Ques 1: Find correct numbering.

Ans: A,E
Ques 2 : Find correct numbering.

Ans: B
Ques 3 : Find correct numbering.

Ans: A,C,D
IUPAC NOMENCLATURE OF COMPOUNDS HAVING FG
 IUPAC NOMENCLATURE OF COMPOUNDS HAVING FG

Senior Rule:
If carbon containing FG is senior then PCC and Numbering starts
from its carbon.
Otherwise PCC is longest carbon chain containing that carbon which bears FG.
1. Hexane-3-sulphonic acid

2. 2,3-Dimethylbutan-1-ol

3.
Pent-4-en-2-ol

4. 2,3-Diethylbut-3-en-1-ol

HINT: Here PCC is longest carbon chain containing that carbon which
bears FG and MB.
5.

4-Ethylpent-4-en-2-ol

6. 3,4-Dimethylpent-1-en-3-ol

7.
8. 7-Amino-6-mercaptooctan-3-ol

HINT: Here OH group is senior FG hence numbering starts from that side.
SH and NH2 groups are junior hence treated as substituents and use prefix for them.

9.
Oct-1-en-3-one

10. Hexan-3-amine
OR 3-Hexanamine
 Butan-2-amine
11. OR 2-Butanamine

Butan-1-amine
12. OR Butanamine

13. N-Methyl Propanamine

14.
N-Ethyl N-Methyl Propanamine
15.
N-Methyl Propan-2-amine

HINT: Longest carbon chain will be PCC.

16. N-Ethyl Butan-2-amine

Q . Find correct IUPAC name of above compound ?

(1): 3-Hydroxymethyl pentane-1,4,5-triol

(2): 3-Hydroxyethyl butane-1,2,4-triol

(3): 4-Hydroxyethyl -1,2,4-trihydroxy butane

(4): 3-Hydroxymethyl pentane-1,2,5-triol

17. 1-Ethoxy propane

HINT: Longest carbon chain will be PCC. Alkoxy is used as prefix for OR group.

18.
2-Ethoxy propane
19. 2,3-Epoxy pentane

HINT: Longest carbon chain will be PCC. Epoxy is used as prefix for cyclic ether.

20. 2,4- Epoxy pentane

21.
7-Ethoxy 3-methoxyoctan-4-one
22.
6-Aminocyclohex-2-en-1-ol

HINT: Senior FG is considered as PFG and junior FG is considered substituent.

Numbering: PFG > MB > Substituent

6-Bromocyclohex-3-en-1-ol
23.
Brainstorming Questions

Q . Find correct IUPAC name of above compound ?

(1): 6-Mercaptocyclohex-4-ene-1,3-diol

(2): 1-Mercaptocyclohex-2-ene-4,6-diol
(3): 1-Mercaptocyclohex-5-ene-2,4-diol

(4): 4-Mercaptocyclohex-2-ene-1,5-diol

HINT: Senior FG is considered as PFG and junior FG is considered substituent.

Numbering: PFG > MB > Substituent
 2,3-Dimethylbut-3-en-1-oic acid
24.

Hint: Here carbon containing FG persent so PCC starts

from its carbon.

25.
26.

n Name of Acid
Dicarboxylic Acid 0 Oxalic acid
O 1 Malonic acid
C OH
(CH2)n 2 Succinic acid
C OH
O 3 Glutaric acid
n  0,1,2,3,4,5 4 Adipic acid
(OMSGAP) 5 Pimelic acid
27.

28.
29.
But-3-ene-1-nitrile
Or 3-Butenenitrile

30.

5-Chloropent-1-en-3-amine

31.
32.

33.

34.
 Hexan-3-one
35.
OR 3-Hexanone

But-2-enal
36. Or 2-Butenal

37. 3-Keto-2-methylhex-4-enal
Brainstorming Questions

Q . Find correct IUPAC name of above compound ?

(1): N-Methyl methanamide

(2):N-Methyl ethanamide
(3): N-oxo methanamine

(4): N-formyl methanamine

 SPECIAL EXAMPLES

Junior Rule:
If carbon containing FG is junior (substituent) then its carbon is not
included in PCC except aldehyde. Use prefix for junior.

1.

or
5-Chlorocarbonylpentanoic acid

2. 4-carbamoylbutanoyl chloride
 Rule: When aldehyde (–CHO group) is present as a junior then
(i) If ‘C’ of –CHO is included in PCC then ‘oxo’ prefix is used.
(ii) If ‘C’ of –CHO is not included in PCC then ‘formyl’ prefix is used.

3.

4.
5.

6.

5-carbamoyl-4-chloroformyl-6-formyloctanoic acid
 WORKSHEET (Date 19-04-21)

Q: Write IUPAC name of following compounds.

1.

2.

3.
4.

5.

6.
7.

8.

9.
Q. Which of the following is correct IUPAC name ?

(1) 3-Methyl-2-ethylpentane
(2) 2-Ethyl-3-methylpentane
(3) 2-Ethyl-2-methylpentane
(4) 3-Ethyl-2-methylpentane
 HOME WORK on 19-04-21

Ex 1= Q 24,26,27,29,35,36,39,40,42,44,45
Ex 2= Q 1,2,8,14