Solutions Chemistry (NM) (Ex-1 & 2)

SOLUTIONS 1
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya Lakshya Lakshya SOLUTIONS

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
Lakshya
EXERCISE
Lakshya Lakshya
- 1Lakshya
: BASICLakshya
OBJECTIVE
Lakshya
QUESTIONS
Lakshya Lakshya Lakshya

Strength of Solutions 8. The mole fraction of C2H5OH (Mol. wt. = 46) in 5 molal
Lakshya Lakshya Lakshya Lakshya Lakshya aqueous
Lakshyaethyl alcohol solution isLakshya
Lakshya Lakshya
1. What is the mass percentage of carbon tetrachloride if 22g
(a) 0.082 (b) 0.82
of benzene
Lakshya is dissolved in
Lakshya 122g of carbon
Lakshya tetrachlorideLakshya
Lakshya ? Lakshya Lakshya Lakshya Lakshya
(a) 84.72% (b) 15.28 % 5

Lakshya Lakshya Lakshya Lakshya Lakshya (c)Lakshya
5 Lakshya (d) Lakshya Lakshya
55.55
(c) 50% (d) 44%
Raoult’s Law
2. What is the molarity of a solution containing 10g of NaOH
Lakshya
in 500 mLLakshya
of solution ? Lakshya Lakshya Lakshya
9. Lakshya
The Lakshya
vapour pressure Lakshya
of pure benzene and tolueneLakshya
are 160
and 60 torr respectively. The mole fraction of toluene in
(b) 0.75 molLakshya Lakshya Lakshya
(a) 0.25 mol L–1 L–1 vapour phase inLakshya
contact with Lakshya Lakshya
equimolar solution of
benzene and toluene is
Lakshya Lakshya
(c) 0.5 mol L–1 Lakshya
(d) 1.25 molLakshya
L–1 Lakshya Lakshya Lakshya Lakshya Lakshya
(a) 0.50 (b) 0.6
Lakshya
3. What willLakshya
be the molarityLakshya
of 30 mL of 0.5Lakshya Lakshya
M H2SO4 solution Lakshya Lakshya Lakshya Lakshya
(c) 0.27 (d) 0.73
diluted to 500 mL ?
Lakshya Lakshya Lakshya Lakshya Lakshya
10. Lakshya
The Lakshya
vapour pressure Lakshya
of a pure liquid A is 70 torr atLakshya
27ºC. It
(a) 0.3 M (b) 0.03 M forms an ideal solution with another liquid B. The mole
fraction of B is 0.2 and total vapour pressure of the solution
(c) 3 M (d) 0.103 M
is 84 torr at 27ºC. The vapour pressure of pure liquid B at
4. What is the mole fraction of glucose in 10% w/w glucose 27ºC.
solution Lakshya
Lakshya ? Lakshya Lakshya Lakshya (a)Lakshya
14 Lakshya (b) 56Lakshya Lakshya
(a) 0.01 Lakshya

Lakshya (b) 0.02
Lakshya Lakshya Lakshya (c)Lakshya
140 Lakshya (d) 70.
Lakshya Lakshya
(c) 0.03 (d) 0.04 11. The vapour pressure of water at room temperature is 23.8
mm Hg. The vapour pressure of an aqueous solution of
5. To a 4L of 0.2M solution of NaOH, 2L of 0.5 M NaOH are sucrose with mole fraction 0.1 is equal to
Lakshya Lakshya
added. The molarity of Lakshya Lakshya
resulting solution is : Lakshya Lakshya Lakshya Lakshya Lakshya
(a) 23.9 mm Hg (b) 24.2 Hg
Lakshya
(a) 0.9 MLakshya Lakshya
(b) 0.3 M Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) 21.42 mm Hg (d) 21.44 mm Hg.
(c) 1.8 MLakshya
Lakshya (d) 0.18 M Lakshya
Lakshya Lakshya
12. Lakshya
Liquid Lakshya
A and B form Lakshya
an ideal solution. If vapourLakshya
pressure
–2 –2
of pure A and B are 500 Nm and 200 Nm respectively,
6. How many
Lakshya grams of a dibasic
Lakshya acid (Mol.Lakshya
Lakshya wt. = 200) should
be present in 100 mL of its aqueous solution to give the vapour pressure of a solution of A in B containing 0.2
decinormal
Lakshya strength ? Lakshya
mole fraction of ALakshya
Lakshya
would be Lakshya Lakshya
–2 –2
(a) 700 N m (b) 300 N m
(a) 1g
Lakshya Lakshya (b) 2g
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
–2 –2
(c) 260 N m (d) 140 N m
Lakshya
(c) 10g Lakshya (d) 20g.
3 13. 3 moles of P and 2 moles of Q are mixed, what will be their
7. The normality
Lakshya Lakshyaof 10% HLakshya
2
SO4 solution (dLakshya
= 1.1g/cm ) isLakshya total vapour pressure
Lakshya in the solution
Lakshya if their partial
Lakshya vapour
Lakshya
pressures are 80 and 60 torr respectively ?
(a) 2.04 (b) 1.02
(a) 80 torr (b) 140 torr
(c) 1.85 (d) 2.25
72 torr Lakshya (d) 70
Lakshya
torr Lakshya
Lakshya Educare
2 SOLUTIONS
Ideal & Non-Ideal

Lakshya LakshyaSolutions
Lakshya Lakshya 17.
Lakshya Intermolecular
Lakshya forces between n-hexane
Lakshya and n-heptane
Lakshya are
Lakshya
nearly same as between hexane and heptane individually.
14. Study the
Lakshya figures given
Lakshya below and mark
Lakshya the correct
When Lakshya
these two are mixed, whichLakshya Lakshya
of the following is not
statement. true about the solution formed ?
(a) It obeys Raoult’s law, i.e. pA = x A p and p B  x B p oB
o
A

H mixing is zero.
(b)Lakshya Lakshya Lakshya Lakshya
Lakshya Lakshya Lakshya Lakshya Lakshya Vmixing is zero.Lakshya

(c)Lakshya Lakshya Lakshya
Lakshya Lakshya Lakshya Lakshya Lakshya (d)Lakshya

It forms minimum boiling azeotrope.
Lakshya Lakshya Lakshya Lakshya Colligative

Lakshya Properties
Lakshya Lakshya Lakshya Lakshya
(a) (i) Nitric acid + Water, (ii) Acetone + Lakshya Relative lowering in V.P.
Ethyl alcohol Lakshya
(b) (i) Water + Ethyl alcohol, (ii) Acetone + Benzene 18. 2g of sugar is added to one litre of water to give sugar
solution. What is Lakshya Lakshyaof sugar
the effect of addition Lakshya
on the
(c) (i) Acetone + Ethyl alcohol (ii) Acetone + Chloroform boiling point and freezing point of water ?
(d) (i) Benzene + Chloroform (ii) Acetone + Chloroform (a) Both boiling point and freezing point increase.
Lakshya Lakshya
15. Two liquids HNO3 (A) andLakshya
water (B) form aLakshya Lakshya
maximum boiling Lakshya Lakshya Lakshya
(b) Both boiling point and freezing point decrease.
Lakshya
azeotrope when mixed in the ratio of 68% and 32%
respectively. It means (c) Boiling point increases and freezing point decreases.
Lakshya
(a) A – BLakshya Lakshya
interactions are stronger thanLakshya
A – A and B –Lakshya
B (d)Lakshya Lakshya and freezing
Boiling point decreases Lakshya Lakshya
point increases.
interactions
Lakshya Lakshya Lakshya Lakshya 19.
Lakshya In Lakshya
three beakers labelled
Lakshyaas (A), Lakshya
(B) and (C), 100 mL of
Lakshya
(b) A – B interactions are weaker than A – A and B – B water, 100 mL of 1M solution of glucose in water and
Lakshya interactions
Lakshya Lakshya Lakshya Lakshya 100 mL of 0.5 MLakshya
Lakshya solution of glucose in water are
Lakshya taken
Lakshya
respectively and kept at same temperature.
(c) vapour
Lakshya pressure of Lakshya
Lakshya solution is more than the pure
components
(d) vapour pressure of solution is less since only one
Lakshya component
Lakshyavaporises.
16. When acetone and chloroform are mixed together, hydrogen
bonds are formed between them. Which of the following
statements is correct about the solution made by mixing Which of the following statements is correct ? Lakshya
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
acetone and chloroform ?
(a) Vapour pressure in all the three beakers is same.
Lakshya Lakshya
(a) On mixing Lakshya
acetone and chloroform Lakshya Lakshya
will form an ideal Lakshya Lakshya Lakshya Lakshya
solution (b) Vapour pressure of beaker B is highest.
(b) On mixing acetone and chloroform positive deviation (c) Vapour pressure of beaker C is highest.
Lakshya is shown
Lakshya Lakshya
since the vapour pressureLakshya
increases. Lakshya Lakshya Lakshya Lakshya Lakshya
(d) Vapour pressure of beaker B is lower than that of C and
(c) On mixing
Lakshya acetone and
Lakshya chloroform negative
Lakshya Lakshyadeviation
Lakshya vapour pressure ofLakshya
Lakshya beaker C is lower than that ofLakshya
Lakshya A.
is shown since there is decrease in vapour pressure.
20. Vapour pressure of a pure liquid X is 2 atm at 300 K. It is
(d) At a specific composition acetone and chloroform will lowered to 1 atm on dissolving 1g of Y in 20g of liquid X. If
Lakshya formLakshya
minimum boiling azeotrope. Lakshya
Lakshya Lakshya
molar mass of X isLakshya
Lakshya
200, what is theLakshya
molar mass ofLakshya
Y?
(a) 20 (b) 10
(c) 100 (d) 30
Lakshya Educare
SOLUTIONS 3
21. The vapour

Lakshya pressure of
Lakshya benzene at aLakshya
Lakshya certain temp.Lakshya
is 28. AtLakshya
certain hill-station, pure waterLakshya
Lakshya boils at 99.725ºC. If Kb
Lakshya
–1
640 mm Hg . A non-volatile-non-electrolyte solid weighing for water is 0.513ºC kg mol , the boiling point of 0.69m
2.175g isLakshya
Lakshya added to 39.0 gLakshya
of benzene. The vapour pressure
solution Lakshya
of urea will be Lakshya Lakshya
of the solution is 600 mm Hg. What is the molecular weight
Lakshya Lakshya
of the solid substance ?Lakshya Lakshya Lakshya (a)Lakshya
100.079ºC Lakshya (b) 103ºC
Lakshya Lakshya
(a) 6.96 Lakshya (b) 60 (c) 100.359ºC (d) unpredictable

–1
(c) 63.8 (d) none of the above 29. The molal b.p. constant for water is 0.513ºC kg mol . When
0.1 mole of sugar is dissolved in 200g of water, the solution
22. The vapour pressure of solution of 5g of non-electrolyte boils under a pressure of 1 atm at
–2
Lakshya Lakshya
in 100g of Lakshya
water at a particular Lakshya
temperature is 2985 NmLakshya
. Lakshya Lakshya Lakshya Lakshya
The vapour pressure of pure water at that temperature is (a) 100.513ºC (b) 100.0513ºC
Lakshya Lakshya
–2 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
3000 Nm . The molecular weight of the solute is (c) 100.256ºC (d) 101.025ºC
Lakshya
(a) 180 Lakshya Lakshya
(b) 90 Lakshya Lakshya
30. AnLakshya Lakshya
aqueous solution Lakshya
containing 1g of urea Lakshya
boils at
100.25ºC. The aqueous solution containing 3g of glucose
(c) 270 Lakshya
Lakshya (d) 200.
Lakshya Lakshya Lakshya inLakshya Lakshya
the same volume will boil at Lakshya Lakshya
23. Vapour pessure of CCl4 at 25ºC is 143 mm Hg. 0.5g of a (a)Lakshya

100.75ºC
Lakshya Lakshya Lakshya Lakshya 3Lakshya Lakshya (b) 100.5ºC
Lakshya Lakshya
non-volatile solute (mol. wt. 65) is dissolved in 100 cm of
(c) 100ºC (d) 100.25ºC
CCl4. Find
Lakshya the vapour pressure
Lakshya Lakshya of the solution.
Lakshya (Density
3
of CCl4 = 1.58 g/cm ). 31. If the elevation in boiling point of a solution of 10gm of
solute (mol. wt. = 100) in 100 gm of water is Lakshya
Tb , the
(a) 141.93 mm (b) 94.39 mm
Lakshya Lakshya Lakshya Lakshya Lakshya ebullioscopic
Lakshya constant of water is
(c) 199.34 mm (d) 143.99 mm
(a)Lakshya
10 (b) 10 Tb
Elevation
Lakshya in Lakshya
Boiling Point
24. A solution
Lakshya containing 12.5g
Lakshya of non-electrolyte
Lakshya LakshyasubstanceLakshya Tb
(c)Lakshya Lakshya (d) Lakshya
Tb /10 Lakshya
in 185g of water shows boiling point elevation of 0.80 K.
CalculateLakshya
Lakshya the molar mass of the substance.
Lakshya Lakshya Depression
Lakshya Lakshyain Freezing Point Lakshya
Lakshya Lakshya
(Kb = –1
) 32.
0.52 K kg molLakshya What weight of glycerol should be added to 600 g of water
in order to lower its freezing point by 10ºC ? (Kf = 1.86ºC m–1).
(a) 53.06g mol–1 (b) 25.3 g mol–1 (Molecular
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya mass of glycerol is 92)Lakshya
Lakshya Lakshya
–1 –1
(c) 16.08g mol (d) 43.92g mol (a) 496 g (b) 297 g
25. If 1g of solute (molar mass = 50g mol–1) is dissolved in 50g (c) 310 g (d) 426 g
in boilingLakshya Lakshya Lakshya Lakshya
of solvent and the elevation point is 1K. The 33. Sprinkling of salt helps in clearingLakshya Lakshya
the snow covered roads
molar boiling constant of the solvent is in hills. The phenomenon involved in the process is
(a) 2 (b) 3 (a) lowering in vapour pressure of snow
(c) 2.5 (d) 5 (b) depression in freezing point of snow
26. The molal
Lakshya elevation constant
Lakshya Lakshyafor water is 0.56ºC per kgLakshya
Lakshya of (c)Lakshya Lakshya
increase in freezing Lakshya
point of snow Lakshya
water. The boiling point of solution made by dissolving
melting of ice due to increase in
Lakshya temperature by
Lakshya putting
Lakshya
6.0g of water (NH2CONH 2
) in 200g of water is
salt.
(a) 10.028ºC
Lakshya Lakshya (b) 100.28ºCLakshya
34. A solution of 1.25g of non-electrolyte in 20g of water freezes
–1
(c) 50.14ºC (d) none of these atLakshya
271.94 K. If KLakshya
= 1.86 K Kg mol , then the molecular
Lakshya Lakshya Lakshya Lakshya Lakshya f Lakshya Lakshya
27. The boiling point of 0.1 molal aqueous solution of urea is weight of the solute will be (Tfo  0º C)
Lakshya
100.18ºCLakshya Lakshya
at 1 atm. The molal Lakshyaof waterLakshya
elevation constant is Lakshya Lakshya Lakshya Lakshya
–1 –1
(a) 179.79g mol (b) 207.8g mol
Lakshya
(a) 1.8 Lakshya (b) 0.18
–1 –1
(c) 18 (d) 18.6 (c) 209.6g mol (d) 109.6g mol
Lakshya Educare
4 SOLUTIONS
35. The amount

Lakshya of urea to Lakshya
Lakshya be dissolved inLakshya
500 cc of water Lakshya (a)Lakshya
Y-hypotonic solution,
LakshyaZ-hypertonic
Lakshyasolution Lakshya
(K = 1.86) to produce a depression of 0.186ºC in the freezing
Lakshya (b)Lakshya
Y-hypertonic solution,
Lakshya Z-hypotonic solution Lakshya
point is Lakshya Lakshya Lakshya Lakshya Lakshya
(c) Y and Z-isotonic solution
(a) 0.3 gm
Lakshya Lakshya (b) 3 gm
(d) Y and Z-hypotonic solutions
(c) 6 gm (d) 9 gm.
36. The molar freezing point constant for water is 1.86º C/m. If 42. Osmotic pressure of a solution containing 2g dissolved
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya 3
342g of cane sugar (C12H22O11) is dissolved in 1000 g of protein per 300 cmLakshya Lakshya
of solution in 20 Lakshya
mm of Hg at 27ºC. The
water, the solution will freeze at molecular mass of protein is
(a) –1.86º (b) 1.86ºC –1 –1
(a) 6239.6g mol (b) 12315.5 g mol
(c) –3.92ºC (d) 2.42ºC
(c) 3692.1 g mol–1 (d) 7368.4 g mol–1
37. Pure benzene freezes at 5.45ºC at a certain place but a
0.374m solution at 43. The osmotic pressure of a solution can be increased by
Lakshya Lakshyaof tetrachloroethane
Lakshya in benzene
LakshyafreezesLakshya Lakshya Lakshya Lakshya Lakshya
3.55ºC. The Kf for benzene is
(a) increasing the volume
Lakshya Lakshya–1 Lakshya Lakshya
–1 Lakshya Lakshya Lakshya Lakshya Lakshya
(a) 5.08 K kg mol (b) 508 K kg mol
(b) increasing the number of solute molecules
Lakshya Lakshya –1 Lakshya Lakshya
(c) 0.508K kg mol (d) 50.8ºC kg mol
(c) decreasing the temperature
38. If 15 gm of a solute in 100 gm of water makes a solution
that freezes at –1.0ºC, then 30 gm of the same solute Lakshya
in (d) removing semipermeable membrane.
100 gm of water will make a solution that freezes at
44. Sea water is desalinated to get fresh water by which of the
Lakshya Lakshya
(a) –0.5ºC Lakshya
(b) –2.0ºC Lakshya Lakshya LakshyamethodsLakshya
following ? Lakshya Lakshya
(c) 0ºC Lakshya

Lakshya (d) 2.0ºC
Lakshya Lakshya Lakshya (a)Lakshya
When pressureLakshya Lakshya
more than osmotic pressure isLakshya
applied
pure water is squeezed out of sea water by reverse
Osmotic
Lakshya Pressure
osmosis.
39. An aqueous
Lakshya solution ofLakshya
Lakshya a non-electrolyte solute boilsLakshya
Lakshya at
100.52ºC. The freezing point of the solution will be (Kf = (b)Lakshya
When excess Lakshya Lakshya
pressure is applied Lakshya
on sea water pure
–1 –1 water moves in by osmosis.
1.86K Kg
Lakshya mol , Kb = 0.52
Lakshya K kg mol ) Lakshya
(a) 0ºC Lakshya (b) –1.86ºC Lakshya (c) Water moves out from sea water due to osmosis.
(c) 1.86ºC (d) None of the above. (d) Salt is precipitated from sea water when kept
undisturbed for sometime. Lakshya Lakshya
40. A solution is made by dissolving 20g of a substance in
Lakshya
500 mL Lakshya LakshyapressureLakshya
was found to Lakshya Lakshya
of water. Its osmotic be 45. Osmotic pressure Lakshya Lakshya
is generally preferred Lakshya
for determining
600mm of Hg at 15ºC. Find the molecular weight of the the molecular masses of protein because
substance.
(a) it is difficult to find out mole fraction of protein for
Lakshya
(a) 1198 Lakshya Lakshya
(b) 500 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
calculations by other methods
(c) 1200 Lakshya
Lakshya (d) 1000
(b)Lakshya Lakshya
at elevated temperature theLakshya
proteins are Lakshya
likely to
41. Grapes placed in three beakers X, Y and Z containing decompose and osmotic pressure is measured around
different type of solutions are shown in figures. room temperature
Lakshya
If beakerLakshya Lakshya
X contains water, Lakshya
Y and Z contain Lakshya Lakshya Lakshya Lakshya Lakshya
(c) the apparatus involved in finding out osmotic pressure
is simpler thanLakshya
Lakshya
other methodsLakshya Lakshya
(d) it is easy to boil or freeze a solution containing proteins.


Lakshya Educare
SOLUTIONS 5
46. What will

Lakshya be the osmotic
Lakshya pressure in pascals
Lakshya exerted byLakshya
Lakshya a 52. Why is the molecular
Lakshya Lakshyamass determined
Lakshya by measuring
Lakshya
solution prepared by dissolving 1.0g of polymer of molar colligative property in case of some solutes is abnormal ?
mass 150,000
Lakshya in 500 mL Lakshya
Lakshya of water at 37ºCLakshya
? Lakshya Lakshya Lakshya Lakshya Lakshya
(a) Due to association or dissociation of solute molecules.
(a) 30.96 Lakshya
Lakshya Pa (b) 34.36 PaLakshya
(b) Due to insolubility of solute molecules.
(c) 68.72 Lakshya
Lakshya Pa (d) 48.25 PaLakshya
(c) Due to decomposition of solute molecules.
Deviation
Lakshya InLakshya
Colligative Lakshya
Properties Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(d) Due to large size of solute molecules.
47. Which ofLakshya
Lakshya the following will have same value
Lakshya of van’t Hoff
53. The elevation in Lakshya
boiling point ofLakshya
a solution of Lakshya
9.43g of
factor as that of K4 [Fe (CN)6] ? –1
MgCl2 in 1 kg of water is (Kb = 0.52 K kg mol , Molar mass
(a) Al2(SO4)3 (b) AlCl3 of MgCl2=94.3g mol–1)
(c) Al(NO3)3 (d) Al(OH)3 (a) 0.156 (b) 0.52
48. What will be the degree of dissociation of 0.1 M Mg(NO3)2 (c) 0.17 (d) 0.94
solution if
Lakshya van’t Hoff factor
Lakshya is 2.74 ? Lakshya
Lakshya Lakshya
54. Lakshya
Which Lakshya
of the following Lakshya
has the highest freezing Lakshya
point ?
(a) 75% Lakshya
Lakshya (b) 87%
Lakshya Lakshya Lakshya (a)Lakshya Lakshya (b) 1m
1m NaCl solution Lakshya
KCl solution Lakshya
(c) 100%Lakshya
Lakshya (d) 92%
1m AlCl3 solution
Lakshya (d) 1m C6H12O6 solution
Lakshya Lakshya
49. A solute Lakshya

Lakshya X when dissolved in a solvent associated
Lakshya Lakshya to form 55.
Lakshya What amount of CaCl
Lakshya (i = 2.47) Lakshya
Lakshya
2
is dissolved in 2Lakshya
litres of
a pentamer. The value of van’t Hoff factor (i) for the solute water so that its osmotic pressure is 0.5 atm at 27ºC ?
will be Lakshya
(a) 3.42 g (b) 9.24 g
(a) 0.5
Lakshya Lakshya (b) 5
2.834 g Lakshya (d) 1.825
Lakshya
g Lakshya
(c) 0.2
Lakshya Lakshya
(d) 0.1
Lakshya Lakshya 56.
Lakshya Which of the following
Lakshya statements
Lakshya is not correctLakshya
Lakshya ?
50. The van’t Hoff factor of 0.005 M aqueous solution of KCl (a)Lakshya
Osmotic pressure () of a solution
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshyais given by the
Lakshya
is 1.95. The degree of ionisation of KCl is relation  = MRT where M is the molarity of the solution.
Lakshya
(a) 0.95 Lakshya Lakshya
(b) 0.97 Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(b) The correct order of osmotic pressure for 0.2 M aqueous
Lakshya solution of each solute is CaClLakshya
> NaCl > CH3Lakshya
COOH >
(c) 0.94 Lakshya Lakshya
(d) 0.96 Lakshya Lakshya Lakshya
glucose.
Lakshya 2

Hoff factorLakshya
51. For which of the following solutes the van’t is (c)Lakshya
Two solutionsLakshya Lakshya
of sucrose of same Lakshya
molality prepared in
not greater than one ? different solvents will have same elevation boiling
point.
(a) NaNO3 (b) BaCl2
Lakshya Lakshya Lakshya Lakshya Lakshya (d)Lakshya Lakshya
Relative lowering in vapourLakshya
pressure of aLakshya
solution
(c) K4[Fe(CN)6] (d) NH2CONH2 containing non-volatile solute is directly proportional
to mole fraction of solute is Raoult’s law.

Lakshya Educare
6 SOLUTIONS

EXERCISE - 2 : PREVIOUS YEAR JEE MAINS QUESTION

Which one of theLakshya Lakshya
following statements is false ?Lakshya
1. An aqueous solution freezes at – 0.186ºC (kf = 1.86; 7. (2004)
kb = 0.512).
Lakshya What is the Lakshya
Lakshya elevation in boiling point (2002)
Lakshya Lakshya (a)Lakshya
Two sucrose solutions
Lakshya of same molality prepared
Lakshya in
Lakshya
different solvents will have same value of Tf
(a) 0.186 ºC (b) 0.512 ºC
(b) Osmotic pressure of a solution is given by equation
(c) 0.86 ºC (d) 0.0512 ºC = MRT where M is molarity of solution
2. In a mixture A and B components show negative deviation (c) The correct order of osmotic pressure for 0.01 M
as
Lakshya Lakshya Lakshya Lakshya (2002) Lakshya aqueous solution
Lakshya of each compound
Lakshya Lakshyais Lakshya
(a) Vmix > 0 (b) Vmix < 0 BaCl2 > KCl > CH3COOH > Sucrose.
(d) Raoult’s law states that vapour pressure of a
(c) A–B interactions are weaker then component over a solution is Lakshya
proportional toLakshya
its mole
fraction.
A–A and B–B interactions
Lakshya Lakshya Lakshya Lakshya 8.
Lakshya ToLakshya
neutralize completely
Lakshya 20 mL ofLakshya
0.1 M aqueousLakshya
solution
(d) None of the above reasons is correct of phosphrous acid (H3PO3), the volume of 0.1 M aqueous
Lakshya
3. If liquid Lakshya Lakshya
A and B from ideal solutions Lakshya (2003)
Lakshya solution
Lakshyaof KOH required
Lakshya is Lakshya (2004)
Lakshya
(a) 60 mL (b) 20 mL
(a) The enthalpy
Lakshya Lakshyaof mixing is zero
(c) 40 mL (d) 10 mL
Lakshya
(b) The entropy
Lakshya
of mixing is zero
9. Which of the following pairs showLakshya Lakshya
positive deviation from
(c) The free energy of mixing is zero Raoult’s law ? (2004)
(d) The free energy as well as entropy of mixing are each (a) Acetone–chloroform (b) Benzene-methanol
Lakshya zero Lakshya Lakshya Lakshya Lakshya (c)Lakshya Lakshya (d) Water
Water-Nitric acid Lakshya Lakshya
hydrochloric acid
4. A pressure cooker reduces cooking time for food because 10. Which one of the Lakshya
following aqueous solutions will exhibit
highest boiling point (2004)
(2003)
Lakshya Lakshya Lakshya Lakshya Lakshya (a)Lakshya Lakshya (b) 0.01
0.015 m glucose Lakshya
m KNO3 Lakshya
(a) heat is more evenly distributed in cooking space
0.015 m urea Lakshya (d) 0.01 m Na2SO4 Lakshya
Lakshya
(b) boiling point of water involved in cooking is increased 20
11. 6.02 × 10 molecules of urea are present in 100 mL of its
Lakshya
(c) higherLakshya
pressure insideLakshya Lakshya
the cooker crushed Lakshya
food material LakshyaThe concentration
solution. Lakshya of ureaLakshya
is Lakshya
(2004)
(d) cooking
Lakshya involves chemical
Lakshya LakshyachangesLakshya
helped by rise Lakshya
in (a)Lakshya
0.1 M Lakshya (b) 0.01 M
Lakshya Lakshya
temperature (c) 0.02 M (d) 0.001 M
5. The elevation in boiling point of a solution of 13.44 g of 12. If  is degree of dissociation of Na2So4, the van’t Hoff’s
–1
CuCl2 (molecular
Lakshya LakshyaweightLakshya
= 134.4, Kb = 0.52 K molarity )Lakshya
Lakshya in factor, i, used for Lakshya
Lakshya calculating the Lakshya
molar mass is Lakshya
(2005)
1 kg water using the following information will be
(a) 1 – 2 (b) 1 + 2
(2003) (c) 1 –  (d) 1 + 
Lakshya
(b) 0.05 Lakshya Lakshya
13. Lakshya
Benzene Lakshya
and toluene form nearlyLakshya
ideal solutions.Lakshya
At 20ºC,
the vapour pressure of benzene is 75 Torr and that of
(c) 0.1 Lakshya
Lakshya (d) 0.2
Lakshya Lakshya Lakshya toluene is 22 Torr.Lakshya
Lakshya The partial vapour pressure ofLakshya
Lakshya benzene
at 20ºC for a solution containing 78 g of benzene and 46 g
6. In 0.2m aqueous solution of weak acid HX, the degree of ofLakshya
toluene in TorrLakshya
is (2005)
ionization is 0.3. Taking Kf for water as 1.85, the freezing
(a) 53.5 (b) 37.5
point of Lakshya
Lakshya solution will beLakshya
nearest to Lakshya (2003) Lakshya Lakshya Lakshya Lakshya Lakshya
(c) 25 (d) 50
(a) + 0.480 ºC (b) – 0.360 ºC
(b) – 0.260 ºC (d) – 0.480 ºC
Lakshya Educare
SOLUTIONS 7
14. Two solutions

Lakshya of a substance
Lakshya (non-electrolyte)
Lakshya Lakshyaare mixed 21.
Lakshya The vapour pressure
Lakshya of water atLakshya
Lakshya 20ºC is 17.5 mmHg.
Lakshya If
in the following manner. 18 g of glucose (C6H12O6) is added to 178.2 g of water at
Lakshya
480 mL Lakshya Lakshya
of 1.5M first solution Lakshya
+ 520 mL Lakshya
of 1.2M second 20ºC, the vapour Lakshya
Lakshya pressure of the resulting
Lakshya solution will be
Lakshya
(2008)
solution.
Lakshya Lakshya Lakshya Lakshya Lakshya (a)Lakshya
17.675 mmHg Lakshya (b) 15.750
Lakshya
mmHg Lakshya
What is the molarity of the final mixture ? (2005)
Lakshya Lakshya
(a) 2.70 M Lakshya
(b) 1.34 M Lakshya Lakshya (c)Lakshya
16.500 mmHg Lakshya (d) 17.325 mmHg
Lakshya Lakshya
22. At 80ºC, the vapour pressure of pure liquid ‘A’ is 520 mm Hg
(c) 1.50 M
Lakshya Lakshya (d) 1.20 M Lakshya
and that of pure liquid ‘B’ is 1000 mm Hg. If aLakshya
mixture
15. 18 g of glucose (C6H12O6) is added to 178.2g of water. The solution of ‘A’ and ‘B’ boils at 80ºC and 1 atm pressure the
amount Lakshya
of ‘A’ in the mixture is (1 Lakshya
atm = 760 mmHg) Lakshya
vapour pressure of water for this aqueous solution at 100ºC
is (pºwaterLakshya
= 760 mm Hg)Lakshya (2006) (2008)
(a) 759.00 Torr (b) 7.60 Torr (a) 52 mole percent (b) 34 mole percent
Lakshya Lakshya Lakshya Lakshya Lakshya (c)Lakshya Lakshya (d) 50
48 mole percent Lakshya
mole percent Lakshya
(c) 76.00 Torr (d) 752.40 Torr
Lakshya
16. Density Lakshya Lakshyaof aceticLakshya
of a 2.05 M solution is 23.
acid in waterLakshya ALakshya
binary liquid solution
Lakshya is prepared by mixing n-heptane
Lakshya Lakshya
1.02g/mL. The molality of the solution is (2006) and ethanol. Which one of the following statements is
Lakshya Lakshya Lakshya Lakshya Lakshya correct
LakshyaregardingLakshya
the behaviour of the solution ?Lakshya
Lakshya (2008)
–1 –1
(a) 1.14 mol kg (b) 3.28 mol kg
(a) The solution formed is an ideal solution
Lakshya Lakshya
–1 Lakshya Lakshya
(c) 2.28 mol kg (d) 0.44 mol kg (b) The solution is non-ideal, showing positive deviation
Lakshya from Raoult’s Lakshya
law.
17. A 5.25%Lakshya
solution of a Lakshya Lakshya
substance is isotonic Lakshya
with a 1.5% Lakshya Lakshya Lakshya
–1
solution of urea (molar mass = 60 g mol ) in the same (c) The solution is non-ideal, showing negative deviation
solvent. If the densities of both the solutions are assumed from Raoult’s law
–3
to be equal to 1.0 g cm , molar mass of the substance will
n-heptane shows positive deviation
Lakshya Lakshya whileLakshya
ethanol
be (2007) show negative deviation from Raoult’s law
–1 –1
Lakshya
(a) 90.0gLakshya
mol Lakshya Lakshya
(b) 115.0g mol Lakshya Lakshya Lakshya Lakshya Lakshya
24. Two liquids X and Y form an ideal solution at 300 K, vapour
–1 –1 pressure of the solution containing 1 mol of X and 3 mol of
(c) 105.0g
Lakshya mol
Lakshya (d) 210.0g mol
Lakshya Lakshya Lakshya YLakshya
is 550 mm Hg. AtLakshya Lakshya if 1 mol
the same temperature, Lakshya
of Y is
18. Equal masses of methaneLakshya
and oxygen areLakshya
mixed in an empty further added to this solution, vapour pressure of the
solution increasesLakshya
by 10 mm Hg.Lakshya
Vapour pressureLakshya
(in mm
container at 25ºC. The fraction of the total pressure exerted
by oxygen is (2007) Hg) of X and Y in their pure states will be, respectively
(2009)
2 1 273 (a)Lakshya
200 and 300 Lakshya (b) 300 and 400
Lakshya
(a) Lakshya (b) 
3 3 298
(c) 400 and 600 (d) 500 and 600
1 1 25. On mixing, heptane and octane form an ideal solution. At
(c) (d)
Lakshya 3 Lakshya Lakshya2 Lakshya Lakshya 373 K, the vapourLakshya
Lakshya pressures of the two liquid components
Lakshya Lakshya
(heptane and octane) are 105 kPa and 45 kPa respectively.
19. A mixture of ethyl alcohol and propyl alcohol has a vapour Vapour pressure of the solution obtained
Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshyaby mixing 25g of
Lakshya
pressure of 290 mm at 300K. The vapour pressure of propyl heptane and 35g octane will be (molar mass of heptane =
–1 –1
alcohol is 200mm. If the mole fraction of ethyl alcohol is 100 g mol and ofLakshya
octane = 114 gLakshya
mol ) (2010)
Lakshya Lakshya
0.6, its vapour pressureLakshya
(in mm) at the Lakshya Lakshya
same temperature Lakshya Lakshya
will be (2007) (a) 72.0 kPa (b) 36.1 kPa
(a) 350 (b) 300 (c) 96.2 kPa (d) 144.5 kPa
(c) 700 (d) 360 26. If sodium sulphate is considered to be completely
dissociated into cations and anions in aqueous solution,
20. The density
Lakshya in g/ml of Lakshya
Lakshya a 3.60 M sulphuric acid solution
the change in freezing point of water (Tf), when 0.01 mole
which is 29% H2SO4 (molar mass = 98 g/mol) by mass will be of sodium sulphate is dissolved in 1 kg of water, is
–1 Lakshya Lakshya
(2007) (kf = 1.86 K Kg mol ) (2010)
Lakshya
(b) 1.64 Lakshya Lakshya (a)Lakshya
0.0372 K Lakshya (b) 0.0558
Lakshya
K Lakshya
(c) 1.88 Lakshya

Lakshya (d) 1.22
0.0744 K Lakshya (d) 0.0186 K
Lakshya Lakshya
Lakshya Educare
8 SOLUTIONS
27. The molality
Lakshya of a urea solution
Lakshya Lakshyain whichLakshya
0.0100g of urea,
Lakshya
34. Consider
LakshyaseparateLakshya
solutions of 0.500 M
Lakshya Lakshya
3
[(NH2)2CO] is added to 0.3000 dm of water at STP is
Lakshya Lakshya Lakshya Lakshya Lakshya C2Lakshya
H5OH(aq), 0.100 M Mg3(PO4)Lakshya
Lakshya 2
(aq), 0.250 MLakshya
KBr(aq)
(2011) and 0.125 M Na3PO4(aq) at 25ºC. Which statement is true
Lakshya
(a) 0.555 m
–4
(b) 5.55 × 10 m
Lakshya about these solutions,
Lakshya LakshyaassumingLakshya
all salts to be strong
Lakshya
electrolytes ? (2014)
–2
Lakshya Lakshya
(c) 33.3 m Lakshya
(d) 3.33 × 10Lakshya
m Lakshya Lakshya Lakshya Lakshya Lakshya
(a) 0.100 M Mg3(PO4) 2(aq) has the highest osmotic
28. A 5% solution
Lakshya of cane sugar
Lakshya (molar mass
Lakshya 342) is isotonic
Lakshya Lakshya pressure.
with 1% of a solution of an unknown solute. The molar
mass of Lakshya
Lakshya unknown soluteLakshya
in g/mol is Lakshya (2011) Lakshya (b)Lakshya
0.125 M Na3PO (aq) has the highest
Lakshya
4 Lakshya osmotic Lakshya
pressure.
(a) 136.2 (b) 171.2 (c) 0.500 M C2H5OH(aq) has the highest osmotic pressure.
(c) 68.4 (d) 34.2 (d) They all have the same osmotic pressure.
29. The degree of dissociation () of a weak electrolyte, AxBy
35. The vapour pressure of acetone at 20°C is 185 torr. When
is relatedLakshya
Lakshya to van’t Hoff factor (i) by the expression
Lakshya Lakshya (2011)
1.2 g of a non-volatile substance was dissolved in 100 g
i 1
Lakshya   Lakshya Lakshya  iLakshya
1 Lakshya
(a) (b) ofLakshya Lakshya
acetone at 20°C, Lakshya
its vapour pressure was 183 Lakshya
torr. The
(x  y  1) x  y 1
–1
Lakshya Lakshya Lakshya Lakshya Lakshya molar mass (g mol
Lakshya ) of the substance
Lakshya is:
Lakshya (2015)
Lakshya
x  y 1 x  y 1
(c)   Lakshya
Lakshya (d)  
Lakshya Lakshya Lakshya (a)Lakshya
128 Lakshya (b) 488
Lakshya Lakshya
i 1 i 1
Lakshya
30. EthyleneLakshya
glycol is used Lakshya
as an antifreezeLakshya Lakshya
in a cold climate. (c)Lakshya
32 Lakshya (d) 64Lakshya Lakshya
Mass of ethylene glycol which should be added to 4 kg of
Lakshya
water toLakshya
prevent it fromLakshya Lakshya
freezing at –6ºC 36.
Lakshya
will be (Kf for 18Lakshya
g glucose (C6Lakshya
H12O6) is addedLakshya
to 178.2 g water. The
Lakshya
–1
water = 1.86 K kg mol . and molar mass of ethylene glycol vapour pressure of water (in torr) for this aqueous solution
Lakshya Lakshya
–1 Lakshya Lakshya Lakshya is:Lakshya Lakshya Lakshya Lakshya
(2016)
= 62 g mol ) (2011)
(a) 804.32
Lakshya g
Lakshya (b) 204.30 gLakshya
Lakshya Lakshya (a)Lakshya
76.0 Lakshya (b) 752.4
Lakshya Lakshya
(c) 400.00 g (d) 304.60 gLakshya (c) 759.0 (d) 7.6

31. A 5.2 molal aqueous solution of methyl alcohol, CH3OH, 37 . The freezing point of benzene decreases by 0.45°C when
is supplied. What is the mole fraction of methyl alcohol in 0.2 g of acetic acid is added to 20 g of benzene. If acetic
the solution
Lakshya ?
Lakshya Lakshya Lakshya (2011) Lakshya Lakshya Lakshya Lakshya Lakshya
acid associates to form a dimer in benzene, percentage
(a) 0.100 (b) 0.190
Lakshya Lakshya Lakshya Lakshya Lakshya association
Lakshya of acetic acid in benzene
Lakshya will be :
Lakshya Lakshya
(c) 0.086 (d) 0.050
Lakshya Lakshya Lakshya Lakshya Lakshya (KLakshya Lakshya
for benzene = 5.12 K kg mol–1)Lakshya Lakshya
(2017)
–1 f
32. Kf for water is 1.86 K kg mol . If your automobile radiator
Lakshya
holds 1.0Lakshya Lakshya
kg of water, how many grams Lakshya Lakshya
of ethylene glycol (a)Lakshya
80.4% Lakshya Lakshya
(b) 74.6% Lakshya
(C H O ) must you add to get the freezing point of the
Lakshya 2 6 2Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
solution lowered to –2.8ºC ? (2012) (c) 94.6% (d) 64.6%
Lakshya
(a) 72 g Lakshya Lakshya
(b) 93 g Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
38 . What quantity (in mL) of a 45% acid solution of a mono-
Lakshya
(c) 39 Lakshya Lakshya
(d) 27 g Lakshya Lakshya Lakshya
protic strong acidLakshya
must be mixedLakshya Lakshya
with a 20% solution of
33. The density
Lakshya of a solution
Lakshya prepared by dissolving
Lakshya Lakshya 120g Lakshya
of theLakshya
same acid to Lakshya
produce 800 mL of a 29.875%
Lakshya acid
Lakshya
urea (mol. mass = 60 u) in 1000 g of water is 1.15g/mL. The solution ? (2017)
Lakshya
molarityLakshya
of this solutionLakshya
is Lakshya (2012) Lakshya Lakshya Lakshya Lakshya Lakshya
(a) 0.50 M (b) 1.78 M Lakshya (a) 320 (b) 325

(c) 1.02 M (d) 2.05 M (c)Lakshya
316 (d) 330
Lakshya Educare
SOLUTIONS 9
Lakshya
39. Lakshya
For 1 molal Lakshya
aqueous solution Lakshya
of the following 5.
Lakshya
compounds, The solubility of N
Lakshya in water at 300
Lakshya
2
K and 500 torr
Lakshya partial
Lakshya
pressure is 0.01 g L”1. The solubility (in g L”1) at 750 torr
which one
Lakshya will show theLakshya
Lakshya highest freezing point? (2018)
Lakshya Lakshya partial pressure isLakshya
Lakshya : Online 2016Lakshya
Lakshya SET (1)
(a) [Co(HLakshya
Lakshya 2
O)4Cl2]Cl.2H2OLakshya
(b) [Co(H2O) Cl3].3H2O
Lakshya
3 Lakshya (a)Lakshya
0.0075 (b) 0.015Lakshya
Lakshya Lakshya
(c) [Co(HLakshya
Lakshya O)6]Cl3 (d) [Co(H2O)
Lakshya Cl]Cl2.H2O Lakshya
Lakshya
(c)Lakshya
0.02 Lakshya
(d) 0.005Lakshya Lakshya
2 5
6. AnLakshya
aqueous solution of a salt MXLakshya
at certain temperature
JEE MAINSLakshya
Lakshya ONLINELakshya
QUESTION
Lakshya Lakshya Lakshya 2 Lakshya
has a van’t Hoff factor of 2. The degree of dissociation for
this solution of the salt is Online 2016 SET (2)
Lakshya
1. Choose Lakshya Lakshya
the correct statement Lakshya
with respect Lakshya
to the vapour Lakshya Lakshya Lakshya Lakshya
pressure of a liquid among the following : (a) 0.33 (b) 0.50
Online 2014 SET (1) (c) 0.67 (d) 0.80
(a) Decreases linearly with increasing temperature
7. 5g of Na2SO4 was dissolved in x g of H2O. The change in
(b) Increases linearly with increasing temperature freezing point was found to be 3.82°C. If Na2SO4 is 81.5%
ionized, the value of x Online 2017 SET (1)
(c) Increases non-linearly with increasing temperature
(Kf for water = 1.86°C kg mol–1) is approximately :
(d) Decreases non-linearly with increasing temperature.
(molar mass of S = 32 g mol and that of Na = 23 g mol–1)
–1
Lakshya
2. Lakshya
For an ideal solution ofLakshya Lakshya
two components Lakshya
A and B, which Lakshya Lakshya Lakshya Lakshya
of the following is true ? Online 2014 SET (4) (a) 15 g (b) 25 g
(a) Hmixing > 0 (zero) (c) 45 g (d) 65 g
(b) A – A, B – B and A – B interactions are identical 8. A solution is prepared by mixing 8.5 g of CH2Cl2 and 11.95
g of CHCl3. If vapour pressure of CH Cl and CHCl
2 2 3
at 298
(c) A – B interaction is stronger than A – A and B – B K are 415 and 200 mm Hg respectively, the mole fraction of
interactions
CHCl Lakshya
in vapour form is : Lakshya
Online 2017Lakshya
SET (2)
3
(d) Hmixing
Lakshya < 0 (zero) Lakshya
(Molar mass of Cl = 35.5 g mol–1)
3. The observed
Lakshya Lakshyaosmotic pressure
Lakshya for a 0.10 M solution Lakshya
Lakshya of
(a)Lakshya
0.162 Lakshya
(b) 0.675Lakshya Lakshya
Fe(NH4)2(SO4)2 at 25°C is 10.8 atm. The expected and
Lakshya Lakshya
experimental (observed)Lakshya
values of Van’t Lakshya Lakshya
Hoff factor (i) will (c)Lakshya
0.325 Lakshya
(d) 0.486Lakshya Lakshya
be respectively :
9. Lakshya
Two Lakshya
5 molal solutions Lakshya
are prepared by dissolvingLakshya
a non-
(R = 0.082 L atm K– mol–1) Online 2014 SET (4) electrolyte non-volatile solute separately in the
Lakshya Lakshya Lakshya Lakshya Lakshya solvents
LakshyaX and Y.Lakshya
The molecularLakshya
weights of the Lakshya
(a) 5 and 4.42 (b) 5 and 3.42 solvents are MX and MY, respectively where
3
(c) 3 and 5.42 (d) 4 and 4.00 MX = MY . The relative lowering of vapour pressure of
Lakshya Lakshya Lakshya Lakshya Lakshya 4
4. Determination of the molar mass of acetic acid in benzene the solution in X is “m” times that of the solution in Y.
using freezing point depression Given that the number of moles of solute is very small in
Lakshya Lakshya Lakshya is affected by :
comparison to that of solvent, theLakshya
value of “m” Lakshya
is :
Lakshya Lakshya Lakshya Online 2015 SET (1)
Online 2018Lakshya
SET (2)
(a) partial
Lakshya ionization
Lakshya (b) dissociation
4 Lakshya 3 Lakshya Lakshya
(a) (b)
(c) complex
Lakshya formation Lakshya
Lakshya (d) associationLakshya Lakshya
3
Lakshya Lakshya
4 Lakshya Lakshya
Lakshya Lakshya Lakshya Lakshya Lakshya 1

Lakshya Lakshya 1 Lakshya Lakshya
(c) (d)
2 4
Lakshya Educare
10 SOLUTIONS
10. The massLakshya
Lakshya of a non-volatile, non-electrolyte
Lakshya solute (molar
Lakshya 15.
Lakshya AnLakshya
Open beaker ofLakshya
water in equilibrium
Lakshyawith water vapour
Lakshya
-1 is in a sealed container. When a few grams of glucose are
mass =50 g mol ) needed to be dissolved in 114 g octane
Lakshya
to reduceLakshya Lakshya
its vapour pressure Lakshya
to 75 percent is : Lakshya added to the beaker
Lakshya of water, the
Lakshya rate at which
Lakshya water
Lakshya
Online 2018 SET (3) molecules : [Main Sep. 02, 2020 (I)]
(1) 37.5 g (2) 75 g (a) leaves the vapour increases
(3) 150 gLakshya
Lakshya (4) 50 g
Lakshya Lakshya Lakshya (b)Lakshya Lakshya
leaves the solution increasesLakshya Lakshya
11. The vapour pressures of pure liquids A and B are 400 and
Lakshya (c)Lakshya
leaves the solution decreasesLakshya
600 mmLakshya Lakshya
Hg, respectively Lakshya
at 298 K. On Lakshya
mixing the two Lakshya Lakshya
liquids, the sum of their volumes is equal to the volume of (d) leaves the vapour decreases.
Lakshya LakshyaThe mole
the final mixture. Lakshya Lakshya
fraction of liquid Lakshya
B is 0.5 in the Lakshya Lakshya Lakshya Lakshya
mixture. The vapour pressure of the final solution, the 16. A set of solutions is prepared using 180g of water as a
Lakshya Lakshya
mole fractions Lakshya
of components A and BLakshya Lakshya
in vapour phase, Lakshya
solvent and 10g Lakshya Lakshya solutes.
of different non-volatile Lakshya
A, B
respectively are : Online 2019 SET (1) and C. The relative lowering of vapour pressure in the
presence of these Lakshya Lakshya
solutes are in order Lakshya
[Given, molar mass
(a) 500 mm Hg, 0.4, 0.6 (b) 500 mm Hg, 0.5, 0.5
of A = 100g mol ; B = 200g mol ; C = 10,000g mol–1]
–1 –1
(c) 450 mm
Lakshya Hg, 0.5, 0.5 Lakshya
Lakshya (d) 450 mm Hg,Lakshya
0.4, 0.6 Lakshya Lakshya Lakshya Lakshya Lakshya
12. Liquid ‘M’ and liquid ‘N’ form an ideal solution. The vapour [Main Sep. 06, 2020 (II)]
Lakshya
pressuresLakshya Lakshya
of pure liquids ‘M’ and ‘N’ Lakshya
are 450 andLakshya (a)Lakshya
B > C >A Lakshya
(b) C > BLakshya
>A Lakshya
700 mm Hg, respectively at the same temperature. Then
Lakshya Lakshya is : Lakshya
correct statement Lakshya Lakshya (c)Lakshya
A> B > C (d) A > CLakshya
Lakshya >B Lakshya
(x = mole fraction of ‘M’ in solution; xN = mole fraction of 17. A graph of vapour pressure and temperature for three
LakshyaM Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
‘N’ in solution. different liquids X, Y, and Z is shown below :
(yM = mole
Lakshya fraction of Lakshya
Lakshya ‘M’ in vapour Lakshya
phase; yN = mole
fraction of ‘M’ in vapour phase) Online 2019 SET (2)
xM yM xM yM
(a) x  Y (b) x  Y
Lakshya N Lakshya
N Lakshya
N N Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya
(c) (x M Lakshya
Lakshya y M )  (x N  y N)
Lakshya x M  yM
(d) x yN
N The following inferences are made :(Main Jan. 08, 2020 (I))
13. At room temperature, a dilute solution of urea is prepared (A) X has higher intermolecular interactions compared to Y.
by dissolving
Lakshya
0.60 g of urea
Lakshya
in 360 g of water.
Lakshya
if the vapour
pressure of pure water at this temperature is 35 mm Hg, (B) X has lower intermolecular interactions compared to Y.
lowring of vapour pressure will be : (molar mass of urea = (C) Z has lower intermolecular interactions compared to Y.
60 g mol–1) Online 2019 SET (3)
(a) (A) and (C) (b) only (A)
(a) 0.027Lakshya
Lakshya mmHg (b) 0.031 mmHg
(c) 0.028 mmHg (d) 0.017 mmHg (c) only (B) (d) only (c)
14. Two open beakers on containing a solvent and the other 18. At 35ºC, the vapour pressure of CS2 is 512 mm Hg and that
containing a mixture of that solvent with a non volatile
Lakshya Lakshya Lakshya Lakshya Lakshya ofLakshya Lakshya
acetone is 344 mm Lakshya
Hg. A solution Lakshya
of CS2 in acetone has
solute are together sealed in a container. Over time;
a total vapour pressure of 600 mm Hg. The false statement
Lakshya Lakshya Lakshya[Main Lakshya
jan. 07, 2020 (II)]
Lakshya Lakshya
amongst Lakshya
the following is : Lakshya
(Main Jan. 7, Lakshya
2020 (I))
(a) the volume of the solution increases and the volume
Lakshya Lakshya
of the solvent decreasesLakshya Lakshya Lakshya (a)Lakshya
Raoult’s law isLakshya
not obeyed byLakshya
this system Lakshya
(b) the volume of the solution decreases and the volume (b) a mixture of 100 mL CS2 and 100 mL acetone has a
of the solvent increases volume < 200 mL
(c) the volume
Lakshya of the solution
Lakshya Lakshyaand theLakshya
solvent does not
Lakshya (c)Lakshya Lakshya
CS2 and acetone Lakshya
are less attracted Lakshya
to each other than
change
to themselves
Lakshya Lakshya
(d) the volume Lakshyadoes not
of the solution Lakshya Lakshya
change and the Lakshya Lakshya Lakshya Lakshya
volume of the solvent decreases. (d) heat must be absorbed in order to produce the solution
Lakshya Lakshya Lakshya Lakshya Lakshya at Lakshya
35ºC Lakshya Lakshya Lakshya
Lakshya Educare
SOLUTIONS 11
Lakshya Lakshya Lakshya ANSWER

Lakshya KEY
Lakshya
EXERCISELakshya
- 1 : BASIC Lakshya Lakshya
OBJECTIVE Lakshya
QUESTIONS Lakshya Lakshya Lakshya Lakshya

1. (a) 2. (c) 3. (b) 4. (a) 5. Lakshya
(b) 6. (a)Lakshya7. (d) Lakshya
8. (a) Lakshya
9. (c) Lakshya
10. (c)
Lakshya
11. (c) Lakshya
12. (c) Lakshya
13. (c) Lakshya
14. (c) 15.Lakshya
(a) Lakshya17. (d) Lakshya
16. (c) 18. (c) Lakshya
19. (d) Lakshya
20. (b)
Lakshya
21. (d) Lakshya
22. (a) Lakshya
23. (a) Lakshya
24. (d) 25.Lakshya
(c) Lakshya
26. (b) 27. (a) Lakshya
28. (a) Lakshya
29. (c) Lakshya
30. (d)
Lakshya
31. (c) Lakshya
32. (b) Lakshya
33. (b) Lakshya
34. (d) 35.Lakshya
(b) Lakshya37. (a) Lakshya
36. (a) 38. (b) Lakshya
39. (b) Lakshya
40. (a)
Lakshya
41. (a) Lakshya
42. (a) Lakshya
43. (b) Lakshya
44. (a) 45.Lakshya
(b) Lakshya
46. (b) 47. (a) Lakshya
48. (b) Lakshya
49. (c) Lakshya
50. (a)
Lakshya
51. (d) Lakshya
52. (a) Lakshya
53. (a) Lakshya
54. (d) 55.Lakshya
(d) Lakshya
56. (c) Lakshya Lakshya Lakshya

EXERCISE - 2 : PREVIOUS YEAR JEE MAINS QUESTIONS
1. (d) 2. (b) 3. (a) 4. (b) 5. (a) 6. (d) 7. (a) 8. (c) 9. (b) 10. (d)
11. (b) 12. (b) 13. (d) 14. (b) 15. (d) 16. (c) 17. (d) 18. (c) 19. (a) 20. (d)
21. (d) Lakshya
Lakshya 22. (d) 23. (b)
Lakshya 24. (c)
Lakshya (c)
25.Lakshya 26. (b)
Lakshya27. (b) Lakshya
28. (c) 29. (a)
Lakshya 30. (a)
Lakshya
31. (c) Lakshya

Lakshya 32. (b) 33. (d)
Lakshya 34. (d)
Lakshya (d)
35.Lakshya Lakshya37. (c)Lakshya
36. (b) 38. (c) Lakshya
39. (b) Lakshya
JEE Mains
Lakshya Online
1. (c)
Lakshya 2. (b)
Lakshya 3. (a)
Lakshya 4. (d)
Lakshya (b)
5. Lakshya 6. (b)Lakshya7. (c) Lakshya
8. (c) 9. (b)
Lakshya 10. (c)
Lakshya
11. (a) Lakshya

Lakshya 12. (a) 13. (d)
Lakshya 14. (b)
Lakshya (a)
15.Lakshya 16. (c)
Lakshya17. (c) Lakshya
18. (b) Lakshya Lakshya

Dream on !!
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Lakshya Educare

Solutions Chemistry (NM) (Ex-1 &amp; 2)

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Solutions Chemistry (NM) (Ex-1 &amp; 2)

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SOLUTIONS 1

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya SOLUTIONS

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

(a) 84.72% (b) 15.28 % 5

(a) 0.01 Lakshya

Ideal & Non-Ideal

Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Vmixing is zero.Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya (d)Lakshya

Lakshya Lakshya Lakshya Lakshya Colligative

21. The vapour

(a) 6.96 Lakshya (b) 60 (c) 100.359ºC (d) unpredictable

23. Vapour pessure of CCl4 at 25ºC is 143 mm Hg. 0.5g of a (a)Lakshya

35. The amount

(c) 0ºC Lakshya

(d) it is easy to boil or freeze a solution containing proteins.

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

46. What will

49. A solute Lakshya

Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

14. Two solutions

(c) 1.88 Lakshya

(c) 400.00 g (d) 304.60 gLakshya (c) 759.0 (d) 7.6

(a) 0.50 M (b) 1.78 M Lakshya (a) 320 (b) 325

Lakshya Lakshya Lakshya Lakshya Lakshya 1

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya ANSWER

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

31. (c) Lakshya

11. (a) Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya Lakshya

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