262c - SANKALP12345 (XII) - ADVPAPER1 - DATE 2.7.2023

Time : 3 Hours Maximum Marks : 216
MAJOR TEST-1
PATTERN : JEE ADVANCED
Batch : Sankalp 1-2-3-4-5 (xii)
Advanced Paper 1 | Date : 02.07.2023
READ THE INSTRUCTIONS CAREFULLY
GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 18 pages and that all
the 18 questions in each subject and along with the options are legible. If not, contact the
invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET :

7. The ORS will be collected by the invigilator at the end of the examination.
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose on
the ORS. Do not write any of these details anywhere else on the ORS. Darken the appropriate
bubble under each digit of your form number.
DARKENING THE BUBBLES ON THE ORS :

10. Use a BLACK BALL POINTSPACE
PEN toFOR
darken the bubbles
ROUGH WORK on the ORS.
11. Darken the bubble  COMPLETELY.
12. The correct way of darkening a bubble is as : ⚫

13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or "un-
darken" a darkened bubble.
Plot No. R-4, Opposite Railway Track, Zone-2, MP Nagar, Bhopal, Madhya Pradesh (India) - 462011
PHYSICS
SINGLE OPTION CORRECT TYPE
This section contains FOUR questions. [16 Marks]
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
• For each question, darken the bubble corresponding to the correct option in the ORS.
• For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
1. Consider a very long stick of length 2R, which extends from just above the surface of the
earth, to a radius 3R. If initial conditions have been set up so that this stick moves in a
circular orbit while always pointing radially. What is the period of this orbit. g represents
acceleration due to gravity on surface of earth.
R R R
(A) 6 (B) 2 6 (C)  6 (D) none of these
2g g g
U
2. At distance 'r' from a point charge, the ratio (where ' U ' is energy density and ' V ' is
V2
potential) is best represented by:
(A) (B)
SPACE FOR ROUGH WORK
(C) (D)
3. With keys k1 and k2 closed : if PS < QR then
(A) VB = VD (B) VB > VD (C) VB < VD (D) None of these
4. A wire has linear resistance  (in Ohm/m). Find the resistance R between points A and B if
the side of the “big” square is d.
d
(A) (B) 2 d (C) 2  d (D) None
2
MORE THAN ONE OPTION CORRECT

• Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of
these four option(s) is (are) correct option(s).
• For each question, choose the correct option(s) to answer the question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
5. Battery shown in figure, has emf E and internal resistance r. Current in the circuit can be
varied by sliding the contact J.
If at an instant current flowing throughthe circuit is i, potential difference between

terminals of the cell is V, thermal power generated in external circuit is Pand thermal
power generated in the cell is equal to  fraction of total electrical power generated in it,
thenwhich of the following graphs are correct ?
(A) (B) (C) (D)
6. For the circuit shown in figure
(A) i1 = 24 A (B) i2 = 2 A (C) i3 = 15 A (D) i4 = 6 A
7. A thin-walled, spherical conducting shell S of radius R is given charge Q. The same
amount of charge is also placed at its centre C. Which of the following statements are
correct?
Q
(A) On the outer surface of S, the charge density is
2 R 2
(B) The electric field is zero at all points inside S
(C) At a point just outside S, the electric field is double the field at a point just inside S
(D) At any point inside S, the electric field is inversely proportional to the square of its
distance from C
8. If a body is projected with speed lesser than escape velocity :

(A) the body can reach a certain height and may fall down following a straight line path
(B) the body can reach a certain height and may fall down following a parabolic path
(C) the body may orbit the earth in a circular orbit
(D) the body may orbit the earth in an elliptic orbit
COMPREHENSION
• This section contains 2 paragraphs. Based upon each paragraph, 2 multiple choice questions
have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY
ONE is correct.
• For each question, darken the bubble corresponding to the correct integer in the ORS.
• For each question, marks will be awarded in one of the following categories:
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.
COMPREHENSION-1
Qtn. No. 9 and 10
A car battery with a 12 V emf and an internal resistance of 0.04  is being charged with a current
of 50 A.
9. The potential difference V across the terminals of the battery are
(A) 10 V (B) 12 V (C) 14 V (D) 16 V
10. The rate at which energy is being dissipated as heat inside the battery is :
(A) 100 W (B) 500 W (C) 600 W (D) 700 W
COMPREHENSION-2
Qtn. No. 11 and 12
In a certain region, there are non-uniform electrical potential (Ve) as well as gravitational potential
(Vg). The electrical potential varies only with x as shown in figure (i), and the gravitational
potential varies only with y as shown in figure (ii).
Consider a particle of mass 200 kg and charge 20 C in this field.

11. If the particle is released from point (5cm, 15 cm), it will try to move toward
(A) +x direction and +y direction (B) +x direction and – y direction
(C) –x direction, +y direction (D) –x direction, – y direction
12. What will be acceleration of the particle at point (25, 35)

(A) (2 î – ˆj )  10–2 m/sec2 (B) (2 î + ˆj )  10–2 m/sec2
(C) (–2 î + ˆj )  10–2 m/sec2 (D) (3 î – ˆj )  10–2 m/sec2
INTEGER TYPE
This section contains SIX questions. [24 Marks]
• The answer to each question is a UPTO 4 DIGIT INTEGER TYPE INCLUDING
DECIMAL (1, 12, 123, 1234, 0.1, 0.12, 1.12) question.
Zero Marks : –1 In all other cases.
13. In the diagram shown, all the wires have resistance R. The equivalent resistance between
the upper and lower dots shown in the diagram is (R = 16 )
14. A satellite is moving around the earth in a circular orbit and in this orbit magnitude of its
acceleration is “a1”. Now a rocket is fired in the direction of motion of satellite from the
satellite due to which its speed instantaneously becomes half of initial, just after the rocket
a
is fired acceleration of satellite have magnitude “a2”. Then fill the 1 in answer sheet
a2
(Assume there is no external force other then the gravitational force of earth before and
after the firing of rocket from the satellite)
15. In the circuit shown, the galvanometer shows zero current. The value of resistance R is :
16. A cell of internal resistance 1 is connected across a resistor. A voltmeter having variable
resistance G is used to measure p.d. across resistor. The plot of voltmeter reading V against
G is shown. What is value of external resistor R?
17. A spherical shell of charge Q and radius R is broken into 2 parts of charge Q/2 each &
made into uniform shells of radius R/2 each. If they are kept such that centres are at a
distance of 2R from each other, what is the work done by external agent? (in J). Take Q =
200µC, R = 0.5 m
18. Two particles of mass ‘m’ and 3m are initially at rest an d infinite distance
apart. Both the particles start moving due to gravitational attraction. At any
 Gm
instant their relative velocity of approach is , where ‘d’ is their
d
separation at that instant. Find  .
CHEMISTRY
correct.
19. Which of the following pair the EAN of central metal atom is not same?
3− 3+ 3+ 3−
(A)  Fe ( CN )6  and  Fe ( NH 3 )6  (B) Cr ( NH 3 )6  and Cr ( CN )6 
3− 2−
(C)  FeF6  and  Fe ( CN 6 )  (D)  Ni ( CO )4  and  Ni ( CN )4 
3−
20. For which of the following pair, the heat of mixing, Hmix, is approximately zero?
(A) CH3COOCH3 + CHCl3 (B) CH3COOH + H2O
(C) C2H5OH + CH3OH (D) CH3COCH3 + C6H6
21. For the reaction 2 N 2O5 ( g ) → 4 NO2 ( g ) + O2 ( g ) , the concentration of NO2 increases by
2.4  10 −2 M in 6 s. What will be the average rate of appearance of NO2 and the average
rate of disappearance of N 2O5 ?
(A) 2 10−3 Ms −1 , 4 10−3 Ms −1 (B) 2 10−3 Ms −1 ,110−3 Ms −1
(C) 2 10 Ms −1 , 2 10−3 Ms −1 (D) 4 10−3 Ms −1 , 2 10−3 Ms −1
22. The mechanism of the reaction A + 2 B → D + E ; H = –v is
(A) (B)
(C) (D)

23. Which of the following pairs of complexes are isomeric with each other but their aqueous
solutions exhibit different molar conductivites?
(A) [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2
(B) [CoCl2(NH3)4]NO2 and [CoCl(NO2)(NH3)4]Cl
(C) [Co(NO2)(NH3)5]Cl2 and [Co(ONO)(NH3)5]Cl2
(D) [CoBr(NH3)5]SO4 and [Co(SO4)(NH3)5]Br
24. Consider the following first – order decomposition reaction
A4 ( g ) → 4 A ( g )
Which of the following statement(s) is/are correct regarding the reaction? (log 2 = 0.3)
(A) At 30 min, only 20% reaction is complete

(B) t1/2 of reaction is 90 min
(C) Rate of reaction decreases linearly with time
(D) The time for intersection of two curves is independent of initial concentration of A4.
25. Find out correct statements regarding resonance energy:

(A) It is equal to energy of resonance hybrid
(B) It is equal to the difference in energies of the most stable cannonical structure and
resonance hybrid
(C) It is energy released by the molecule
(D) It is equal to the energy of least stable cannonical structure
26.
Among following anions which are more stable then
(A)
(B)
(C) (D)
COMPREHENSION
ONE is correct.
COMPREHENSION-1
Qtn. No. 27 and 28
Complex compounds are molecular compounds which retain their identities even when dissolved
in water. They do not give all the simple ions in solution but instead furnish complex ions. The
complex compounds are often called coordination compounds because certain groups called
ligands are attached to the central metal ion by coordinate or dative bonds. Coordination
compounds exhibit isomerism, both structural and stereoisomerism. The structure, magnetic
property, colour and electrical properties of complexes are explained by various theories.
27. Arrange the following compounds in order of their molar conductance:
(i) K Co ( NO2 )4 ( NH 3 )2 
(ii) Cr ( ONO )3 ( NH 3 )3 
(iii) Cr ( NO2 )( NH 3 )5  Co ( NO2 )6 
3 2
(iv) Mg Cr ( NO2 )5 ( NH 3 )

(A) (ii) < (i) < (iv) < (iii) (B) (i) < (ii) < (iii) < (iv)
(C) (ii) < (i) < (iii) < (iv) (D) (iv) < (iii) < (ii) < (i)
28. In which of the following pairs, both the complexes have the same geometry?
2− 3+
(A)  NiCl4  ,  Ni ( CN )4  (B) CoF6  , Co ( NH 3 )6 
2− 3−
2− + 2+
(C)  Ni ( CO )4  ,  Ni ( CN )4  (D) Cu ( NH 3 )4  ,  Ni ( NH 3 )4 
COMPREHENSION-2
Qtn. No. 29 and 30
When ( C − H )  electrons are in conjugation to pi bond, this conjugation is known as
hyperconjugation. For any compound to show hyperconjugation:
(i) Compound should have one sp 2 – hybridised carbon.
(ii)  –carbon with respect to sp 2 should be sp 3 .
(iii)  –carbon should contain at least one hydrogen atom
No. of  – carbon  stability of cation and alkene
29. Which of following cations is hyperconjugation destabilized?
(A) (C)
(B) (D)
30. Which of following alkyl benzene has maximum electron density?
(A) (C)
(B) (D)
INTEGER TYPE
31. Brown colour of complex [Fe(H2O)5(NO)]SO4 is due to C.T. spectrum which causes
momentary change in oxidation state. Find out oxidation state of Fe in this complex.
32. Consider the following ligands NH 2− , OH − , O2− , DMG, NO2− , CO32− , Cl − ,

CH 3COO − , en, SO42− . Then calculate value of " P + Q − R − S "
Here
P: Total number of ligands which act as bridging as well as monodentate only
Q: Total number of flexidentate ligands
R: Total number of bidentate ligands only
S: Total number of unsymmetrical bidentate ligands
33. The vapour pressure of water over an aqueous solution of NH 3 at 70°C is 186.8 torr. Given
that the mole fraction of NH 3 in the solution at equilibrium is 0.20 and the vapour pressure
of pure H 2O ( l ) at 70°C is 233.5 torr, determine whether the solution is ideal or not.
Answer ‘1’, if the solution is ideal and ‘2’, if the solution is non – ideal.
34. How many grams of ethylene glycol should be mixed in 795 g water to form an antifreeze
solution that will not start to freeze until the temperature reaches –30°C? ( K f for water =
1.86)
35. The number of reactions among the following, as written, could describe elementary
reaction, is
36. How many compounds from following exhibit d – orbital resonance.
MATHEMATICS
correct.
 2x  x
37. If f ( x ) = Sin −1  2 
− e . Then intervals in which f’(x) = 0 is
 1+ x 
(A) (0, 1) (B) (–1, 0) (C) (1, 2) (D) None of these
 2x 
38. What is the value of sin −1  2 
+ 2 tan −1 x , if x > 1 ?
1+ x 
(A) 0 (B) π (C) 1 (D) None of these
39. Find the exhaustive set of domain of the following function f(x) = (–x2 + x – 2)x+1
(A) x  R (B) x  I (C) x  N (D) None of these
40. Derivative of differentiable odd function is always

(A) Odd (B) Even (C) Even or Odd (D) Can’t say

41. If A and B are square matrices of the same order such that A2 = A, B2 = B, AB = BA, then
which one of the following may be true-
(A) A(B)2 = O (B) (A + B)2 = A + B
(C) (A – B)2 = A – B (D) none of these
1   14   
42. The value of cos  cos −1 cos  −    is
 2   5  
 7     2   3 
(A) cos  −  (B) sin   (C) cos   (D) − cos  
 2   10   5   5 
 a b ( a − b ) 
 
43. Matrix  b c ( b − c )  is non invertible if
 2 1 0 
(A)  = 1/ 2 (B) a, b, c are in A.P.
(C) a, b, c are in G.P. (D) a, b, c are in H.P.
44. If A is a square matrix, then

(A) AA’ is symmetric (B) AA’ is skew - symmetric
(C) A’A is symmetric (D) A’A is skew-symmetric
COMPREHENSION
ONE is correct.
COMPREHENSION-1
Qtn. No. 45 and 46
The domain and range of inverse circular function are defined as follows:
3
45. sin −1 x  then solution set of x is
4
 1   1   1 1 
(A)  ,1 (B)  − , −1 (C)  − ,  (D) None of these
 2   2   2 2
46. sin–1 x + cosec–1 x at x = –1 is

(A) π (B) 2 π (C) 3 π (D) – π
COMPREHENSION-2
Qtn. No. 47 and 48
Suppose we are making a machine, and due to lack of hardware at the start of our project we are
first making a simulation for engine. And so, the working of machine is defined by following
function.
(
ln x 2 − 3 x − 4 )
f ( x) = e ,
After successful run of the simulation, we made some changes in the system by adding another
engine after first engine.
The working of 2nd engine is defined by g(x).
Overall working is like this
47. What should be the input of first machine in-order to successful run the first engine.
(A) ( −, −1) ( 4,  ) (B) ( 4,  )
(C) ( − , −1 (D) None of these
48. Limit the input and design g(x) in such a way that final out is same as initial input. So, g(x)
will be
3 + 25 + 4 y 3 − 25 + 4 y
(A) (B)
2 4
25 + 4 y
(C) (D) None of these
2
INTEGER TYPE
49. If A is an idempotent matrix and I is an identity matrix of the same order, find the value of
n, nN , such that ( A + I )n = I + 127 A.
  
50. Find the number of values of x   − ,  satisfying the equation sin2 (2 cos–1 (tan x)) = 1.
 4 4
51. Let M be a 3 × 3 matrix satisfying

 0   −1 1 1 1  0 
   
M 1 = 2 , M  −1 =  1  and M 1 =  0 
           
 0   3   0   −1 1 12 
Then the sum of the diagonal entries of M is
x x x x
52. Using the product of cos .cos 2 .cos 3 ...............cos n , we got
2 2 2 2
 1 x  1 x
 nr=1  r tan r  = n cot n − cot x , then value of  is
2 2   
' 68
If f(x) = x3 + x2 + x + 4, then value of ( f (18 ) ) 
−1
53. is _______.
2
f ' (1) f " (1) f "' (1) f n (1)

If f(x) = x then the value of f (1) + + .......... + ( −1)
n
54. n
+ + where n
1! 2! 3! n!
= 10 is______.


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Time : 3 Hours Maximum Marks : 216

OPTICAL RESPONSE SHEET :

DARKENING THE BUBBLES ON THE ORS :

11. Darken the bubble  COMPLETELY.

12. The correct way of darkening a bubble is as : ⚫

SPACE FOR ROUGH WORK

3. With keys k1 and k2 closed : if PS < QR then

(A) VB = VD (B) VB > VD (C) VB < VD (D) None of these

MORE THAN ONE OPTION CORRECT

SPACE FOR ROUGH WORK

If at an instant current flowing throughthe circuit is i, potential difference between

(A) (B) (C) (D)

6. For the circuit shown in figure

(A) i1 = 24 A (B) i2 = 2 A (C) i3 = 15 A (D) i4 = 6 A

SPACE FOR ROUGH WORK

8. If a body is projected with speed lesser than escape velocity :

SPACE FOR ROUGH WORK

Consider a particle of mass 200 kg and charge 20 C in this field.

12. What will be acceleration of the particle at point (25, 35)

SPACE FOR ROUGH WORK

SPACE FOR ROUGH WORK

SPACE FOR ROUGH WORK

MORE THAN ONE OPTION CORRECT

SPACE FOR ROUGH WORK

(A) At 30 min, only 20% reaction is complete

25. Find out correct statements regarding resonance energy:

(iv) Mg Cr ( NO2 )5 ( NH 3 )

SPACE FOR ROUGH WORK

30. Which of following alkyl benzene has maximum electron density?

32. Consider the following ligands NH 2− , OH − , O2− , DMG, NO2− , CO32− , Cl − ,

36. How many compounds from following exhibit d – orbital resonance.

SPACE FOR ROUGH WORK

40. Derivative of differentiable odd function is always

MORE THAN ONE OPTION CORRECT

44. If A is a square matrix, then

SPACE FOR ROUGH WORK

46. sin–1 x + cosec–1 x at x = –1 is

51. Let M be a 3 × 3 matrix satisfying

SPACE FOR ROUGH WORK

f ' (1) f " (1) f "' (1) f n (1)

SPACE FOR ROUGH WORK

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