Solutions Chemistry (NM) (Ex-3 & 4)

SOLUTIONS 1
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya Lakshya Lakshya SOLUTIONS

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya
EXERCISE
Lakshya
- 3 : ADVANCED
Lakshya Lakshya
OBJECTIVE
Lakshya Lakshya
QUESTIONS
Lakshya Lakshya Lakshya

1. All questions marked “S” are single choice questions
LakshyaAll questions
2. LakshyamarkedLakshya Lakshya
“M” are multiple Lakshya
choice questions Lakshya Lakshya Lakshya Lakshya
3.
Lakshya
All questions
Lakshya
marked “C” are comprehension
Lakshya Lakshya
based questions
Lakshya Lakshya Lakshya Lakshya Lakshya
4. All questions marked “A” are assertion–reason type questions
Lakshya(A) If both assertionLakshya
Lakshya and reason are correct and Lakshya
Lakshya reason is the correct
Lakshyaexplanation of assertion.
(B) If both assertion and reason are true but reason is not the correct explanation of assertion.
(C) If assertion is true but reason is false.
Lakshya(D) If reason
Lakshya is true Lakshya
but assertion isLakshya
false. Lakshya Lakshya Lakshya Lakshya Lakshya
5. All questions marked “X” are matrix–match type questions
LakshyaAll questions
6. LakshyamarkedLakshya Lakshya
“I” are integer Lakshya
type questions Lakshya Lakshya Lakshya Lakshya

Strength of Solutions To 5.85 g of NaCl, one kg of water is added to prepare
Lakshya Lakshya Lakshya Lakshya 7. (S)
Lakshya Lakshya Lakshya Lakshya Lakshyaa
1. (S) In which mode of expression, the concentration of solution. What is the strength of NaCl in this solution ?
Lakshya
solution remains independent
Lakshya Lakshya
of temperature
Lakshya
? Lakshya (Molecular weight
Lakshya of NaCl = 58.5)
(a) Molarity (b) Normality (a) 0.1 Normal (b) 0.1 Molal
Lakshya (c) Formality
Lakshya Lakshya
(d) MolalityLakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) 0.1 Molar (d) 0.1 Formal
2. (S)
Lakshya If 0.50Lakshya
mole of BaCl2 isLakshya
mixed with 0.20 mole of Na3POLakshya
Lakshya 4
, 8. (S) What is the normality
Lakshya Lakshyaof a 1 MLakshya
solution of H3PO ?
Lakshya
4
the maximum number of moles of Ba3(PO4)2 that can be (a) 0.5 N (b) 1.0 N
Lakshya formed Lakshya
is Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) 2.0 N (d) 3.0 N
(a) 0.1 (b) 0.2 9. (S) The normality of a 2.3 M sulphuric acid solution is
(c) 0.5 (d) 0.7 (a) 0.46 N (b) 0.23 N
Lakshya
3. (S) Lakshyaof 10%Lakshya
The normality Lakshya
(weight/volume) acetic acid isLakshya Lakshya Lakshya Lakshya Lakshya
(c) 2.3 N (d) 4.6 N
(a) 1 N (b) 10 N
10. (S) Lakshya Lakshya
50 ml of 0.2 N HCl, Lakshya
50 ml of 0.1 N H SO and 100Lakshya
ml 0.2 N
2 4
(c) 1.7 N (d) 0.83 N
Lakshya
HNO3 are mixed. The normality of resulting solution is
4. (S) 30 ml Lakshya Lakshya by 15Lakshya
of solution is neutralised Lakshya
ml of 0.2 N base. Lakshya Lakshya Lakshya Lakshya
The strength of the acid solution is (a) 0.10 N (b) 0.15 N
(a) 0.1 N (b) 0.15 N (c) 0.175 N (d) 0.20 N
Lakshya (c) 0.3Lakshya
N (d) 0.4 N
11. (S) Lakshya
In a solution ofLakshya Lakshya
7.8 g of benzene (C6H6) andLakshya
46 g of
5. (S) The formula weight of H2SO4 is 98. The weight of the toluene (C6H5CH ), the mole fraction of benzene is
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
3 Lakshya Lakshya
acid in 400 ml of 0.1 M solution is
(a) 1/6 (b) 1/5
Lakshya a) 2.45Lakshya
g (b) 3.92 g Lakshya
(c) 1/2 (d) 1/3
(c) 4.90 g (d) 9.8 g
12. (S) Lakshya
The molarity ofLakshya
a solution of NaLakshya Lakshya
CO having 10.6 g/500
6. (S) 10 ml of 3N-HCl, 20 ml of N/2 H2SO4 and 30 ml of N/3 2 3
ml of solution is
Lakshya HNO3Lakshya
are mixed together and volumeLakshya
Lakshya made to one litre.
The normality of the resulting solution is (a) 0.2 M (b) 2 M
Lakshya (a) N/2Lakshya Lakshya
(b) N/10 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) 20 M (d) 0.02 M
Lakshya (c) N/20
Lakshya (d) N/40
Lakshya Educare
2 SOLUTIONS
13. (S) Molarity

Lakshya of a solutionLakshya
Lakshya containing 1g NaOH in 250 mlLakshya
Lakshya of where, XA is mole
Lakshya fraction of
Lakshya A in mixture.
Lakshya Hence
Lakshya
solution is
p0 and pB0 are (in torr) :
A
(a) 0.1 M (b) 1 M
Lakshya Lakshya Lakshya Lakshya Lakshya (a) 254, 119
Lakshya Lakshya (b) 119, 254
Lakshya Lakshya
(c) 0.01 M (d) 0.001 M
(c) 135, 254 (d) 154, 119
14. (S) Which one of the following solutions of sulphuric acid
Lakshya will exactly neutraliseLakshya
Lakshya 25 ml of 0.2 M Lakshya
sodium hydroxide
Lakshya Lakshya 1Lakshya 1 Lakshya Lakshya
19. (S) The plot of y against x is linear with slope and
solution ? A A
(a) 12.5 ml of 0.1 M solution (b) 25 ml of 0.1 M intercept respectively :
Lakshya solution
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
PA0 PA0  PB0 PA0 PB0  PA0
Lakshya (c) 25 Lakshya
ml of 0.2 M solution (d) 50 ml of
Lakshya 0.2 M solutionLakshya
Lakshya (a)
Lakshya
and Lakshya (b) and
PB0
PB0
PLakshya
B
0
PB0 Lakshya
Raoult’s
Lakshya LawLakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
0 0 0 0
15. (A) Assertion (A) : The sum of mole fractions of al BP P P A BP P  PA0
B
0
B
Lakshya Lakshya Lakshya Lakshya Lakshya (c)
Lakshya
0
and Lakshya (d) and Lakshya
Lakshya
components of a solution is unity. AP PA0 P PB0 0
A
Lakshya Reason
Lakshya Lakshya
: Mole fraction Lakshya
is independent Lakshya
of temperature. Lakshya Lakshya Lakshya Lakshya
20. (S) If PA is the vapour pressure of a pure liquid A and the
Lakshya (a) A Lakshya (b) B
Lakshya Lakshya Lakshya mole fraction ofLakshya
Lakshya A in the mixture of two liquidsLakshya
Lakshya A and B
(c) C Lakshya (d) D is x, the partial vapour pressure of A is :
16. (S) A solution is prepared containing a 2 : 1 mol ratio of (a) (1  x) PA (b) xPA
dibromo ethane (C 2 H 4Br 2) and dibromo propane
Lakshya (C3H6Lakshya
Br2) what is the total vapour pressure
Lakshya Lakshya over the
Lakshya x
Lakshya Lakshya 1Lakshya
x Lakshya
solution assuming ideal behaviour ? (c) (1  x) PA (d) PA
x
Vapour pressure (mm Hg)
21. (S) Which statement about the composition of vapour over
C2H4Br2 173 an ideal 1 : 1 molar mixture of benzene and toluene is correct
Lakshya Lakshya Lakshya Lakshya Lakshya ? Assume the temperature
Lakshya Lakshya is constant
Lakshyaat 25ºC.Lakshya
C3H6Br2 127
Vapour pressure data (25ºC) :
(a) 300 mm Hg (b) 158 mm Hg
Benzene 75 mm Hg
Lakshya (c) 150Lakshya
mm Hg Lakshya
(d) 142 mmLakshya
Hg Lakshya Lakshya Lakshya Lakshya Lakshya
Toluene 22 mm Hg
Lakshya
17. (S) WhichLakshya Lakshya
of the following Lakshya
graphs represent Lakshya
the behaviour Lakshya Lakshya Lakshya Lakshya
of ideal binary liquid mixture ? (a) The vapour will contain higher percentage of
Lakshya Lakshya Lakshya Lakshya Lakshya benzene Lakshya
(a) Plot of 1/PTotal against yA is linear
Lakshya Lakshya Lakshya Lakshya Lakshya (b) The vapour
Lakshya will containLakshya
Lakshya higher percentage of
Lakshya
(b) Plot of 1/PTotal against yB is non-linear toluene
(c) Plot of PTotal against yA is linear (c) The vapour will contain equal amount of benzene
Lakshya Lakshya Lakshya Lakshya Lakshya and tolueneLakshya
(d) Plot of PTotal against yB is linear
Lakshya Lakshya Lakshya Lakshya Lakshya (d) Not enough
Lakshya information
Lakshya is given to Lakshya
Lakshya make a
18. (S) Mixture of volatile components A and B has total vapour prediction
Lakshya pressure (in torr) : Lakshya
Lakshya Lakshya P =Lakshya

254 – 119XA Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Educare
SOLUTIONS 3
Ideal and Non-ideal

Lakshya Lakshya Solutions
Lakshya Lakshya 28. (S)
Lakshya Which one of the
Lakshya following pairs
Lakshya will not formLakshya
Lakshya an ideal
solution ?
22. (S) 100 mlLakshya
Lakshya of a liquid A was mixed with 25Lakshya
Lakshya ml of a liquid BLakshya
to Lakshya Lakshya Lakshya Lakshya
give a non-ideal solution of A-B mixture. The volume of (a) Benzene and toluene
Lakshya this mixture
Lakshya would beLakshya Lakshya Lakshya Lakshya
(b) ChloroformLakshya
and acetone Lakshya Lakshya
(a) 75 ml (b) 125 ml

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshyaand 2-propanol
(c) 2-Methyl propanol Lakshya Lakshya
(c) close to 125 ml (d) just more than 125 ml
Lakshya Lakshya Lakshya Lakshya Lakshya (d) Ethylene bromide
Lakshya and propylene
Lakshya bromide Lakshya
Lakshya
23. (S) A mixture of benzene and toluene forms
29. (S) The diagram given below is a vapour pressure-
(a) an ideal solution (b) non-ideal solution composition diagram for a binary solution of A and B. In
Lakshya (c) suspension
(d) emulsion Lakshya the solution, A–B
Lakshya interactions Lakshya
Lakshya are Lakshya
24. (S) WhichLakshya

of the following liquid pairsLakshya
shows a positive (a) similar to A–A and B–B interactions
deviation from Raoult's law ? (b) greater than A–A and B–B interactions
(a) Water–hydrochloric acid
(c) smaller than A–A and B–B interactions
Lakshya (b) Water–nitric
Lakshya acid Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(d) unpredictable.
Lakshya (c) Acetone–chloroform
(d) Benzene–methanol
25. (S) Which of the following pairs shows a negative deviation
Lakshya from Raoult's
Lakshyalaw ? Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya (a) Acetone–benzene

Lakshya (b) Acetone–ethanol
Lakshya (c) Acetone–chloroform

Lakshya (d) Benzene–methanol
26. (S) An azeotropic solution of two liquids has boiling point
Lakshya lower Lakshya Lakshya
than either of them when it Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya (a) Shows

Lakshya
a negative Lakshya LakshyaLaw
deviation from Raoult's Lakshya Lakshya Lakshya Lakshya Lakshya
30. (M) A binary liquids mixture of two liquid A and B showing
Lakshya (b) Shows no deviation
Lakshya from Raoult'sLakshya
Lakshya Law Lakshya the departure from
Lakshya the ideal behaviour
Lakshya Lakshya : Lakshya
(c) Shows positive deviation from Raoult's Law (a) behaves as an ideal solutionLakshya
of B into A when XB0
(d) Is saturated (b) behaves as an ideal solution of A into B when XA0
27. (S) Which of the following statements is correct for a binary
(c) H is always positive
Lakshya solution ?
Lakshya Lakshya Lakshya Lakshya Soln
Lakshya Lakshya Lakshya Lakshya
(a) A solution in which heat is evolved exhibits positive (d) TSSoln is always positive
deviations from Raoult's law.
31. (M) Which pair (s) of liquids on mixing are expected to show
Lakshya (b) ALakshya Lakshya Lakshya
solution in which heat is absorbed shows negativeLakshya Lakshya
no net volume Lakshya
change and no Lakshya
heat effect Lakshya
deviations from Raoult's law.
Lakshya Lakshya Lakshya Lakshya Lakshya (a) acetone andLakshya
Lakshya ethanol Lakshya Lakshya
(c) When one component in solution shows negative
(b) chlorobenzene and bromobenzene
Lakshya Lakshya from Raoult's
deviation Lakshya law, the
Lakshya Lakshya
other exhibits Lakshya Lakshya Lakshya Lakshya
positive deviation. (c) chloroform and benzene
(d) When one component in solution shows positive (d) n-butyl chloride and n-butyl bromide.
Lakshya deviation
Lakshyafrom Raoult's
Lakshya law, so does the other. Lakshya

Lakshya Educare
4 SOLUTIONS
32. (M) Composition

Lakshya Lakshya of an azeotrope
Lakshya Lakshya 37. (S)
Lakshya Air contains O2Lakshya
Lakshya and N2 in the ratio of 1 : 4. TheLakshya
Lakshya ratio of
their solubilities in terms of mole fractions at atmospheric
Lakshya
(a) is Lakshya
independent ofLakshya
external pressure because it isLakshya
Lakshya
a Lakshya Lakshya
pressure and room temperatureLakshya
will be (GivenLakshya
Henry’s
compound 7 7
constant for O2 = 3.30 × 10 torr, for N2 = 6.60 × 10 torr)
(b) alters on changing the external pressure
(a) 1 : 2 (b) 2 : 1
Lakshya (c) remains
Lakshya Lakshya
unchanged Lakshya
during distillation Lakshya
at a constant Lakshya Lakshya Lakshya Lakshya
(c) 4 : 1 (d) 1 : 4
external pressure
Colligative Properties
(d) fluctuates even at constant pressure
38. (M) Lakshya Lakshya
Colligative properties Lakshya
of the solution depend Lakshya
on
33. (M) In binary liquid mixture of components, A and B, the
Lakshya formerLakshya Lakshyato escape
has greater tendency Lakshya Lakshya
into the vapour (a) Nature of solute
state than demanded by Raoult’s law. Indicate the correct (b) Nature of solvent
statement(s)
(c) Number of solute particles present in the solution
Lakshya (a) Component
Lakshya A shows
Lakshya Lakshya and the
positive deviation Lakshya Lakshya Lakshya Lakshya Lakshya
component B negative deviation (d) Number of moles of solvent only

(b) Both components show positive deviations 39. (S) Which one is a colligative property ?
(c) Component A shows negative deviation and the (a) Boiling point (b) Vapour pressure
Lakshya Lakshya B positive
component Lakshyadeviation Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) Osmotic pressure (d) Freezing point
Lakshya (d) The component Lakshya
Lakshya B has also greater tendency Lakshya
Lakshya to 40. (S) Lakshya Lakshya
The relative lowering Lakshya
of the vapour pressure isLakshya
equal to
escape into the vapour state than demanded by the ratio between the number of
Lakshya Lakshya
Raoult’s law Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(a) solute molecules to the solvent molecules
34. (M) The solution
Lakshya Lakshya showingLakshya
positive deviation
(b) solute molecules to the total molecules in the
(a) have V (mixing) =Lakshya
+ ve solution
(b) have H (mixing) = – ve (c) solvent molecules to the total molecules in the
solution Lakshya Lakshya Lakshya
(c) form minimum boiling azeotropes.
Lakshya Lakshya Lakshya Lakshya Lakshya (d) solvent molecules
Lakshya Lakshyato the total number of ions
Lakshya of the
Lakshya
(d) have lower vapour pressure of each component in solute
Lakshya the solution
Lakshya than theirLakshya
pure vapour pressure.
41. (S) Vapour pressure of a solution of non-volatile solute is
35. (A) Assertion (A) : Hmix and Vmix are zero for the ideal
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya to the
(a) directly proportional Lakshya Lakshya
mole fraction of the
solution.
solvent
Lakshya Reason : The interactions
Lakshya Lakshyabetween the particle of the
components of a solution are almost identical as between (b) Independent of mole fraction of the solute
Lakshya particles in the liquids.
(c) inversely proportional Lakshya
to the Lakshya
mole fraction of the
(a) A (b) B solvent
(c) C (d) D (d) directly proportional to the mole fraction of the
solute Lakshya Lakshya Lakshya
Henry’s Law
Lakshya Lakshya of N gasLakshya Lakshya Lakshya Vapour pressureLakshya
42. (S) Lakshya of a solution of 5 g of non-electrolyte
Lakshya Lakshya
36. (S) The millimoles that will dissolve in 1L of water
2
is 100 g of water at a particular temperature is 2985 N/m2.
at 298 K. when it is bubbled through water and has a 2
The vapour pressure Lakshya
of pure water is 3000 N/mLakshya
, the
partial pressure of 0.96 bar will be
molecular weight of the solute is
(Given Lakshya
that at 298 K Lakshya
KH = 76.8 k bar) Lakshya Lakshya Lakshya Lakshya
(a) 60 (b) 120
Lakshya (a) 0.59
Lakshya (b) 0.69
(c) 178.2 (d) 380
(c) 0.79 (d) 0.89
Lakshya Educare
SOLUTIONS 5
43. (S) The vapour

Lakshya pressure of
Lakshya benzene at a certain
Lakshya temperature
Lakshya Lakshya The freezing point
49. (S) Lakshya of a 0.05 molal
Lakshya solution of
Lakshya a non-
Lakshya
is 640 mm of Hg. A nonvolatile electrolyte solute electrolyte in water is
Lakshya weighing
Lakshya Lakshya
2.175 g is added to 30.08 gLakshya Lakshya
of benzene. If the Lakshya Lakshya Lakshya Lakshya
(a) –1.860C (b) –0.930C
vapour pressure of the solution is 600 mm of Hg, what is
the molecular weight of the solid substance ? (c) –0.0930C (d) 0.930C
Lakshya (a) 79.82
Lakshya Lakshya
(b) 84.46 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
50. (S) During depression of freezing point in a solution the
Lakshya (c) 59.60
Lakshya (d) 49.50
Lakshya Lakshya Lakshya following are inLakshya
Lakshya equilibrium Lakshya Lakshya
44. (M) Which of the following is/are correct statements (s) about (a) liquid solution, solid solvent
the Raoult’s law applied to a solution of non-volatile
(b) liquid solvent, solid solute
Lakshya soluteLakshya
? Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) liquid solute, solid solute
(a) Vapour pressure of solution is proportional to mole
Lakshya Lakshya
fraction of soluteLakshya Lakshya Lakshya Lakshya Lakshya
(d) liquid solute, solid solvent
Lakshya Lakshya
Lakshya (b) V.P.

Lakshya
of solution isLakshya
proportional toLakshya Lakshya
the mole fraction 51. (S) Lakshya Lakshya weight
Calculate the molecular Lakshya Lakshya
of a substance if the
of solvent freezing point of a solution containing 100 g of benzene
(c) Relative lowering of V.P. = mole fraction of solute and 0.2g of the substance is 0.17 K below that of
Lakshya Lakshya
benzene. The cryoscopic constant of benzene Lakshya
is 5.16 K
(d) Relative loweringLakshya Lakshya
of vapour pressure Lakshya
is proportional Lakshya
–1
kg mol .
Lakshya Lakshya
to the mole fraction of solute.
0
(a) 70.46 (b) 85.66
45. (S) Elevation in boiling point was 0.52 C when 6 gm of a
(c) 60.23 Lakshya (d) 178.25
Lakshya Lakshya
compound X was dissolved in 100 gm of water. Molecular
Lakshya weightLakshya
of X is (Kb of water is 0.52 K-kg/mol)
Lakshya Lakshya On freezing anLakshya
52. (S) Lakshya
Lakshya aqueous solution sugar, the solid
Lakshya that
Lakshya
(a) 120 (b) 60 starts separating out is
(c) 600 (d) 180 (a) sugar (b) ice
(c) solution with the same composition
46. (S) The molal b.p. constant for water is 0.5130C kg mol–1.
Lakshya WhenLakshya Lakshya
0.1 mole of sugar is dissolved Lakshya Lakshya
in 200 g of water, Lakshya Lakshya
(d) solution with Lakshya
a different composition. Lakshya
the solution boils under a pressure of 1 atom at
53. (M) Lakshya Lakshya
In the depression in freezingLakshya Lakshya
point experiment, it is
(a) 100.5130C kg/mol (b) 100.05130C kg/mol observed that
(c) 100.2560C kg/mol (d) 101.0250C kg/mol (a) the vapour pressure of the solution is less than that
of pure solvent. Lakshya Lakshya
47. (S) The latent heat of vaporisation of water is 9700 cal/mole
Lakshya and ifLakshya 0
the b.p. is 100Lakshya Lakshya
C, the ebullioscopic constant Lakshya
of Lakshya
(b) the vapourLakshya
pressure of theLakshya Lakshya
solution is more than
water is that of pure solvent
(a) 0.5130C kg/mol (b) 1.0260C kg/mol (c) only solute molecules solidify at the freezing point
(c) 10.260C kg/mol (d) 1.8320C kg/mol (d) only solvent molecules solidify at the freezing point.
48. (S) The normal boiling point of toluene is 110.70C, and its 54. (I) When 1.0 of urea is dissolved in 200 g of an unknown
Lakshya boiling
Lakshya Lakshya
point elevation Lakshya
constant is 3.32 Lakshya
K kg mol–1. The solvent X, the Lakshya
Lakshya X freezing point is lowered byLakshya
Lakshya 0.25ºC.
enthalpy of vapourization of toluene is nearly When 1.5g of an unknown, non-electrolytic solute Y is
Lakshya Lakshya Lakshya Lakshya Lakshya dissolved in 125
Lakshya g of same solvent
Lakshya X, freezingLakshya
Lakshya point is
(a) 17.0 kJ mol–1 (b) 34.0 kJ mol–1 lowered by 0.2 ºC and vapour pressure is lowered by
1%. If freezingLakshya
point of X, isLakshya
12ºC, determineLakshya
molar
–1 –1
(c) 51.0 kJ mol (d) 68.0 kJ mol enthalpy of fusion of X in kJ.

Lakshya Educare
6 SOLUTIONS
55. (S) 10 g ofLakshya

Lakshya glucose (1), 10 g of urea (2) and
Lakshya 10 g of sucrose
Lakshya Two aqueous solutions
61. (S) Lakshya
Lakshya Lakshya S1 andLakshya
S2 are separated by a
Lakshya
(3) are dissolved in 250 mL of water at 300 K ( = osmotic semi-permeable membrane. S2 has lower vapour pressure
pressure of solution). The relationship between the than S1. Then
osmotic pressure of the solutions is
(a) More solvent will flow from S1 to S2
(a) 1 > 2 > 3 (b) 3 > 1 > 2
(c) 2 > 1 > 3 (d) 2 > 3 > 1 (b) More solvent will flow from S2 to S1
56. (S) A semipermeable membrane (c) Solvent from S1 and S2 will flow at equal rates
Lakshya (a) allows both the solute
Lakshya Lakshyaand solvent molecules Lakshya
Lakshya to Lakshya Lakshya Lakshya Lakshya
(d) No flow will take place.
pass through
(b) does not allow the solute and solvent molecules to 62. (S) What would happen if a thin slice of sugar beet is placed
pass through in a concentrated solution of NaCl ?
(c) allows only the solute molecules to pass through (a) Sugar beet will lose water from its cells
(d) allows the solvent molecules to pass through but (b) Sugar beet will absorb water from solution
Lakshya blocks the passage
Lakshya of the solute Lakshya
Lakshya molecules Lakshya Lakshya Lakshya Lakshya Lakshya
(c) Sugar beet will neither absorb nor lose water
57. (S) Which statement is incorrect about osmotic pressure
(), volume (V) and temperature (T) ? (d) Sugar beet will dissolve in solution
Lakshya (a) 1/v when T isLakshya
Lakshya constant. Lakshya Lakshya
63. (S) Lakshya Lakshya
A plant cell shrinks Lakshya
when it is kept in Lakshya
Lakshya
(b) T when V is constant.
Lakshya Lakshya Lakshya Lakshya (a) Hypotonic solution
(c)  V when T is constant.
Lakshya Lakshya Lakshya Lakshya Lakshya (b) A hypertonic
Lakshya solution
(d) V is constant when T is constant.
(c) A solution isotonic with cell sap
Lakshya
58. Lakshya
(S) The osmotic pressureLakshya Lakshyaif the Lakshya
of a solution increases Lakshya Lakshya Lakshya Lakshya
(d) Water.
Lakshya (a) number of solute molecules
Lakshya Lakshya is increased
64. (M) Study the figure given aside and pick out the correct
(b) temperature is decreased
Lakshya Lakshya Lakshya Lakshya Lakshya option(s) of theLakshya
Lakshya following : Lakshya Lakshya
(c) volume is increased
(d) value of R is increased
Lakshya
of the following Lakshya
pairs of solutions is isotonicLakshya
? Lakshya Lakshya Lakshya Lakshya
Lakshya
(a) 6%Lakshya
urea and 6% glucose
Lakshya
(w/v) Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(b) 18% urea and 18% glucose (w/v)
(c) 6% urea and 18% fructose (w/v)
Lakshya Lakshya
(d) 34.2% sucrose andLakshya Lakshya
60% glucose (w/v) Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya
60. Lakshya A and
(S) Two solutions Lakshya
B are separatedLakshya Lakshya
by a semi- Lakshya Lakshya Lakshya Lakshya
permeable membrane. As a result of osmosis, the level
of solution A is found to rise. It implies that
Lakshya (a) Solution
Lakshya Lakshya
A is more concentrated Lakshya
than solution BLakshya Lakshya Lakshya
(a) A white precipitate of AgCl Lakshya Lakshya
is formed on AgNO side
3
Lakshya (b) Solution

Lakshya B is more concentrated Lakshya
Lakshya than solution ALakshya (b) A white precipitate
Lakshya Lakshya of AgClLakshya
is formed on BaCl side
Lakshya
2
(c) The solute molecules of A are smaller than those of B (c) No precipitate is formed onLakshya
either side
(d) The solute molecules of B are smaller than those of A. (d) Meniscus ofLakshya
BaCl2 solutionLakshya
rises and that ofLakshya
AgNO3
solution falls in due course of time
Lakshya Educare
SOLUTIONS 7
65. (S) Consider

Lakshya the following
Lakshya statements Lakshya
Lakshya Which of the Lakshya
70. (S) Lakshya
Lakshya following colligative
Lakshya properties can
Lakshya
1. Isotonic solutions have the same molar provide molar mass of proteins (or polymers of colloids)
Lakshya Lakshya
concentration at aLakshya Lakshya
given temperature. Lakshya Lakshya Lakshya
with greater precision ? Lakshya Lakshya
Lakshya 2. The molal elevation

Lakshya constant Kb is
Lakshya characteristicLakshya
Lakshya of Lakshya Lakshya
(a) Relative lowering to vapourLakshya
pressure Lakshya
a solvent, and is independent of the solute added.
Lakshya Lakshya (b) Elevation ofLakshya
boiling point Lakshya
3. The freezing pointLakshya Lakshya
of a 0.1 M aqueous Lakshya
KCl solution Lakshya Lakshya
Lakshya is Lakshya
more than that of a 0.1 M aqueous
Lakshya AlCl3 solution.
Lakshya Lakshya (c) Depression Lakshya
Lakshya in freezing point
Lakshya Lakshya
Which of these statements is correct. (d) Osmotic pressure.
(a) 1 and 2 (b) 2 and 3
71. (M) Colligative properties of a solution are
Lakshya (c) 1 and
Lakshya
3 Lakshya
(d) 1, 2 andLakshya
3 Lakshya Lakshya Lakshya Lakshya Lakshya
66. (S) Raoult's law states that for a dilute solution, (a) independent of the nature of solute
(a) the lowering of vapour pressure is equal to the mole (b) inversely proportional to molecular mass of solute
Lakshya Lakshya
fraction Lakshya
of the solute Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) Proportional to concentration of solute
(b) the relative lowering of vapour pessure is
proprotional to the amount of solute in the solution (d) independent of the amount of solvent.
Lakshya (c) the relative lowering
Lakshya of vapour pressure
Lakshya Lakshya is equalLakshya
to Lakshya Lakshya Lakshya Lakshya
72. (X) Hf = Molar heat of fusion of ice ; Lf = Latent heat of
the mole fraction of the solute –1
Lakshya Lakshya Lakshya Lakshya Lakshya fusion of ice (gLakshya
Lakshya ) Lakshya Lakshya
(d) the vapour pressure of the solution is equal to the
Lakshya mole fraction of the
Lakshya solvent
Lakshya Lakshya Lakshya Hv = Molar heat
Lakshya of vaporisation
Lakshya of water ; LvLakshya
Lakshya = Latent
–1
67. (S) Which one of the following is not a colligative heat of vaporisation of water (g )
Lakshya property
Lakshya
? Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Match the following appropriately
Lakshya (a) Relative
LakshyaLoweringLakshya
of vapour pressure of a solution
Lakshya Lakshya COLUMN -Lakshya
Lakshya I COLUMN
Lakshya - II Lakshya
(b) Elevation in boiling point of a solution
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya 18  373  373  R
Lakshya Lakshya
(c) Critical point (A) Molal depression (P)
1000H v
Lakshya (d) Osmotic
Lakshya
pressure Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
constant of water
68. (S) GivenLakshya
Lakshya that Tf is the depression
Lakshya in freezing
Lakshyapoint of the
solvent in a solution of a nonvolatile solute of molality 373  373  R
Lakshya Lakshya Lakshya Lakshya Lakshya (B)Lakshya
Molal elevationLakshya (Q) Lakshya
1000 L v Lakshya
 T f 
quantity mlt1 Lakshya
Lakshya 1, the Lakshya  is equalLakshya
to Lakshya Lakshya Lakshya Lakshyaof water
constant Lakshya
 m 
18  273  273  Lakshya
R
(a) Lf (latent heat of fusion) (C) Tf of solution (R) 1000 H f
(b) Kb (ebullioscopic constant)
containing 9.0 g of
Lakshya (c) K Lakshya Lakshya
(cryoscopic constant) Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
f glucose in 50g of water
Lakshya (d) HLakshya
fus
(enthalpy ofLakshya
fusion) Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
273  273  R
68. (S) An aqueous solutionLakshya
freezes at –2.55 0
C. What is Lakshya
its (D) Tb of solution (S) 1000 L
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya f Lakshya
boiling point
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya containing
Lakshya 3.0g of
Lakshya
Lakshya
KH
b
2O
 0.52 K / m;
Lakshya
K fH 2 O
Lakshya

 1.86 K / m ?
urea in 50 g of water
Lakshya Lakshya
0 0
(a) 107.0 C (b) 100.6 C
0 0
(c) 100.1 C (d) 100.7 C
Lakshya Educare
8 SOLUTIONS
Deviation
Lakshya inLakshya
Colligative Lakshya
Properties Lakshya 81. (S)
Lakshya The osmotic pressures
Lakshya Lakshya of equimolar
Lakshya solutions of
Lakshya
73. (S) If a solute undergoes dimerization andLakshya

trimerization, the Al2(SO4)3, KCl and sugar will be in the order
minimum values of the van't Hoff factors are
(a) KCl < Al2(SO4)3< sugar
Lakshya (a) 0.50
Lakshya
and 1.50 Lakshya
(b) 1.50 andLakshya
1.33 Lakshya Lakshya Lakshya Lakshya Lakshya
(c) 0.50 and 0.33 (d) 0.25 and 0.67 (b) sugar < KCl < Al2 (SO4)3
74. (S) The van't Hoff factors i for an electrolyte which
Lakshya undergoes
Lakshya Lakshya Lakshya Lakshya (c) sugar > KClLakshya
Lakshya > Al2 (SO4)3 Lakshya Lakshya
dissociation and association in solvents are
respectively
Lakshya Lakshya Lakshya Lakshya Lakshya (d) KCl < sugarLakshya
Lakshya < Al2 (SO4)3 Lakshya Lakshya
(a) greater than 1 and greater than 1
Lakshya (b) less
Lakshya Lakshya
than 1 and greater than 1 Lakshya Lakshya Solutions A, B, Lakshya
82. (S) Lakshya C and D are respectively
Lakshya 0.1 MLakshya
glucose,
0.05 M NaCl, 0.05 M BaCl2 and 0.1 M AlCl3. Which of
(c) less than 1 and less than 1
Lakshya Lakshya Lakshya Lakshya Lakshya the following pairs
Lakshya is isotonic ?Lakshya
Lakshya Lakshya
(d) greater than 1 and less than 1
Lakshya Lakshya Lakshya Lakshya Lakshya (a) A and B
Lakshya Lakshya (b) BLakshya
and C Lakshya
75. (S) When 1.345 g of CuCl2 is dissolved in 1 kg of water, the
(c) A and D (d) A and C
Lakshya elevation in boiling point
Lakshya will be (Kb =Lakshya
Lakshya 0.52, molar mass
of CuCl2 = 134.5) 83. (S) 0.004 M Na2SO4 is isotonic with 0.01 M glucose. The
(a) 0.05 (b) 0.30 degree of dissociation of Na2SO4 is
(a) 75% Lakshya (b) 50%
Lakshya Lakshya
(c) 0.15 (d) 0.015
Lakshya
one has the highest b.p. ? Lakshya Lakshya (c) 25%
Lakshya Lakshya (d) 85%
Lakshya Lakshya
84. (S) The average osmotic pressure of human blood is 7.8 bar
Lakshya (a) 0.1Lakshya
N Na2SO4 (b) 0.1 N MgSO
Lakshya Lakshya
4
Lakshya Lakshya
0 Lakshya Lakshya Lakshya
at 37 C. What is the concentration of an aqueous NaCl
M Al2(SO4)3 Lakshya
(d) 0.1 M BaSO
Lakshya Lakshya solution that could
Lakshya be introduced
Lakshya in the bloodstream
Lakshya ?
Lakshya
4
77. (S) WhichLakshya

of the following aqueous solutions has the (a) 0.16 mol L–1 (b) 0.32 mol L–1
highest boiling point ? –1 –1
(c) 0.45 mol L (d) 0.65 mol L
(a) 0.1 M KNO3 (b) 0.1 M Na3PO4
85. (S) An aqueous solution of NaCl freezes at –0.1860C. Given
M BaCl Lakshya
(d) 0.1 M KLakshya
SO Lakshya Lakshya Lakshya Lakshya Lakshya
2 2 4 that K b 2 O  0.512 K kg mol–1 and K Hf 2 O  186
H
. K kg
Lakshya
78. Lakshya
(S) The freezing point ofLakshya Lakshyaassuming
1 molal NaCl solution Lakshya Lakshya Lakshya
mol–1, the elevation in boiling Lakshya Lakshya
point of this solution is
NaCl to be 100% dissociated in water is
Lakshya Lakshya Lakshya Lakshya Lakshya (a) 0.0585 K
Lakshya Lakshya (b) 0.0512 K
Lakshya Lakshya
(a) –1.860C (b) –3.720C
Lakshya Lakshya Lakshya Lakshya Lakshya (c) 1.864 K
Lakshya Lakshya (d) 0.0265 K
Lakshya Lakshya
0 0
(c) +1.86 C (d) +3.72 C
86. (S) Among 0.1 M solutions of urea, Na3PO4 and Al2 (SO4)3,
79. (S) The molal freezing point constant for water is 1.860C/ which is incorrect
Lakshya mole. Therefore,
Lakshya the freezing
Lakshyapoint of 0.1M NaCl solution
(a) the vapour pressure and freezing point are the
in water is expected to be
lowest for Lakshya
Lakshya
urea Lakshya Lakshya
(a) –1.860C (b) –0.1860C
(b) the vapour pressure and freezing point are the
(c) –0.3720C (d) +0.3370C highest for urea
Lakshya
80. (S) 0.01 MLakshya
solution each Lakshya
of urea, common Lakshya
salt and Na2SO Lakshya
4
Lakshya
(c) the boilingLakshya Lakshya
point is the highest for Al2(SOLakshya
)
4 3
Lakshya
are taken, the ratio ofLakshya
Lakshya
depression of freezing
Lakshya
point isLakshya Lakshya Lakshya
(d) the depression in freezingLakshya Lakshya
point is the highest for
(a) 1 : 1 : 1 (b) 1 : 2 : 1 Al (SO4)3
Lakshya Lakshya Lakshya Lakshya Lakshya 2
(c) 1 : 2 : 3 (d) 2 : 2 : 3
Lakshya Educare
SOLUTIONS 9
87. (A) Assertion

Lakshya (A) : The boiling
Lakshya point of 0.1
Lakshya M urea solution
Lakshya 93. (I)
Lakshya A mixture of NaCl
Lakshya and sucrose Lakshya
Lakshya of combined mass 10.2 g
Lakshya
is less than that of 0.1 M KCl solution. is dissolved in enough water to make up a 250 mL
Lakshya Reason
Lakshya Lakshya
(R) : Elevation of boilingLakshya Lakshya
point is directly solution. the osmotic
Lakshya LakshyapressureLakshya
of the solutionLakshya
is 7.32
proportional to the number of species present in the atm at 23ºC. Calculate the mass percentage of NaCl in
the mixture. Lakshya Lakshya Lakshya
solution.
94. (I) A non-volatile organic compound X was used to make-
Lakshya (a) A Lakshya Lakshya
(b) B Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
up two solution. Solution A contains 5.0 g of X in 100 g
Lakshya (c) C Lakshya (d) D
Lakshya Lakshya Lakshya of water and solution
Lakshya LakshyaB contains 2.0 g of X inLakshya
Lakshya 100 g of
benzene. Solution A has vapour pressure of 754.5 mm of
88. (A) Assertion (A) : NaCl in water and organic acids in
Lakshya benzene
Lakshya Lakshya
show abnormal Lakshya
molecular mass Lakshya Hg at normal boiling
Lakshya Lakshyapoint of water and solution
Lakshya B has
Lakshya
the same vapour pressure at the normal boiling point of
Lakshya Reason (R) : Abnormal
Lakshya molecular mass
Lakshya is obtained when
benzene. Assuming X undergoLakshya Lakshya
partial dimerization in
the substance in the solution undergoes dissociation benzene, determine percentage of X dimerized in benzene
Lakshya or association.
solution.
(a) A (b) B 95. (M) The following is a graph plotted between the vapour
(c) C (d) D pressure of two volatile liquids against their respective
Lakshya Lakshya Lakshya Lakshya Lakshya mole fractions.Lakshya
Comprehension
Lakshya A Protein has been isolated
Lakshya Lakshyaas sodium salt with their
+
molecular formula NaxP (this notation means xNa ions
protein P ).Lakshya Lakshya Lakshya Lakshya Lakshya
–x
are associated with a negatively charged A
Lakshya
solution of this salt was
Lakshya
prepared byLakshya
Lakshya
dissolving 0.25g
of this sodium salt of protein in 10g of water and
Lakshya ebullioscopic
Lakshyaanalysis revealed thatLakshya
Lakshya solution boils Lakshya
at Lakshya Lakshya Lakshya Lakshya
–3
temperature 6.78 × 10 ºC higher than the normal boiling
Lakshya point of
Lakshya –1
pure water. KLakshya
b
of water of 0.52Lakshya Lakshya
K kg mol . Also Lakshya Lakshya Lakshya Lakshya
elemental analysis revealed that the salt contain 1% Which of the following combinations are correct ?
sodium metal by weight.
(a) When XA = 1 and XB = 0, then P = PAo
89. (C) Deduce
Lakshya molecular formula
Lakshya Lakshya of protein.Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(a) NaP (b) Na2P (b) When XB = 1 and XA = 0, then P > P o
A
Lakshya
(c) NaLakshya
4
P Lakshya
(d) Na5P Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
90. (C) Determine

Lakshya molecularLakshya
Lakshya weight of sodium salt of protein.
Lakshya Lakshya
(c) When XA =Lakshya
Lakshya
1 and XB = 0, then P< o
LakshyaPB Lakshya
(a) 2300 (b) 4600
o
Lakshya (c) 9200
Lakshya Lakshya
(d) 11500 Lakshya Lakshya (d) When XB =Lakshya
Lakshya 1 and XA = 0, then P = PB
Lakshya Lakshya
91. (C) Determine molecular weight of acidic form of protein :
Lakshya Lakshya Lakshya Lakshya 96. (M)
Lakshya Among 0.1 M Lakshya
Lakshya solution of NH CONH2, Na3Lakshya
Lakshya
2
PO4 and
(a) 11390 (b) 2278
Al2(SO4)3 :
Lakshya (c) 9112
Lakshya (d) 4556 Lakshya
(a) The V.P. and freezing point are the highest for urea
92. (X) Mn = Normal molecular mass of solute
(b) The elevation in boiling point is the highest for
Mo = Observed molecular mass of solute from colligative
Lakshya property
Al2(SO4)3
measurement
(c) The V.P. and freezing point are the lowest for urea
Lakshya MatchLakshya
the following :Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
COLUMN - I COLUMN - II (d) The depression in freezing point in the highest for
the Al2(SO4)3. Lakshya Lakshya Lakshya
(A) Mo < Mn (P) 0.1 M CH3COOH is benzene
(B) Mo  Mn/3 (Q) 0.1 M urea in water
Lakshya
(C) Mo >Lakshya
Mn (R) Lakshya
0.05 M bariumLakshya Lakshya
chloride in water Lakshya Lakshya Lakshya Lakshya
(D) Mo =Lakshya
Lakshya Mn (S) Lakshya
0.1 M CH3COOH in water
Lakshya Educare
10 SOLUTIONS
97. (M) StudyLakshya
Lakshya the followingLakshya
figure, and select the correct
Lakshya The maximum elevation
(iii) (C) Lakshya
Lakshya Lakshya in b.pt. is noticed in :Lakshya
Lakshya
statements.
(a) 1N NaCl (b) 1N Na2SO4
(c) 1N Na3PO4 (d) 1N Al2(SO4)3
(iv) (C) For 1M solution of HA having > 0.05, the dissociation
constant Ka in Lakshya
terms of van’tLakshya
Hoff factor (i)Lakshya
can be
written as :
(i  1) 2 (i  1) 2
(a) Lakshya (b) Lakshya Lakshya
i i
i (i  1) 2
Lakshya (a) There will be no movement
Lakshya Lakshya of any solution across
Lakshya Lakshya (c)
Lakshya Lakshya (d) Lakshya Lakshya
(i  1) 2 (2  i)
the membrane
(v) (C) Lakshya Lakshya
The correct order Lakshya
of osmotic pressure Lakshya:
for the solutions
(b) Water from BaCl2 will flow towards the NaCl solution
Lakshya Lakshya Lakshya (I) 1N urea Lakshya (II) 1N NaCl
(c) Water from NaCl will flow towardsLakshya
the BaCl2 Lakshya Lakshya Lakshya Lakshya
Lakshya (d) The

(III) 1N Na2SO4Lakshya (IV) 1N
Lakshya
Na3PO4 is : Lakshya
Lakshya
osmotic pressure of 0.1 M NaCl is higher than
the osmotic pressure of 0.05 M BaCl 2, assuming (a) I > II > III > IV (b) IV > III > II > I
Lakshya complete
Lakshya
dissociationLakshya Lakshya
of the electrolyte. Lakshya Lakshya Lakshya Lakshya Lakshya
(c) II > III > IV > I (d) I > IV > III > II
Lakshya Comprehension
98. Lakshya : Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(vi) (C) van’t Hoff factor ‘i’ for 100% dissociated NaCl solution
Lakshya Colligative propertiesLakshya
Lakshya i.e., the properties
Lakshyaof solution
Lakshya
is :
which depends upon the number of particles present in
(a) 1 (b) 2
Lakshya solution are osmotic Lakshya
Lakshya pressure, depression
Lakshyain freezing
point, elevation in boiling point and lowering in vapour (c) 1/2 (d) 3
Lakshya pressure. Experimental
Lakshya values of colligative
Lakshya Lakshya properties
for electrolytes are always higher than those obtained Assertion Reastion
Lakshya theoretically
Lakshya because Lakshya
electrolytes dissociates
Lakshyato furnish
Lakshya Lakshyais correct
(A) Assertion Lakshya
but Reason isLakshya
wrong. Lakshya
more ions in solution. On the other hand experimentally
Lakshya obtained values of colligative
Lakshya Lakshyaproperties for associating
Lakshya (B) Assertion
Lakshya Lakshyais wrong but Reason isLakshya
Lakshya correct Lakshya
nature of solute are lower than those obtained
(C) Both Assertion and Reason are correct and Reason is
Lakshya theoretically.
LakshyaThe ratio of experimental
Lakshya Lakshyacolligative
correct explanation of Assertion.
properties to theoretical colligative properties is called
Lakshya as vantLakshya
Hoff factor (i).Lakshya Lakshya Lakshya
(D) Both Lakshya
Assertion andLakshya Lakshya
Reason are correct Lakshya
but Reason is not
correct explanation of Assertion.
(i) (C) van’t Hoff
Lakshya factor (i) for
Lakshya dimerisation Lakshya
Lakshya of benzoic acidLakshya
in Lakshya Lakshya Lakshya Lakshya
water, assuming 30% degree of association is : 99. (A) Assertion : Osmosis is a bilateral process.
Lakshya (a) 0.85
Lakshya Lakshya
(b) 0.95 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Reason : In osmosis net flow from dilute to concentrated
Lakshya (c) 0.90
solution is noticed.
(d) 1
(a) A (b) B
(ii) (C) The degree
Lakshya Lakshyaof dissociation
Lakshyaof electrolyte AxBy is given
by the relation : (c) C (d) D
i 1 i 1 100. (A) Assertion : An ideal solution is one which obey Raoult’s
(a)  Lakshya (b)   law.
Lakshya x  y 1 Lakshya x Lakshya
y 1 Lakshya Lakshya Lakshya Lakshya Lakshya
Reason : KClaq. is an ideal solution.
i 1
(c)   (d) None of these (a) A (b) B
x  y 1
(c) C (d) D
Lakshya Educare
SOLUTIONS 11
101. (A) Assertion

Lakshya : Ebullioscopy
Lakshya or cryoscopy
Lakshya can not be used
Lakshya How many gm Lakshya
104. (I) Lakshya
Lakshya of glucose mustLakshya
be present in 0.45 litre
Lakshya
for the determination of mol. wt. of polymers. of a solution for its osmotic pressure to be same as that
Lakshya Reason Lakshya Lakshya Lakshya Lakshya of solution of 8.89
Lakshya gm glucoseLakshya
Lakshya per litre ? Lakshya
: High molecular weight solute leads to very
of Tb or Lakshya
Tf . 105. (I) What weight of glucose (mol. wt. = 180) would have to
Lakshya low value
be added to 1700 g of water at 20ºC to lower its vapour
(a) A (b) B pressure by
0.001 mm Hg ? The vapour pressure of pure water is 17
(c) C (d) D mm Hg at 20ºC.Lakshya
102. (A) Assertion : Reverse osmosis is used to purify saline 106. (I) x g of urea was dissolved in 500g of water and cooled
Lakshya water.Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
upto –0.5ºC whereby Lakshya
128g of ice separates outLakshya
from the
Reason : Solvent molecules pass from concentrate solution. If cryoscopic constant for water be 1.86ºC/m.
Calculate the value of x. Lakshya Lakshya
solution to dilute solution through semipermeable
Lakshya
membrane if high Lakshya
Lakshya
pressure is applied on highly
Lakshya Calculate the mass
107. (I) Lakshya
Lakshya of ascorbic
Lakshya acid (C6H8OLakshya
Lakshya ) to be
6
concentrated solution side. dissolved in 74g of acetic acid to lower its melting point
Lakshya (a) A Lakshya Lakshya
(b) B Lakshya Lakshya Lakshya
by 1.5ºC. Kf forLakshya
CH3COOH is 3.9 Lakshya
K kg mol–1. Lakshya
Lakshya (c) C Lakshya (d) D

Lakshya Lakshya 3.24 g of sulphur
108. (I) Lakshya
Lakshya dissolved in Lakshya
Lakshya 40g of benzene, boiling
Lakshya
point of the solution was higher than that of benzene
103. (A) Assertion
Lakshya : AdditionLakshya
Lakshya of a non-volatile solute causesLakshya
Lakshya a Lakshya
by 0.81 K. Kb forLakshya
benzene is 2.53Lakshya Lakshya
K Kg mol–1. If molecular
depression in vapour pressure.
formula of sulphur is Sn. Then find the value of n. (at.
Lakshya Reason
Lakshya Lakshyaof a solution
: Vapour pressure Lakshya Lakshya
is directly Lakshya Lakshya Lakshya Lakshya
wt. of S = 32).
proportional to mole fraction of solvent.
(a) A (b) B
(c) C (d) D

Lakshya Educare
12 SOLUTIONS
Lakshya
EXERCISE
Lakshya
- Lakshya
4 : PREVIOUS
Lakshya
YEAR
Lakshya
JEELakshya
ADVANCED
Lakshya
QUESTION
Lakshya Lakshya

1. Pure water freezes at 273 K and 1 bar. The addition of 34.5 3. The freezing point (inº C) of solution containing 0.1g of
g of ethanol
Lakshya to 500 g ofLakshya
Lakshya water changes the freezing point
Lakshya Lakshya KLakshya Lakshya
[Fe(CN)6] (mol. Lakshya
wt. 329) in 100g of water (Kf Lakshya
= 1.86 K
3 –1
of the solution. Use the freezing point depression constant kg mol ) is (2011)
Lakshya -1
of waterLakshya
as 2 K kg mol Lakshya Lakshya
. The figures shown below Lakshya Lakshya –2
Lakshya Lakshya–2 Lakshya
represent plots of vapour pressure (V.P.) versus (a) – 2.3 × 10 (b) – 5.7 × 10
is 46 g molLakshya –3 –2
(c)Lakshya Lakshya
(d) – Lakshya Lakshya
-1
temperature (T). [molecular weight of ethanol ] – 5.7 × 10 1.2 × 10
Among the following, the option representing change
Lakshya Lakshya
the freezing point is Lakshya Lakshya (2017) 4.
Lakshya The Henry’s law Lakshya
Lakshya constant for theLakshya
solubility of N gas in
Lakshya
2
5
water at 298 K is 1.0 × 10 atm. The mole fraction of N2 in
Lakshya Lakshya Lakshya Lakshya Lakshya airLakshya Lakshya
is 0.8. The number of moles ofLakshya Lakshya
N2 from air dissolved in
10 moles of water of 298 K and 5 atm pressure is
(2009)
(a) –4 –5
Lakshya Lakshya Lakshya Lakshya Lakshya (a)Lakshya
4.0 × 10 Lakshya (b) 4.0 × 10
Lakshya Lakshya
–4 –6
Lakshya Lakshya Lakshya Lakshya Lakshya (c)Lakshya
5.0 × 10 Lakshya (d) 4.0 × 10
Lakshya Lakshya
5. When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya –1 Lakshya Lakshya
benzene (Kf = 1.72 K kg mol ), a freezing point depression of
2K is observed. The Van’t Hoff factor (i) is (2007)
(a) 0.5 (b) 1
(b)
Lakshya Lakshya Lakshya Lakshya Lakshya (c)Lakshya
2 Lakshya (d) 3 Lakshya Lakshya
6. The elevation in boiling point, when 13.44 g of freshly
prepared CuCl2 are added to one kilogram of water, is.
–1
[Some useful data, kb = 0.52 kg K mol , molecular weight
of CuCl2 = 134.4 g]. (2005)
0.05 Lakshya (b) 0.1
Lakshya Lakshya
(c) (c) 0.16 (d) 0.21

7. The elevation in boiling point of a solution of 13.44g of
Lakshya Lakshya Lakshya Lakshya Lakshya CuCl in 1 kg of water
Lakshya
2
using the following
Lakshya Lakshyainformation will
Lakshya
b e ( M o l e cu la r weight of CuCl 2 = 134.4 and
–1
Lakshya Lakshya Lakshya Lakshya Lakshya KLakshya
= 0.52 K molalLakshya
) Lakshya Lakshya
(2005)
b
(a) 0.16 (b) 0.05
(c) 0.1 (d) 0.2
Lakshya
(d) Lakshya Lakshya Lakshya Lakshya
8. Lakshya
0.004 M Na2SO4 Lakshya
is isotonic with Lakshya
0.01 M glucose.Lakshya
Degree
of dissociation of Na2SO4 is (2004)
(a) 75% (b) 50%
2. For a dilute
Lakshya solution containing
Lakshya Lakshya 2.5g of aLakshya
non-volatile non-
Lakshya (c)Lakshya
25% Lakshya (d) 85%Lakshya Lakshya
electrolyte solute in 100g of water, the elevation in boiling 9. During depression of freezing point in a solution the
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshyaare in equilibrium
following Lakshya Lakshya Lakshya
(2003)
point at 1 atm pressure is 2ºC. Assuming concentration of
(a) liquid solvent, solid solvent
solute isLakshya
Lakshya much lower than the concentration
Lakshya Lakshyaof solvent,
Lakshya
(b)Lakshya
liquid solvent,Lakshya
solid solute Lakshya Lakshya
the vapour pressure (mm of Hg) of the solution is (take Kb
Lakshya –1 (c)Lakshya
liquid solute, solid solute
= 0.76 KLakshya
kg mol ). Lakshya Lakshya Lakshya
(2012) Lakshya Lakshya Lakshya
(d) liquid solute, solid solvent
Lakshya
(a) 724 Lakshya Lakshya
(b) 740 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya
(c) 736 Lakshya Lakshya
(d) 718 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya Educare
SOLUTIONS 13
10. The molecular

Lakshya LakshyaweightLakshya
of benzoic acid in benzene Lakshya
Lakshya as 17. Benzene
Lakshya and naphthalene
Lakshya form an ideal solutionLakshya
Lakshya at room
determined by depression in freezing point method temperature. For this process, the true statements is (are)
corresponds to : (1996) (2013)
(a) ionization of benzoic acid.
(b) dimerization
Lakshya Lakshyaof benzoic acid.
(a)Lakshya
G is positive Lakshya
(b) Lakshya
Ssystem is positive
Lakshya
(c) trimerization of benzoic acid. (c) Ssurroundings  0 (d) H  0
Lakshya Lakshya
(d) solvation of benzoicLakshya
acid. Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
18. Mixture(s) showing positive deviation from Raoult’s law
11. 0.2 molalLakshya
Lakshya acid HX is 20% ionised in solution.
Lakshya LakshyaKf = 1.86Lakshya
K atLakshya
35ºC is (are) Lakshya Lakshya (2016)
Lakshya
–1
molality . The freezing point of the solution is :
(a) carbon tetrachloride + methanol
Lakshya Lakshya Lakshya Lakshya (1995) Lakshya Lakshya Lakshya Lakshya Lakshya
(b) carbon disulphide + acetone
(a) – 0.45 (b) – 0.90
Lakshya
(c) – 0.31Lakshya Lakshya
(d) – 0.53 Lakshya Lakshya (c)Lakshya
benzene + tolueneLakshya Lakshya Lakshya
12. The freezing point of equimolal aqueous solutions will be (d) phenol + aniline
Lakshya Lakshya
highest for Lakshya Lakshya (1990) Lakshya Lakshya Lakshya Lakshya Lakshya
Comprehension-I
(a) C6H5Lakshya
Lakshya NH3Cl (aniline Lakshya
hydrochloride) Lakshya Lakshya Properties
Lakshya such asLakshya
boiling point, freezing
Lakshyapoint and vapour
Lakshya
(b) Ca(NO3) pressure of a pure solvent change when solute molecules
Lakshya Lakshya Lakshya Lakshya Lakshya are added to get homogeneous
Lakshya Lakshya solution.
LakshyaThese are called
Lakshya
(c) La (NO )
3 3 colligative properties. Applications of colligative
(d) C6H12
Lakshya O6 (glucose) Lakshya
Lakshya Lakshya Lakshya properties
Lakshya are very useful in day-to-day
Lakshya Lakshya life. One of its
Lakshya
13. Which of the following 0.1 M aqueous solutions will have examples is the use of ethylene glycol and water mixture
the lowest
Lakshya freezing point
Lakshya ?
Lakshya Lakshya (1989)Lakshya
asLakshya
anti-freezing liquid in the radiator
Lakshya
of automobiles.
Lakshya Lakshya
(a) Potassium sulphate (b) Sodium chloride A solution M is prepared by mixing ethanol and water.
Lakshya Lakshya Lakshya Lakshya Lakshya The mole fractionLakshya
Lakshya of ethanol in the mixture is 0.9Lakshya
Lakshya
(c) Urea (d) Glucose
Given, Freezing point depression constant of water
14. For a dilute
Lakshya
solution, Raoult’s
Lakshya Lakshya
law states that
Lakshya
(1985)
–1
(a) the lowering of vapour pressure is equal to the mole (k fwater ) = 1.86 K kg mol
Lakshya fraction of solute Lakshya
Lakshya Lakshya Lakshya Lakshyapoint depression
Freezing Lakshya constant
Lakshya
of ethanol Lakshya
(b) the relative lowering of vapour pressure is equal to –1
ethanol
Lakshya the mole fraction ofLakshya
Lakshya solute Lakshya Lakshya Lakshya Lakshya (k
Lakshya
f ) = 2.0 KLakshya
kg mol
(c) the relative lowering of vapour pressure is proportional Boiling point elevation constant of water
Lakshya to the Lakshya Lakshya
amount of solute in solution Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
–1
(d) the vapour pressure of the solution is equal to the (k water
b ) = 0.52 K kg mol
Lakshya moleLakshya Lakshya
fraction of solvent. Lakshya Lakshya Lakshya
Boiling Lakshya
point elevation constant Lakshya
of ethanol Lakshya
15. An azeotropic solution of two liquids has boiling point ethanol –1
Lakshya Lakshya
lower than either of themLakshya
when it Lakshya Lakshya
(1981) Lakshya Lakshya (k
Lakshya
b ) = 1.2 KLakshya
kg mol
(a) shows negative deviation from Raoult’s law Standard freezing point of water = 273 K
(b) shows no deviation from Raoult’s law Standard freezing point of ethanol = 155.7 K
Lakshya
(c) showLakshya Lakshya
positive deviation Lakshya
from Raoult’s law Lakshya Standard
Lakshyaboiling point of water =Lakshya
Lakshya 373 K Lakshya
Standard boiling point of ethanol = 351.5 K
(d) is saturated
Vapour pressure of pure water = 32.8 mm Hg
Objective Questions (One or more than one correct
Lakshya Lakshya Lakshya Lakshya Lakshya Vapour pressure of
Lakshya pure ethanol =Lakshya
Lakshya 40 mm Hg Lakshya
option –1
Molecular weight of water = 18 g mol
16. In the depression
Lakshya Lakshya
of freezing point experiment,
Lakshya Lakshya
it is found
Lakshya Lakshya weightLakshya Lakshya –1 Lakshya
that the (1999) Molecular of ethanol = 46g mol
(a) vapour
Lakshya pressure ofLakshya
Lakshya the solution isLakshya
less than that Lakshya
of InLakshya
answering the following questions,
Lakshya Lakshya consider the
Lakshya
pure solvent solutions to be ideal dilute solutions and solutes to be
Lakshya Lakshya non-volatile
Lakshya and Lakshya
non-dissociative. (2008)
(b) vapour pressure of Lakshya
the solution is Lakshya
more than that Lakshya
of Lakshya Lakshya
pure solvent 19. The freezing point of the solution M is
268.7 K Lakshya (b) 268.5
Lakshya
K Lakshya
(c) only solute molecules solidify at the freezing point
(d) onlyLakshya
solvent molecules solidify at the freezing point (c) 234.2 K (d) 150.9 K

Lakshya Educare
14 SOLUTIONS
20. The vapour
Lakshya the solution MLakshya
is Lakshya vapour
Lakshyapressure Lakshya
of the solutionLakshya
and the mole Lakshya
fraction
(a) 39.3 mm Hg (b) 36.0 mm Hg of methanol in the vapour. (1986)
(c) 29.5 mm
Lakshya Hg
Lakshya (d) 28.8 mmLakshya
Lakshya Hg Lakshya
29. Lakshya Lakshya Lakshya
The vapour pressure of a dilute aqueous solution of Lakshya
21. Water is added to the solution M such that the mole fraction
Lakshya
of water Lakshya Lakshya 0.9. The
in the solution becomes Lakshya
boiling point Lakshya
of glucose
Lakshya (C6H12OLakshya
6
) is 750 mmLakshya
of mercury atLakshya
373 K.
this solution is Calculate (i) molality and (ii) mole fraction of the solute.
(a) 380.4Lakshya
Lakshya K (b) 376.2 K Lakshya
Lakshya Lakshya Lakshya Lakshya Lakshya (1989)
Lakshya
(c) 375.5 K (d) 354.7 K 30. The vapour pressure of pure benzene at a certain
Lakshya
Fill Lakshya
in the Blanks Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
temperature is 640 mm Hg. A non-volatile, non-electrolyte
22. Given that
Lakshya Tf is the depression
Lakshya Lakshya in freezing
Lakshya point of the
Lakshya
solid weighing 2.175g
Lakshya Lakshya
is addedLakshya
to 39.0g of benzene.
Lakshya
solvent in a solution of a non-volatile solute of molality, The vapour pressure of the solution is 600 mm Hg.
Lakshya Lakshya
m, the quantity lim (TfLakshya
/ m) is equal toLakshya
................. Lakshya Lakshya
What Lakshya
is the molecular weight ofLakshya Lakshya?
the solid substance
m0
(1994) (1990)
True/False 31. The degree of dissociation of Ca(NO 3) 2 in dilute
23. Following
Lakshya statement isLakshya
Lakshya true only under some specific
Lakshya Lakshya aqueous
Lakshya solution,Lakshya
containing 7.0g of the salt per
Lakshya 100g
Lakshya
conditions. Write the condition, for it “Two volatile and of water at 100ºC is 0.7, calculate the vapour pressure
miscibleLakshya
Lakshya liquids can be separated
Lakshya by fractional distillation
Lakshya Lakshya ofLakshya
the solution. Lakshya Lakshya Lakshya
(1991)
into pure components.” (1994)
32. Addition of 0.643g of a compound to 50 mL of benzene
Subjective
Lakshya Questions
(density : 0.879 g/mL) lowers the freezing point from
Lakshya
24. What is the molarity and molality of a 13% solution (by
weight) of
Lakshya sulphuric acid
Lakshya with a densityLakshya
Lakshya of 1.02 g/ml ? To
Lakshya 5.51ºC to 5.03º C.Lakshya
Lakshya If kf for benzene is 5.12, calculate
Lakshya Lakshyathe
what volume should 100 ml of this acid be diluted in order molecular weight of the compound. (1992)
to prepare
Lakshya a 1.5 N solution
Lakshya ?
Lakshya Lakshya (1978) Lakshya
33. Lakshya
What weight of theLakshya
non-volatileLakshya
solute urea (NH Lakshya
–CO–
2
25. The vapour pressure of pure benzene is 639.70 mm of NH2) needs to be dissolved in 100 g of water, in order
Hg and the vapour pressure of solution of a solute in to decrease the vapour pressure of water by 25% ?
Lakshya
benzeneLakshya Lakshya
at the same temperature Lakshya
is 631.9 Lakshya
mm of Hg. What will be theLakshya
Lakshya molality of theLakshya
solution ? Lakshya(1993)
Calculate the molality of the solution. (1981) 34. The molar volume of liquid benzene (density = 0.877 g/mL)
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya by a factor
increases Lakshya of 2750 asLakshya
it vaporisesLakshya
at 20ºC
26. Two liquids A and B form ideal solution. At 300 K, the
and that of liquid toluene (density = 0.867g mL–1)
vapour pressure
Lakshya Lakshya of a solution
Lakshyacontaining 1 mole ofLakshya
Lakshya A Lakshya Lakshya Lakshya Lakshya
increases by a factor of 7720 at 20ºC. A solution of
and 3 moles of B is 550 mm of Hg. At the same
Lakshya Lakshya Lakshya benzene and toluene at 20ºC has a vapour pressure of
temperature, if one more mole of B Lakshya Lakshya
is added to this Lakshya Lakshya Lakshya Lakshya
45.0 torr. Find the mole fraction of benzene in the vapour
solution, the vapour pressure of the solution increases
above Lakshya
the solution. Lakshya Lakshya
(1996)
by 10 mm of Hg. Determine the vapour pressure of A
35. A solution of a non-volatile solute in water freezes at –
and B inLakshya
Lakshya their pure states.
Lakshya Lakshya (1982)Lakshya Lakshya Lakshya Lakshya Lakshya
0.30ºC. The vapour pressure of pure water at 298K is
27. An organic compound (CxH2yOy) was burnt with twice
Lakshya Lakshya Lakshya Lakshya Lakshya 23.51 mm Hg andLakshya
Lakshya kf for water is 1.86 K kg mol–1. Calculate
Lakshya Lakshya
the amount of oxygen needed for complete combustion
the vapour pressure of this solution at 298 K. (1998)
to CO2 Lakshya
Lakshya
and H2O. The Lakshya
hot gases when cooled to 0ºC
36. Nitrobenzene is formed as the major product along with
and 1 atm pressure, measured 2.24 L. The water
a minor product in the reaction of benzene with a hot
Lakshya Lakshya
collected Lakshya
during cooling Lakshya
weigh 0.9g. Lakshya
The vapour Lakshya Lakshya Lakshya Lakshya
mixture of nitric acid and sulphuric acid. The minor
pressure of pure water at 20ºC is 17.5 mm Hg and is
Lakshya product consists Lakshya
of carbon : 42.86%, hydrogenLakshya
: 2.40%,
loweredLakshya
by 0.104 mm Lakshya
when 50g Lakshya Lakshya
of the organic Lakshya Lakshya
nitrogen : 16.67% and oxygen : 38.07%,
compound
Lakshya are dissolved
Lakshya in 1000 g of Lakshya
Lakshya water. Lakshya (i)Lakshya Lakshya formula
Calculate the empirical Lakshya
of the minorLakshya
product.
Given the molecular formula of the organic compound. (ii) When 5.5g of the minor product is dissolved in 45g
Lakshya Lakshya Lakshya Lakshya (1983)
of benzene, the boiling point of the solution is 1.84ºC
28. The vapour
Lakshya ethanol and methanol
Lakshya are 44.5
Lakshya higher than that Lakshya
Lakshya of pure benzene. Calculate the
Lakshya molar
Lakshya
and 88.7 mm Hg respectively. An ideal solution is mass of the minor product then determine its molecular
formed Lakshya
Lakshya at the same temperature
Lakshya by the mixing 60g Lakshya
Lakshya of andLakshya Lakshya
structural formula. (Molal Lakshya Lakshya
boiling point elevation
ethanol with 40g of methanol. Calculate the total constant of benzene is 2.53 K kg mol .) –1
(1999)
Lakshya Educare
SOLUTIONS 15
3 –3
37. To 500 cm
Lakshya of water, 3.0Lakshya
Lakshya × 10 kg of acetic acid is added.Lakshya
Lakshya if 42. Lakshya
Liquids A and BLakshya Lakshyaover the
form ideal solution Lakshya
entire
23% of acetic acid is dissociated, what will be the depression range of composition. At temperature T, equimolar
–1
Lakshya Lakshya
in freezing point ? Kf andLakshya Lakshya
density of water are 1.86 K kgLakshya Lakshya
binary Lakshya
solution of liquids A andLakshya
B has vapour Lakshya
pressure
–1 –3
mol and 0.997 g cm , respectively. (2000) 45 Torr. At the same temperature, a new solution of A
and Lakshya
B having mole fractions xLakshya Lakshya
and xB, respectively,
A
38. Consider the three solvents of identical molar masses. has vapour pressure of 22.5 Torr. The value of xA/xB in
the new solution Lakshya
is ............. . Lakshya Lakshya
Match their boiling point with their kb values (2003)
Lakshya (given that the vapour pressureLakshya
of pure liquidLakshya
A is 20
SolventsLakshya Lakshya
Boiling point Lakshya
kb values Lakshya Lakshya Lakshya
Torr temperature T) (2018)
Lakshya X Lakshya 100ºCLakshya Lakshya
0.92 Lakshya
43. Lakshya
Liquids Lakshya
A and B form Lakshya
ideal solution Lakshya
for al compositions of
A and B at 25ºC. Two such solutions with 0.25 and 0.50
Lakshya Y Lakshya 27ºCLakshya 0.63
mole fractions of Lakshya
A have the totalLakshya Lakshya
vapor pressures of 0.3
and 0.4 bar, respectively. What is the vapor pressure of
Lakshya Z Lakshya 283ºCLakshya 0.53
pure Lakshya
liquid B in bar ? Lakshya Lakshya
(2020)
39. 1.22 g ofLakshya
Lakshya
benzoic acid isLakshya
dissolved in 100 g of acetone and
Lakshya Lakshya Question StemLakshya
Lakshya for Question No. 44 and 45 Lakshya
Lakshya
100 g of benzene separately. Boiling point of the solution
The boiling point of water in a 0.1 molal silver nitrate
in acetone
Lakshya increases by Lakshya
Lakshya 0.17ºC, while that in the benzene
solution (solutionLakshya Lakshya
A) is x ºC. To this solution A,Lakshya
an equal
increases by 0.13ºC; Kb for acetone and benzene is 1.7 K volume of 0.1 molal aqueous barium chloride solution is
Lakshya Lakshya
–1 Lakshya
–1 Lakshya Lakshya Lakshya
added to make a Lakshya
new solution B.Lakshya Lakshya
The difference int eh
Kg mol and 2.6 K kg mol respectively. Find molecular
boiling points of water in the two solutions A and B is
weight of benzoic acidLakshya
in two cases Lakshya
and justify your
Lakshya Lakshya Lakshya 10–2 ºC.
y ×Lakshya Lakshya Lakshya Lakshya
answer. (2004)
Lakshya Lakshya Lakshya Lakshya Lakshya (Assume
Lakshya : Densities of the solutions
Lakshya A and B are Lakshya
Lakshya the same
40. 75.2 g of C6H5OH (phenol) is dissolved in 1kg of solvent as that of water and the soluble salts dissociate completely)
of kf = 14.
Lakshya If the depression
Lakshya in freezingLakshya
Lakshya point is 7K, then
Use : Molal elevation constant (Ebullioscopic Constant),
find the percentage of phenol that dimerises. (2006) –1
Kb = 0.5 K kg mol ; Boiling point of pure water as 100ºC.)
41. 29.2% (w/W) HCl stock solution has density of 1.25 g 44. The value iof x is ................... . (Adv. 2021)
mL–1. The
molecular weight 36.5g mol–1. The
of HCl is Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
45. The value of |x| is .................. . (Adv. 2021)
volume (mL) of stock solution required to prepare a
200 mL solution 0.4 M HCl is (2012)

Lakshya Educare
16 SOLUTIONS
Lakshya Lakshya Lakshya ANSWER

Lakshya KEY

EXERCISE - 3 : ADVANCED OBJECTIVE QUESTIONS
1. (d) 2. (a) 3. (c) 4. (a) 5. (b) 6. (c) 7. (b) 8. (d) 9. (d) 10. (c)
11. (a) 12. (a) 13. (a) 14. (b) 15. (b) 16. (b) 17. (a) 18. (c) 19. (c) 20. (b)
Lakshya
21. (a) Lakshya
22. (c) Lakshya
23. (a) Lakshya
24. (d) Lakshya26. (c) Lakshya
25. (c) 27. (d) Lakshya
28. (b) Lakshya
29. (c) 30. Lakshya
(a,b,d)
31. (b,d) 32. (b,c) 33. (b,d) 34. (a,c) 35. (a) 36. (b) 37. (a) 38. (c) 39. (c) 40. (b)
41. (a) 42. (c) 43. (b) 44. (b, c, d) 45. (b) 46. (c) 47. (a) 48. (b) 49. (c) 50. (a)
51.
Lakshya (c) Lakshya
52. (b) 53. (a,d)
Lakshya 0034 55. (c)
54.Lakshya 56.
Lakshya (d) 57. (c)
Lakshya 58. (a)
Lakshya 59. (c)
Lakshya (a)
60. Lakshya
61. (a) 62. (a) 63. (b) 64. (c,d) 65. (d) 66. (c) 67. (c) 68. (c) 69. (d) 70. (d)
Lakshya
71. (abc)Lakshya Lakshya
72. (A–R, S; B–P, Q; C–R, Lakshya
S; D–P, Q) Lakshya73. (c) Lakshya
74. (d) Lakshya
75. (d) Lakshya
76. (c) 77. Lakshya
(b)
78. (b) Lakshya
Lakshya
79. (c) 80. (c)
Lakshya
81. (b)
Lakshya
82. (a)
Lakshya
83. (a) Lakshya 84. (a) Lakshya85. (b) 86. (a)
Lakshya
(a)
87. Lakshya
88. (a) 89. (d) 90. (d) 91. (a) 92. (A–R, S; B–R; C–P; D–Q) 93. (0020) 94. (0085)
Lakshya Lakshya
95. (abcd) 96. (abd) Lakshya
97. (bd) Lakshya
98. (i) (a); (ii) (a);Lakshya Lakshya
(iii) (d); (iv) (d); (v) (c); (vi) (b)Lakshya
99. (d) Lakshya
100. (a) 101.Lakshya
(c)
102. (c) 103. (c) 104. (0004) 105. (0001) 106. (0006) 107. (0005) 108. (0008)
EXERCISE
Lakshya - 4 : (PREVIOUS
Lakshya YEARLakshya
Lakshya JEE ADVANCED
LakshyaQUESTIONS)

1. (c) 2. (a) 3. (a) 4. (a) 5. (a) 6. (c) 7. (a) 8. (a) 9. (a) 10. (b)
Lakshya
11. (a) Lakshya
12. (d) Lakshya
13. (a) Lakshya
14. (b) Lakshya16. (a,d)Lakshya
15. (c) 17. (bcd) Lakshya
18. (a,b) Lakshya
19. (d) 20. Lakshya
(a)
o o
21. (b) Lakshya
Lakshya 22. kf 23. (T)
Lakshya 1.52m, 1.35M,Lakshya
24.Lakshya 180 ml 25. 0.158 Lakshya
Lakshya 26. p A  400mm, p B  600mm.
Lakshya Lakshya
27. C5H10
Lakshya O5
Lakshya 28. 66.16 mm, Lakshya
Lakshya 0.657 29. 0.74 molal; 1/76Lakshya
Lakshya 30. 65.25 Lakshya 31. 746.32
Lakshya Lakshya
32. 156 g/mol

Lakshya Lakshya 33. 111g, 18.5Lakshya 34. 0.72
Lakshya Lakshya35. 23.44 mm
36. (i) C3H2NO2 (ii) 168g/mol; C6H4N2O4;
Lakshya Lakshya
37. 0.23ºC Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
38.
Lakshya Solvents
Lakshya Boiling point
Lakshya kb Lakshya
values Lakshya Lakshya Lakshya Lakshya Lakshya
X 100ºC 0.63
Lakshya Lakshya
Y Lakshya
27ºC Lakshya
0.53 Lakshya Lakshya Lakshya Lakshya Lakshya
Z 283ºC 0.92
39. 122; 244 40. (0075) 41. (0008) 42. (19) 43. (0.02) 44. (100.1) 45. (2.5)

Dream on !! Lakshya Lakshya Lakshya Lakshya
Lakshya Lakshya Lakshya 

Lakshya Educare

Solutions Chemistry (NM) (Ex-3 &amp; 4)

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Solutions Chemistry (NM) (Ex-3 &amp; 4)

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SOLUTIONS 1

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya SOLUTIONS

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

13. (S) Molarity

Lakshya Lakshya P =Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Ideal and Non-ideal

(a) 75 ml (b) 125 ml

24. (S) WhichLakshya

Lakshya (a) Acetone–benzene

Lakshya (c) Acetone–chloroform

Lakshya (a) Shows

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

32. (M) Composition

component B negative deviation (d) Number of moles of solvent only

43. (S) The vapour

Lakshya (b) V.P.

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

55. (S) 10 g ofLakshya

Lakshya (b) Solution

65. (S) Consider

Lakshya 2. The molal elevation

73. (S) If a solute undergoes dimerization andLakshya

77. (S) WhichLakshya

87. (A) Assertion

90. (C) Determine

Lakshya (d) The

101. (A) Assertion

Lakshya (c) C Lakshya (d) D

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

(c) (c) 0.16 (d) 0.21

10. The molecular

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Solutions Chemistry (NM) (Ex-3 & 4)

Solutions Chemistry (NM) (Ex-3 & 4)