.

Xinh CN NooH
-

NasH-> pha long nap buret chian I han

(
-

Lich Thi dien chink - Chron do lai

-

Ne ro thi cher
nem
trong khung 3-4 lin = En is t chink ar as (3-4 CSCN 4)
-

· Tam 2 lan v Cn -0 1N , ,
che var
thing chia ro dem chuan chink xar

· CN < 0 099 ,
: UD : 0 09 ,
/bat 500 mL)
0,09 500
- Tink lai C Nattah : Co =
.

Vo
- V
lay bot

-
Tink Hoan : Co .
U, + 0 09
. , Us = 0 1 ,
. 500 >
-
U can them

↳ e batm
big vidie o
Virange Uchuan do Her <500 Chem V che
( deng
-
,

Chan di
Vi va Ve sas che lay 1

·
EN 0, 109 : UD 0, 11 N

- Tink Foan : 0 11.

. . Uz =
01 ,
/Ve + Unc) >
-

Unc

PTCA :
H2GOg + 204- >
-
Ge Mel

> the chan ma mas

·

plaz-pkan = 4, 27-1 , 23 =
3 02 (4
,
-

rieng 1 va

Akad :
pho +plo s
+
pP+ = 4, 27 + 1, 310, 3 = 5 , 87 <8 - Cr the chien do chink xc
ng 2 mas voi do chink x > 99, 9 %

· F =
1, 999 : [HS2G] = 0, 1 % CoPF = 2 3 , .
10 M ; [G8n] = 99, 9 % CoDF = 2 , 3 18 M
.

2, 3 10
pH 4
, 27 by
.

>
-

= + =
7, 27

25
, ,
10:5

367
·
F = 2 , 000 : [CrO9") = Co .
DF =
0 825 M
,
-
> [OH) =
↓189179 .
0 025
.
=
18- p

>
-

pH = 14 -
le [8H = 8 33,

·
F = 2 , 001 : [CrO9] = Co .
DF =
0 825 M
, ;
[OU) = 0, 1 % CoDF = 2, 5 .
18" na

>
-

pH = 14
le [8H = 9 98,

>
-
KBN : 7 , 27 -

9 48
,

Chi thi
hong
n
-
:
Phenolphtalin loai 8, 1 % (pT = 9 01,
-

8 man >
-

18PT
14
189-14
And on =e
-

·
Sai so chi Thi :
1
&
+ 100 = e
1
= 0 020 %
,
,

I
CoPE
2 0 03
. .

Ding chan to khi hong: mat

· del
Chuyer t man
lang
man bin
trong
30s

*
Xinh nong to H2804
- PTCA :
Hefte + 201 >
-
800 - He

·
Alect :
pKaz +
phot PDF = 1, 92 1, 31 0 3 ,
= 3 3 (8
,
-
> the chean do mai 2 chink as him 99, 9 %

· F =
1, 999 : [H80G] = 0, 1 % CoPF = 2 3 , .
10 M ; [S8n] = 99, 9 % CoDF = 2 , 9 18 M ,

>
-

pH =
1 , 9
by 999%
83
·
F = 2 , 000 : [SO9 ) = Co .
DF = 0 825 M
,
-
> [OH) = ↓18721 .
0 015
.
=
18-6 .

pa

>
-

pH = 14
le [8H = 7, 19

·
F = 2 , 001 : [SO9 ] = Co .
DF =
0 825 M
, ; [OU) = 0, 1 % CoDF = 2, 3 .
18" na

pH = 14
ly [8H] = 9 98,

>
- KBN : 4 90 ,
-

9 , 40
 - Chi Thi :

-
pT = 5 1 ,
(oto who >
- rank luc
'PT
An UsOG -1104
1 10
·
Sai so chi thi : = - < 100 = = -0 , 03: o
,
2
Kaz

Ring cheer khi man de

chuyin T d nhe sang and luc
~
Phenolphtalin 0 1%,
-

pT = 9/ man-hing
18PT-14 +1 189-19
·
Sai so hi Thi And on- :
,
= =
1
&
x 100 = = + 0, 020 %

I
CoPE
2 0 03
. .

Ding chan to khi hong: mat

· del
Chuyer t man
lang
man bin
trong
30s

-
pT = 9, 9
/vang >
-
Tim
14
180T 1899-19
-

Thi And on =e
1 1
·
sai so hi : &
+ 100 = e =
+ 0 16 %
,
,
I
CoPE
2 0 03 . .

Dung chan do khi i man Tim

· del
Chuyer vang rang

* Xink HzPOs /Gri 0 1 M)

,

Co the chan chink as him

·
Pkac-pKas = 7 , 21-2 , 12 = 5, 89)4 >
-

to rieng mas 1 99 %

·
pkas-pkan = 7 , 21-2 , 12 = 5, 0934 va pkas-pkan =
12 , 33 - 7, 21 = 5, 214

Co the chron chink as him

>
-

to rivg mas 1 99 %

Xet chuan den nic 1:

-
PTCA : HyPOn < OH-
>
MePOn - M2N

-
Abeot : pKantpC + pPF = 2 12,
+ 1 + 0, = 3 43
,
<8 - The chuan do n 1 hink xo him 99, 9 %

.
F = 0, 99 : [HyPOg] = 1% CoDF ; [HzPOn] = 99 % CoDE
99 %
/1 %
>
-

pH = 2 12
,
by = 4 12
,

F 1 88 [HuPOn] CoME >

pH
112 12 + 7 21) 4, 67
-

= : = = , =
· , ,

·
F : 1 01 , : [H2POG] = CoPF ; [HPOG] = 1 % CoPF

>
-

pH =
7, 21 +
by (1 %) = 5 21,

>
-
KBN : 4, 12 -

5, 21

- Chi thi :
pT = 5, 1 /its who >
-

rank luc -

1jtill
·
Sai so che thi : An ,
Pg2- = f
Kaz
x 100 = e x 100 = 0 78 %
,

18-PT 10-5 ,
1

Ring cheer khi man de

chuyin T d nhe sang and luc
Xet chuan den nic 2 :

-
PTCA : MyPOn - IOH- >
-

MPOY - Me

-
Abeot : pKan T pC + pPF = 7, 21 + 1 + 0, 48 = 8, 69 < 10 >
-
The chian to we 1 hink xe him 99 %

.
F = 1 , 99 : [H2POGT = 1% CoDF ; [HBOY] = 99 % CoDE

>
-

pH = 7, 21
ly 99 = 9 21,

F 2 88 [HPOP] CoMF >

pH
1 (7 21 + 12, 33) = 9 77
-

= : = = ,
· , ,

·
F = 2 01 , : [MPOG" ] = CoDE ; [POY] = 1 % CoPF

>
-

pH = 22 , 33 +
ly) 1 %) = 10, 33

>
- KBN : 9 21,
-
10, 33
 -

Chi thi :
pT = 99 ,
(vang >
-
Tim
-
12 , 33
10
Thi And on =e
sai so hi
1 Kaz x 100
1
x 100 + 0 19 %
· : - I = ,

,
2
18-PT 2
10-9 9 ,

Dung chan do khi i man Tim

·
del
Chuyer vang rang

* Xatinh Ch HeSOn - HyPOn

Preet : 11 mas HyPOn) H28Og - 20H- - SO e 2He

MyPOg - OU >
-
H2POn - Huf

12 mac H3POn H28Oo - 28H- - SO e 2He

MyPOg - OU >
-
H2POn - Huf

(2Va- Vp) Naon

Un Va Utb
Us Comason
.

... = =... IS
CrMS0Nation) ...

(Val 2Ukh
pT = E1
,

(Vb-Va) Nash
pT 99 (Up Conpapog CMMPouldin)"
.

=
, = .... =

Val

* Xdtinl %N
-

NNaon 14 , 0067 TNaOHIN UNaon

:

Un Ve Us Ut YoN
.

...

TNaOH/N = : - 100

1000 Upipet
Phenolphtalein

* Chian do hom hep NazC8s + NatCO, (Fory Con = 0 TM)

.

-
Pico : CO; + IH" <
H2CO, >
-
HO e CO2

HCO;- H >
HeCOs -Hat e
CO2
3, 98
·
F = 1 , 99 : THCO; ] = 1% CoPF = 10- pa ; TH2COs) be =
0, 001 M
, 48
18-3
>
-

pH =
6 33 4
,
by = 5, 87
, 001
0

68
·
F = 2, 00 :
TH2COs]bh =
0, 081M >
-
THY] = Kan THeCOs]
.
=
189 ,

pa

>
-

pH = 4, 68

-
3, 48
·
F= 2 01 , : [H, CO, ] ph = 0 801M
, ;
[H2) = 1 % CoDF = 18 pa

-
>
pH = 3, 48

>
-
KBN : 5, 87 -

3, 48