Books Doubtnut Question Bank

CHEMISTRY
BOOKS - S DINESH & CO CHEMISTRY (HINGLISH)
SOLUTIONS
Multiple Choice Questions
1. Which of the following is not a characteristic property of the polar
liquids?
A. They have high boiling points
B. They have high heat of evaporation
C. They have low viscosity
D. They have low vapour pressure
Answer: C
Watch Video Solution
2. In liquid CCI , which of the following has maximum solubility?

4
A. CI 2
B. Br 2
C. I
2
D. KCI
Answer: C
3. CuSO 4
.5H2 O , a hydrated salt, is a coordination compound of Cu
2+
ions with H2 O molecules as the ligands. It can also be regarded as a
solution of
A. solution of solid in a liquid

B. solution of liquid in a solid
C. salt of CuSO and water

4
D. co-ordination compound of copper sulphate with water molecules
Answer: D
4. Out of molarity (M), molality (m), formality (F) and mole fraction (x)
those independent of temperature are:
A. M,m
B. F,x
C. m,x
D. M,x
Answer: C

5. The molarity of 720 g of pure water is
A. 40M
B. 4M
C. 55.5M
D. Unpredictable
Answer: C
6. Two bottles A and B contain M and

1 1 m aqueous solution of
sulphuric acid respectively
A. A is more concentrated than B
B. B is more concentrated than A
C. Concentration of A = Concentration of B
D. It is not possible to compare the concentration
Answer: A
7. One among the following is an incorrect statement
A. Normality of 0.5M aqueous solution of H 2

C2 O4 .2H2 O is 1N
B. Molality of a solution relates moles of solute and mass of solvent
C. Molality of a solution is dependent on the temperature
D. Molarity of a solution is dependent on the temperature
Answer: C

8. The correct expression relating molality (m), molarity (M), density of
solution (d) and molar mass (M 2

) of solute is :
M
A. m = × 1000
d + M M2
M
B. m = × 1000
1000d − M M2
d + M M2
C. m = × 1000
M
1000d − M M2
D. m = × 1000
M
Answer: B
9. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with
250 mL of 2 M HCl will be
A. 0.875M
B. 1.00M
C. 1.25M
D. 2.5M
Answer: A
10. For an ideal binary solution (A) and (B), y is the mole fraction of A in
A
vapour phase. Which of the following plot should be linear?
A. P Total
vs y
A
B. P Total
vs y
B
1
C. vs y A
PTotal
1
D. vs (y B
+ yA )
PTotal
Answer: C

11. The determination of correct molecular weight from Raoult's law is
applicable to
A. a volatile solute in concentrated solution
B. an electrolyte in solution
C. a non-volatile solute in a dilute solution
D. a non-electrolyte in a concentrated solution
Answer: C
12. A substance will be deliquescent if its vapour pressure is:
A. is equal to the atmospheric pressure
B. is equal to that of water vapour in air
C. is less than that of water vapour in air
D. is greater than that of water vapour in air

Answer: C
13. If to a solvent (vapour pressure = p

∘
) , n moles of a non volatile
solute are dissolved then the vapour pressure of the solution p is
A. p ∘
− p = p
n
B. p = p
∘
(1 − n)
C. p = p
∘
n
D. None of the above
Answer: D
14. The relative lowering in vapour pressure is:

A. ∝ x solute
1
B. ∝
x solute
C. = x solute
D. ∝ m
Answer: C
15. The lowering of vapour pressure of the solvent takes place on
dissolving a non-volatile solute because
A. the density of the solution increases
B. the surface tension of the solution decreases
C. the molecules of the solvent on the surface are replaced by the
molecules of the solute
D. the mole fraction of solvent is less than 1

Answer: D
16. Which of the following plots does not represent the behaviour of an
ideal binary liquid solution?
A. Plot of p versus x (mole fraction of A in liquid phase) is linear

A A
B. Plot of p versus x is linear

B B
C. Plot of p
total
versus x (or x
A B
) is linear
D. Plot of p
total
versus x is non-linear
A
Answer: D
17. For an ideal binary liquid solution with p ∘

A
> p
B
∘
which of the following
relations between xA (mole fraction of A in liquid phase) and yA (mole

fraction of A in vapour phase) is correctly represented?
A. x A
= yA
B. x A
> yA
C. x A
< yA
D. x and y cannot be correlated with each other

A A
Answer: C
18. If n2 moles of non-volatile solute are dissolved in n1 moles of the
solvent, Raoult's law is expressed mathematically as
∘
p − ps n2
A. ∘
=
p n1 + n2
∘
p − ps n1
B. ∘
=
p n1 + n2
∘
p − ps n2
C. =
ps n1 + n2
∘
p − ps n1
D. =
ps n1 + n2
Answer: A
19. 5mL of acetone is mixed with 100mL of H 2

O . The vapour pressure of
water above the solution is
A. equal to the vapour pressure of pure water
B. equal to the vapour pressure of the solution
C. less than the vapour pressure of pure water
D. more than the vapour pressure of pure water
Answer: C
View Text Solution
20. On mixing 10mL of acetone with 50mL of chloroform the total
volume of the solution is

A. < 60mL
B. > 60
C. = 60mL
D. unpredictable
Answer: A
21. Which of the following condition is not satisfied by an ideal solution?
A. ΔH mixing
= 0
B. ΔV mixing
= 0
C. Raoult's law is obeyed
D. Formation of an azeotropic mixture
Answer: D

22. On mixing 25 mL of CCl4 with 25 mL of toluene, the total volume of
the solution is
A. = 50mL
B. > 50mL
C. < 50mL
D. unpredictable
Answer: A
23. Which of the following conditions is not correct for ideal solution?
A. No change in volume on mixing
B. No change in enthalpy on mixing
C. It obeys Raoult's law

D. Ionisation of solute should occur to a small extent
Answer: D
24. Which statement is true about the solution of chloroform and
acetone ?
A. The solution formed is ideal
B. A non-ideal solution with positive deviation
C. A non-ideal solution with negative deviation
D. Unpredictable
Answer: C

25. Which of the following behaviour is true about the ideal binary liquid
solution?
A. Plot of P Total
vsXA is non-linear
B. Plot of P Total
vsXB is linear
C. Plot of P Total
vsXB is linear with slope = 0
D. Plot of P Total
vsXA is linear with slope = 0
Answer: B
26. A binary solution of ethanol and n-heptane is an example of
A. Ideal solution
B. Non-ideal solution with +ve deviation
C. Non-ideal solution with -ve deviation
D. Unpredictable behaviour
Answer: B
27. The diagram given below is a vapour pressure composition diagram
for a binary solution of A and B. In the solution A-B interactions are
A. similar to A − A and B − B interactions
B. greater than A-A and B-B interactions
C. smaller than A-A and B-B interactions
D. unpredictable
Answer: B
28. In the diagram given in the point D refers to composition where, the
solution exhibits
A. Maximum boiling azeotropy
B. Minimum boiling azeotropy
C. Highest vapour pressure
D. Lowest boiling point
Answer: A
View Text Solution
29. If the vapour pressure of solutions of two liquids are less than those
expected ideal solution they are said to have:

A. negative deviations from ideal behaviour
B. positive deviations from ideal behaviour
C. ideal behaviour
D. positive deviations for lower concentration and negative deviations
for higher concentration
Answer: A
30. The boiling point of an azeotropic mixture of water - ethanol is less
than that of both water and ethanol. Then:
A. no deviation from Raoult's law
B. positive deviation from Raoult's law
C. negative deviation from Raoult's law
D. that the solution is unsaturated

Answer: B
31. A liquid mixture which boils without changes in the composition is
called a/an
A. binary liquid mixture
B. azeotropic mixture
C. isotropic mixture
D. no specific name
Answer: B
32. Azeotropic mixture of water and C2 H5 OH boils at 351 K. By distilling
the mixture it is possible to obtain

A. Pure HCI only
B. Pure water only
C. Neither water nor HCI
D. Both water and HCI in pure state
Answer: C
33. Colligative properties depend upon the amount fraction of solute in
solution.
A. relative number of solute molecules irrespective of the nature of
the solute and solvent
B. relative number of solute molecules in solution and nature of
solvent
C. relative number of solute molecules and the nature of solute and
solvent
D. relative number of solvent molecules.
Answer: B
34. Which of the following property does not depend upon the number of
solute particles only?
A. Boiling point elevation
B. Lowering in a vapour pressure
C. Osmotic pressure
D. Depression in freezing point
Answer: B

35. Which of the following is a colligative property?
A. Change in free energy
B. Dipole moment
C. Heat of vaporisation
D. Osmotic pressure.
Answer: B
36. Which one of the following solutions exhibits the maximum elevation
in boiling point?
A. 0.1mN aCI
B. 0.1mCaCI 2
C. 0.1mBaCI 2
D. 0.1mF eCI 3
Answer: D
37. Choose the correct statement
A. The boiling point of the solution falls on increasing the amount of
the solute
B. The freezing point of the solution is lowered on adding more of
solvent
C. The freezing point of the solution is raised on adding more of
solute
D. The freezing point of the solution decreases on increasing the
amount of the solute.
Answer: D
38. Which of the following solutions will have the highest boiling point?
A. 0.1M F eCI 3
B. 0.1M BaCI 2
C. 0.1M N aCI
D. 0.1M urea (N H 2
CON H2 )
Answer: D
39. Molal depression constant is calculated from the enthalpy of fusion
(ΔHf ) and boiling point of solvent using the relation
2
M1 RT
A. K
0
f =
1000ΔHf
2
1000RT
B. K
0
f
=
M1 ΔHf
2
1000M1 T
C. K
0
f =
RΔHf
ΔHf
D. K f =
2
1000M1 RT
0
Answer: A
40. n moles of a non volatile solute are dissolved in wg of water. If K is

f
the molal depression constant of water, the freezing point of the solution
will be
1000Kf n
A.
w
1000Kf n
B. −
w
1000Kf w
C.
n
1000Kf w
D. −
n
Answer: A

41. On freezing an aqueous solution of sodium chloride, the solid that
starts separating out is
A. sodium chloride
B. ice
C. solution with same composition
D. solution with a different composition
Answer: B
42. Which of the following aqueous solutions have higher freezing point?
A. 0.1mAl 2 (SO 4 )
3
B. 0.1mBaCl 2
C. 0.1mAlCl 3
D. 0.1mN H 4
Cl
Answer: D
43. The depression in freezing point of 0.1M aqueous solution of
H CL, CuSO4 and K2 SO4 are in the ratio.
A. 1 : 1 : 1
B. 1 : 2 : 3
C. 1 : 1 : 1.5
D. 2 : 4 : 3
Answer: C

44. Which of the following aqueous solution do you expect to have the
lowest freezing point?
A. 0.1m glucose (C 6
H12 O6 )
B. 0.1mN aCl
C. 0.1m surcose (C 12
H22 O11 )
D. 0.1mBaCl 2
Answer: D
45. The osmotic pressure of a solution of benzoic acid dissolved in
benzene is less than expected because:
A. Benzoic acid is an organic solute
B. Benzene is a non-polar solvent
C. Benzoic acid gets associated in benzene

D. Benzoic acid dissociates is benzene
Answer: C
46. The osmotic pressure of the solution having concentration 0.05M
A. decreases with increase in temperature
B. increases with increase in temperature
C. does not change with change in temperature
D. initially decreases and then increases with rise in temperature
Answer: B
47. Blood is isotonic with:

A. 0.16M N aCI
B. Conc. N aCI
C. 50 % N aCI
D. 30 % N aCI
Answer: A
48. The osmotic pressure of equimolar solutions of urea, BaCl2 and
AlCl3 will be in the order
A. AlCl 3
> BaCl2 > U rea
B. BaCl 2
> AlCl3 > U rea
C. Urea > BaCl2 > AlCl3
D. BaCl 2
> Urea > AlCl3
Answer: A
49. 0.5M solution of urea is isotonic with
A. 0.5M N aCl solution
B. 0.5M sugar solution
C. 0.5M BaCl solution

2
D. 0.5M solution benzoic acid in benzene.
Answer: B
50. The molecular mass of N aCI as determined by osmotic pressure
measurement is
A. 58.5
B. less than 58.5

C. more than 58.5
D. unpredictable
Answer: B
51. The plant cell shrink when placed in a
A. solution isotonic with the cell sap
B. Water
C. Hypertonic solution
D. Hypotonic solution
Answer: C

52. The relationsip between the values of osmotic pressure of solutions
obtained by dissolving 6.00gL

−1
of CH3 COOH (π 1 ) and 7.45gL
−1
of
KCL(π 2 ) is
A. π 1
< π2
B. π 1
> π2
C. π 1
= π2
π1 π2
D. =
π1 + π2 π1 + π2
Answer: A
53. The solutions having same osmotic pressure w.r.t. same semi-
permeable membrane are called
A. Equivalent solutions
B. Ideal solutions
C. Equimolar solutions
D. Isotonic solutions
Answer: D
54. A glucose solution is to be injected into the blood stream. It must
have the same....as the blood stream
A. molarity
B. vapour pressure
C. osmotic pressure
D. viscosity
Answer: C

55. According to Boyle-Vant Hoff law for solutions, the osmotic pressure
of a dilute solutions is
A. equal to its volume
B. directly proportional to its volume
C. inversely proportional to its volume
D. none of the above
Answer: C
56. Solutions A,B,C and D are respectively 0.1M glucose,
0.05M N aCl, 0.05M BaCl2 and 0.1M AlCl3 . Which one of the following
pairs is isotonic?
A. A and B
B. B and C
C. A and D
D. A and C
Answer: A
57. For a non-electrolytic solution, van't Hoff factor is equal to
A. 0
B. 1
C. 2
D. between 0 -1
Answer: D

58. The substance A when dissolved in solvent B shows the molecular
mass corresponding to A . The vant Hoffs factor will be:

3
A. 1
B. 2
C. 3
D. 1 / 3
Answer: D
59. In case of electrolyte which dissociates in the solution the van Hoff
factor I
A. > unity
B. < unity
C. = unity
D. can be > or < 1
Answer: A
60. Van't Hoff factoe (i) is the ratio of
A. Observed molecular mass to calculated molecular mass
B. Obserbed colligative property to calculated value
C. Calculated colligative property to obserbed value
D. Number of moles dissolved to the total number of moles taken
Answer: B
61. The van't Hoff factor (i) for a dilute aqueous solution of glucose is:
A. zero
B. 1
C. 1.5
D. 2.0
Answer: B
62. The van't Hoff factor for a very dilute solution of F e 2

(SO4 )
3
is
A. 9
B. 5
C. 24
D. none of these
Answer: B

63. In case a solute associates in solution, the van't Hoff factor,
A. i > 1
B. i = 1
C. i < 1
D. none of these
Answer: C
64. The elevation in boiling points of 0.1m aqueous solutions of
N aCI, CuSO4 and N a 2

SO4 are in the ratio
A. 1 : 1 : 1
B. 1 : 2 : 3
C. 1 : 1 : 1.5
D. 2 : 6 : 7
Answer: C
65. Which of the following aqueous solutions will have highest freezing
point?
A. 0.1mAI 2
(SO4 )
3
B. 0.1m glucose
C. 0.1mKCI
D. 0.1mCaCI 2
Answer: B

66. Acetic acid undergoes dimerisation in benzene, the van't Hoff factor i
is related to degree of association of acid a, as
A. i = 1 − α
B. i = 1 + α
C. i = 1 + α /2
D. i = 1 − α /2
Answer: D
67. What is expected value of van't Hoff factor for K3 [F e(CN ) ]

6
in the
dilute solution?
A. i = 11
B. i = 5
C. i = 1 / 11
D. i = 10
Answer: B
68. For a very dilute aqueous solution of H 3

P O3 van't Hoff factor
A. i = 7
B. i = 3
C. i = 4
D. i = 5
Answer: B

69. The van't Hoff factor for a very dilute aqueous solution of KAg(CN ) 2
is
A. 4
B. 3
C. 2
D. none of these
Answer: C
70. If 100mL of 1.0M N aOH solution is diluted to 1.0L, the resulting
solution contains
A. 1 mole of N aOH
B. 0.1 mole of N aOH
C. 10.0 mole of N aOH

D. 0.05 mole of N aOH
Answer: B
71. An aqueous solution of non-electrolyte 'A' with molecular mass 60
contains 6g in 500mL and has a density equal to 1.05gmL

−1
. The
molality of solution is
A. 1.25
B. 0.19
C. 0.25
D. 0.30
Answer: B

72. The vapour pressure of a pure liquid A is 70 torr at 300K. It forms an
ideal solution with another liquid B. The mole fration of B in the solution
is 0.2 and total pressure of solution is 84 torr at 300K. The vapour
pressure of pure liquid B at 26 ∘

C is
A. 0.14 torr
B. 560 torr
C. 140 torr
D. 70 torr
Answer: C
73. 6g of urea is dissolved in 90g of water. The relative lowering of vapour
pressure is equal to
A. 0.02
B. 0.05
C. 0.1
D. 0.04
Answer: A
74. A 5% solution of glucose (molar mass 180) is isotonic with a 2.5%
solution of substance X at the same temperature. The molar mass of X is
A. 90
B. 45
C. 180
D. 360
Answer: A

75. 0.01 mole of a non-electrolyte is dissolved in 10 g of water. The
molality of the solution is :
A. 0.1m
B. 0.5m
C. 1.0m
D. 0.18m
Answer: C
76. 10 g of glucose is dissolved in 150 g of water. The mass percentage of
glucose is :
A. 0.05
B. 0.0625
C. 0.9375
D. 0.15
Answer: B
77. To a 4L of 0.2M solution of N aOH , 2L of 0.5M N aOH are added. The
molarity of resulting solution is
A. 0.9M
B. 0.3M
C. 1.8M
D. 0.18M
Answer: B

78. The osmotic pressure of 0.2 molar solution of urea at
300K(R = 0.082) litre atm mol −1

K
−1
is
A. 4.92 atm
B. 1 atm
C. 0.25 atm
D. 27 atm
Answer: A
79. Which of the following exhibits lowest boiling point?
A. 0.1M N aCl
B. 0.1M CaCl 2
C. 0.1M CH 3
COON a
D. 0.1M glucose
Answer: D
80. A 0.01M solution of glucose in water freezes at − 0.0186 ∘

C . A 0.01M
solution of KCI in water will freeze at temperature
A. higher than − 0.0186 ∘

C
B. 0 ∘
C
C. 0.0186 ∘
C
D. lower than − 0.0186 ∘

C
Answer: D
81. A 5% solution of cane sugar is isotonic with 8.77 % of X. The
molecular weight of substance X is

A. 55.98
B. 119.96
C. 95.58
D. 126.98
Answer: A
82. Cryoscopic constant of a liquid is:
A. decrease in freezing point when 1 g of solute is dissolved per kg of
the solvent
B. decrease in freezing point when 1 mole of solute is dissolved per kg
of the solvent
C. the elevation for 1 molar solution
D. a factor used for calculation of elevation in boiling point.

Answer: B
83. An aqueous solution of glucose was prepared by dissolving 18g of
glucose in 90g of water. The relative lowering in vapour pressure is
A. 0.02
B. 1.1
C. 20
D. 196
Answer: A
84. Depression in freezing point of solution of electrolytes are generally

A. lower
B. higher than what should be normally
C. low or high depending upon nature of electrolyte
D. what it should be normally
Answer: B
85. If the observed and theoretical molecular mass of N aCI is found to
be 31.80 and 58.50, then the degree of dissociation of N aCI is:
A. 0.8396
B. 0.0839
C. 0.9
D. 1
Answer: A
86. The benzene (V . P . = 268mm) and ethylene chloride
(V . P . = 236mm) form ideal solution. The total pressure made by
dissolving 2 moles of benzene and 3 moles of ethylene chloride will be
A. 504 mm
B. 248.8mm
C. 255.2mm
D. none of these
Answer: B
87. The molecular mass of a solute cannot be calculated by one of the
following relations
Kb × 1000 × wB
A. M B
=
ΔTb × wA
wB × RT
B. M B
=
πV
p0 × wB × MA
C. M B
=
(p0 − p) × wA
ΔTb wB
D. M B
= × 1000
Kb wA
Answer: A
88. What is expected value of van't Hoff factor for K3 [F e(CN ) ]

6
in the
dilute solution?
A. 4
B. 0.25
C. 0.5
D. 5
Answer: A
89. If an equimolar solution of CaCI2 and AICI3 in water have boiling
point of T and T respectively then

1 2
A. T 1
> T2
B. T 2
> T1
C. T 1
= T2
D. T 1
≥ T2
Answer: B
90. If 100mL of 1M KOH is diluted to 1 litre, the concentration of
resulting solution is
A. 1.0M
B. 10.0M
C. M / 100
D. 0.1M
Answer: D
91. 1g mole of oxalic acid is dissolved in 2 litre of solution. The
concentration of solution is
A. 0.5N
B. 2.0N
C. 2.5N
D. 1.0N
Answer: D

92. The molality of a soluton having 18 g of glucose (Molar mass=180)
dissolved in 500 g of water is :
A. 1.2m
B. 0.4m
C. 0.1m
D. 0.2m
Answer: D
93. The vapour pressure of water at room temperature is 23.8 mm Hg. The
vapour pressure of an aqueous solution of sucrose with mole fraction 0.1
is equal to
A. 2.39mmH g
B. 2.42mmH g
C. 21.42mmH g
D. 21.44mmH g
Answer: C
94. The molarity of an aqueous solution of N aOH containing 8 g in 2L of
solution is
A. 0.1M
B. 0.2M
C. 0.25M
D. 0.15M
Answer: A

95. The vapour pressure of a pure liquid A is 60 torr at 300K. It forms an
ideal solution with another liquid B. The mole fraction of B is 0.25 and the
total pressure of the solution is 82.5 torr at 300K. The vapour pressure of
pure liquid B at 300K is
A. 37.5
B. 150
C. 75
D. 187.5
Answer: B
96. The vapour pressure of benzene and pure toluene at 70

∘
C are 500
mm and 200 mm Hg respectively. If they form an ideal solution what is

the mole fraction of benzene in a mixture boiling at 70
∘
C at a total
pressure of 380 mm Hg?
A. 0.2
B. 0.4
C. 0.6
D. 0.8
Answer: C
97. The number of iodine atoms present in 40 mL solution of its 0.1 M
solution is
A. 4.81 × 10
21
B. 24.08 × 10 21
C. 0.408 × 10 23
D. 6.02 × 10 22
Answer: A
98. A sample of alcohol at 200 torr and 70

∘
C is cooled at constant
volume to 25
∘
C . What would exist at 25
∘
C ? Vapour pressure of alcohol
at 25 ∘
C is 100 torr
A. Alcohol liquid and vapour at 100 torr
B. Alcohol liquid at 100 torr
C. Alcohol liquid at 200 torr
D. Alcohol vapour at 200 torr
Answer: A
View Text Solution

99. Equal volume of 0.1M urea and 0.1M glucose are mixed. The mixture
will have
A. same osmotic pressure
B. lower osmotic pressure
C. higher osmotic pressure
D. none of these
Answer: A
100. Solubility curve of N a2 SO4 .10H2 O in water with temperature is
given as
A. Solution process is exothermic
B. Solution process is exothermic till 32.4

∘
C and endothermic after
∘
32.4 C
C. Solution process is endothermic till 32.4

∘
and exothermic
thereafter
D. Solution process is endothermic
Answer: C
View Text Solution

101. A 5.8 % solution of N aCI has vapour pressure closets to:
A. 5.8% solution of urea
B. 2m solution of glucose
C. 1m solution of urea
D. 5.8% solution of glucose
Answer: B
102. When 5 gram of BaCI2 is dissolved in water to have 6

10 gram of
solution. The concentration of solution is:
A. 2.5 ppm
B. 5 ppm
C. 5M
D. 5gmL −1
Answer: B
103. 0.2 moles of HCI and 0.1 moles of calcium chloride were dissolved in
water to have 500mL of solution, the molarity of CI −

ions is
A. 0.04M
B. 0.8M
C. 0.4M
D. 0.08M
Answer: B

104. 25mL of 3M H CI were added to 75 mL of 0.05M H CI . The molarity
of HCI in the resulting solution is approximately
A. 0.55M
B. 0.35M
C. 0.787M
D. 3.05M
Answer: C
105. In order to prepare 100cm of 0.250M barium chloride solution, the

3
amount of BaCI 2
.2H2 O required will be
A. 0.250 moles
B. .0025 moles
C. 2.5 moles
D. 6.1g of BaCI 2
.2H2 O
Answer: D
106. In certain solvent, phenol dimerizes to the extent of 60%. Its
observed molecular mass in that solvent should be
A. > 94
B. 94
C. < 94
D. unpredictable
Answer: A

107. 10 gram of solute with molecular mass 100 gram mol
−1
is dissolved
in 100 gram solvent to show 0.3

∘
C elevation in boiling point. The value
of molal elevation constant will be:
A. 10
B. 3
C. 0.3
D. unpredictable
Answer: C
108. At certain Hill-station pure water boils at 99.725 ∘

C . If K for water is
b
0.513
∘
Ckgmol
−1
, the boiling point of 0.69m solution of urea will be:
A. 100.079 ∘
C
B. 103 ∘
C
C. 100.359 ∘
C
D. unpredictable
Answer: A
109. Pure benzene freezes at 5.45

∘
C at a certain place but a 0.374m
solution of tetrachloroethane in benzene freezes at 3.55

∘
C . The Kf for
benzene is
A. 5.08Kkgmol −1
B. 508Kkgmol −1
C. 0.508Kkgmol −1
D. 50.8 ∘
Ckgmol
−1
Answer: A

110. At 300K, 36g of glucose present per litre in its solution had an
osmotic pressure 4.98 bar. If the osmotic pressure of solution is 1.52 bar
at the same temperature, what would be its concentration.
A. 1.6M
B. 0.61M
C. 0.061M
D. None of these
Answer: C
111. Two elements A and B form compounds having molecular formula
AB 2 and AB 4 . When dissolved in 20g of benzene, 1g of AB lowers the

2
fpt by 2.3K whereas 1g of AB 4 lowers it by 1.3K(Kf for
C6 H6 = 5.1Km
−1
) At. Mass of A and B are
A. 42.64 and 25.58
B. 25.58 and 42.64
C. 22.64 and 55.58
D. 45.64 and 22.58
Answer: B
112. A solution containing 30g of a non-volatile non-electrolyte solute
exactly in 90g water has a vapour pressure of 2.8kP a at 298K. Further,
18g of water is then added to solution, the new vapour pressure becomes
2.9kP a at 298K. The solutions obey Raoult's law and are not dilute, molar
mass of solute is
A. 23gmol −1
B. 34gmol −1
C. 43gmol −1
D. 32gmol −1
Answer: A
113. The vapour pressure of water is 12.3kP a at 300 K. The V.P. of 1M
solution of a non-volatile non electrolyte solution is
A. 10.08kP a
B. 12.08kP a
C. 8.3kP a
D. 10.3kP a
Answer: B

114. Volume of 0.1M H CI required to react completely with 1g equimolar
mixture of N a 2
CO3 and N aH CO is 3
A. 100mL
B. 200mL
C. 157.9mL
D. 159.7mL
Answer: C
115. If all symbols have their usual meaning, then for a non-volatile non-
ΔTf
electrolyte solute Lt m→ 0
( ) is equal to
m
A. zero
B. Infinity
C. ΔT f
D. Kf
Answer: D
116. We have 100mL of 0.1M KCl solution. To make it `0.2M,
A. acid 0.1 mol KCI
B. add 100mL of 0.1M KCI
C. evaporate 50 mL water
D. evaporate 50 mL solution
Answer: D

117. If pKa = 4 at a particular temperature then van't Hoff factor,i for
0.01M monobasic acid is,
A. 1.01
B. 1.02
C. 1.10
D. 1.20
Answer: C
118. Elevation in boiling point of an aqueous solution of urea is
0.52
∘
C(Kb for water = 0.52Kmolality
−1
. The mole fraction of urea in
)
this solution is :
A. 0.982
B. 0.018
C. 0.0567
D. 0.943
Answer: B
119. An aqueous solution of an electrolyte AB has b.pt of 101.08

∘
C . The
solute is 100% ionised ay b.pt of water. The f.pt of the same solution is
− 1.80
∘
C . Hence AB(K
b
/ Kf = 0.3)
A. is 100% ionised at f.pt of solution
B. is 50% ionised at f.pt of solution
C. behaves as a non-electrolyte at f.pt of solution
D. forms a dimer at f.pt of solution
Answer: C

120. Density of 1M solution of C6 H12 O6 is 1.18g / cm
3
. If Kf (H2 O) is
1.86Km
−1
, the solution freezes at
A. − 1.58 ∘
C
B. − 1.86 ∘
C. − 3.16 ∘
C
D. − 3.58 ∘
C
Answer: B
121. Human blood gives rise to an osmotic pressure of approximately 7.65
atm at body temperature , 37

∘
C Hence , molarity of an intravenous
glucose solution be to have the same osmotic pressure as blood is :
A. 0.30M
B. 0.10M
C. 0.50M
D. 0.20M
Answer: A
122. Osmotic pressure of insulin solution at 298K is found to be 0.0072
atm. Hence height of water column due to this osmotic pressure is
(density of H g = 13.6gcm
−3
)
A. 0.76mm
B. 70.28mm
C. 74.42mm
D. 760mm
Answer: C
View Text Solution
123. At a given temperature total vapour pressure (in Torr) of a mixture of
volatile components A and B is given by P = 12 − 75XB hence vapour
pressure of pure A and B respectively (in Torr) are
A. 120,75
B. 120,195
C. 120,45
D. 75,45
Answer: C
124. Moles of K2 SO4 to be dissolved in 12 moles of water of lower its
vapour pressure by 10mm Hg at a temperature at which vapour pressure
of pure water is 50mm Hg is

A. 3mol
B. 2mol
C. 1mol
D. 0.5mol
Answer: C
125. A mixture contains 1 mole of volatile liquid A(P =100mm Hg) and 3
A
∘
moles of volatile liquid B (P

∘
B
=80 mm Hg). If solution behaves ideally, the
total vapour pressure of the distillate is :
A. 85 mm Hg
B. 86 mm Hg
C. 90 mm Hg
D. 92 mm Hg
Answer: B
126. Vapour pressure of pure water is 40 mm. if a non-volatile solute is
added to it, vapour pressure falls by 4 mm. Hence, molarity of solution is
A. 6.17m
B. 3.09m
C. 1.54m
D. 0.77m
Answer: A
127. Relative decrease in vapour pressure in vapour pressure of an
aqueous solution NaCI is 0.1067, Number of moles of NaCI present in 180

gH 2
O is:
A. 2 mol
B. 1 mol
C. 3 mol
D. 4 mol
Answer: B
128. The depression in freezing point of 0.01m aqueous CH3 C∞H
solution is 0.02046
∘
, 1m urea solution freezes at − 1.86
∘
C . Assuming
molality equal to molarity, pH of CH 3

COOH solution is
A. 2
B. 3
C. 3.2
D. 4.2
Answer: B
129. pH of a 0.1M monobasic acid is found to be 2. Hence, its osmotic
pressure at a given temperature T K is
A. 1.1RT
B. 0.1RT
C. 0.11RT
D. 0.01RT
Answer: C

130. Lowering of vapour pressure of an aqueous solution of a non-volatile
non-electrolyte 1 m aqueous solution at 100 ∘

C is,
A. 14.12 Torr
B. 312 Torr
C. 13.45 Torr
D. 352 Torr
Answer: C
Revision Question
1. A non-volatile electrolyte dissolved in an aqueous solution in same
molal proportion as non-eletrolyte produces
A. same coligative effect

B. higher colligative effect
C. lower colligative effect
D. no colligative effect
Answer: B
2. The molal depression constant depends upon
A. Nature of solute
B. Nature of solvent
C. ΔH solution
D. Vapour pressure of solution
Answer: B

3. Which of the following is not a colligative property?
A. ΔT f
B. π
C. ΔT b
D. K b
Answer: D
4. An example of colligative property is
A. Boiling point
B. Osmosis
C. Freezing point
D. Osmotic pressure.
Answer: D
5. If 0.1M solution of glucose and 0.1M solution of urea are placed on
two sides of the semipermeable membrane to equal heights, then it will
be be correct to say that
A. There will be no net movement across the membrane
B. Glucose will flow towards urea solution
C. Urea will flow towards glucose solution
D. Water will flow from urea solution to glucose solution
Answer: A
6. The osmotic pressure of a solution increases if

A. decreasing the temperature
B. increasing the volume
C. increasing the number of molecules of the solute
D. None of the above
Answer: C
7. The process of osmosis was first discovered by
A. Nollet
B. Pfeffer
C. Traube
D. Dutrochet
Answer: A

8. Isotonic solutions at a particular temperature have the same
A. density
B. normality
C. molar concentration
D. volume
Answer: C
9. A solution containing 6.8 g of non-ionic solute in 100g of water was
found to freeze at − 0.93

∘
C . If Kf for water is 1.86, the mol. Mass of
solute is
A. 13.6
B. 34
C. 68
D. 136
Answer: D
10. An aqueous solution containing 1g of urea boils at 100.25

∘
C . The
aqueous solution containing 3g of glucose in the same volume will boil
be
A. 100.75 ∘
C
B. 100.5 ∘
C
C. 100 ∘
C
D. 100.25 ∘
C
Answer: D

11. Equal volumes of 0.1M AgN O3 and 0.2M N aCI are mixed. The
concentration of N O −
3
ions in the mixture will be
A. 0.1M
B. 0.05M
C. 0.2M
D. 0.15M
Answer: B
View Text Solution
12. How many grams of methanol would have to be added to water to
prepare 150mL of solution which is 2M CH 3

OH ?
A. 9.6
B. 2.4
C. 9.6 × 10 3
D. 4.3 × 10 2
Answer: A
13. At25 ∘
C the highest osmotic pressure is exhibited by 0.1M solution of
A. CaCI 2
B. KCI
C. Glucose
D. Urea
Answer: A

14. Which one of the following salts will have the same value of van't hoff
factor (i) as that of K 4

[F e(CN ) ]
6
?
A. AI 2
(SO4 )
3
B. N aCI
C. AI(N O 3
)
3
D. N a 2
SO4
Answer: A
15. A 0.50 molal solution of ethylene glycol in water is used as coolant in a
car . If the freezing point constant of water is 1.86

∘
per molal , at which
temperature will the mixture freeze?
A. 0.93 ∘
C
B. − 0.93 ∘
C
C. 1.86 ∘
C
D. − 1.86 ∘
C
Answer: B
16. If 5.85 g of are dissolved in90g of water,the moles fraction of

N aCl
N aCl is
A. 0.1
B. 0.01
C. 0.2
D. 0.0196
Answer: D

17. 120g of urea is present in 5L of solution, the active mass of urea is
A. 0.2
B. 0.06
C. 0.4
D. 0.88
Answer: C
18. Which of the following is not a colligative property ?
A. Depression in freezing point
B. Elevation of boiling point
C. osmotic pressure
D. Modification of refractive index

Answer: D
19. The osmotic pressure of a 5 % (weight / volume) solution of cane
sugar at 150 ∘
C is
A. 4 atm
B. 5.07 atm
C. 3.55 atm
D. 2.45 atm
Answer: B
20. Equivalent weight of crystalline oxalic acid is

A. 90
B. 63
C. 53
D. 45
Answer: B
21. 4.0g of caustic soda is dissolved in 100 cc of solution. The normality of
solution is
A. 1
B. 0.1
C. 0.5
D. 4
Answer: A
22. Isotonic solutions have same
A. Molar concentration
B. Molality
C. Normality
D. None of these
Answer: A
23. Which of the following method is used for measuring the osmotic
pressure of the solution
A. Ostwald method
B. Berkeley Hartley method

C. Solvay method
D. Haber's method
Answer: B
View Text Solution
24. Normal boiling point of water is 373K . Vapour pressure of water at
298K is 23mm enthalpy of vaporisation is 40.656kJ mol

−1
if atmopheric
pressure becomes 23mm, the water will boil at:
A. 250K
B. 298K
C. 51.6k
D. 12.5K
Answer: B

25. Which of the following concentration terms is independent on
temperature ?
A. Normality
B. Mass-volume percent
C. Molality
D. Molarity
Answer: C
26. According to Raoult's law, relative lowering of vapour pressure of a
solvent is equal to
A. Mole fraction of solute
B. Moles of solute
C. Mole fraction of solvent
D. Moles of solvent
Answer: A
27. The molarity of the solution containing 7.1g of N a2 SO4 in 100mL of
aqueous solution is
A. 2M
B. 0.5M
C. 1M
D. 0.05M
Answer: B

28. The volume of 0.1M H2 SO4 required to neutralise completely 40mL
of 0.2M N aOH solution is
A. 10mL
B. 40mL
C. 20mL
D. 80mL
Answer: B
29. Vapour pressure of CCl at 25

4
∘
C is 143 mm Hg . 0.5 g of a non-volatile
solute ( molar mass = 65mol −1

) is dissolved in 100 mL of CCl (density =
4
1.538g mL −1
) Vapour pressure of solution is :
A. 141.93mm
B. 94.39mm
C. 199.34mm
D. 143.99mm
Answer: A
30. What is the molarity of H 2

SO4 solution that has a density 1.84 g/c c
at 35 C and contains 98% by weight?

∘
A. 4.18M
B. 8.14M
C. 18.4M
D. 18M
Answer: C

31. The relationship between osmotic pressure at 273K when 10g glucose
(P1 ), 10g urea (P2 ) and 10g sucrose (P3 ) are dissolved in 250mL of
water is:
A. P 1
> P2 > P3
B. P 3
> P1 > P2
C. P 2
> P1 > P3
D. P 2
> P3 > P1
Answer: C
32. Units of molarity are
A. g/lit
B. mol/lit
C. kg/lit
D. None of these
Answer: B
33. Osmotic pressure can be increased by
A. increasing temperature
B. decreasing temperature
C. increasing volume
D. None of these
Answer: A
34. Lowering in vapour pressure is highest for

A. 0.2M sugar
B. 0.1M glucose
C. 0.1M M gSO 4
D. 0.1M BaCI 2
Answer: D
35. An azeotropic mixture of H Cl and water has
A. 84 % H CI
B. 22.2 % H CI
C. 63 % H CI
D. 20.2 % H CI
Answer: D

36. The Van't Hoff factor of very dilute solution of Ca(N O 3
)
2
A. 1
B. 2
C. 3
D. 4
Answer: C
37. Which of the following 0.10M aqueous solution will have the lowest
freezing point?
A. AI 2
(SO4 )
3
B. C 6
H12 O6
C. C 12
H12 O11
D. KI
Answer: A
38. 0.15g of a substance dissolved in 15g of a solvent boiled at a temp.
higher by 0.216 ∘
C than that of the pure solvent. Find out the molecular
weight of the substance (K for solvent is 2.16

b
∘
C )
A. 1.01
B. 10.1
C. 100
D. 10
Answer: C

39. Which of the following will have the highest boiling point at 1atm
pressure?
A. 0.1M N aCI
B. 0.1M glucose
C. 0.1M BaCI 2
D. 0.1M glucose
Answer: C
40. What will be the molality of solution having 18 g of glucose (
molecular weight = 180 ) dissolved in 500 g of water ?
A. 1m
B. 0.5m
C. 0.2m
D. 2m
Answer: C
41. An aqueous solution freezes at
− 0.186
∘
C(Kf = 1.86
∘
,K
b
= 0.512
∘
) . What is the elevation in boiling
point?
A. 0.186
B. 0.512
0.512
C.
1.86
D. 0.0512
Answer: D

42. Which one of the following is a colligative property?
A. Surface tension
B. Osmotic pressure
C. Viscosity
D. Refractive index
Answer: B
43. An ideal solution was obtained by mixing methanol and ethanol. If the
partial vapour pressure of methanol and ethanol are 2.619kP a and
4.556kP a , respectively, the composition of vapour (in terms of mole
fraction) will be
A. 0.635M eOH , 0.365EtOH
B. 0.365M eOh, 0.635EtOH

C. 0.574M eOH , 0.326EtOH
D. 0.173M eOH , 0.827EtOH
Answer: B
44. The freezing point of a solution prepared from 1.25g of non-
electrolyte and 20g of water is 271.9K . If the molar depression constant
is 1.86Kmol −1
, then molar mass of the solute will be
A. 105.7
B. 106.7
C. 115.3
D. 93.9
Answer: A

45. The relative lowering of vapour pressure is equal to the mole fraction
of thesolute. This law is called
A. Henry's law
B. Raoult's law
C. Ostwald's law
D. Arrhenius law
Answer: B
View Text Solution
46. The molal depression constant for water is 1.86 ∘

C . The freezing point
of a 0.05 − molal solution of a non-electrolyte in water is
A. − 1.86 ∘
C
B. − 0.93 ∘
C
C. − 0.093 ∘
C
D. 0.93 ∘
C
Answer: C
47. A 5 % solution of cane sugar (molecular weight =342) is isotonic with
a 1 % solution of substance X . The molecular weight of X is
A. 171.2
B. 68.4
C. 34.2
D. 136.2
Answer: B

48. The vapour pressure of a solvent decreased by 10 mm of Hg when a
non-volatile solute was added to the solvent. The mole fraction of solute
in solution is 0.2, what would be the mole fraction of solvent if the
decrease in vapour pressure is 20 mm of Hg?
A. 0.8
B. 0.6
C. 0.4
D. 0.2
Answer: C
49. Solutions having the same osmotic pressure are called:
A. Hypertonic
B. Hypotonic
C. Isotonic
D. Normal
Answer: C
50. The molar solution of sulphuric acid is equal to
A. N solution
B. 2N solution
C. N / 2 solution
D. 3N solution
Answer: B
View Text Solution

51. If 100mL of 1N sulphuric acid were mixed with 100mL of 1N sodium
hydroxide, the solution will be
A. Acidic
B. Basic
C. Neutral
D. Slightly acidic
Answer: C
52. How many grams of a dibasic acid (Mol. Wt. =200) should be present in
100 ml of its aqueous solution to give decinormal strength
A. 1g
B. 2g
C. 10g
D. 20g
Answer: A
53. The vapour pressure of pure benzene at a certain temperature is
640mm of Hg . A non-volatile non-electrolyte solid weighing 2.175g
added 39.0g of benzene. The vapour pressure of the solution is 600mm
of H g. What is the molecular weight of solid substance?
A. 49.5
B. 59.6
C. 69.6
D. 79.82
Answer: C

54. The rise in boiling point of a solution containing 1.8g glucose in 100g
of a solvent is 0.1 ∘
C . The molal elevation constant of the liquid is-
A. 0.01K / m
B. 0.1K / m
C. 1K / m
D. 10K / m
Answer: D
55. Number of moles of a solute per kilogram of a solvent is called
A. molarity
B. molality
C. Normality
D. formality
Answer: B
56. The osmotic pressure of one molar solution at 27 ∘

C is
A. 2.46 atm
B. 24.6 atm
C. 1.21 atm
D. 12.1 atm
Answer: B
57. For a 1 molar solution of NaCI in water at 25 ∘

C and 1 atm pressure
A. Molality = normality
B. Molarity = normality
C. Molality = mole fraction
D. Normality = mole fraction
Answer: B
58. 1.8 g of fructose (C6 H12 O6 ) is added to 2 kg of water. The freezing
point of the solution is
A. − 1.86 ∘
C
B. 0.186 ∘
C
C. − 0.0186 ∘
C
D. − 0.0093 ∘
C
Answer: D

59. For determination of molar mass of colloids, polymers and protein
which colligative property is used
A. Diffusion pressure
B. Atmospheric pressure
C. osmotic pressure
D. Turgor pressure
Answer: C
60. Which solutions are mixed to form a buffer solution?
A. A strong acid and its salt of a strong base
B. Strong acid and its salt of weak base
C. Weak acid and its salt of a strong base

D. Weak acid and its salt of weak base.
Answer: C
61. Which of the following is not a colligative property ?
A. Osmotic pressure
C. Depression in freezing point
D. Increase in freezing point
Answer: D

62. Partial pressure of a solution component is directly proportional to its
mole fraction. This statement is known as
A. Henry's law
B. Raoult's law
C. Distribution law
D. Ostwald's dilution law
Answer: B
63. A 1% aqueous solution (M/V) of a certain substance is isotonic with a
3% solution of glucose (M. mass 180). The molar mass of the substance is
A. 60
B. 120
C. 180
D. 360
Answer: A
64. The aqueous solution that has the lowest vapour pressure at a given
temperature, is
A. 0.1m sodium phosphate
B. 0.1mBaCI 2
C. 0.1mN aCI
D. 0.1m glucose
Answer: A

65. How much of NaOH is reuired to neutralise 1500 cm
3
of 0.1 N HCl
(Na=23)?
A. 60g
B. 6g
C. 4g
D. 40g
Answer: B
66. The volume of water to be added to 100cm

3
of 0.5N H2 SO4 to get
decinormal concentration is
A. 400cm 3
B. 500cm 3
C. 450cm 3
D. 100cm 3
Answer: A
67. Which one of the following aqueous solution will have the lowest
freezing point?
A. 0.1m urea
B. 0.1m sucrose
C. 0.1mCH 3
COOH
D. 0.1mCaCI 2
Answer:

68. The temperature at which the vapour pressure of a liquid becomes
equals to the external (atmospheric) pressure is its
A. melting point
B. sublimation point
C. inversion point
D. boiling point
Answer:
69. At a particular temperature, the vapour pressure of two liquids A and
B are 120 and 180 mm Hg respectively. If 2 mole of A and 3 mole of B are
mixed to form an ideal solution, the vapour pressure of the solution at
the same temperature will be (in mm Hg)
A. 156
B. 145
C. 150
D. 108
Answer: A
70. Molarity of H CI(aq) if its density is 1.17 g/cc
A. 36.5
B. 18.25
C. 32.05
D. 42.1
Answer: C

71. The depression of freezing point is directly proportional to
A. mole fraction of the solution
B. molarity of the solution
C. molality of the solution
D. molarity of the solvent
Answer: C
72. The vapour pressure of a solution (P) and the vapour pressure of the
solvent (P
∘
) are related to each others as (x 1 is the mole fraction of
solvent)
A. P = P
∘
x2
B. P = P
∘
x1
C. P ∘
= P x1
D. P ∘
= P x2
Answer: B
73. The solubility of a gas in water depends upon
A. nature of the gas
B. temperature
C. pressure of the gas
D. All of the above
Answer: D
74. In a mixture A and B compounds show negative deviation as

A. ΔV mix
> 0
B. ΔH mix
< 0
C. A-B interaction is weaker than A-A and B-B interaction
D. None of the above reason is correct
Answer: B
75. A solution contains non-volatile solute of molecular mass M2 . Which
of the following can be used to calculate the molecular mass of solute in
terms of osmotic pressure?
Here n2 = mass of solute, V = volume of solution, π = osmotic
pressure.
m2
A. M 2
= [ ]V RT
π
m2 RT
B. M 2
= [ ]
V π
m2
C. M 2
= [ ]nRT
V
m2 π
D. M 2
= [ ]
V RT
Answer: B
76. Which of the following is correctly matched?
Solvent Ebullioscopic constant

A.
Acetone 0.51

B.
Benzene 2.53

C.
Water 1.86

D.
Chloroform 1.22
Answer: B

77. When the solute is present in trace quantities the following
expression is used
A. gram per million
B. milligram percent
C. microgram percent
D. parts per million
Answer:
78. Identify the mixture that shows positive deviations from Raoult's law
A. CH CI 3
+ (CH3 ) CO
2
B. (CH 3
) CO + C6 H5 N H2
2
C. CH CI 3
+ C6 H6
D. (CH 3
) CO + CS2
2
Answer: D
79. 2.5 litre of 1M N aOH solution is mixed with another 3 litre solution
of 0.5M N aOH solution. Then the molarity of the resulting solution is
A. 0.80M
B. 1.0M
C. 0.73M
D. 0.50M
Answer: C
80. At room temperature the mole fraction of a solution is 0.25 and the
vapour pressure of the solvent is 0.80 atm. Then the lowering of vapour
pressure is
A. 0.75
B. 0.6
C. 0.2
D. 0.8
Answer: C
81. The boiling point of a solution of 0.11g of a substance is 15g of ether
was found to be 0.1

∘
C higher than that of pure ether. The molecular
weight of the substance will be (K b

= 2.16)
A. 148
B. 158
C. 168
D. 178
Answer: B
82. Formation of a solution from two componenets can be considered as :
(i) pure sovent → separated solvent molecules, △ H1
(ii) Pure solute → separated molecules, △ H2
(iii) separated sovent and solute molecules → solution, △ H3
solution so formed will be ideal if :
A. ΔH soln
= ΔH3 − ΔH1 − ΔH2
B. ΔH soln
= ΔH1 + ΔH2 + ΔH3
C. ΔH soln
= ΔH1 + ΔH2 − ΔH3
D. ΔH soln
= ΔH1 − ΔH2 − ΔH3
Answer: B

83. In a 0.2 molal aqueous solution of a weak acid HX the degree of
ionization is 0.3. Taking Kf for water as 1.85, the freezing point of the
solution will be nearest to
A. − 0.480 ∘
C
B. − 0.360 ∘
C
C. − 0.260 ∘
C
D. + 0.480 ∘
C
Answer: A
84. 25 mL of a solution of barium hydroxide on titration with a 0.1 molar
solution of hydrochloric acid gave a titre value of 35 mL. The molarity of
barium hydroxide solutions was

A. 0.07
B. 0.14
C. 0.28
D. 0.35
Answer: A
85. If liquids A and B from an ideal solution
A. the enthalpy of mixing is zero
B. the entropy of mixing is zero
C. the free energy of mixing is zero
D. the free energy as well as the entropy of mixing are each zero
Answer: A

86. The volume of water to be added to N / 2H CI to prepare 500cm
3
of
N / 10 solution is
A. 45cm 3
B. 400cm 3
C. 450cm 3
D. 100cm 3
Answer: B
87. Which one of the following given below concerning properties of
solutions, describe a colligative effect ?
A. Boiling point of pure water decreases by the addition of ethanol

B. Vapour pressure of pure water decreases by the addition of nitric
acid
C. Vapour pressure of pure benzene decreases by the addition of
napthalene
D. Boiling point of pure benzene increases by the addition of toluene
Answer: C
88. Which of the following statement is true?
A. The relative lowering of vapoure pressure of a solution is equal to
the mole fraction of the solute present in the solution
B. Passage of solute molecules towards solution side through
semipermeable membrane is osmosis
C. The boiling point of a solution is always lower than the solvent

D. The boiling point of a liquid is the temperature at which its vapour
pressure becomes equal to 260 mm
Answer: A
89. How much K2 Cr 2 O7 (M . W . = 294.19) is required to prepare one
litre of 0.1N solution?
A. 9.8063g
B. 7.3548g
C. 3.6774g
D. 4.903g
Answer: D

90. The ionic strength of a solution containing 0.1mole / kg of KCI and
0.2mole / kg of CuSO is
4
A. 0.3
B. 0.6
C. 0.9
D. 0.2
Answer: C
91. 3.65grams of HCI dissolved in 16.2g of water. The mole fraction of HCI
in the resulting solution is
A. 0.4
B. 0.3
C. 0.2
D. 0.1
Answer: D
92. A 0.001 molal solution of [P t(N H3 ) CI4 ]

4
in water had a freezing
point depression of 0.0054

∘
C . If Kf for water is , the correct
1.80
formulation for the above molecule is
A. [P t(N H 3
) CI3 ]CI
4
B. [P t(N H 3
) CI2 ]CI2
4
C. [P t(N H 3
) CI]CI3
4
D. [P t(N H 3
) CI4 ]
4
Answer: B

93. 5mL of N H CI, 20mL of N / 2H2 SO4 and 30 mL of N / 3H N O3 are
mixed together and volume made to one litre. The normality of the
N
A.
5
N
B.
10
N
C.
20
N
D.
40
Answer: D
94. What is the effect of the addition of sugar on the boiling and freezing
points of water?
A. Both boiling point and freezing point increases
B. Both boiling point and freezing point decreases

C. Boiling point decreases and freezing point increases
D. Boiling point increases and freezing point decreases
Answer: D
95. When 2.0g of a non-volatile solute was dissolved in 90 gm of benzene,
the boiling point of benzene is raised by 0.88K. Which of the following
may be the solute?
Kb for benzene = 2.53Kkgmol

−1
)
A. CO(N H 2
)
2
B. C6
H12 O6
C. N aCI
D. None of these
Answer: A
96. After adding non-volatile solute, freezing point of water decreases to
− 0.186
∘
C . Calculate ΔT if :
b
−1 −1
Kf = 1.86K kg mol and Kb = 0.521K kg mol
A. 0.521
B. 0.0521
C. 1.86
D. 0.0186
Answer: B
97. Which one of the following aqueous solution will exhibit highest
boiling point?
A. 0.01M N a 2
SO4
B. 0.015M glucose
C. 0.015M urea
D. 0.01M KN O 3
Answer: A
98. 6.02 × 10
20
molecules of urea are present in 100 mL of its solution.
The concentration of urea solution is
(Avogadro constant, N A
23
= 6.02 × 10 mol
−1
)
A. 0.001M
B. 0.1M
C. 0.002M
D. 0.01
Answer: D
99. An azeotropic mixture of H Cl and water has
A. 48 % H CI
B. 22.2 % H CI
C. 36 % H CI
D. 20.2 % H CI
Answer: D
100. Vapour pressure of dilute solution of glucose is 750m of mercury at
373K. The mole fraction of solute is
A. 1 / 76
B. 1 / 7.6
C. 1 / 38
D. 1 / 10
Answer: A
101. Volume of 0.1M K2

Cr 2 O7 required to oxidise 35mL of 0.5M F eSO 4
solution is
A. 29.2mL
B. 17.5mL
C. 175mL
D. 145mL
Answer: A

102. 100 cc of 0.6N H 2
SO4 and 200 cc of 0.3N H CI were mixed together.
The normality of the solution will be
A. 0.2N
B. 0.4N
C. 0.8N
D. 0.6N
Answer: B
103. Which of the following solutions will have the highest b.d?
A. 0.1M F eCI 3
B. 0.1M BaCI 2
C. 0.1M N aCI
D. 0.1M Urea
Answer: A
104. Maximum freezing point fall is
A. Comphor
B. Nepththalene
C. Benzene
D. Water
Answer: A
105. Relative lowering in vapour pressure of solution containing non-
volatile solute is directly proportional to mole fraction of solute. Above
statement is
A. Henry law
B. Dulong and Petit law
C. Raoult's law
D. Le-Chatelier's principle
Answer: C
106. A solution contains 1.2046 × 10

24
hydrochloric acid molecules in one
dm
3
of the solution. The strength of the solution is
A. 6N
B. 2N
C. 4N
D. 8N
Answer: B
107. The average osomotic pressure of human blood is 7.8 bar at 37

∘
C .
What is the concentration of an aqueous N aCI solution that could be
used in the blood stream?
A. 0.16mol / L
B. 0.32mol / L
C. 0.60mol / L
D. 0.45mol / L
Answer: A
108. Camphor is often used in molecular mass determination because
A. it is solvent for organic substances

B. it is readily available
C. it has a very high cryoscopic constant
D. it is volatile
Answer: C
109. The statement "the relative lowering of the vapour pressure is equal
to the ratio of the molecules of the solute to the total number of the
molecules in the solution" refers to
A. Hess's law
B. Dalton's law
C. Raoult's law
D. Charle's law
Answer: C
110. Ethylene glycol is added to water as an antifreeze. It will
A. Decrease the freezing point of water in the winter and increase the
boiling poing of water in the summer
B. Only decrease the freezing point of water
C. Only increase the boiling point of water
D. Be used for cleaning the radiator in a car
Answer: A
111. The weight of pure N aOH required to prepare 250cm

3
of 0.1N
solution is
A. 4g
B. 1g
C. 2g
D. 5g
Answer: B
112. The volumes of 4N H CI and 10N H CI required to make 1 litre of
6N H CI are
A. 0.75 litre of 10N H CI and 0.25 litre of 4N H CI
B. 0.25 litre of 4N H CI and 0.75 litre of 10N H CI
C. 0.67 litre of 4N H CI and 0.33 litre of 10N H CI
D. 0.80 litre of 4N H CI and 0.20 litre of 10N H CI
Answer: B

113. Which of the following colligative property can provide molar mass of
proteins (or polymers or colloids) with greatest precision?
A. Relative lowering of vapour pressure
C. Depression in freezing point
D. Osmotic pressure
Answer: D
114. If α is the degree of dissociation of N a 2

SO4 the van't Hoff's factor (i)
used for calculating the molecular mass is
A. 1 + α
B. 1 − α
C. 1 + 2α
D. 1 − 2α
Answer: C
115. Benzene and toluene form nearly ideal solutions. At 20 ∘

C , the vapour
pressure of benzene is 75 torr and that of toluene is 22 torr. The partial
vapour pressure of benzene at 20

∘
C for a solution containing 78 g of
benzene and 46 g of toluene in torr is
A. 50
B. 25
C. 37.5
D. 53.5
Answer: A
116. Two solutions of a substance (non-electrolyte) are mixed in the
following manner. 480mL of 1.5M first solution + 520mL of 1.2M
second solution. What is the molarity of the final mixture?
A. 1.20M
B. 1.50M
C. 1.344M
D. 2.70M
Answer: C
117. The vapour pressure of two liquids 'P' and 'Q' are 80 and 60 torr
respectively. The total vapour pressure of solution obtained by mixing 3
mole of P and 2 mol of Q would be

A. 140 torr
B. 20 torr
C. 68 torr
D. 72 torr
Answer: D
118. A solution of urea (mol mass 56gmol

−1
) boils at 100.18
∘
C at the
atmospheric pressure. If Kf and Kb for water are 1.86 and
0.512Kkgmol
−1
respectively, the above solution will freeze at,
A. − 6.54 ∘
C
B. 6.54 ∘
C. 0.65 ∘
C
D. − 0.654 ∘
C
Answer: D
119. 0.5M of H2 SO4 is diluted from 1 litre to 10 litre, normality of
A. 1N
B. 0.1N
C. 10N
D. 11N
Answer: B
120. Which of the following solutions are isotonic with one another?
1. 0.15M urea 2. 0.05M CaCI 2

3. 0.1M M gSO 4. 0.15M glucose
4
Select the correct answer using the codes given below.
A. 1 and 4
B. 2 and 3
C. 1,2 and 4
D. 2,3 and 4
Answer: C
121. 50mL of 10N H 2

SO4 , 25mL of 12N H CI and 40mL of 5N H N O are
3
mixed and the volume of the mixture is made 1000 mL by adding water.
The normality of resulting solution will be
A. 1N
B. 2N
C. 3N
D. 4N
Answer: A
122. Equal volumes of ethylene glycol (molar mass = 62) and water (molar
mass = 18) are mixed. The depression in freezing point of water is (given
Kf of water = 1.86Kmol
−1
kg and specific gravity of ethylene glycol is
1.11)
A. 0.0033
B. 3.33
C. 0.333
D. 33.3
Answer:

123. The vapour pressure of water at 23
∘
C is 19.8 mm of Hg 0.1 mol of
glucose is dissolved in 178.2g of water. What is the vapour pressure (in
mm Hg) of the resultant solution?
A. 19.0
B. 19.602
C. 19.402
D. 19.202
Answer: B
124. The vant Hoff factor (i) accounts for
A. degree of solubilisation of solute
B. the extent of dissolution of solute
C. the extent of dissociation of solute

D. the degree of decomposition of solution
Answer: C
125. To neutralize completely 20 mL of 0.1M aqueous solution of
phosphorus acid (H3 P O3 ) the volume of 0.1M aqueous KOH solution
required is
A. 10mL
B. 20mL
C. 40mL
D. 60mL
Answer: C

126. In 100g of naphthalene, 2.423g of S was dissolved. Melting point of
naphthalene = 80.1
∘
CΔTf = 0.661
∘
C. Lf = 35.7cal / g of
naphthalene, molecular formula of sulphur is
A. S 2
B. S 4
C. S 6
D. S 8
Answer: D
127. Mole fraction of a solute in an aqueous solution is 0.2. The molality of
the solution will be
A. 3.2
B. 2
C. 4
D. 3.4
Answer: A
128. Equimolar solutions in the same solvent have-
A. same boiling points but different freezing points
B. same freezing points but different boiling points
C. same boiling points and same freezing points
D. different boiling points and different freezing points
Answer: C

129. The mole fraction of the solute in one molal aqueous solution is:
A. 0.027
B. 0.036
C. 0.018
D. 0.009
Answer: C
130. Which has minimum osmotic pressure ?
A. 200mL of 2M N aCI solution
B. 200mL of 1M glucose solution
C. 200mL of 2M urea solution
D. all have same

Answer: B
131. Solution A contains 7 g/L of M gCl and solution B contains 7 g/L of

2
NaCl. At room temperature, the osmotic pressure of :
A. solution A is greater than B
B. both have same osmotic pressure
C. solution B is greater than A
D. can't determine
Answer: C
132. If two substances A and B have p A

∘
:p
B
∘
= 1: 2 and have mole fraction
in solution as 1:2 then mole fraction of A in vapour phase is

A. 0.33
B. 0.25
C. 0.52
D. 0.2
Answer: D
133. At same temperature, which pair of the following solutions are
isotonic solutions?
A. 0.2M BaCI and 0.2 urea

2
B. 0.1M urea and 0.1M N aCI
C. 0.1M N aCI and 0.1M K 2

SO4
D. 0.1M Ba(N O 3
)
2
and 0.1M N a 2
SO4 .
Answer: D
134. The mass of glucose that would be dissolved in 50g of water in order
to produce the same lowering of vapour pressure as is produced by
dissolving 1g of urea in the same quantity of water is :
A. 1g
B. 3g
C. 6g
D. 8g
Answer: B
135. Which will from maximum boiling azeotrope ?
A. H N O 3
+ H2 O solution
B. C2
H5 OH + H2 O solution
C. C6
H6 + C6 H5 CH3 solution
D. None of these
Answer: A
136. The Van't Hoff factor of very dilute solution of Ca(N O 3

)
2
A. one
B. two
C. three
D. four
Answer: C

137. 5 litre of a solution contains 25 mg of CaCO3 . What is its
concentration in ppm? (mol.wt of CaCO is 100)

3
A. 25
B. 1
C. 5
D. 250
Answer: C
138. The van't Hoff factor for a solute that associates in solution is
A. zero
B. 1
C. less than 1
D. more than one

Answer: C
139. Consider the following aqueous solutions and assume 100%
ionisation in electrolytes :
I. 0.1m urea
II. 0.04mAl 2
(SO4 )
3
III. 0.0.5mCaCl 2
IV. 0.005mN aCl
The correct statement regarding the above solutions is :
A. Freezing point will be lowest for solution 1
B. Freezing point will be highest for solution 4
C. Boiling point will be highest for solution 4
D. Vapour pressure will be highest for solution 2
Answer: B
140. Solubility curve of a hydrated salt in water with temperature is given.
The curve indicates that the solution process is
A. exothermic temperature
B. exotehrmic till 60 ∘
C and endothermic after 60 ∘
C
C. endothermic till 60 ∘
C and exothermic there-after
D. endothermic
Answer: C
View Text Solution
141. Blood cells do not shrink in blood because blood is
A. hypotonic
B. isotonic
C. equimolar
D. hypertonic
Answer: B
142. Phenol dimerises in benzene having van't Hoff factor 0.54. what is the
degree of association?
A. 0.46
B. 0.54
C. 0.27
D. 0.92
Answer: D
143. The relative lowering of vapour pressure of an aqueous solution
containing a non-volatile solute, is 0.0125. The molality of the solution is
A. 0.70
B. 0.50
C. 0.60
D. 0.80
Answer: A
144. Two liquids X and Y form an ideal solution. The mixture has a vapour
pressure of 400 mm at 300 K when mixed in the molar ratio 1:1. when
mixed in the molar ratio of 1:2 at the same temperatre the vapour
pressure of the mixture is 350 mm. The vapour pressure of the two pure
liquids X and Y respectively are
A. 250mm, 550mm
B. 350mm, 450mm
C. 350mm, 700mm
D. 550mm, 250mm
Answer:
145. 2N H CI solution will have the same molar concentration as a

A. 4.0N H 2
SO4
B. 0.5N H 2
SO4
C. 1N H 2
SO4
D. 2N H 2
SO4
Answer: A
146. The freezing point of water is depressed by 0.37

∘
C in a 0.01 molar
NaCI solution. The freezing point of 0.02 molar solution is depressed by
A. 0.37 ∘
C
B. 0.74 ∘
C
C. 0.185 ∘
C
D. 0 ∘
C
Answer: A
147. What is molality of pure water?
A. 1
B. 18
C. 55.5
D. None of these
Answer: C
View Text Solution
148. The increase in boiling point of a solution containing 0.6g urea in
200 gram water is 0.50 ∘

C . Find the molal elevation constant
A. 10Kgrammol −1
B. 1.0Kkgmol −1
C. 10Kkgmol −1
D. 10Kkg mol
Answer: C
149. A 6% of urea is isotonic with
A. 1M solution of glucose
B. 0.05M solution of glucose
C. 6% solution of glucose
D. 2.5% solution of glucose
Answer: A

150. Which of the following aqueous solution has the highest boiling
point
A. 0.1M KN O 3
B. 0.1M N a 3
P O4
C. 0.1M BaCI 2
D. 0.1M K 2
SO4
Answer: B
151. The molarity of 98% by wt. H 2

SO4 (d = 1.8 g/ml) is
A. 6M
B. 18M
C. 10M
D. 4M
Answer: B
152. If the various terms in the following expressions have usual
meanings, the van't Hoff factor 'i' cannot be calculated by which of the
following expression ?
A. πV = ∈ RT
B. ΔT f
= iKf m
C. ΔT b
= iKb m
∘
p − psolution n
D. solvent
∘
= i( )
p N + n
solvent
Answer: D

153. A 5% (w/V ) solution of cane sugar (molecular mass = 342) is isotonic
with 1% (w/V) solution of a subtance X. The molecular mass of X is :
A. 136.2
B. 68.4
C. 34.2
D. 171.2
Answer: B
154. Molality of an aqueous solution that produce an elevation of boiling
point of 1.00 K at 1 atm pressure. K for water is 0.512Kkgmol

b
−1
A. 0.512m
B. 0.195m
C. 1.95m
D. 5.12m
Answer: C
155. During depression of freezing point in a solution, the following are in
equilibrium:
A. liquid solvent and solid solvent
B. liquid solute and solid solvent
C. liquid solute and solid solute
D. liquid solvent and solid solute
Answer: A

156. Which of the following concentration terms is/are independent of
temperature ?
A. Molality only
B. Molality and mole fraction
C. Molality and mole fraction
D. Molality and normality
Answer: B
157. Henry's law constant of oxygen is 1.4 × 10

−3
mol lit
−1
atm
−1
at 298
K. How much of oxygen is dissolved in 100 mL at 298 K when the partial
pressure of oxygen is 0.5 atm?
A. 1.4g
B. 3.2g
C. 25.4mg
D. 2.24mg
Answer: D
158. An 1% solution of KCI(I), N aCI(II), BaCI2 (III) and urea (IV),
have their osmotic pressure at the same temperature in the ascending
order (molar masses of N aCI, KCI, BaCI2 and urea are respectively
58.5, 74.5, 208.4, 60gmol

−1
Assume 100% ionization of the electrolytes
at this temperature
A. I < III < II < IV
B. III < I < II < IV
C. I < II < III < IV
D. III < IV < I < II
Answer:
159. The difference between the boiling point and freezing point of an
aqueous solution containing sucrose (molecular mass = 342gmol

−1
) in
100 g of water is 105.04. If K and K of water are 1.86 and 0.51Kgmol

f b
−1
respectively, the weight of sucrose in the solution is about
A. 34.2g
B. 342g
C. 7.2g
D. 72g
Answer: D
160. What is the osmotic pressure of a 0.0020 mol dm

−3
sucrose
(C12 H22 O11 ) solution at 20

∘
C ? (Molar mass contant,
−1 −1 3 3
R = 8.314J K mol . 1dm = 0.001m )
A. 4870 Pa
B. 4.87 Pa
C. 0.00487 Pa
D. 0.33 Pa
Answer: A
161. A real solution is that which:
A. obeys Raoult's law
B. obeys Henr's law
C. does not obey Raoult's law
D. obeys Ohm's law
Answer: A
162. The vapour pressure of a dilute aqueous solution of glucose is 740
mm of mercury at 373 K. The mole fraction of the solute is:
1
A.
20
1
B.
38
1
C.
76
1
D.
760
Answer: B
163. The vapour pressure of a pure liquid is 0.80 atm. When a non-volatile
solute is added to this liquid, its vapour pressure drops to 0.60 atm. The
mole fraction of the solute in the solution is

A. 0.75
B. 0.2
C. 0.25
D. 0.85
Answer: C
164. 36 g of glucose (molar mass = 180g / mol) is present in 500 g of
water, the molarity of the solution is
A. 0.2
B. 0.4
C. 0.8
D. 1
Answer: B
165. For getting accurate value of molar mass of a solute by osmotic
pressure measurement
A. the solute must be volatile
B. the solution concentration must be high
C. the solute should undergo dissociation
D. the solute must be non-volatile
Answer: D
166. For a dilute solution, Raoult's law states that
A. Lowering of vapour pressure is equal to the mole fraction of the
solute
B. Relative lowering of vapour pressure is equal to mole fraction of
the solvent
C. Relative lowering of vapour pressure of the solvent is equal to the
mole fraction of the solute
D. Vapour pressure of the solution is equal to the mole fraction of the
solute
Answer: C
167. 200 mL of an aqueous solution of a protein contains its 1.26g. The
osmotic pressure of this solution at 300K is found to be 2.57 × 10 −3

bar.
The molar mass of protein will be (R = 0.083L¯

¯
m̄ol
−1
K
−1
)
A. 51022gmol −1
B. 122044gmol −1
C. 31011gmol −1
D. 61038gmol −1
Answer: D
168. The empirical formula of a non-electrolyte is CH2 O . A solution
containing 3 g L
−1
of the compound exerts the same osmotic pressure
as that of 0.05 M glucose solution. The molecular formula of the
compound is :
A. CH 2
O
B. C2
H4 O 2
C. C4
H8 O 4
D. C3
H6 O 3
Answer: B

169. A solution containing 1.8 g of a compound (empirical formula CH 2
O )
in 40 g of water is observed to freeze at − 0.465

∘
C. The molecules
formulea of the compound is (K of water =1.86kg Kmol

f
−1
):
A. C2
H4 O 2
B. C3
H6
C. C4
H8 O 4
D. C6
H12 O6
Answer:
170. Ethylene glycol is used as an antifreeze in a cold cliamate Mass of
ethylene glycol which should be added to 4 kg for water to prevent it
from freezing at −6
∘
C will be (K for water =1.86Kkgmol
f
−1
and molar
mass of ethylene glycol =62gmol −1

)
A. 304.60kg
B. 804.328g
C. 204.30g
D. 400.00g
Answer: B
171. The degree of dissociation (α) of a weak electrolyte, A x

By is related
to van't Hoff's factor (i) by the expression:
x + y − 1
A. α =
i − 1
i − 1
B. α =
(x + y − 1)
i − 1
C. α =
x + y + 1
x + y − 1
D. α =
i − 1
Answer: B
172. A 5.2 molal aqueous of methyl alcohol, CH 3

OH , is supplied. What is
the molefraction of methyl alcohol in the solution ?
A. 0.050
B. 0.100
C. 0.190
D. 0.086
Answer: D
173. Dissolving 120g of urea (mol wt 60) in 100 g of water gave solution of
density 1.158g / mL. The molarity of the solution is
A. 1.78M
B. 2.00M
C. 2.05M
D. 2.22M
Answer: C
174. The freezing point (in .

∘
C) of a solution containing 0.1g of
K3 [F e(CN ) ]
6
(Mol. wt. 329) in 100g of water (K
f
= 1.86Kkgmol
−1
) is
A. − 2.3 × 10 −2
B. − 5.7 × 10 −2
C. − 5.7 × 10 −3
D. − 1.2 × 10 −2
Answer: A
175. The freezing point depression constant for water is − 1.86 ∘

Cm
−1
. if
5.00gN a2 SO4 is dissolved in 45.0gH2 O ,the freezing point is changed by
− 3.82
∘
C ,Calculate the van't Hoff factor for N a 2
SO4
A. 2.05
B. 2.63
C. 3.11
D. 0.83
Answer: B
176. Mole fraction of a solution in 1.00 molal aqueous solution is
A. 0.1770
B. 0.0177
C. 0.0344
D. 0.83
Answer: B
177. The system that forms maximum boiling azeotrope is
A. carbon disulphide acetone
B. benzene toluene
C. acetone-chloroform
D. n-hexane-n-heptane
Answer: C

178. The van't Hoff factor i for a compound which undergoes dissociation
in one solvent and association in other solvent is respectively.
A. less than one and greater than one
B. less than one and less than one
C. greater than one and less than one
D. greater than one and greater than one
Answer: C
179. A 0.1 molal aqueous solution of a weak acid is 30 % ionized. If K for f
water is 1.86 ∘
C /m , the freezing point of the solution will be.
A. − 0.1 ∘
C
B. − 0.54 ∘
C
C. − 0.3 ∘
C
D. − 0.24 ∘
C
Answer: D
180. A solution containing 1.8 g of a compound (empirical formula CH 2

O )
in 40 g of water is observed to freeze at − 0.465

∘
C. The molecules
formulea of the compound is (K of water =1.86kg Kmol

f
−1
):
A. C2
H4 O 2
B. C3
H6 O 3
C. C4
H8 O 2
D. C6
H12 O6
Answer:

181. P A
and PB are the vapour pressure of pure liquid components ,Aand
B respectively of an ideal binary solution,If xA represents the mole
fraction of component A, the total pressure of the solution will be
A. P A
+ XA (PB − PA )
B. P A
+ XA (PA − PB )
C. P B
+ XA (PB − PA )
D. P B
+ XA (PA − PB )
Answer: D
182. For a dilute solution containing 2.5g of a non-volatile non-electrolyte
solution in 100g of water, the elevation in boiling point at 1 atm pressure
is 2
∘
C . Assuming concentration of solute is much lower than the
concentration of solvent, the vapour pressure (mm of H g) of the solution
is:
(take k b
= 0.76Kkgmol
−1
)
A. 724
B. 740
C. 736
D. 718
Answer: A
183. Kf for water is 1.86Kkgmol

−1
. IF your automobile radiator holds
1.0kg of water, how many grams of ethylene glycol (C2 H6 O2 ) must you
add to get the freezing point of the solution lowered to − 2.8 ∘

C ?
A. 27g
B. 72g
C. 93.3g
D. 39g
Answer: C
184. 6.02 × 10 20
molecules of urea are present in 100 ml of its solution.
The concentration of solution is :
A. 0.02M
B. 0.01M
C. 0.001M
D. 0.1M
Answer: B
185. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl
with 250 mL of 2 M HCl will be

A. 0.975M
B. 0.875M
C. 1.00M
D. 1.75M
Answer: B
186. How many grams of concentrated nitric acid solution should be used
to prepare 250mL of 2.0M H N O ? The concentrated acid is 70 % H N O

3 3
A. 45.0 g conc. H N O 3
B. 90.0 g conc. H N O 3
C. 70.0 g conc. H N O 3
D. 54.0 g conc. H N O 3
Answer: B
Objective Type Mcqs
1. The osmotic pressure of a solution is
A. directly proportional to the concentration at constant temperature
B. inversely proportional to the molecular mass of the solute at
constant temperature
C. indirectly proportional to the concentration at constant
temperature
D. directly proportional to the temperature
Answer: A::B::D

2. If P ∘
and P5 are the vapour pressure of the solvent and its solution
respectively and x and x are the mole fraction of the solvent and solute
1 2
respectively, then
A. P s
= P
∘
2x 2
B. P ∘
− Ps = P
∘
x2
C. P s
= P
∘
x1
D. (P ∘
− Ps ) / Ps = x 1 / (x 1 + x 2 )
Answer: B::C
3. Which statement is incorrect about osmotic pressure(π), volume (V ) ,
and temperature (T )?
1
A. π ∝ if T is constant
V
B. π ∝ T if V is constant
C. π ∝ V if T is constant
D. πV is constant if T is constant
Answer: A::B::D
4. Which of the following is more accurate method to express the
concentration of a solution?
A. Molarity
B. Molality
C. Normality
D. Mole fraction
Answer: B::D

5. Which of the following modes of expressing concentration is
independent of temperture?
A. Mass percentage
B. Volume percentage
C. Strength
D. Molarity
Answer: A::B
View Text Solution
6. Vapour pressure of a liquid depends upon its
A. temperature
B. surface area
C. nature of liquid
D. external pressure
Answer: A::C
7. Ideal solution is formed when its components
A. have zero enthalpy of mixing
B. have zero volume change on mixing
C. obey Raoult's law
D. have equal vapour pressures
Answer: A::B::C
8. A solution showing a large positive deviation from ideal behaviour have
A. lower boiling point than both the components

B. higher boiling point than both the components
C. ΔH mixing
is positive
D. ΔH mixing
is negative
Answer: A::C
9. A solution of two liquids A and B showing a large negative deviation
from ideal behaviour have
A. higher boilint point than both the components
B. ΔH mixing
is negative
C. ΔV mixing
is negative
D. A.........B interactions are stronger than A........A and B........B
interactions.
Answer: A::B::C::D
10. In the depression of freezing point experiment, it is found that the:
A. The vapour pressure of the solution is less than that of pure water
B. The vapour pressure of the solution is more than that of pure
solvent
C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point
Answer: A::D
11. An azeotropic solution of two liquids has a boiling point lower than
either of them when it:
A. shows a negative deviation from Raoult's law

B. shows no deviation from Raoult's law
C. shows positive deviation from Raoult's law
D. is saturated
Answer: C
12. A liquid is in equilibrium with its vapour at its boiling point . On an
average the molecules in the two phases have equal :
A. intermolecular forces
B. potential energy
C. temperature
D. None of these
Answer: D

13. A molal solution is one that contains one mole of a solute in
A. 1000 g of the solvent
B. one litre of solvent
C. one litre of solution
D. 22.4 litre of the solution
Answer: A
14. When mercuric iodide is added to the aqueous solution of potassium
iodide, then:
A. freezing point is raised
B. freezing point does not change
C. freezing point is lowered

D. boiling poing does not change
Answer: A
15. In which mode of expression, the concentration of a solution remains
independent of temperature?
A. Molarity
B. Normality
C. Formality
D. Molality
Answer: D

16. The freezing point among the following equimolal aqueous solutions
will be highest for
A. C6
H5 N H3 CI (aniline hydrochloride)
B. Ca(N O 3
)
2
C. La(N O 3
)
3
D. C6
H12 O6 (glucose)
Answer: D
17. Osmotic pressure of a solution is 0.0821atm at a temperature of 300
K. The concentration in mole/litre will be
A. 0.33
B. 0.066
C. 0.3 × 10 −2
D. 3
Answer: C
18. Increasing the temperature of an aqueous solution wil case
A. decrease in molality
B. decrease in molarity
C. decrease in mole fraction
D. decrease in % (ww).
Answer: B

19. The vapour pressure of a solution of 5g of non-electrolyte in 100g of
water at a particular temperature is 2985N m

−2
. The vapour pressure of
pure water at that temperature is 3000N m

−2
. The molecular weight of
the solute is
A. 180
B. 90
C. 270
D. 200
Answer: A
20. How many moles of F e 2+

ions are formed when excess iron is treated
with 500 mL of 0.4N H CI under inert atmosphere? Assume no change in
volume
A. 0.4
B. 0.1
C. 0.2
D. 0.8
Answer: B
21. The van't Hoff factor for 0.1M Ba(N O3 )

2
solution is 2.74. The degree
of dissociation is
A. 91.3 %
B. 87 %
C. 100 %
D. 74 %
Answer: B
22. An aqueous solution of 6.3g oxalic acid dihydrate is made up to
250mL . The volume of 0.1N N aOH required to completely neutralise
10mL of this solution is
A. 40 mL
B. 20 mL
C. 10 mL
D. 4 mL
Answer: A
23. During depression of freezing point in a solution, the following are in
equilibrium:
A. liquid solvent, solid solvent
B. liquid solvent, solid solute
C. liquid solvent, solid solute
D. liquid solute, solid solvent
Answer: A
24. A 0.004M solution of N a2 SO4 is isotonic with a 0.010M solution of
glucose at same temperature. The apparent degree of dissociation of
N a2 SO4 is
A. 25 %
B. 50 %
C. 75 %
D. 85 %
Answer: C
25. The elevation in boiling point, when 13.44g of freshly prepared CuCI
2
are added to one kilogram of water, is [Some useful data,
−1
Kb (H2 O) = 0.52kgKmol , mol.wt ofCuCI2 = 134.4gm]
A. 0.05
B. 0.10
C. 0.16
D. 0.20
Answer: C

26. Density of 2.05M solution of acetic acid in water is 1.02g / mL. The
molality of same solution is:
A. 2.28molkg −1
B. 0.44molkg −1
C. 1.14molkg −1
D. 3.28molkg −1
Answer: A
27. 18g of glucose (C6 H12 O6 ) is added to 178.2g of water. The vapour
pressure of water for this aqueous solution at 100 ∘

C
A. 76.00 Torr
B. 752.40 Torr
C. 759.00 Torr
D. 7.60 Torr
Answer: B
28. During osmosis, flow of water through a semipermeable membrane is:
A. from both sides of semipermeable membrane with unequal flow
rates
B. from solution having lower concentration only
C. from solution having higher concentration only
D. from both sides of semipermeable membrane with equal flow rates
Answer: A

29. A solution of acetone in ethnol
A. behaves like a near ideal solution
B. obeys Raoult's law
C. shows a negative deviation from Raoul'ts law
D. shows a positive deviation from Raoult's law
Answer: D
30. A 5 % solution (by mass) of cane sugar in water has freezing point of
271 K. Calculate the freezing point of a 5% glucose (by mass) in water. The
freezing point of pure water is 273.15 K.
A. 271K
B. 273.15K
C. 269.07K
D. 277.23K
Answer: C
31. Concentrated aqueous sulphuric acid is 98 % H2 SO4 by mass and has
a density of 1.80gmL
−1
. Volume of acid required to make one litre of
0.1M H2 SO4 solution is:
A. 5.55mL
B. 11.10mL
C. 16.65mL
D. 22.20mL
Answer: A

32. 0.5 molar aqueous solution of a weak acid (HX) is 20% ionised. If Kf
for water is 1.86Kkgmol

−1
, the lowering in freezing point of the
solution is
A. − 0.56K
B. − 1.12K
C. 0.56K
D. 1.12K
Answer: D
33. The density (in g mL

−1
) of a 3.60M sulphuric acid solution that is
29 % H2 SO4 (Molar mass = 98gmol

−1
) by mass will be
A. 1.45
B. 1.04
C. 1.88
D. 1.22
Answer: D
34. A 5.25 % solution of a substance is isotonic with a 1.5 % solution of
urea (molar mass = 60gmol

−1
) in the same solvent. If the densities of
both the solutions are assumed to be equal to 1.0gcm

−3
, molar mass of
the substance will be:
A. 210.0gmol −1
B. 90.0gmol −1
C. 115.0gmol −1
D. 105.0
Answer: A
35. When 20g of naphtholic acid (C11 H8 O2 ) is dissolved in 50g of
benzene (Kf = 1.72Kkgmol

−1
) a freezing point depression of 2K is
observed. The van'f Hoff factor (i) is
A. 0.5
B. 1
C. 2
D. 3
Answer: A
36. At 80 ∘
C , the vapour pressure of pure liquid 'A' is 520 mm Hg and that
of pure liquid 'B' is 1000 mm Hg. If a mixture solution of A and B boil at

80
∘
C and 1 atm pressure, than the amount of A in the mixture is (! Atm
= 760mmH g)
A. 48 mol percent
B. 50 mol percent
C. 52 mol percent
D. 34 mol percent
Answer: B
37. The vapour pressure of water at 20

∘
is 17.5mmH g . If 18g of glucose
(C6 H12 O6 ) is added to 178.2g of water at 20

∘
C , the vapour pressure of
the resulting solution will be
A. 16.500mmH g
B. 17.325mmH g
C. 17.675mmH g
D. 15.750mmH g
Answer: B
38. 0.002m aqueous solution of an ionic compound Co(N H3 ) (N O2 )CI

5
freezes at − 0.00732
∘
C .Number of moles of ions which 1 mole of ionic
compound produces in water will be (K f

= 1.86
∘
C / m)
A. 1
B. 2
C. 3
D. 4
Answer: B

39. A binary liquid solution is prepared by mixing n-heptane and ethanol.
Which one of the following statements is correct regarding the behaviour
of the solution ?
A. The solution formed is non-ideal.
B. The solution is non-ideal showing positive deviations from Raoult's
law
C. The solution is non-ideal showing negative deviations from Raoult's
law.
D. n-heptane shows positive while ethanol shows negative deviations
from Raoult's law.
Answer: B
40. The Henry's law constant for the solubility of N gas in water at 298K
2
is 5
1.0 × 10 atm . The mole fraction of N2 in air is . The number of
0.8
moles of N from air dissolved in
2
10 moles of water at 298K and 5atm .
Pressure is:
A. 4 × 10 −4
B. 4.0 × 10 −5
C. 5 × 10 −4
D. 4.0 × 10 −6
Answer: A
41. An aqueous solution is 1.00 molal in KI . Which change will cause the
vapor pressure of the solution to increase?
A. addition of N a 2
SO4
B. addition of 1.00 molal KI
C. addition of water
D. addition of NaCI
Answer: C
42. A solution of sucrose (molar mass = 342gmol

−1
) has been prepared
by dissolving 68.5g of sucrose in 1000g of water. The freezing point of the
solution obtained will be: (K for water

f
= 1.86Kkgmol
−1
)
A. − 0.520 ∘
C
B. + 0.372 ∘
C
C. − 0.570 ∘
C
D. − 0.372 ∘
C
Answer: D

43. The degree of dissociation (α) of a weak electrolyte A x By is related
to van't Hoff factor (i) by the expression
i − 1
A. α =
x + y + 1
x + y − 1
B. α =
i − 1
x + y + 1
C. α =
i − 1
i − 1
D. α =
x + y − 1
Answer: D
44. Ethylene glycol is used as an antifreeze in a cold climate. Mass of
ethylene glycol which should be added to 4 kg of water to prevent it from
freezing at −6
∘
C will be (Kf for water = 1.86Kkgmol
−1
, and molar
mass of ethylene glycol = 62gmol

−1
)
A. 204.30g
B. 400.08g
C. 304.60g
D. 804.32g
Answer: D
45. A 5.2 molal aqueous of methyl alcohol, CH 3

OH , is supplied. What is
the molefraction of methyl alcohol in the solution ?
A. 0.190
B. 0.080
C. 0.050
D. 0.100
Answer: D

46. The freezing point depression constant for water is 1.86
∘
Cm
−1
. If
5.00gN a2 SO4 is dissolved in 45.0H2 O , the freezing point is charged by
− 3.82
∘
C . Calculate the van't Hoff factor for N a 2
SO4 .
A. 3.11
B. 0.381
C. 2.05
D. 2.61
Answer: D
47. Dissolving 120g of urea (mol wt = 60) in 1000g of water gave a
solution of density 1.15 g/mL. The molarity of the solution is
A. 1.78M
B. 2.00M
C. 2.05M
D. 2.22M
Answer: C
Paragraph 1
1. A solution M is prepared by mixing ethanol and water. The mole
fraction of ethanol in the mixture is 0.9
Given: Freezing point depression constant of water
water −1
(K = 1.86Kkgmol )
f
Freezing point depression constant to ethanol
ethanol −1
(K ) = 2.0Kkgmol )
f
Boiling point elevation constant of water
water −1
(K ) = 0.52Kkgmol )
b
Boiling point elevation constant of ethanol

ethanol −1
(K ) = 1.2Kkgmol )
b
Standard freezing point of water = 273K
Standard freezing point of ethanol = 155.7K
Standard boiling point of water = 373K
Standard boiling point of ethanol = 351.5K
Vapour pressure of pure water =32.8mmH g
Vapour pressure of pure ethanol =40mmH g
Molecular weight of water =18gmol −1
Molecular weight of ethanol =46gmol −1
In anwering the following questions consider the solutions to be ideal
dilute solutions and solutes to be non-volatile and non-dissociative.
The freezing point of the solution M is
A. 268.7K
B. 268.5K
C. 234.2K
D. 150.9K
Answer: D
Paragraph 2
1. In the case of immiscible liquids, the addition of one liquid to another
does not after the properties of either liquid. Hence liquid exerts its own
vapour pressure independently of the pressure of the other. Since boiling
point of any system is the temperature at which its total vapour pressure
becomes equal to the prevailing pressure, so by knowing the miscibility of
two liquids, we can find out boiling temperature.
If we mix two immiscible liquids A and B then boiling point of the mixture
will be (Given p
A
∘
> p
B
∘
)
A. greater than T and lower than T

B A
B. greater than either of T and T A B
C. lower than T and higher than T

B A
D. lower than either of T and T A B

Answer: D
View Text Solution
Paragraph
water −1
(K = 1.86Kkgmol )
f
ethanol −1
(K ) = 2.0Kkgmol )
f
water −1
(K ) = 0.52Kkgmol )
b
ethanol −1
(K ) = 1.2Kkgmol )
b

The vapour pressure of the solution M is
A. 39.3mmH g
B. 36.0mmH g
C. 29.5mmH g
D. 28.8mmH g
Answer: B

water −1
(K = 1.86Kkgmol )
f
ethanol −1
(K ) = 2.0Kkgmol )
f
water −1
(K ) = 0.52Kkgmol )
b
ethanol −1
(K ) = 1.2Kkgmol )
b

Water is added to the solution M such that the mole fraction of water in
the solution becomes 0.9. The boiling point of this solution is
A. 380.4K
B. 376.2K
C. 375.5K
D. 354.7K
Answer: B

In which of the following mixtures, vapour pressure of each component is
independent of the amount of the other components?
A. Mixture of water and aniline
B. Mixture of toluene and benzene
C. Mixture of water and sulphuric acid
D. Mixture of N2
(g) and O 2
(g)
Answer: A
View Text Solution

If the vapour pressure of two liquids X and Y in their pure state at 300K
are 85 mm of Hg and 120 mm of Hg respectively and if their mole fraction
in liquid solution are 0.45 and .55 respectivel. Then find out the total
vapour pressure above the mixture containing two immiscible liquids at
300 K.
A. 104.25mm of Hg
B. 205mm of Hg
C. 27.75mm of hg
D. 35 mm of Hg
Answer: B
View Text Solution
In question 6, if we decrease the amount of liquid X in the mixture then
what will be the effect on the boiling point of the mixture at constant
temperature?
A. It will remain constant
B. Decrease
C. Increases
D. Can't predict
Answer: A
View Text Solution
An immiscible mixture of water and quinoline is prepared and distillation
is done. If p
∘
quinoline
= 7.9 torr and p
∘
water
= 732.04 torr at the boiling
point of 98.9
∘
C . Find out the relative masses of water and quinoline in
the distillate. If it is given that no of moles of any component in the
vapour phase ∝ its vapour pressure. (Molar mass of water = 18 g/mol
and molar mass of quinoline = 129g / mol )
A. W water
: Wquinoline : : 13 : 1
B. W water
C. W water
D. W Water
: Wquinoline : : 7.1 : 1
Answer: A
View Text Solution
Matrix Match Type Mcqs

1. Here each question contains statements given in two columns which
have to be matched. Statement in Column I are labelled as A,B, C are D
whereas statements in column II are labelled as p,q,r and s. the answers
to these questions are to be appropriately bubbled as illustrated in the
following example. If the correct matches are A-p, A-s, B-q, B-r, C-p, C-q and
D-p then the correctly labelled 4 × 4 matrix look like.
ColumnI ColumnII
(A)Molality (p)Elevation on boiling point
(B)Molarity (q)Volume of solution
(C)Normality (r)Wt of solvent
(D)Mole fraction (s)Moles of solute
View Text Solution

2. Here each question contains statements given in two columns which
have to be matched. Statement in Column I are labelled as A,B, C are D
whereas statements in column II are labelled as p,q,r and s. the answers
to these questions are to be appropriately bubbled as illustrated in the
following example. If the correct matches are A-p, A-s, B-q, B-r, C-p, C-q and
D-p then the correctly labelled 4 × 4 matrix look like.
ColumnI ColumnII
(A)Elevation in boiling point (p)Colligative property
(B)Osmotic pressure (q)Cryoscopic constant
(C)Relative lowering in vapour pressure (r)Berkely-Hartley method
(D)Depression in freezing point (s)Ostwald and Walker method

View Text Solution
Integer Type Questions
1. 29.2 % (w / w)H Cl stock, solution has a density of 1.25gmL

−1
. The
molecular weight of H Cl is 36.5gmol

−1
. The volume (mL) of stock
solution required to prepare a 200mL solution of 0.4M H Cl is :
2. Osmotic pressure of a solution obtained by mixing 100mL of 1.4%
solution of urea (mol mass = 60) and 100mL of 3.42 % of cane sugar
solution (mol mass = 342) at 20 ∘

C(R = 0.0821LatmK
−1
mol
−1
)

3. The molality of a sulphuric acid in which the mole fraction of water is
0.86 is.........
4. It potassium ferrocyanide is 75% ionized in the solution, its van't Hofff
factor is.....
Reason Assertion Type
1. Assertion: A solution which contains one gram equivalent of solute per
litre of solution is known as molar solution.

Mol.wt .of solute
Reason : Normality = Molarity ×
Eq.wt.of solute
A. Both A and R are true and R is the correct explanation of A
B. Both A and R are true but R is not a correct explanation of A

C. A is true but R is false
D. A is false but R is true
Answer: D
2. Assertion : The molality of the solution does not change with change in
tempc- nature.
: The molality is expressed in units of moles per 1000 g of solvent. Reason
Answer: A

3. Assertion: Boiling point of rectified spirit is 78.15 ∘
C .
Reason: Ethyl alcohol and water form non ideal solution with negative
deviation.
Answer: C
4. Assertion: ΔH mix
and ΔV mix
for an ideal solution is zero
Reason: A........B interactions in an ideal solution are same as between
A......A and B.......B.

Answer: A
5. Assertion: Among the equimolecular solutions of urea, KCI and K 2

SO4 ,
the solution of urea shows lowest osmotic pressure.
Reason: Urea is non-electrolyte while KCI and K 2

SO4 are electrolytes.
Answer: A
6. Assertion: Observed molecular mass of NaCI as determined by any
colligative method is less than 58.5.
Reason: NaCI gets ionised in water as it is a strong electrolyte.
Answer: A
7. Assertion: Van't Hoff' s factor for benzoic acid is less than one.
Reason: Benzoic acid behaves as a weak electrolyte in benzene.

Answer: C
View Text Solution
8. Assertion: Molecular mass of a polymer is usually determined by
osmotic pressure.
Reason: This method measure more accurately the molecular mass of a
polymer than by any other colligative property.

Answer: A
9. Assertion: A solution contains one gram equivalent of solute per litre
of the solution is called a normal solution.
Reason: A normal solution means a solution in which the solute does not
associate or dissociate.
Answer: C

10. Assertion: The sum of mol fractions of all the components of a
solution is unity.
Reason: Mole fraction is temperature dependent mode of concentrations.
Answer: C
11. Assertion: Iodine is more soluble in CCI than in water.

4
Reason: None-polar solutes are more soluble in non-polar solvents.

Answer: A
12. Assertion: Addition of 1,2-ethanediol to water lowers its freezing point.
Reason: 1,2-Ethanediol is insoluble in water due to lack of its ability to
form H-bonds with water molecules.
Answer: C
View Text Solution

13. Assertion: If solutions of sugar, urea, glucose in water are prepared by
dissolving one mole of each of the solute in 1000g of water, they will
show identical lowering of vapour pressure.
Reason: Colligative properties depend entirely on the number of particles
of solute present in solution and not on the nature of solute.
Answer: A
14. Assertion: If solutions of sugar and sodium chloride are prepared by
dissolving one mole of each of the solute in 1000g of water they will show
different lowering in freezing point.
Reason: The colligative properties depend on the nature of the solute.
Answer: C
View Text Solution
15. Assertion: Isotonic solutions must have the same molar
concentrations.
Reason: Solution which have the same osmotic pressure at the same
temperature are known as isotonic solutions.

Answer: A
16. Assertion: Osmotic pressure is a colligative property.
Reason: Osmotic pressure of a solution at any temperature T depends on
the molar concentration.
Answer: A

17. Assertion: Lowering in vapour pressure is not a colligative property.
Reason: Lowering of vapour pressure of a solvent depends on the
number of moles of the solute dissolved in given amount of the solvent
at a given temperature.
Answer: D
18. Assertion: Dilute solutions are taken as ideal solutions.
Reason: The solutions which follow the Raoult's law at any temperature
and concentration are known as ideal solution.Most of the solution show
the deviation from Raoult's law.
Answer: A
19. Assertion: Boiling point elevation is a colligative property.
Reason: Boiling poing elevation in a dilute solution is directly
proportional to the molar concentration of the solute in a given solvent
and is independent of the nature of the solute.

Answer: A
20. Assertion: The molecular weight of benzoic acid when dissolved in
benzene is found to be higher than the theoretically calculated molecular
weight from formula.
Reason: Many organic solutes when dissolved in non-aqueous solvents
undergo dissociation.
Answer: C
View Text Solution
21. Assertion: Isotonic solutions do not show phenomenon of osmosis.
Reason: Isotonic solutions have equal osmotic pressure.
Answer: B
Ultimate Preparatory Package
1. The temperature at which molarity of pure water is equal to its molality

A. 273K
B. 298K
C. 277K
D. none of these
Answer: C
2. Some pure ice is put in brine taken in a perfect insulated container at
0
∘
C . The mass of ice
A. will not change with time
B. will increase with time
C. will increase with time
D. will first increase than decrease with time
Answer: C
3. For the dissolution of an ionic solid in water
A. hydration energy should be more than lattice energy
B. lattice energy should be more than hydration energy
C. lattice energy should be equal to hydration energy
D. none of these
Answer: D
View Text Solution
4. A 1m solution can be more concentrated than a 1M solution if
A. density of solvent is more than 1
B. density of solvent is equal to 1
C. density of solvent is less than 1

D. it is never possible
Answer: A
View Text Solution
5. A substance is hygroscopic at a constant temperature if vapour
pressure of its saturated solution is
A. more than the vapour pressure of water in the atmosphere
B. equal to the vapour pressure of water in the atmosphere
C. less than the vapour pressure of water in the atmosphere
D. None of these
Answer: C
View Text Solution

6. A substance is efflorescent at a particular level if its vapour pressure is
A. more than that of water vapour in the atmosphere
B. equal to that of water vapour in the atmosphere
C. less than that of water vapour in the atmosphere
D. None of these
Answer: A
View Text Solution
7. The beakers A and B containing pure water (A) and an aqueous solution
of sugar (B) are placed in a closed glass container. The temperature of the
container is kept constant. It is observed that
A. level of water in beaker A decreases and that in beaker B increases
with time
B. level of water in beakers A and B remains constant with time

C. level of water in beaker A increases and that in beaker B decreases
with time
D. level of both the beakers decreases with time
Answer: A
8. A Beckmann thermometer is used to measure
A. low temperatures
B. high temperatures
C. normal temperatures
D. None of these
Answer: D
View Text Solution

9. Some common salt is added to ice taken in a flask kept at 0
∘
C . With
time
A. there is no change in the mass of the ice
B. mass of ice decreases
C. vapour pressure in the flask increases
D. none of these
Answer: B
View Text Solution
10. Calculate the freezing point of an aqueous soltuion of non-electrolyte
having an osmotic pressure 2.0atm at 300K . (K' f

= 1.86Kmol
−1
kg
and S = 0.0821 litre atm K −1

mol
−1
)
A. − 0.15 ∘
C
B. + 0.15 ∘
C
C. − 0.51 ∘
C
D. − 0.17 ∘
C
Answer: A

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CHEMISTRY

BOOKS - S DINESH & CO CHEMISTRY (HINGLISH)

Multiple Choice Questions

1. Which of the following is not a characteristic property of the polar

A. They have high boiling points

B. They have high heat of evaporation

C. They have low viscosity

D. They have low vapour pressure

2. In liquid CCI , which of the following has maximum solubility?

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ions with H2 O molecules as the ligands. It can also be regarded as a

A. solution of solid in a liquid

C. salt of CuSO and water

D. co-ordination compound of copper sulphate with water molecules

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those independent of temperature are:

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6. Two bottles A and B contain M and

sulphuric acid respectively

A. A is more concentrated than B

B. B is more concentrated than A

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7. One among the following is an incorrect statement

A. Normality of 0.5M aqueous solution of H 2

B. Molality of a solution relates moles of solute and mass of solvent

C. Molality of a solution is dependent on the temperature

D. Molarity of a solution is dependent on the temperature

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solution (d) and molar mass (M 2

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9. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with

250 mL of 2 M HCl will be

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vapour phase. Which of the following plot should be linear?

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A. a volatile solute in concentrated solution

C. a non-volatile solute in a dilute solution

D. a non-electrolyte in a concentrated solution

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12. A substance will be deliquescent if its vapour pressure is:

A. is equal to the atmospheric pressure

B. is equal to that of water vapour in air

C. is less than that of water vapour in air

D. is greater than that of water vapour in air

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13. If to a solvent (vapour pressure = p

solute are dissolved then the vapour pressure of the solution p is

D. None of the above

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14. The relative lowering in vapour pressure is:

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15. The lowering of vapour pressure of the solvent takes place on

dissolving a non-volatile solute because

A. the density of the solution increases

B. the surface tension of the solution decreases

C. the molecules of the solvent on the surface are replaced by the

molecules of the solute

D. the mole fraction of solvent is less than 1

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ideal binary liquid solution?

A. Plot of p versus x (mole fraction of A in liquid phase) is linear

B. Plot of p versus x is linear