Lampiran 2.

Perhitungan

A. Penentuan Densitas Larutan (d)

W - We
d = × do
Wo - We

46,5484 – 19,9537 3
d1 = × 0,995944 g/cm 3 = 1,0546 g/ cm
45,0671 – 19,9537

45,7851 – 19,9537 3
d2 = × 0,995944 g/cm 3 = 1,0243 g/ cm
45,0671 – 19,9537

45,4241 – 19,9537 3
d3 = × 0,995944 g/cm 3 = 1,0100 g/ cm
45,0671 – 19,9537

45,2416 – 19,9537 3
d4 = × 0,995944 g/cm 3 = 1,0028 g/ cm
45,0671 – 19,9537

B. Penentuan Molalitas Larutan

1
m =
(d/M) – (BM/1000)

1
m1 = = 1,5513 mmol/g
(1,0546/1,5) – (58,5/1000)

1
m2 = = 0,7649 mmol/g
(1,0244/0,75) – (58,5/1000)

1
m3 = = 0,3795 mmol/g
(1,0101/0,375) – (58,5/1000)

1
m4 = = 0,1890 mmol/g
(1,0028/0,1875) – (58,5/1000)

C. Penentuan Volume Molal Parsial ()

=
1
d ( BM – (m1000 ×
W - Wo
Wo – We ))
1 =
1
1,0546 ( 58,5 – ( 1000
1,5515
×
46,5484 - 45,0671
45,0671 - 19,9537 )) 3
= 19,4178 cm /mol

2 =
1
1,0244 ( 58,5 – ( 1000
0,7649
×
45,7851 - 45,0671
45,0671 - 19,9537 )) 3
= 20,6204 cm /mol

3 =
1
1,0101 ( 58,5 – ( 1000
0,3794
×
45,4241 - 45,0671
45,0671 - 19,9537 )) 3
= 20,8327 cm /mol

4 =
1
1,0028 ( 58,5 – ( 1000
0,1890
×
45,2416 - 45,0671
45,0671 - 19,9537 )) 3
= 21,6822 cm /mol

No. x (√m ) y (ϕ) xy x2 y2

1. 1,2455 19,4 178 24,1856 1,5513 377,0537

2. 0,8745 2 0,6204 18,0345 0,7649 425,2016

3. 0,6160 20,8327 12,8338 0,3795 434,0050

4. 0,4347 2 1,6822 9,4271 0,1890 470,1207

82,5533
Σ 3,1709 64,4812 2,8848 1706,3812

Δy 21,6822 – 19,4178 2,2644

slope = tan α = = = = -2,7927
Δx 0,4347 - 1,2455 -0,8108

slope =  = -2,7927 cm3/mol

y = ax + b

dimana, a = slope

b = intercept

n xy - x. y
a= 2 2
n( x ) – ( x)
4 (64,4812) – (3,1709) (82,5533)
= 4 (2,8848) – (10,0550)

= -2,5927
 2
( y) ( x ) – ( x) ( xy)
b= 2 2
n ( x ) – ( x)

(82,5533) (2,8848) – (3,1709) (64,4812)

= 4 (2,8848) – (10,0550)

= 22,6937

y = -2,5927x + 22,6937

R2 = tetapan kelurusan grafik

2
(n xy – ( x. y))
R2 =
( n x2 - ( x) 2 )( n y 2 - ( y) 2)

2
((4 x 64,4812 – (3,1709 x 82,5533))
=
(4 x 2,8848 – 10,0550) (4 x 1706,3812 – 6815,0552)

= 0,953