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CODE

0
FULL SYLLABUS TEST-2 (FST-2)-JEE (ADVANCED)
TARGET : JEE (ADVANCED)-2013 COURSE : REVISION CLASSES
Date : 08-05-2013 Duration : 3 Hours Max. Marks : 204
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS
PAPER - 2
A. General :
1. This Question Paper contains 45 questions.
2. The question paper CODE is printed on the right hand top corner on this sheet of this booklet.
3. No additional sheets will be provided for rough work.
4. Blank paper, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
in any form are not allowed.
5. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately.
6. Do not Tamper / mutilate the ORS or this booklet.

DO NOT BREAK THE SEALS WITHOUT BEING


INSTRUCTED TO DO SO BY THE INVIGILATOR
7. Do not break the seals of the question-paper booklet before instructed to do so by the invigilators.
8. Write your Name, Roll No. and Sign in the space provide on the back page of this booklet.
B. Filling the Top-half of the ORS :
Use only Black ball point pen only for filling the ORS. Do not use Gel / Ink / Felt pen as it might smudge the
ORS.
9. Write your Roll no. in the boxes given at the top left corner of your ORS with black ball point pen. Also, darken
the corresponding bubbles with Black ball point pen only. Also fill your roll no on the back side of your ORS
in the space provided (if the ORS is both side printed).
10. Fill your Paper Code as mentioned on the Test Paper and darken the corresponding bubble with Black ball
point pen.
11. If student does not fill his/her roll no. and paper code correctly and properly, then his/her marks will not be
displayed and 5 marks will be deducted (paper wise) from the total.
12. Since it is not possible to erase and correct pen filled bubble, you are advised to be extremely careful while
darken the bubble corresponding to your answer.
13. Neither try to erase / rub / scratch the option nor make the Cross (X) mark on the option once filled. Do not
scribble, smudge, cut, tear, or wrinkle the ORS. Do not put any stray marks or whitener anywhere on the
ORS.
14. If there is any discrepancy between the written data and the bubbled data in your ORS, the bubbled data will
be taken as final.
C. Question paper format and Marking scheme :
15. The question paper consists of 3 parts (Physics, Chemistry & Mathematics). Each part consists of Three
Sections.
16. For each question in Section–I, you will be awarded 4 marks if you darken the bubble corresponding to the
correct choice for the answer and zero mark if no bubbled is darkened. There is no negative marking for
incorrect answer(s) in this section.
17. For each question in Section–II, you will be awarded 2 marks for each row in which you have darkened the
bubble corresponding to the correct answer. Thus, each question in this section carries a maximum of
8 marks. There is no negative marking for incorrect answer(s) in this section.
18. For each question in Section–III, you will be awarded 4 marks if you darken the bubble(s) corresponding
to the correct choice for the answer and zero mark if no bubbled is darkened. In case of bubbling of
incorrect answer, minus one (–1) mark will be awarded.
PHYSICS

PART- I - PHYSICS

SECTION - I
Multiple Correct Answers Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct.

 1
1. The figure shows a ray incident at angle i  . If the plot drawn show the variation of r  i versus k,
3 2
(r = angle of refraction)

2 
(A) the value of k1 is (B) the value of 1 
3 6

(C) the value of  2  (D) the value of k2 is 1.
3

Space for Rough Work

RESONANCE P2FST2080513C0-1
PHYSICS
2. A hollow double convex lens is made of a very thin transparent material, It can be filled with water (refractive
index  w ) or either of two liquids L1 or L2 with refractive indices 1 and  2 respectively   2   w  1  . The
lens will diverge a parallel beam of light incident on it, if it is filled with
(A) L1 and immersed in L2
(B) L2 and immersed in water
(C) water and immersed in L2
(D) air and immersed in either water or L1 or L2

3. A conductor is made of an isotropic material and has the shape of a truncated cone.

A battery of constant emf is connected across it. If at a distance x from left end, electric field intensity and
the rate of generation of heat per unit length are E and H respectively, which of the following graphs is/are
correct?

E H

(A) (B)

x O x
O

H E

Space for Rough Work

(C) (D)

O x O x

Space for Rough Work

RESONANCE P2FST2080513C0-2
PHYSICS
4. Consider a spring that exerts the following restoring force :
F = –kx for x>0
F = –4kx for x<0
A mass m on a frictionless surface is attached to the spring displaced to x = A by stretching the spring and
released :

3 m
(A) The period of motion will be T = 
2 k

A
(B) The most negative value the mass m can reach will be x = 
2

A 5 m
(C) The time taken to move from x = A to x =  , straight away will be equal to
2 8 k

5 2
(D) The total energy of oscillations will be kA
2

5. A light metal wire of length L is suspended vertically from a rigid support, when a body of mass M is attached
to the lower end of wire, the elongation of the wire is L in its equilibrium position then.
(A) The loss in gravitational potential energy of mass M is MgL
(B) The elastic potential energy stored in the wire is MgL
1
(C) The elastic potential energy stored in the wire is MgL
2
(D) None of these

SECTION - II
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
Space for Rough
given Work
statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :

Space for Rough Work

RESONANCE P2FST2080513C0-3
PHYSICS
6. A conducting sphere A of radius a, with charge Q is placed concentrically inside a conducting shell B of
radius b. B is earthed, C is the common centre of A and B. If P is the point between shells A and B at
distance r from center C then for (a = 1m, b = 3m and r = 2 m)

b
a
A C
B

Column - I Column - II
2KQ
(A) Electric field at point P is (p)
3
(B) Electric potential at point P is (v = 0) (q) zero
KQ
(C) Electric potential difference between A and B is (r)
4
KQ
(D) Electric field outside the shell B at distance (s)
6
5 m from centre C is

KQ
(t)
15

Space for Rough Work

Space for Rough Work

RESONANCE P2FST2080513C0-4
PHYSICS
7. An ideal monoatomic gas is subjected to the processes mentioned in Column-I. Column-II mentions some
values of molar specific heat capacity. Match the process in column-I to its corresponding molar specific
heat capacity in Column-II.
Column - I Column - II
V 9
(A) = constant (p) R
T2 2
V 3
(B) = constant (q) R
T3 2
11
(C) PT2 = constant (r) R
2
7
(D) PT3 = constant (s) R
2

(t) R

SECTION - III
Integer Answer Type

This section contains 8 questions. The answer to each of the questions is


a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.

Space for Rough Work

Space for Rough Work

RESONANCE P2FST2080513C0-5
PHYSICS
8. Consider a huge charge reservoir at potential V = 200volts . A spherical capacitor C1 = 40nF is brought in
contact with the charge reservoir and then removed. Next another spherical capacitor C2 = 30nF is brought
in contact with C1 and removed. We repeat this process a large number of times. Assume that potential of
reservoir does not change during this exercise. Then the charge (in C ) on C2 after a very long time is?

9. A long straight wire is carrying current I1 = 2/5A in +z direction. The x - y plane contains a closed circular loop
carrying current I2 = 5/2A and not encircling the straight wire, then the force (in newton) on the loop will be ?
(radius of the circular loop R = 3/4m).

10. A magnetic field directed along Z axis varies as B = B0x/a, where B0 = 2 tesla and a = 1m. A conducting
square loop of side  = 1/2m is placed with its edges parallel to X and Y axes. If the loop is made to move with
a constant velocity v0 = 6m/s directed along X axis, the induced emf (in volts) in the loop is :

11. The difference between (n + 2)th Bohr radius and nth Bohr radius is equal to the (n – 2)th Bohr radius. The value
of n is ?

12. The figure shows an RC circuit with a parallel plate capacitor. Before switching on the circuit, plate A of the
capacitor has a charge –Q0 while plate B has no net charge. Now, at t = 0, the circuit is switched on. How
much time (in second) will elapse before the net charge on plate A becomes zero. (Given C = 1F, Q0 = 1mC,

2  10 6
 = 1000 V and R )
ln 3
–Q0

A B
R
S

Space for Rough Work

RESONANCE P2FST2080513C0-6
PHYSICS

1
13. A thin non conducting disc of mass M = 2kg, charge Q = 2 x 10-2C and radius R  m is placed on a
6
frictionless horizontal plane with its centre at the origin of the coordinate system. A non uniform, radial

magnetic field B  B0 r exists in space, where B0 = 10T and r is a unit vector in the radially outward
direction. The disc is set in motion with an angular velocity   x  102 rad/sec, about an axis passing
through its centre and perpendicular to its plane, as shown in the figure. At what value of x, the disc will lift off
from the surface.

14. All springs, string and pulley shown in figure are light. Initially when both the springs were in their natural state,

the system was released from rest. The maximum displacement of block m is x  
 5mg  . Calculate x.

 k 

Space for Rough Work

15. In Young's Double slit experiment, a thin glass mica strip of thickness (t = 8  ) is pasted infront of slit S1. If
the same strip is now shifted in front of other slit S2. If the number of fringes which will cross the central point
on the screen is N. Find N ? (D >> d,  << d and nmica = 1.5)

Space for Rough Work

RESONANCE P2FST2080513C0-7
CHEMISTRY

PART- II - CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION - I
Multiple Correct Answers Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct.

16. A mixture of an alkane and C3H6 has volume 24cc at a given temperature and pressure. To burn completely,
the mixture required 114cc of oxygen. The combustion product, CO2 occupied 72cc. Considering complete
combustion, find which of the following is/are correct? Consider all volumes are measured at same temperature
and pressure and (ideal behaviour).
(A) The alkane is C2H6 (B) The alkane is C3H8
(C) The mole % of C3H6 is 50% (D) The vapour density of the mixture is 21.5.

17. Colourless solutions of Na2S and Na2SO3 in water are given in two separate unknow test tubes, then

S2– and SO 32  can be be distinguished by using which one of the following test ?
(A) Lead acetate test (B) Barium chloride test
(C) Sodium nitroprusside test (D) Methylene blue test

18. Which of the following statements is/are correct ?.


(A) [Co(pn)2Cl2]+ form cis-trans isomers.
(B) [Co(NH3)4(H2O)Cl]Br2 exhibits both ionization as well as hydrate isomerism.
(C) [Cr(gly)3] exhibits both geometrical and optical isomerism.
(D) [Co(NH3)4Cl2]NO2 exhibits both ionization as well as linkage isomerism.

Space for Rough Work

RESONANCE P2FST2080513C0-8
CHEMISTRY
19. The correct order(s) is/are :
(A) Ph–CH2–Br > Ph–Cl > Ph–Br .......... (SN reaction with NaOH/ )
(B) > > ..... (Hydrolysis with NaOH)

(C) > CH3–CH2–COOH > CH3–COOH ............... (rate of esterification)

(D) (a > b > c) ............ (Basicity of N)

20. The correct statements about the following reaction sequence are :

KOH
 
 R– X
(1)  

( 2)

R – NH2 +

(A) The hydrolysis reaction is step –3.


(B) The bimolecular nucleophilic substitution reaction (SN2) is step – 2.
(C) Step–1 is an acid –base reaction.
(D) Only primary amines can be synthesised by this method.

Space for Rough Work

RESONANCE P2FST2080513C0-9
CHEMISTRY

SECTION - II
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :

21. Colum I Column II


(Characteristic of salt) (Salt)
(A) Leave(s) no residue on heating (p) Ag2C2O4
(B) Form(s) brown ring on reaction with FeSO4 and conc. H2SO4 (q) (NH4)2CO3
(C) Colourless acidic gas is evolved on heating (r) Pb(NO3)2
(D) Colourless gas with linear shape is evolved on heating (s) NH4NO3
(t) CaCO3

Space for Rough Work

RESONANCE P2FST2080513C0-10
CHEMISTRY
22. Coulmn - I Coulmn - II
(Compounds) (Positive tests with following reagents)

(A) (p) Na - metal

(B) (q) Turns red litmus blue

(C) (r) NaHCO3

(D) (s) FeCl3

(t) NaNO2 / HCl, -Naphthol / OH

SECTION - III
Integer Answer Type

This section contains 8 questions. The answer to each of the questions is


a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.

Space for Rough Work

RESONANCE P2FST2080513C0-11
CHEMISTRY
23. Calculate the maximum volume of 0.25M copper (II) nitrate solution that can be prepared by dissolving
36.25g of copper (II) nitrate trihydrate in sufficient water. Give answer in decilitre.

24. KCN + CuSO4  K3[Cu(CN)4] + K2SO4 + (CN)2

a3
In the above balanced equation, if the stoichiometric coefficient of K3[Cu(CN)4] is a, find .
2

25. 2 moles of an ideal monoatomic gas undergoes a reversible process for which P2V = constant. The gas
sample is made to expand from initial volume of 1L to final volume of 4L starting from initial temperature of
300K. Find the value of Ssys for the above process. Report your answer as 'X' where Ssys = XRn2.

26. The number of non-polar and non-planar species is :


(i) SO3 (ii) PCl3F2 (iii) P4 (iv) NH3
(v) CO2 (vi) CF4 (vii) BF3 (viii) SiCl4
(ix) HClO4 (x) SF4

27. Mg burns in air to form two compounds (A) and (B). (A) is sparingly soluble in water and the resulting solution
is weakly basic. (B) dissolves in water to form (C) and gas (D). Gas (D) with dilute HNO3 gives (E). E on
heating gives gas (F) which behave as an oxidising agent too. Gas F on reaction with Phosphorus produce
an important dehydrating agent ‘G’. How many of the following is/are correctly matched ?
(i) A = Mg3N2 (ii) A = Mg(OH)2 (iii) B= MgO (iv) C = Mg(OH)2
(v) D = N2O (vi) B = MgCO3 (vii) E = NH4NO3 (viii) G = P4O10
(ix) F= Cl2 (x) D = NH3 (xi) C = MgCl2 (xii) G = PCl3
(xiii) F = N2O (xiv) F= N2

28. How many chlorine atoms will be substituted by H2O / acetone (excess) ?
Cl
Cl

Cl Cl

Cl Cl Cl
O

Space for Rough Work

RESONANCE P2FST2080513C0-12
CHEMISTRY
29. How many 3º-free radical can be formed by homolysis of C—H bonds of alkanes having molecular formula
C6H14 ?

30. How many of the following compounds can exhibit tautomerism ?


O O O
O
(a) (b) (c) (d)
O
NH O

COCH3 NO2 CH3


|
(e) (f) (g) (h) CH3  C  CH3
|
NO2

O
CH3 O
O


(i) (j) (k) Ph – CH2 – C – CH3 (l) CH 3 – C – C – H


CH3
O
Ph O
– –

(m) Ph – C – C – H (n) H – C – Ph (o) (p) HCN


Ph O

(q) (r) (s) (t)

Space for Rough Work

RESONANCE P2FST2080513C0-13
MATHEMATICS

PART- III - MATHEMATICS

SECTION - I
Multiple Correct Answer Type
This section contains 5 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/are correct.

 
31. Let f(x) = tanx – tan3x + tan5x – tan7x + ........, where x   0,  , then which of the following is/are correct ?
 4
/6
1    1 f ( x)
(A)  f ( x ) dx  8
0
(B) f    
 12  2
(C) lim
x0 x
1 (D) f(x) is an odd function

      
32. If a, b, c are three non-zero vectors such that a  b  c and b  c  a , choose the INCORRECT option
      
(A) a.b  b.c  c.a = 0 (B) | b || c | (C) a is a unit vector (D) c is a unit vector

33. The general solution of differential equation x (1 + y2) dx + y(1 + x2) dy = 0 is


1
(A) n (1 + x2) (1 + y2) = k (B) (1 + x2)(1 + y2) = c
2
(C) (1 + y4) = c (1 + x2) (D) n [(1 + x2)/(1 + y2)] = k

Space for Rough Work

RESONANCE P2FST2080513C0-14
MATHEMATICS
34. The equations of common tangents to the parabola y = x2 and y = – (x – 2)2 is /are
(A) y = 4(x – 1) (B) y = 0 (C) y = – 4(x – 1) (D) y = – 30x – 50

   
35. The inequation 2 sin2  x –  – 5 sin  x –   2  0 is satisfied
 3   3 

 5 5   5  
(A) is satisfied in  – ,  (B) is satisfied in  – , 
 6 6   6 2

 (12n – 5) ( 4n  1)    1


(C) is satisfied in  ,  , n  (D) is satisfied for all x for which sin  x –  
 6 2   3 2

SECTION - II
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be drakened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :

Space for Rough Work

RESONANCE P2FST2080513C0-15
MATHEMATICS
36. Column – I Column – II
1
(A) If a > 0 then maximum area of the triangle formed by straight line (q)
8

x + a (a2 +1) y – a = 0 with co-ordinate axes is equal to


3 , when i  j 2
(B) Let A = [aij]3 x 3 be such that aij =  then (q)
 0, otherwise 3

 det( adj (adjA )) 


  [Where : {k} denotes fractional part of k.]
 5 

1
(C) There are n distinct points on the circumference of a circle. (r)
5
The number of pentagons that can be formed with these points
as vertices is equal to the number of possible triangles. Then
1
the value of is-
n
1
(D) The chance that the vowels are separated in an arrangement of (s)
4
the letters of the word "HORROR" is:
1
(t)
9

Space for Rough Work

RESONANCE P2FST2080513C0-16
MATHEMATICS
37. Column – I Column – II

(A) In a  ABC, co-ordinates of orthocentre, centroid and (p) 16


vertex A are (3, 2), (3, 1) and (1, 2) respectively. Then
x-coordinate of vertex B is

(B) The number of ways in which the number 27720 (q) 4


can be split into two factors which are co-primes, is

(C) If (, 4) is the orthocentre of the triangle whose vertices (r) 12

lie on the rectangular hyperbola xy = 16, then  is equal to

(D) Given two circle x2 + y2 + 3 2 (x + y) = 0 and x2 + y2 + 5 2 (x + y) = 0, (s) 8


let the radius of the third circle, which is tangent to the two given
2p  1
circles and to their common diameter, be , then the value of p is
p
(t) 20

Space for Rough Work

RESONANCE P2FST2080513C0-17
MATHEMATICS

SECTION - III
Integer Answer Type

This section contains 8 questions. The answer to each of the questions is


a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.

38. Let g be continuous function on R such that  g( x) dx  f ( x)  C , where C is constant of integration. If f(x) is
1
2 
an odd function, f(1) = 3 and f ( x ) g( x ) dx = , then is equal to
2
–1

39. Normals drawn at three different points P,Q,R on rectangular hyperbola xy = c2 intersect at some another
point
ab
S on the hyperbola, then centriod of the triangle PQR is (a, b), then equals
c

x2 2x | x|
2  2 
40. Find the number of real values of x which satisfy the equation  a  a  1 =  a  a  1 ,
 
for all those real values of a, for which a2 – 1 > 0.

Space for Rough Work

RESONANCE P2FST2080513C0-18
MATHEMATICS

     
41. Let OABC IS a tetrahedron with equal edges and OA  a, OB  b and OC  c where a  b  c = 2.

If p̂, q̂ and r̂ are unit vectors along bisectors of angle between pair of edges represented by
  
[a b c ]
OA, OB ; OB, OC and OC, OA respectively and [p̂  q̂ q̂  r̂ r̂  p̂] =  3 , then  is equal to

1
42. lim e11x – 7 x
 
3x = e  , then [] is equal to (where [.] denotes greatest integer function)
x

3 1 1 
43. If P (B) = , P (A  B  C ) = and P (A  B  C ) = , then P (B  C) is , where  and µ are
4 3 3 µ
coprime, then µ – 5 is

44. A circle touches the sides AB and AD of a rectangle ABCD at P and Q respectively and passes through
the vertex C. If the distance of C from chord PQ is 5 units and the area of the rectangle is , then find

the value of .
5
 
45. Let sin 2 is the geometric mean between sin  and cos , if cos 4 is equal to  sin2     , then  is
 4 
Space for Rough Work

RESONANCE P2FST2080513C0-19
Name of the Candidate Roll Number

I have read all the instructions and I have verified all the information
shall abide by them. filled in by the Candidate.

-------------------------------- --------------------------------
Signature of the Candidate Signature of the Invigilator

(Space for rough work)

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