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Module
Introductory Concepts,
Unit 1 - Introduction 1
Definitions and Units
Learning Objectives
Thermodynamics focuses on phase, phase equilibria and the three laws.
These topics are came from the books written by the people who played an
important role in the development of thermodynamics, including Robert Boyle, Sadi
Carnot, Charles Cagniard de la Tour, Émile Clapeyron, Julius Robert von Mayer,
Hermann von Helmholtz, Rudolf Clausius, William Thomson (Lord Kelvin), Thomas
Andrews, James Clerk Maxwell, Josiah Willard Gibbs, Johannes Diderik van der
Waals, François-Marie Raoult, Émile-Hilaire Amagat, and Walter Nernst.
The Physics of Heat
In a substance also known as thermodynamics, focuses largely on how a heat
transfer is related to various energy changes within a physical system undergoing a
thermodynamic process. Such processes usually result in work being done by the
system and are guided by the laws of thermodynamics.
Upon reading this chapter, you are able to gain understanding regarding to
the following: Basic concepts of Thermodynamics, Basic definitions and units used,
Archimedes Principle, Pressure and its scale and lastly, the Temperature.
From this module you are expected to:
Recognize terms associated with thermodynamics.
Describe basic concepts of thermodynamics.
Identify the properties of a system.
Fully understand the concepts of temperature.
Familiarize yourself with the following terminologies. They will be useful as you go
through the module.
Thermodynamics - Is the study of energy, its transformation, and its
relation to its matter. It is also defined as the science of energy.
Energy - Is the ability causes changes. It can be categorized into either
stored or transient form.
Length - Measures distance between objects.
Lesson 1 - Introcution
Every science has its own vocabulary associated with it. Precise definition of
basic concepts and prevent possible misunderstanding careful study of this concept
is essential for a good understanding of topics in thermodynamics.
The study of changes in energy associated with physical and chemical
reaction is called as thermodynamics. In general, it is the study of effect of work,
heat and energy on a system.
place to another and from one form to another. The key concept is that heat is a
form of energy corresponding to a definite amount of mechanical work.
This is the science of energy, including energy storage and energy in transit.
The Conservation of Energy Principle states that energy cannot be created or
destroyed, but can only change its form. The three forms of energy storage of
greatest interest to us are Potential Energy (PE), Kinetic Energy (KE), and Internal
Energy (U), which we introduce below. The two The two forms of energy in transit
that we consider are Work (W) and Heat (Q), and the interactions between these
various forms of energy are defined in terms of the First Law of Thermodynamics.
It is included in the field of physics that deals with the relationship between
heat and other properties (such as pressure, density, temperature, etc.) in a
substance. Specifically, thermodynamics focuses largely on how a heat transfer is
related to various energy changes within a physical system undergoing a
thermodynamic process. Such processes usually result in work being done by the
system and are guided by the laws of thermodynamics.
In simplest term, thermodynamics is the science of energy. it includes energy
storage and energy in transit. The Conservation of Energy Principle states that
energy cannot be created or destroyed, but can only change its form. The three
forms of energy storage of greatest interest to us are Potential Energy (PE),
Kinetic Energy (KE), and Internal Energy (U), which we introduce below. The
two forms of energy in transit that we consider are Work (W) and Heat (Q), and the
interactions between these various forms of energy are defined in terms of the First
Law of Thermodynamics.
The analysis of thermal systems is achieved through the application of the
governing conservation equations, namely Conservation of Mass, Conservation
of Energy (1st law of thermodynamics), the 2nd law of thermodynamics
and the property relations. Energy can be viewed as the ability to cause changes.
SYSTEM UNIT USED
There are two widely used systems of units: the International System
(or Systeme International d'Unites in French), S.I.; and the English System.
The base units in the S.I. system are meters (m) for length, second (s) for
time, and kilogram (kg) for mass. The force unit is derived using Newton's 2nd Law:
F = ma = 1 kg (1 m/s2) = 1 kg m/s2 = 1 N
The base units in the English system are foot (ft) for length, second (s) for
time, and pound-force (lbf) for force. The mass unit is derived using Newton's 2nd
Law:
m = F/a = 1 lb/(ft/s2) = 1 lb s2/ft
= 1 slug = 32.174 lbm
Source:https://thermo.pressbooks.com/chapter/chapter-1/
Source: https://studylib.net/doc/10689191/measures--english--metric--and-equivalents-
Source: https://studylib.net/doc/10689191/measures--english--metric--and-equivalents-
SAMPLE PROBLEM
Example 1: A car's speedometer doesn't measure feet per second, so I'll have to
convert to some other measurement. I choose "miles per hour". I know the
following conversions: 1 minute = 60 seconds, 60 minutes = 1 hour,
and 5280 feet = 1 mile.
Example 2: They gave me something with "feet" on top so, in my "5280 feet to 1
mile" conversion factor, I'll need to put the "feet" underneath so as to cancel with
what they gave me, which will force the "mile" up top. This is right where I
wanted it, so I'm golden.
Self Check - 1
= =
=
K is proportionally constant.
Acceleration
∆
=
SAMPLE PROBLEM
1. Suppose you’re driving 90.0 kilometers an hour and suddenly see red flashing
lights in the rearview mirror. You pull over, taking 20.0 seconds to come to a
stop. What was your average acceleration, in m/sec2?
1 ℎ
Solution: 90 × × 1
= 0.025
60 60
1000
0.025 × = 25
1
The mass of the body is the absolute quantity of matter in it. The weight
means the force of the gravity on the body.
To find an object’s mass using its weight, the formula is Mass equals Weight
divided by the Acceleration of Gravity (M = W ÷ G).
Units: Because mass and weight are separate quantities, they have different
units of measure. In the International System of Units (SI), the kilogram is the
basic unit of mass, and the newton is the basic unit of force. The non-SI
kilogram-force is also a unit of force typically used in the measure of weight.
How to find: To convert between mass and weight, you use the value for
gravitational acceleration g = 9.81 meters per second squared. To calculate
the weight, W, in Newton, you multiply the mass, m, in kilograms times g: W =
mg. To get mass from weight, you divide the weight by g: m = W/g.
SAMPLE PROBLEM:
Solution: 8.5
9.8
= 0.87
2
Volume of Solids
The volume of a solid is the number of unit cubes it takes to fill up the solid.
Cube = ℎ × ℎ × ℎ ℎ
Example:
v= l× × ℎ
v= 6 × 4 × 7 = 168 3
Circular Cylinder = 2
ℎ
= 3.1416
= ÷ 2
Example:
= 2
ℎ
= 3.1416 × 4 2
×10
= 502.66 3
Cone = 1 2
ℎ
3
Example: = 1 2ℎ
3
Prism = 1
2
ℎ
Example: 1
ℎ
2
3
=
1
= × 4 × 6 × 12 = 144
2
Sphere = 4 3
3
Example:
4 3
=
3
4
= × 3.1416 × 53 = 5236.6 3
3
This principle, also known as the law of hydrostatics, applies to both float and
submerged bodies, and to all fluids.
= 2
− 1
= .2 − (.1 )
= .2 − .1
Where: y= unit weight of fluid, VD = volume displayed or volume of the body below
the liquid surface.
= =
If the body of height H has a constant horizontal cross-sectional area such as vertical
cylinders, blocks etc.
= =
If the body is of uniform vertical cross-sectional area A, the area submerged Asis:
= =
Self Check - 2
Lesson 4 - Pressure
PRESSURE
The amount of force exerted (thrust) on a surface per unit area is defined as
‘Pressure’. It can also be defined as the ratio of the force to the area (over which the
force is acting).
P=F/A
Types of pressure
= ℎ
Thermodynamic system
HETEROGENEOUS SYSTEM - The system that has more than one phase i.e. the
combination of solid, liquid and gaseous state.
Example: Mixture of ice and water, Water plus gasoline, Wet steam
(Vapors in contact with liquid being evaporated)
Mass and Weight- the mass (m) of a body is the measure of the amount of material
present in that body. The weight (wt.) of a body is the force exerted by that body
when its mass is accelerated in a gravitational field.
wt. = mg/g
where:
TYPES OF PROPERTIES
DENSITY is the mass per unit volume. It is a measure of the size of the
molecules and how closely the molecules are spaced in a material.
= = =
. . =
Volume
Cube = ℎ × ℎ × ℎ ℎ
Circular Cylinder = ℎ
2
Cone = 1 2ℎ
3
Prism = 1
ℎ
2
Sphere = 4 3
3
Temperature Scale
℉ − 32
℉ → ℃ =
1.8
℃ → ℉ = 1.8 × ℃ + 32
= ℃ + 273
= ℉ + 459.67
Lesson 5 - Temperature
Fahrenheit is a temperature scale that bases the boiling point of water at 212 and
the freezing point at 32. It was developed by Daniel Gabriel Fahrenheit, a German-
born scientist who lived and worked primarily in the Netherlands. Today, the scale is
used primarily in the United States and some Caribbean countries. The rest of the
world uses the Celsius scale.
Kelvin temperature scale was the brainchild of Belfast-born British inventor and
scientist William Thomson — also known as Lord Kelvin. It is one of the three best-
known scales used to measure temperature, along with Fahrenheit and Celsius.Like
other temperature scales, the freezing and boiling points of water are factors in
establishing the scale’s range. There are 100 degrees between the temperate at
which water freezes at (273.16 K) and boils (373.16 K).Each unit on this scale, called
a Kelvin rather than a degree, is equal to a degree on the Celsius scale. For this
reason, just the K, not the degree symbol, is used when reporting temperatures in
Kelvin. There are no negative numbers on the Kelvin scale, as the lowest number is
0 K.
℉ − 32
℉ → ℃ =
1.8
℃ → ℉ = 1.8 × ℃ + 32
= ℃ + 273
= ℉ + 459.67
The zeroth law of thermodynamics states that “when two bodies are in
thermal equilibrium with a third body, they are in thermal equilibrium with each other
and hence are at the same temperature”. Consider two blocks of materials, say, iron;
if these two blocks are brought together and there is no change in any observable
property, then the two blocks are said to be in thermal equilibrium and their
temperatures are the same.
Self Check- 4
1. 34.80°C to °F and K
2. 113 °F to °C and K
3. Convert -40 °C to °F and °R
4. 1752 °R to °C and K
5. 373 K to °F and °R
Lesson 5 - Temperature
Lets Summarized!
Self-Assessment Questions
a) Heat
b) Work
c) internal energy
d) boundary energy
12. It is the science of the relationship between heat, work, temperature and energy.
a) Law of Conservation of Energy
b) Gas Law
c) Fluid Static
d) Thermodynamics
13. This Law of Thermodynamics states that “Heat does not flow spontaneously
from a colder region to a hotter region, or, equivalently, heat at a given
temperature cannot be converted entirely into work. What law is it?
a) First Law of Thermodynamics
b) Second Law of Thermodynamics
c) Third Law of Thermodynamics
d) Fourth Law of Thermodynamics
14. What is the unit of Power?
a) Joule
b) Watt
c) Ampere
d) Ohms
15. How much Kelvin is there at 1 degree Celsius?
a) 271.15 K
b) 272.15 K
c) 273.15 K
d) 274.15 K
II. Identification
16. mg/g
17. Patm + Pgage
18. Fluid per unit area
19. 2 − 1
22. 4 3
3
23.
26. Which law of thermodynamics states that heat is a form of energy, and
thermodynamic processes are therefore subject to the principle of conservation
of energy?
27. Who formulated the Boyle’s Law?
28. It is system that can exchange both matter and energy with the surrounding.
What type of system it is?
29. It is the heat required to convert the state of matter of a substance without
changing its temperature.
30. It is the measure of the average kinetic energy of the particles in an object.
31. It is defined as the energy stored in a system as a result of its position in the
earth’s gravitational field.
32. It is the ratio of the amount of heat required to change its temperature to cause
the same temperature change in the same mass of water.
IV. Computation
33. A balloon with a volume of 2.0 L is filled with a gas at 3 atm. If the pressure is
reduced to 0.5 atm without a change in temperature, what would be the final
volume of the balloon?
34. On a sunny day in summer, a temperature reads at 39 degree Celsius. What is
the temperature measurement in degree Fahrenheit?
35. Convert -12 degrees Fahrenheit to Kelvin.
36. The mass of a grape was recorded as 125 mg. What is the weight of the grape in
N? (Note: 1000 mg = 1 g, 1000 g = 1 kg)
37. The mass of an apple is 1.02 g and the weight of an orange is 0.05 N. Which is
heavier?
38. A bullet comes to rest in a block of wood in 1.0 x 10–2 seconds, with an
acceleration of –8.0 x 104 m/s2.What was its original speed, in meters per
second?
39. The light turns red, and you ease to a halt. Checking your stopwatch, you see
that you stopped in 4.5 seconds. Your acceleration was 1.23 x 10–3 miles per
second2 in a direction opposite to your original velocity.What was your original
speed in miles per hour?
40.
41.
42.
43.
44.
45.
16. A farmer is lifting some moderately heavy rocks from a field to plant crops. He
lifts a stone that weighs 40.0 lb. (about 180 N). What force does he apply if the
stone accelerates at a rate of 1.5m/s2?
17. Calculate the density of 36 mL of solution that weighs 170 grams.
18. Calculate the density of 0.49 L of solution weighing 133 grams.
19. You decide you want to carry a boulder home from the beach. It is 30
centimeters on each side, and so has a volume of 27,000 cm3. It is made of
granite, which has a typical density of 2.8 g/cm3. How much will this boulder
weigh?
20. Rocks are sometimes used along coasts to prevent erosion. If a rock needs to
weigh 2,000 kilograms (about 2 tons) in order not to be shifted by waves, how
big (what volume) does it need to be? You are using basalt, which has a typical
density of 3200 kg/m3
Hand-In Assignment
1. What is thermodynamics
2-3. Two types of Law conservation
4. It state that when or during an interaction of energy can change from
one another.
5. Site an example of first and second law of thermodynamics
20. Some fish have a density slightly less than that of water and must exert a force
(swim) to stay submerged. What force must an 85.0-kg grouper exert to stay