be improved.

• Chemical resistance
Add 5% hardener in Lacper® 4210 lacquer.
Aquolin® 268/MPA Competitor/MPA
Properties Blank Aquolin® 268 Competitor
80% solid 80% solid
Mix by hand - 5 3 5 3
Transparence of the dry film 5 5 5 3 2
Gloss 20°/60°, % 59.6/82 63.5/84.5 67.8/86.2 41.2/72.9 6.8/31.8
Gloss 20°/60°, overnight 23°C, % 59.6/82 63.9/84.5 - 55.4/85.7 -
Particle size in 2K, nm - 109.3 111.4 110 131.9
Pencil hardness B F F -
Water resistance, 24h 5 5 5 -
Alcohol resistance 50%, 1h 3 5 5 -
Acetic acid resistance 30%, 1h 3 5 5 -
NaHCO3 resistance, 5%, 1h 5 5 5 -

Best-5, Worst-1.

Case: Add 5% Aquolin® 268/MPA 80% in Lacper® 4210 lacquer.

Water immersion resistance at RT is increased from 5 days to 7 days on wood-plastic panel.
Wanhua WB 1K: Lacper® 4210

• Good Adhesion
On Wood
on Carbon Steel/Tinplate Tin/Aluminium
on PC/PC+ABS/PVC

Further Improvement:
Aquolin® 268 could improve the adhesion on PVC/PU/ plastic-wood.
Silane Coupling Agent Z-6040 could improve the adhesion on melamine.

On pine + PU, Lacper® 4210 On PVC, white top On melamine, Lacper® 4210
Aquolin 268 could improve the early adhesion Lacper® 4210 + Aquolin® 268 + Z-6040 (4% to recipe)
(2% to binder)
Wanhua WB 1K: Lacper® 4210

• Flexibility

Lacper® 4210 on PVC, Lacper® 4210 on tinplate tin

excellent flexibility/adhesion/stackability
Wanhua WB 1K: Lacper® 4221

Lacper® 4221 could be used alone.

With Aquolin® 268, chemical resistance will be improved.
And the gloss keeps the same.

• Chemical resistance
Aging 7 days at RT
Alcohol Acetic acid NaHCO3 Hot Water Dry heat,
Lacper® 4221 lacquer* Gloss 60°, % Water 24h
50%, 1h 30%, 1h 5%, 1h resistance*** 70°C 20min

0% 268 (70% in MPA) 88 5 3** 3** 5 5 5

Without matting agent 5% 268 (70% in MPA) 88 5 5 5** 5 5 5
10% 268 (70% in MPA) 88 5 5 5 5 5 5
0% 268 (70% in MPA) 30 5 3** 4** 5 5 5
With 0.7% CP4-8991 5% 268 (70% in MPA) 30 5 5** 5** 5 5 5
10% 268 (70% in MPA) 30 5 5 5** 5 5 5

* 75% Lacper® 4221 in the recipe.

** The part of film is white when the disc is removed.
*** Drop the boiling water on the film and keep a glass bottle with 250ml boiling water on it, remove the bottle after cooling.
Wanhua WB 1K: Lacper® 4221
• Stackability
Sub: HDF, with 2 layers of WBUV lacquer based from Urosin® 4699, 100g/m2 for each layer.
Apply WB lacquers by 150um applicator. Flash off 3min at 25C, then 40C 40min, cooling 3min.
Stack at RT 24h and 50C 15h, pressure 0.12kg/m2.
50C 15h 25C 24h

Lacper® 4221

Competitor PUD

Competitor PA
Wanhua WB 1K: Lacper® 4221

• Hardness development

120
100
80
60
40
20
0 c
1h 4h 1d 3d 7d
Lacper® 4221 Lacquer
Lacper® 4221 Lacquer + 5%268 (70% in MPA)
Lacper® 4221 Lacquer + 10%268 (70% in MPA)

75% Lacper® 4221 in the Lacquer.

Apply on glass by 100um spiral applicator, and aging at 25°C, RH 50%.
Wanhua WB 1K: Lacper® 4221

• Excellent adhesion
1. Solid wood
2. Dip SB 2K PU as 1st layer
3. Spray 3 layers 2K WB
lacquer
Wanhua WB 1K: Lacper® 4055
• Lacper® 4055在白色底漆中的应用
• Application of Lacper® 4055 in white primer

• 填充能力：对粉料承载力好。为面漆
提供平整的底层。 1
Raw Material
Water
% Supplier
7
Good building up property 2 Orotan 731A 1 Dow
• 遮盖力：遮盖基材底色，提高最终漆 3 BYK 190 0.5 BYK

膜颜色的均一性。 4
5
Tego Airex 902w
Talc 1250 mesh
0.5 Tego
13
Good hiding power 6 Ti-Pure R-706 13 Dupont

• 打磨性：易打磨，且不易砂穿。 7 Talc 1250 mesh

Grinding 30min, add water if necessary
12

Good sandability 8 Lacper® 4055 42 Wanhua

• 稳定性：长期储存无沉淀，粘度变化 9
10
BYK 346
DPM
0.5
4
BYK

小。 11 Water 3.85
Stable, no settling 12 Laponite S 0482 10% water solution 2 Rockwood
13 VesmodyTM U 604 30% water solution 0.65 Wanhua
• 成膜性：MFFT仅为29°C，成膜助剂 100
用量少。 Specification
Good film formation 1 Fresh visco, Stomer 83KU
2 Visco after 8 days at RT, Stomer 88.5KU
• 干燥快：提高施工效率。
Fast drying
Wanhua WB 1K: Lacper® 4055
• Lacper® 4055在户外漆中的应用
• Application of Lacper® 4055 in Exterior wood coating

优异的早期耐水白性 Outstanding early water whitening resistance

清漆，粘度: 70-80KU。
Clear lacquer, visco 70-80KU.
在松木上刷涂2道，封边，每道室温或50°C干燥过夜。
Brush 2 layers on pine, including the edges. Drying at RT or 50°C overnight for each layer.
浸水过夜，均无发白。
Immerse in water overnight, no whitening.
Wanhua WB 1K: Lacper® 4055
• Lacper® 4055在户外漆中的应用
• Application of Lacper® 4055 in Exterior wood coating

户外暴晒 281天（至2014-6-10），烟台，距海1.8km，松木
Outdoor exposure, 281 days, Yantai, 1.8km to the coast, on pine
哑光白漆 Mat white 哑光红漆 Mat red
Wanhua WB 1K: Lacper® 4316

• 快干 • 耐水性好
Fast drying Good water resistance
• 打磨性好 • 铅笔硬度 HB
Excellent sandability Pencil hardness HB
• 加入Aquolin® 296，具有一定的封 • 光泽高
闭性
High gloss, 20°/60°=68%/93%
Could be used with Aquolin® 296
as isolation sealer

Lacper® 4316, P320 Lacper® 4316, P320

on maple veneer on rubber wood
Wanhua WB 1K: Lacper® 4316

清底漆 Sealer 哑光面 Mat top

Raw Material % Supplier Raw Material % Supplier
1 Lacper® 4316 50 Wanhua 1 Lacper® 4316 50 WANHUA
2 BYK028 0.3 BYK 2 BYK028 0.3 BYK
High speed 10min, check craters High speed 10min, check craters
3 DPM 3
3 DPM 3
4 DPNB 5.6
4 DPNB 5.6
5 H2O 3
5 H2O 3
6 BYK346 0.4 BYK
6 BYK346 0.4 BYK 7 Tego Airex 904w 0.2 Tego
7 Tego Airex 904w 0.3 Tego Premix 3-7, adding slowly at high speed, 10min, check craters,
Premix 3-7, adding slowly at high speed, 10min, check then middle speed
craters, then middle speed 8 Neptune 5223 NR 2.5 SHAMROCK
8 Lacper® 4316 30 Wanhua High speed 10min
9 Tego Glide 410 0.1 Tego 9 Laponite S 482 10% solution 2 ROCKWOOD
10 H2O 6.55 Middle speed
11 VesmodyTM U604 (70%) 0.75 Wanhua 10 Lacper® 4316 30 WANHUA
11 Tego Glide 410 0.1 Tego
100
12 H2O 2.3

Specification 13 VesmodyTM U604 (70%) 0.75 WANHUA

1 viscosity 23°C, DIN4 s 35-40

100.15
Specification
1 Viscosity 23°C, DIN4 s 35-40
2 Gloss, 60° 28-32%
Wanhua WB 1K: Lacper® 4400

• 同时具有较高的硬度和柔韧性。
• 优秀的耐水性。
• 适合用于半户外及家具漆。
• Excellent flexibility and higher hardness.
• Good water resistance.
• Recommended for window frame/door and furniture.

Lacper® 4400 Competitor 1 Competitor 2

Type Acrylic emulsion Acrylic emulsion Acrylic dispersion
MFFT, °C 40 35 <10
Breaking elongation, % 229.58 113.48 124.82
Impact resistance, cm 40 10 40
Hardness, könig, s
1d 35 18 15
2d 38 33 24
3d 38 33 25
5d 40 40 26
7d 41 42 30

Water resistance
Wanhua WB 1K: Lacper® 4400

• 户外暴晒 128天无开裂，烟台，距海1.8km，松木
• Outdoor exposure, 128 days, no cracks, Yantai,
1.8km to the coast, on pine

• 附着力优异，与Aquolin®固化剂搭配附着力更好。
• Good adhesion on UV/plastic-wood/PVC, etc.
• Better adhesion with Aquolin® hardener.

On plastic-wood, black, On birch + UV, mat top, gloss 10%

Lacper® 4400 + Aquolin® 296 (7% to binder) Lacper® 4400 + Aquolin® 268 (5% to binder)
Wanhua WB 1K: Lacper® 4501
Item Lacper® 4501
• 优异的化学品抗性。
Gloss, 60° 33%
• 均衡的性能。 Alcohol 50% 1h 4+
• 低成膜助剂需求。 Acetic acid 30% 1h 5
• 配方宽容度高。 NaHCO3 5% 1h 5
• Excellent chemical resistance. Coffe 4% 4
• Good comprehensive properties. Water 24h 5

• Low VOC needed. 2 layers lacquer on maple veener, ageing 7 days.

• Easy to be formulated. 1% TS-100 and 2% Neptune 5223NR in the recipe.

硬度
5

3
丰满度 早期耐水性
2

抗堆叠性 VOC

打磨性
Lacper® 4501 Lacper® 4316 Competitor 1
Competitor 2 Lacper® 4560
Wanhua WB 1K: Lacper® 4501

清底漆 Sealer 哑光面 Mat top

物料 % 供应商 物料 % 供应商
1 Lacper® 4501 50 万华 1 Lacper® 4501 50 万华
2 DPM 3
2 DPM 3 3 DPnB 3
4 Water 6
3 DPnB 3
5 Surfynol 104 BC 0.5 Air
4 BYK 346 0.5 BYK
5 Water 6 6 CP4-8991 1 Grace
将2, 3, 4, 5预混后，慢加快搅 7 Tego Airex 902w 0.7 Tego
6 Tego Airex 902w 0.5 Tego 8 Vesmody U605/Water=1/1 0.4 万华
TM
7 Vesmody U605/water=1/1 0.4 万华 高速分散>10min, 检查弹坑
高速分散>10min, 检查弹坑 9 Neptune 5223NR 2 Shamrock
8 Lacper® 4501 25 万华 10 Laponite S 0482 10%水溶液 2 Rockwood
9 Water 10 高速分散>10min
98.4 11 Lacper® 4501 25 万华
12 Water 6
13 Vesmody U605/Water=1/1 0.57 万华
指标
100.17
1 Visco, overnight, DIN4 80-90s
指标
1 Visco 95-98 KU
2 Gloss, 60° 18%
Wanhua WB 1K: Lacper® 4560
• 优异的抗粘连 Good stackability

黑胡桃贴皮上喷涂一道， 110g/m2，室温干燥，
压强0.33kg/cm2，50°C堆叠4h。
Spray on black walnut veneer, 110g/m2, 1 layer.
Pressure 0.33kg/cm2，stack @ 50°C, 4h.

1 day

3 day

6 day

Lacper® 4560 Lacper® 4500/4210 (9/1) Competitor

Wanhua WB 1K: Leasys® 5530

• Leasys® 5530非常适合用于着色剂体系中的固色树脂：
Leasys® 5530 is strongly recommended for stain.
-粒径小，<30nm，易于渗透木材；
- Very fine particle size, <30nm, good permeability to wood.
-成膜性极佳，PUD，不需要外加成膜助剂；
- PUD, excellent film formation, no cosolvent needed.
-可以溶于乙醇/异丙醇，制成修色剂。
- Good compatibility with alcohol/isopropanol
Wanhua WB 2K system: Overview

万华的2K解决方案
羟基丙烯酸分散体+HDI三聚体
Hydroxy functional polyacrylic dispersion + WB 2K solution of
Hydrophilically modified polyisocyanate based on HDI
WANHUA

NCO/OH相对固定，配方设计复杂，施工
灵活
易出错。 Flexible
Fixed NCO/OH, complex recipe design and
mixing on site.

高性价比
固化剂加入量高，成本高。 High performance
High level of hardener needed, high cost. price ratio

干燥慢，施工效率低。 快干
Slow drying, low production efficiency. Fast drying
Wanhua WB 2K system: Product

A 组份用树脂
Binders for A part
Product Type Solids, % MFFT, °C Performance
Lacper® 4210 PUD (Aliphatic) 40 44 Outstanding stackability, flexible

Lacper® 4316 Styrene-acrylate copolymer emulsion 40 60 Fast drying, good sandability

Water resistance, flexible,

Lacper® 4400 Acrylic emulsion, self-crosslinking 40 40
good adhesion on difficult sub

Lacper® 4500 Acrylic emulsion, self-crosslinking 45 35 Low VOC possible, chemical resistance

B组份用固化剂
Hardeners for B part
Product Type Solids, % NCO, % Performance
Hydrophilically modified Fast drying, excellent water dispersion,
Aquolin® 296 80 11
polyisocyanate based on MDI economical, TDI free
Hydrophilically modified, aliphatic
Aquolin® 268 100 20.5 Excellent water dispersion, transparency
polyisocyanate based on HDI
Wanhua WB 2K Sealer

Aquolin® 296在底漆中的应用 Lacper® 4316 Lacper® 4400

Application of Aquolin® 296 in sealer A Part
Binder 75 75
Byk-346 0.5 0.5
DPM/DPnB/water
11 11
• 快干 3/5/3
Fast drying water 13.5 13.5
Total 100 100
• 易打磨
B Part
Improve sandability Aquolin® 296 7 7
• 提高耐水性 Mixing
Improve water resistance fresh visco,
13 12
DIN4, s
• 提高硬度
Gloss, % 29.7 23.6
Improve hardness visco after
13 12
• 具有一定的封闭性 35°C 4h, DIN4, s
Sealing property Gloss after
74 70
35°C 4h, %
• 极佳的手分散性
Pencil hardness
Very easy to mix by hand A part
HB B

• 可使用时间长 Pencil hardness

F F
Long pot life 2K, initial
Pencil hardness
F F
2K, after 35°C 4h
Wanhua WB 2K system: Water resistance
• 提高耐水性 Improve water resistance

白枫板，喷涂第一道，80g/m2，干燥35°C 0.5h，喷涂第二道， 80g/m2

Maple veneer, spray sealer, 80g/m2, drying 35°C 0.5h, spray top, 80g/m2

干燥35°C 1h，
测试耐水16h
Drying 35°C 1h,
water resistance 16h

干燥35°C 1h，23°C养护7天，
测试耐水16h
Drying 35°C 1h, 23°C 7day,
water resistance 16h

Lacper® 4316 Lacper® 4316 +

7% Aquolin® 296
Wanhua WB 2K system: Hardness & Pot life
• 提高硬度 Improve hardness

140
120
100
80
60
40
20
0
1h 2h 3h 8h 16h 7d

Lacper® 4316 Lacper® 4316 + 7% Aquolin® 296

100μm湿膜，23°C养护，玻璃板上测试
100um wet film on glass, ageing @ 23°C

• 可使用时间长 Long pot life

35°C 4h，粘度没有变化；底部没有沉淀。
Visco keeps the same and no settling
35°C 4h，对单宁酸保持一定的封闭性。
Keep the sealing property to tannin-acid
35°C 4h，对木塑基材保持一定的附着力。
Keep the adhesion to plastic-wood
可使用时间取决于具体的指标要求。 2K体系35°C 4h的沉淀比较。左: Lacper® 4316, 右: Lacper ® 4400
The settling of 2K system after 35°C 4h. Left: Lacper® 4316, right: Lacper ® 4400
Wanhua WB 2K Sealer: Isolation 1
Lacper® 4316 + Aquolin® 296
• 封闭性及可使用时间 Sealing property and valid time
Without 2K Lacper® 4316 + Lacper® 4316 + 基材及工艺：Substrate and cycle:
Aquolin® 296 0h Aquolin® 296 4h 35°C 1.白枫板，P240砂磨，喷一道10%单宁酸
水溶液，室温晾干。
1. Maple veneer, P240 sanding, spray 10%
tannin-acid water solution, drying.
2.封闭清漆，60-70g/m2，40°C干燥
30min，喷一道白面漆。
2. Spray 2K sealer, 60-70g/m2, drying @
40°C 30min, spray white top.
评估：Evaluation:
70°C烘箱放置，隔夜观察效果。
Without 2K Lacper® 4400 + Lacper® 4400 + 70°C overnight, check bleeding.
Aquolin® 296 0h Aquolin® 296 4h 35°C

结论：Conclusion:
35°C 4h的放置使得2K体系对单宁酸的
封闭性略有下降，Lacper® 4316作为A组
份稳定性更好。
The sealing property is decreased a little
after 35°C 4h. Lacper® 4316 as A part is
better.
Wanhua WB 2K Sealer: Isolation 1

柏木 Chinese
Weeping Cy-press

松木 Pine
Wanhua WB 2K Sealer: Isolation 2
粘度 (DIN4, s) 随时间(h)的变化 Viscosity change with time
Lacper® 4500 + Aquolin® 268
20
18
A Part % 16
14
Lacper® 4500 67.5 12
10
BYK-346 0.5 8
6
BG 2 4
2
DPnB 2 0
0 1 2 3 4 5 6 7
Water 21
24℃ 35℃

B Part %
Aquolin® 268 70% 7 Lacper® 4500 + Without 2K
Aquolin® 268
Total 100

基材及工艺：Substrate and cycle:

1.白枫板，P240砂磨，喷一道10%单宁酸
水溶液，室温晾干。
1. Maple veneer, P240 sanding, spray 10%
tannin-acid water solution, drying.
2.封闭清漆，60-70g/m2，40°C干燥30min，
喷一道白面漆。
2. Spray 2K sealer, 60-70g/m2, drying @ 40°C
30min, spray white top.
评估：Evaluation:
70°C烘箱放置，隔夜观察效果。
70°C overnight, check bleeding.
Wanhua WB 2K Top
• Aquolin® 268在2K中的应用: 面漆
• Application of Aquolin® 268 in 2K system: top

Typical Properties Aquolin® 268 Competitor

Solids, % 100 100

NCO% 20.1 21.2

Viscosity 63# 12r, cP 25°C 3985 3419

Viscosity 62# 50r, cP 25°C
202 272.9
80% solid in MPA

Particle size in water1, nm 139.8 209.2

1. Dilute the hardener by MPA to 80% solid, and then mix by hand
in water. Hardener solution to water, 1:10 by weight. Lacper® 4210 + Aquolin® 268
Wet film
Wanhua WB 2K Top: Resistance & Hardness

在Lacper® 4210清漆中加入5%固化剂。Add 5% hardener in Lacper® 4210 lacquer.

• Aquolin® 268具有更优异的分散性。Better dispersion for Aquolin® 268.
• 提高面漆的化学品抗性和硬度。Improve chemical resistance and hardness.

Aquolin® 268/MPA Competitor/MPA

Properties Blank Aquolin® 268 Competitor
80% solid 80% solid
Mix by hand - 5 3 5 3
Transparence of the dry film 5 5 5 3 2
Gloss 20°/60°, % 59.6/82 63.5/84.5 67.8/86.2 41.2/72.9 6.8/31.8
Gloss 20°/60°, overnight 23°C, % 59.6/82 63.9/84.5 - 55.4/85.7 -
Particle size in 2K, nm - 109.3 111.4 110 131.9
Pencil hardness B F F -
Water resistance, 24h 5 5 5 -
Alcohol resistance 50%, 1h 3 5 5 -
Acetic acid resistance 30%, 1h 3 5 5 -
NaHCO3 resistance, 5%, 1h 5 5 5 -

Best-5, Worst-1.

举例: Lacper® 4210清漆中加入5% Aquolin® 268/MPA 80%，在木塑板上的耐常温水浸泡由5天提高至7天以上。

Case: Add 5% Aquolin® 268/MPA 80% in Lacper® 4210 lacquer.
Water immersion resistance at RT is increased from 5 days to 7 days on wood-plastic panel.
Wanhua WB 2K Top: Adhesion

• 在UV、PU以及塑料如PVC等基材上，万华
的2K面漆具有优异的附着力
• The adhesion of Wanhua 2K top on
UV/PU/PVC is perfect.

On PVC, white top

Lacper® 4210 + Aquolin® 268 (2% to binder)

On pine + PU, clear top On birch + UV, mat top, gloss 10%
Lacper® 4210 + Aquolin® 268 (5% to binder) Lacper® 4400 + Aquolin® 268 (5% to binder)
Wanhua WB UV: Product

Product Solids, % pH Application

Urosin® 4617 40±1 7.0-9.0 Multicoat or top for panel furniture, kitchen cabinet.
Urosin® 4695 40±1 7.0-9.0 High gloss, multicoat or top for panel furniture, kitchen cabinet.
Urosin® 4632 38±1 6-8 Adhesion and stain sealer for floor and furniture. By roller and moose rubber.

橱柜 Kitchen cabinet 地板 Floor

Wanhua WB UV: Urosin® 4617
Urosin® 4617的特点 Typical Properties
• 无APEO, NMP及有机锡
APEO, NMP, Organic-tin free
• 对哑粉排布佳，消光效率高
Good matting agent arrangement, high matting effiency
• UV固化前指触干，不粘灰
Dust free before UV curing

Properties Urosin® 4617 Competitor

Gloss 60°, % 91.3 7 92.5 11
Water resistance, 24h 5 5 5 5
Acetic acid resistance 30%, 2h 5 5 3 3
Alcohol resistance 50%, 2h 5 5 3 3
Coffee resistance 4%, 1h 5 5 5 5
Heat resistance1 5 5 5 5
Pencil hardness H 2H 2H 2H
Scratch resistance 5 5 5 5
Fineness of the mat film2 / 5 / 3
Film before UV curing dust free dust free sticky sticky

1. Heat resistance: keep the metal cup with boiling water on the film with and without
water, 15min.
2. Best-5, Worst-1.
Wanhua WB UV: Urosin® 4695

• 极高的光泽，镜面效果
High gloss, mirror effect

Raw Material % Supplier

1 Urosin® 4695 50.0 Wanhua

2 DPM 2.0
3 Water 2.0
4 BYK 346 0.5 BYK
将2, 3, 4, 5预混后，慢加快搅
5 Tego Airex 902w 0.1 Tego
PC+ABS, Lacper® 4210 as sealer,
6 Iragcure 500 0.5 Ciba
Urosin® 4695 as top
7 VesmodyTM U605/water=1/1 1.0 Wanhua Gloss 60°/20°95%/91%
8 Laponite S 0482 10% in water 2.0 Rockwood
高速分散>10min, 检查弹坑
9 Urosin® 4695 25.0 Wanhua
10 Water 16.0
11 VesmodyTM U605/water=1/1 0.5 Wanhua
99.6

Specification
PC+ABS, Lacper® 4210 as sealer,
1 Visco, overnight, DIN4, 25°C 51s
Urosin® 4695 as white top
2 Gloss, 60° 96% Gloss 60°/20°94%/87%
Wanhua WB UV: Application
底面合一施工工艺：Multicoat application:
1. 基材打磨 P240。Wood sanding P240.
2. 喷涂第一道，80-90g/m2。Spray 1st layer, 80-90g/m2.
3. 闪干1min，50°C干燥15min（因通风条件不同，此时间有浮动），2×Hg
灯固化，50%能量，≥400mJ/cm2。Flash off, 1min, 50°C, 15min, 2*Hg
curing, 50% energy, ≥400mJ/cm2.
4. 底漆打磨P320。Sanding P320.
5. 喷涂第二道，80-90g/m2 。Spray 2nd layer, 80-90g/m2.
6. 闪干1min，50°C干燥15min（因通风条件不同，此时间有浮动），2×Hg
灯固化，50%能量，≥400mJ/cm2 。 Flash off, 1min, 50°C, 15min, 2*Hg
curing, 50% energy, ≥400mJ/cm2.
7. 下线。Stack and package.
Wanhua WB UV: Urosin® 4632

Urosin® 4632 is an aliphatic urethane acrylate dispersion designed for floor and furniture
with outstanding wood wetting, high flexibility and hardness. It has good compatibility
with pigments and dyes.

• For floor: adhesion sealer

• For Furniture: stain base
• APEO/NMP/Organotin-free

Floor line Moose Rubber

Wanhua WB UV: Urosin® 4632

• Stability of pH

pH Competitor 1 Urosin 4632 Competitor 2

0d 7.04 6.59 6.65
1d 6.97 6.58 6.62
2d 6.94 6.58 6.65
5d 6.86 6.49 6.56
Keep the binder at 50C
Wanhua WB UV: Urosin® 4632
• Stability with dyes and pigments
WBUV binder/Black dye=1/1, Keep at room temperature 5 days, check the stability.
pH of the black dye=6.7.
Competitor 1 Urosin® 4632 Competitor 2

Flocculation

WBUV binder/Black pigment=1/1, Keep at room temperature 5 days, check the

stability. pH of the black pigment=7.6.
Competitor 1 Urosin® 4632 Competitor 2

A little settling
Wanhua WB UV: Urosin® 4632
• Calcium ion stability Add 5% 1.5%CaCl2 to the binder.
Competitor 2 Urosin® 4632

• Re-emulsifiability
Competitor 1 Urosin® 4632 Competitor 2

Best
• Apply the binder by 100um spiral applicator, drying 50C 10min. Dip tap water on
the dry film, check the re-emulsifiability.
Products 地坪涂料产品线

Type Product Solids, % OH/NCO, % Performance Application

硬度高，施工方便 1K, DIY地坪

PUA Crysol® 6140 40±1 -
High hardness, easy to apply. 1K, DIY
优异的柔韧性及耐磨性 2K，运动地坪涂料
OH-PUD Crysol® 6512 48±1 1.5
Excellent flexibility and wear resistance. 2K, Sports floor coating
优异的封闭性和渗透性 2K，工业地坪底漆
Wantipro® 0676 47±1 1.3
Excellent penetration and sealing property. 2K, Primer of industrial floor coating
OH-PA
优异的耐候性，高光高硬 2K，工业地坪面漆或罩光
Antkote® 2033 46±1 3.3
Excellent weatherability and solvent resistance, high gloss. 2K, Topcoat/Varnish
耐性优异、活化时间长 2K，地坪涂料
Hardener Aquolin® 161 100 18.5
Excellent chemical resistance, long pot life. 2K, Floor coating
Industrial floor coating 工业地坪涂料

Industrial
Industrialfloor
floorcoating
coating

Garage 车库 Warehouse 仓库 Workshop 厂房

Industrial floor coating 工业地坪涂料

2033 + Aquolin
Antkote® ®
Antkote®2033 Aquolin®161
161

Wantipro®®0676 Aquolin ®® 161

Wantipro 0676 + Aquolin 161
Varnish
Topcoat 罩光
Primer 面漆
Property Result Standard Cement 底漆
Drying time, h
Table dry 4 GB/T1728 水泥基面
Hard dry 12 GB/T1728
Pencil hardness H-2H GB/T6739
Adhesion 0-1 GB/T9286
Taber resistance, CS-17, 750g/500r, mg 15 GB/T1768
Water resistance, h 240 GB/T1733
3% NaCl resistance, h 168 GB/T9274
120# Gasoline resistance, h 72 GB/T9274
20% NaOH resistance, h 168 GB/T9274
10% H2SO4 resistance, h 72 GB/T9274

Primer底漆: 30-60um, 20C 50%RH 1D

Surface treatment of substrate
Topcoat面漆: 50-70um, 20C 50%RH 7D
基材表面处理，平整，清除涂层
杂质、油污
Wantipro® 0676: For Primer 底漆

• Excellent water resistance, 物料 % 供应商

alkali resistance A组分
优异的耐水,抗碱性能 1 Wantipro® 0676 75.5 树脂/万华
• Excellent penetration and 2 DMEA 0.6 pH调节剂
sealing property 3 Tego wet 270 0.3 润湿剂/赢创
优异的封闭性和渗透性 4 二丙二醇丁醚 8.3 助溶剂
5 Tego Foamex 825 0.2 消泡剂/赢创
6 去离子水 3.6 /
B组分
1 Aquolin® 161 9.2 固化剂/万华
2 丙二醇甲醚醋酸酯 2.3 /
Antkote® 2033: For Topcoat/Varnish 面漆/罩光

• Excellent solvent resistance

优异的耐溶剂性能 物料 % 供应商
• Excellent wear resistance 打浆
优异的耐磨性
1水 150 /
• Excellent weatherability
2 Orotan 731A 25 分散剂/陶氏
优异的耐候性
3 TRITON CF-10 2.5 润湿剂/陶氏
• Good appearance
良好的外观 4 Tego Airex 901w 2 消泡剂/赢创
5 Ti-Pure R-902+ 295 钛白粉/杜邦
6 沉淀硫酸钡 185 /
7 滑石粉 185 /
A组分
1 Antkote® 2033 45 乳液/万华
2 Tego Airex 902w 0.4 消泡剂/赢创
3 Tego wet 270 34.4 润湿剂赢创
4 浆料 0.5 /
5 各色色浆 6 /
B组分
1 Aquolin® 161 16.4 固化剂/万华
2 丙二醇甲醚醋酸酯 4.1 /
Sports floor coating 运动地坪涂料

®® 6512
Crysol 6512 +
Crysol Aquolin ®
Aquolin®161
161

Appearance 外观

Property Result Standard

Table dry 8 GB/T1728
Drying time, h*
Hard dry 19 GB/T1728
Pencil hardness* H GB/T6739
Adhesion* 0-1 GB/T9286
Taber resistance, CS-17, 750g/500r, mg** 10 GB/T1768
Impact resistance, cm, 1kg*** 100 GB/T1732
Flexibility, mm*** 0.5 GB/T1731
Water resistance, h* 360 GB/T1733
3% NaCl resistance, h* 168 GB/T9274
120# Gasoline resistance, h 72 GB/T9274
20% NaOH resistance, h* 168 GB/T9274
10% H2SO4 resistance, h
PU topcoat 聚氨酯面涂
72 GB/T9274
*High density polyurethane foam layer
** Glass
***Tinplate HD PU foam 高密度聚氨酯泡沫层
Adhesive 粘合剂
Thickness: 100um
Drying: 20C 50%RH
Cement 水泥层
Sports floor coating 运动地坪涂料

• Excellent chemical resistance: Water/acid 物料 % 供应商

/alkali/gasoline/salt water A组分
1 Crysol® 6512 67.66 树脂/万华
优异的耐化学品性: 水/酸/碱/汽油/盐水
2 Tego Foamex 805 0.15 消泡剂/赢创
• Excellent impact and wear resistance 3 Tego Airex 902w 0.1 消泡剂/赢创
卓越的耐冲击性、耐磨性 4 Tego wet 270 0.35 润湿剂/赢创
• Excellent weatherability 5 去离子水 13.56 /
优异的耐候性 6 TS-100 2 消光粉/赢创
• Excellent adhesion to HD PU foam 7 色浆 4 苏州世名
与高密度聚氨酯泡沫层具有优异的附着力 B组分
1 Aquolin® 161 9.74 固化剂/万华
2 丙二醇甲醚醋酸酯 2.44 /
DIY地坪涂料: 1K

® For indoor and outdoor concrete floor, such as garage, balcony etc.
Crysol
Crysol®6140
6140 用于室内外水泥地面的涂装防护，如车库，阳台等场所

• Outstanding hardness: 2H
物料 % 供应商
优异的硬度: 2H
白浆
• Outstanding film formation property 1 水 18.1 /
优异的成膜性 2 BYK-190 3.9 分散剂/毕克
• Excellent impact and wear resistance 3 Ti-pure R706 78 钛白粉/杜邦
研磨至细度15um以下
优异的耐冲击性、耐磨性
配漆
• Excellent weatherability 1 Crysol® 6140 62.4 乳液/万华
优异的耐候性 2 AMP-95 0.2 pH调节剂
• Easy construction 3 Corsal 2.5 成膜助剂
施工方便 4 BYK-348 0.3 润湿剂/毕克化学
5 BYK-025 0.2 消泡剂/毕克化学
6 白浆 28 色浆
7 色浆 2 色浆
8 水 2.4 /
9 亚硝酸钠(20%水溶液) 0.5 防闪锈助剂
10 VesmodyTM U604/DPM=2/1 1.5 增稠剂/万华