Professional Documents
Culture Documents
Sebutan tentang : Gris yang mengandungi minyak mineral yang sangat tersuling
persiapan dan bahan tambahan.
272-028-3
Maklumat tambahan : Minyak galian yang amat tersuling ini mengandungi <37o (w/w)
eksirak btrrtSO, mengikut lP 346. Rujuk kepada bab 16 untuk
frasa-frasa-R Penuh EC.
3. PENGENALAN BAHAYA.BAHAYA
Bahaya-Bahaya kePada : Tidak dijangka menjadi bahaya kepada kesihatan jika diguna di
kesihatan dalam keadaan-keadaan biasa. Sentuhan kulit yang
berpanjangan atau berulang-ulang tanpa pembersihan yang
baik boleh menyumbat liang roma kulit lalu mengakibatkan
gangguan seperti akne minyak. Suntikan tekanan tinggi di
bawah kulit boleh menyebabkan kerosakan yang serius,
termasuk nekrosis setempat. Gris yang sudah terpakai
mungkin mengandungi bendasing merbahaya.
Tanda-Tanda dan : Nekrosis setempat terbukti dengan rasa sakit dan kerosakan
simptom tisu terlengah yang timbul beberapa jam selepas disuntik.
Tanda dan gejala akne minyak/folikulitis mungkin merangkumi
1t19
Cetak Tarikh / Print Date: 2013112108 00000001 9487
MSDS-MY
Shell Gadus S,2V2m2
Versi / Version 1.1
ffioLoNGANCEMAS
Maklumat am Tidak dijangka menjadi bahaya kepada kesihatan jika diguna di
dalam keadaan-keadaan biasa.
Penyedutan : Rawatan tidak perlu diberikan dalam.keadaan penggunaan
biasa. Jika gejala berlarutan, dapatkan nasihat perubatan'
Sentuhan kulit : Tanggalkan pakaian yang tercemar. Jiruskan kawasan yang
terd6dah dengan air dan diikuti dengan basuhan dengan
sabun, jika ada. Jika gangguan berlaku berterusan, dapatkan
nasinaf OoXtor. Apabiia menggunaXan peralatan tekanan tinggi'
suntikanprodukkebawahkulitbolehberlaku.Jikakecederaan
tekanan iinggi berlaku,mangsa mestilah dihantar segera ke
hospital. Jangan tunggu sehingga terbentuk simptom-simptom'
Dapatkan peihatian perubatan walaupun kecederaan tidak
kelihatan.
Penyentuhan ke mata : Bilas mata dengan air yang banyak' Jika gangguan berlaku
berterusan, dapatkan nasihat doktor.
Penelanan : Secaraamnya.rawatantidakdiperlukanjikatertelankecuali
pun'
apabila ditelan dengan banyaknya. Walau bagaimana
dapatkan juga nasihat doktor.
Nasihat kePada doktor Rawat seiaia simptomatik. Kecederaan suntikan tekanan
tinggi memerlukan campur tangan pembedahan serta merta
daihungkin terapi steroid, untuk meminimumkan kerosakan
tisu dan [ehilangan fungsi. Oleh sebab luka pada permukaan
kulit adalah keci'idan tidlk membayangkan keparahan sebenar
kecederaan di bawahnya, tinjau periksa secara bedah mungkin
perlu dijalankan untuk menentukan tahap penjejasan'
Anesteiik setempat atau rendaman panas hendaklah dielakkan
kerana ini boleh menyebabkan bengkak, vasospasma dan
iskemia. Penyahmampatan, pembuangan tisu dan
-bahan
pengeluaran asing hendaklah segera dilakukan dengan
menggunakan anestetik umum, dan tinjau periksa secara
meluas adalah Penting.
apt.
Keluarkan semua orang yang bukan kakitangan kecemasan dari kawasan
2t19
00000001 9487
Cetak Tarikh / Print Date: 2O13l12l0g
MSDS-MY
Shell Gadus S;2V22O2
Versi / Version 1'1
Date 2013/01/15
Tarikh Berkesan' / Effective
Bahan
Lembaran Data Keselamatan
frl"ioi"r SafetY Data Sheet
r atau kabul €e rb:j"['T
B u ih, sembu ra n
i, Ii1:fl;[3-??l
ai
Bahantarapemadaman' 3$l;,1?lllJi:illH.H;i;n;iil"akanuntukkebakaran
Sesuai
yang kecil sahaia'
i;;;;; gunat<an air di dalam Pancutan'
Media Pemadam Yang '
tidak scsuq,
iloaK sesuai
Peralatan p":tif:l: ,n : perrindunsan vang
Alat perlindunoan
Arat
o,pux""i
vans
apaUita
b"tYll::TT::?i:liti""J:ilffi
'"""-
uE\u'|
menuju ke
kebakaransatu i
di
mestitah "r"r,
LntuX anggota bomba ruang tertutuP'
ENGAJA
Untuk mendapatkan
atau y?lg,gi!?outkan'
bahan y?ngl:rtumpah 8 Helaian Data
Etakkan daripada terkena
k"ien,gkapa;;:iiffi;;;;;tiriJtinat.gan
oanduan tentang ;'ilih;;
k"ser"matanB"#;ilil';i;k;4":*lid:lh,:u***"m:""u?:sJ""rT:uansan
peraturan berkenaam sar
Patuhi semua
fsrunlil#**n l;gl]xTi3frtri'ffiflli,i#4]ffi1iil.'ffi"
ati,]';;;;l k; am
me reuar.
d ar I o ngka
r" n
t""gsunakan Pasir' tanah
H',5'L']L?l"J"i# "
:::;:l
Kaedah pembersiha6 5fl1ffi :,"":iiili:1ffi,1?::il?:;:?::3;l'ff::1nT"'"*
peraturan temPatan'
l tll-r-."fl 1TftL?:?"nlll'u"nnberpanjansan.atauberurane-
q9q 9?:/u"u kabus'
Pengendalian ulang. Elakkun ou'ipuil?E"v"i"1 oatam deram' kasut
Aoabila mengendarr ffijil;i;Jux aloiat-al at pensendalian vang
jiiji;ilioa^
keselamatan,'n"'tl karn
sesuai mestirah o,gJl".
I;"gi"n a"ng"n baik sebarang
untuk
,"""illil""gi"i"n dicdmarkan
tan atau bahan
rapat dan simpan di tempat
F:Lt'-"jiT:1":"i$il3l'"nutuo -3lLi,:i"":J:H
SimPanan
ffi :?i":-".;::'l["S;*;9"'*,fl iff
dilabel dengan tePa
lembut atau
ir*l*t3!il'I3i,u pelapis bekas' sunakan keluli
Bahan'Bahan Yang ' ;'i;ilii;'["turnPutun
iingsi (HDPE)'
disarankan : PVC
i"ftan'eanan Yang tidak
kepada suhu
sesuai tidak boleh terdedah
Bekas-bekas poliethilin
Maklumat tambahan
3/19 000000019487
te:2013/12108 MSDS-MY
Cetak Tarikh / Print Da
li
Shell Gadus S.2V22O2
Versi / Version 1.1
M PENDEDAHAN/PERLINDUNGAN PERIBADI
Had Pendedahan
Bahan Sumber Jenis ppm mq/m3 Nota-Nota
Kabus minyak, ACGIH TWA(Pecah 5 mg/m3
mineral an boleh
sedut.)
lndeks Dedahan Biologi (BEl) - Lihat rujukan untuk mendapatkan butir-butir lengkap
Had biologi tidak diPeruntukkan.
4t19
Cetak Tarikh i Print Date: 2013112108 000000019487
MSDS-MY
Shell Gadus S.2V220 2
Versi / Version 1.1
Tarikh Berkesan. / Effective Date: 2013/01/1 5
5/19
Cetak Tarikh / Print Date: 2013112108 00000001 9487
MSDS_MY
Shell Gadus S.2V22Oz
Versi / Version 1-1
Tarikh Berkesan. / Effective Dater 2013/01/15
Kemantapan Mantap.
Keadaan-Keadaan yang Suhu ekstrim dan sinar matahari langsung.
perlu dielakkan
Bahan-Bahan yang perlu Agen-agen pengoksid kuat.
dielakkan
Produk penguraian Produk-produk terurai (reputan) yang berbahaya tidak dijangka
berbahaya terjadi semasa simpanan biasa.
1 1. MAKLUMAT TOKSIKOLOGI
-tllrgdi(tps+Q.gv")- -l ,
. ....- .. . ..
PEMBUANGAN
Pembuangan bahan Ambil balik atau kitar semula jika boleh' Menjadi
i""gg""gi"*ab penjana sisa untuk menentukan sifat-sifat
menentukan
f<etJ[sixlir dan fizikal bahan yang terhasil' untuk
yang betul menurut
p"ng"fu""" sisa dan kaedah-pelupusan
i"rJtut"n yang dipakai. Jangan buang.ka.n.kedalam ruangan
aliran air'
atam seritir, xldatam longking atau didalam
sebaik-
Pembuangan bekas ,' ArangXan mengikut peraturan-peraturan yang ada'
pengambil atau kontraktor yang
Uuikniu kepadiseorang"pen
o i ixtirl*un.
Kel ayakan gimbil atau kontraktor itu mestilah
ditentukan dahulu sebelumnYa'
dan
Undang-Undang : Pembuangannya mestilah mengikuti undang-undang
dan tempatan'
peraturanlperaluran wilayah, negara,
tempatan
atur
Darat (mengikut pengelasan ADR): Tidak dikawal
8/19
00000001 9487
Cetak Tarikh / Print Date: 2013112108 MSDS_MY
$hsllGadus s2J"Ti?
IMDG
peraturan-peraturan IMDG'
Bahan ini tidak dikelaskan sebagai berbahaya di bawah
ffipeRlruRRN'PERATURAN
meliputi kesemuanya' Peraturan-
Maklumat tentang peraturan-peraturan tidak diniatkan sebagai
peraturan lain mungkin dikenakan kepada bahan ini'
lnventori TemPatan
EINECS Semua
komponen
terdaftar kecuali
polimer.
TSCA Semua
komponen
terdaftar.
g/19
000000019487
Cetak Tarikh / Print Date: 2013112108
MSDS-MY
Shell Gadus 52V2202
Versi / Version 1.1
Frasa (frasa-frasa)-R
Tidak diklasifikasi.
R38 Mengganggukan kulit.
R41 Risiko kerosakan teruk kepada mata.
R51/53 rorrir kepada organisma-organisma di air, boleh menyebabkan kesan-kesan
buruk jangka panjang pada persekitaran perairan'
SDS semakan Garis vertikal (l) pada batas garis sebelah kiri menunjukkan
perubahan dari versi sebelumnYa.
'Nlaklumat
Pembahagi SDS di dalam dokumen ini hendaklah disediakan kepada
semua orang yang mungkin mengendalikan produk ini'
Penolak tanggungan Maklumat iniberdasarkan pengetahuan kami sekarang ini dan
bertujuan untuk menerangkan tentang produk untuk tujuan
kepeiluan kesihatan, keselamatan dan alam sekitar sahaja'
Oleh itu ia tidak seharusnya dianggap sebagai menjaminkan
sebarang ciri khusus sesuatu produk.
10/19
000000019487
Cetak Tarikh / Print Date: 2013112108
MSDS MY
Shell Gadus S2V22O2
Versi /Version 1.1
2. COMPOSITION/INFORMATION ON INGREDIENTS
Additional lnformation The highly refined mineral oil contains <3olo (w/w) DMSO-
extract, atcording to 1P346. Refer to chapter 16 for full text of
EC R-phrases.
3. HAZARDS IDENTIFICATION
Health Hazards Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
grease may contain harmful impurities.
Signs and SymPtoms Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculiiis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas'
lngestion may result in nausea, vomiting and/or diarrhoea'
Safety Hazards Not classified as flammable but will burn.
Environmental Hazards Not classified as dangerous for the environment.
I 1/19
00000001 9487
Cetak Tarikh / Print Date: 2013112108
MSDS MY
Shell Gadus $2V220 2
Versi / Version 1.1
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other approPriate barriers.
Clean Up Methods : Shovel into a suitable clearly marked container for disposal or
reclamation in accordance with local regulations'
Ex Lamlts
Material Source Tvpe ppm mo/m3 Notation
Oil mist, mineral ACGIH TWA(lnhala 5 mg/m3
ble fraction.)
Biological Exposure lndex (BEl) ' See reference for full details
No limit allocated.
13/19
00000001 9487
Cetak Tarikh / Print Date: 2013112108
MSDS MY
Shell Gadus SZV22O2
Versi / Version 1.1
Exposure Controls The level of protection and types of controls necessary will vary
depending upon potential exposure conditions' Select controls
based on a risk assessment of local circumstances'
Approprrate measures include: Adequate ventilation to control
or
airborne concentrations. where material is heated, sprayed
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective Personal protective equipment (PPE) should meet
Equipment recommended national standards. check with PPE suppliers.
Respiratory Protection No respiratory protection is ordinarily required under normal
conditions of use. ln accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. li engineering controls do not maintain airborne
concentrationJ to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specificconditionsofuseandmeetingrelevantlegislation.
inecf with respiratory protective equipment suppliers' Where
air-filtering respirators are suitable, select an appropriate
combinatiin oi mask and filter. Select a filter suitable for
point
combined particulate/organic gases and vapours [boiling
>65"C(149'F)1.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e'g' Europe: EN374'
lis' fzabi made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
it"g", e.g. frequency and duration of co.ntact, chemical
resiitancJ of glove material, dexterity' Always seek advice
trom gtove sulpliers. Contaminated gloves should be replaced'
Persolnal hygiene is a key element of effective hand care'
gloves'
Gloves musionty be worn on clean hands' After using
and dried thoroughly' Application of a
hands should be washed
non-perfumed moisturizer is recommended'
For continuous contact we recommend gloves with
preference
breakthrough time of more than 240 minutes with
> where suitable gloves can be identified' For
for 480 minutes
short-term/splash protection we recommend the same' but
iecognise that suiiable gloves offering this level of protection
may"not be available and in this case a lower breakthrough
time may be acceptable so long as appropriate maintenance
andrepl-acementregimesarefollowed.Glovethicknessisnot
good predictor of gtove resistance to-a.chemical as it is
"dJpendent on the eiact composition of the glove material'
Eye Protection :Wearsafetyglassesorfullfaceshieldifsplashesarelikelyto
occur.
Protective Clothing :Skinprotectionnotordinarilyrequiredbeyondstandardissue
work clothes.
Monitoring Methods :Monitoringoftheconcentrationofsubstancesinthebreathing
to
zone of workers or in the genbral workplace may be required
1,4119
000000019487
Cetak Tarikh / Print Date: 2013112108
MSDS-MY
Shell Gadus S2V22O2
Versi / Version 1.1
1 5/19
Cetak Tarikh / Print Date: 2013112108 000000019487
MSDS_MY
Shell Gadus S2V22O2
Versi / Version 'l .1
Stability : Stable.
Conditions to Avoid '.
Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment lnformation given is based on data on the components and the
toxicology of similar products.
Unless indicated othenryise, the data presented is
representative of the product as a whole, rather than for
individual component(s).
Acute OralToxicity Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute DermalToxicity Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute lnhalation Toxicity Not considered to be an inhalation hazard under normal
conditions of use.
Skin lrritation Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oilacne/folliculitis.
Eye lrritation Expected to be slightly irritating.
Respiratory lrritation lnhalation of vapours or mists may cause irritation.
Sensitisation Not expected to be a skin sensitiser.
Repeated Dose Toxicity Not expected to be a hazard.
Mutagenicity Not considered a mutagenic hazard.
Carcinogenicity Not expected to be carcinogenic. Product contains mineral oils
of types shown to be non-carcinogenic in animal skin-painting
studies. Highly refined mineral oils are not classified as
carcinogenic by the lnternational Agency for Research on
Cancer (IARC).
J[*flkl- -- ; "i-9-"*-eines"enisi!y*gles-s-ifiiafi;n
,..
Highly refined mineral oil I : ACGIH Group 44: Not
I classifiable as a numan A;cilog;n
(tP346 <3"/o)
Highly refined mineral oil
16/19
Cetak Tarikh i Print Date: 2013112108 00000001 9487
MSDS-MY
Shell Gadus g.2VZ2O 2
Versi /Version 1.1
Tarikh Berkesan. / Effective Date: 201 3/01/15
Lembaran Data Keselamatan Bahan
Material Safety Data Sheet
Ecotoxicological data have not been determined specifically for this product. lnformation given is
based on a knowledge of the components and the ecotoxicology of similar products. UnlJss
indicated othenivise, the data presented is representative of the product as a whole, rather than
for individual component(s).
Acute Toxicity Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/1L50 >
100 mg/l (to aquatic organisms) LL/ELS0 expressed as the
nominal amount of product required to prepare aqueous test
extract. Mineral oil is not expected to cause any chronic effects
to aquatic organisms at concentrations less than 1 mg/|.
Microorganisms Data not available
Mobility Semi-solid under most environmental conditions. lf it enters
soil, it will adsorb to soil particles and will not be mobile. Floats
on water.
Persistence/degradabi I ity Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation Contains components with the potential to bioaccumulate.
Other Adverse Effects Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
1 3. DISPOSAL CONSIDERATIONS
Material Disposal : Recover or recycle if possible. lt is the responsibility of the
waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Do not dispose into the environment, in
drains or in water courses.
Container Disposal '.
Dispose in accordance with prevailing regulations, preferably to
a recognised collector or contractor. The competence of the
collector or contractor should be established beforehand.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
17t19
Cetak Tarikh / Print Date: 20i3t12t\B
00000001 9487
MSDS MY
Shell Gadus S.2V22O2
Versi / Version 1.1
IMDG
ihis material is not classified as dangerous under IMDG regulations.
Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.
R-phrase(s)
Not classified.
R38 lrritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic otgaiisms, may cause long-term adverse effects in the aquatic
environment.
18t19
00000001 9487
Cetak Tarikh / Print Date: 2013112108
MSDS-MY
Shell Gadus 32V22O 2
Versi / Version 'l .1
SDS Revisions : A vertical bar (l) in the left margin indicates an amendment
from the Previous version-
SDS Distribution : ihe information in this document should be made available to
allwho maY handle the Product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health'
safety and environmental requirements only' lt should not
therefore be construed as guaranteeing any specific property
of the product.
19/19
00000001 9487
Cetak Tarikh I Print Date: 2013112108
MSDS MY