2 "'-,-t,G- NEET-AIPMT Chapterwise Topicwis

e Solutions GU§i,jlt
(;) ✓3 x 288 pm
(a) 8
(b) ✓ 2 X 288 pm .. :_ · .. ' .
(b) 2
(c) 6 (d) 4 (NE ET-I 2016) 4 4 . . . .
18. The num ber of octa hedr al void(s)
per atom pres ent 4
in a cubic close-packed stru ctur e is 4 ~ '
(c) ✓3 x 288 pm (d) ✓ 2 x 288
(a) 1 (b) 3 pm (2020 )
(c) 2 (d) 4 (2012)
19. Stru ctur e of a mix ed oxide is cubi 28. The vaca nt spac e in bee latti ce unit
c close pack ed cell is
(ccp). The cubic unit cell of mix ed oxide (a) 48% .(b) 23%
is com pose d
of oxide ions. One four th of the tetra hedr (c) 32% (d) 26%
al voids . (2015, 2008)
are occu pied by divalent meta l A and the
octa hedr al 29. If a is the leng th of the side of a cube , the distance
voids are occu pied by a mon oval ent meta betw een the bod y-ce ntre d atom and
l B. The one_·• corner
form ula of the oxide is atom in the cube will be
(a) ABO 2 · · ·
(b) A 2B0 2 . 2
(c) A 2B30 4 (d) AB 20 2 (a) ✓?,a
b 4
(Mains 2012) ( ) ✓?,a
20. A solid compound XYhas NaCl stru
ctur e. If the radi us
(c) ✓3 a (d) ✓3 a
of the cation is 100 pm, the radi us of the
anio n (Y-)
v.rill be ., ..., ''(2014)
4 2
(a) 275.1 pm (b) 322.5 pm ·
(c) 241.5 pm 30. A met al crystallises with a face -cen
(d) 165.7 pm( Mai ns 2011) tred cubic lattice.
The edge of the unit cell is 408 pm. The
21 . A com pou nd formed by elem ents X and diameter of
Y crystallises the met al atom is
in a cubic stru ctur e in whi ch the X atom
s are at the (a) 288 pm (b) 408 pm_
corn ers of a cube and the Y atom s are at
the face- (c) 144 pm , (d) 204 pm· .
centres. The form ula of the com pou nd is (2012)
(a) XY3 31. AB crystallizes in a bod y-ce ntre
(b) X 3 Y d cubic lattice
(c) XY with edge leng th 'a' equa l to 387 pm. The
(d) XY2 (2004) distance
22. In cube of any crystal A-a tom betw een two oppo sitel y char ged ions in
plac ed at ever y the lattice is
(a) '335 pm (b) 250 pm
corn ers and B-at om plac ed at ever y cent
re of face. (c) 200 pm (d) 300 pm
The formula of com pou nd is (2010)
(a) AB 32. Lith ium meta l crystallises in a body-centred cubic
(b) AB 3
(c) A 2B2 (d) A 2B3 crystal. If the leng th of the side of the
(2000) unit cell of
In crystals of whi ch one of the follo lithi um is 351 pm, the atomic radius oflit hium
wing ioni c will be
(a) 151.8 pm (b) 75.5 pm ·· ·
, com pou nds wou ld you expe ct max imu
m dista nce (c) 300. 5 pm
· betw een centres of cations and anions? (d) 240. 8 pm _ , (2009)
. (aJ Csl 33 . Cop per crystallises in a fac~ -cen tred cubic
(b) CsF lattice
· (c) LiF (d) Ln' . . -~--·-·· ,.. (1998) with a unit cell leng th of 361 pm. Wha t
is the radius
of copp er atom in pm?
· The seco nd orde r Bragg diffr actio n of •.(a) 157 . ·;
.X-rays with (b) 181
l::= 1.00 A from a set of para llel plan es in
a met al _ (c) _108 (d) 128 (2009)
. : occu rs at an angle 60°. The dista nce
betw een the 34. .. Whi ch of the following state men ts is
:.. scat terin g plan es in the crys tal is. not correct?
(a) The num ber of carb on atom s in a
~ (a) 2.00 A unit cell of
(b) 1.00 A diam ond is 8. . ... _ _ . .
: ;(c) 0.57 5 A · .
· ··· (d) 1.15 A- (1998) (b) The num ber of Bravais lattices in whic
h a crystal
• )Ihe inte rme talli c com pou nd LiAg can be categorized is 14. · · · · . · · · · ·
crystallizes in · ' ··
)t cubic lattice in whi ch both-lith ium and ( C) The frac tion of the tota l volu me occupied by the
silver have .
-1 : :coo rdin atio n num ber of eight. The atom s in a prim itive cell is 0.48. : ·· , , ,
crys tal class is ·: ·
( d) Mol ecul ar solids are gene rally volatile
. (a) face -cen tred cube (b) · simp le cube ... :_ (2008)
· ·• 35. If a stan ds for the
. :: '(c)- bod y-ce ntre dcu be (d) non eoft edge leng th, of the cubic ~ystems:
hese . (1997) simp le cubic, bod y-ce ntre d cubi c and foce-
· • · 1n the fluo rite stru
1 centred
ctur e, the coor dina tion num ber cubic, then the ratio of radi i of the sp~e
:·, e-a,2+ ion is ., ,,· , _ syst~ms will be respectively · · · · ·· ·
~e~ in these
. . J~ . (b) .6 ,'. . , (c) 8 . . · ·-·,;; . ' ·
(d) 3 ,(1993)
. . -~: ·.;_;..:·.';~
~- ..
-.; ,· '•': ·::
·· ~a) . !,a : ·✓2: (b) ·.'~'a · ~·
$a ·: Ji; ·. '~\[2a · .
·o.c.ing Efficiency . ., •., ·: , - . ; , . .2 2 . : ,.,•. 2 ,·_:· ; ·-.;_;·;·. ' :;:- "
.. ·:·.,._, •. '; ·.

a
. • : _..... ' . • C. • • ; ·' • ·_ - ' ,. : .
..-. . . 1 ✓ 3 · ' l ·•
(c) -a : - a : - a (d) -a :.. "13a
-· 1.-<· .,·i' l · .. / .
'nt has _b ody cent ered C\lbic (bee) stru ctur
e. ~ -:Jia, · _ ·, ·
.e,dge _of 288 pm ..'.The a\om ic ra~i us is
·
.. 2 __ 4-''>t iJi _/ ::i ,,_ · ? ~<?~~8} ·:z:/,:
~--;:·-~:, .... :· . . i·,_ •. ;. .. - - .~•·,· , . ..•. '··
. "<-~ ·..\/ ~-, -.
~----~- ::·, /'' ,":..<·\:··'.•."'~ -~,_·~\-;_j'_·.~ r; ;_·:_~- : :·_::_::;/ ~}{~~J-
 .=·. 1·dState
'f!!B,so,
:::r;Jhe frac_tion ?f total volume occupied b 3
'::_. .present rn a simple cube is Y the atoms 44. An element (atomic mass = 100 g/mol) having bee
> 1\' 1' 1t st ructur~ has unit cell edge 400 pm. The density of
,.(~) 3✓ 2 (b) 4✓2 (c) 4 1t
element 1s
(d)
6 (2007) (a) 7.289 g/cm 3 (b) 2.144 g/cm 3
~, 'Ihe pyknom etric density of sodium chlori (c) 10.376 g/cm 3 (d) 5.188 g/cm3 (1996)
~--·-· is 2.165 x 10:i kgm-3 while its X- .. ,dde c:rstal
,, - · ray ens1ty 15 ·
E'J.9 · Imperfections in Solids
, 3
·: ,2.178 x 10· kgm- . The fraction of unoccu . .
. ·• in sodium chloride crystal is pied sites
.-}: (a) 5.96 (b) 5.96 x 10-2 45. Given below are two statements: one is labelled as
1
:·: {c) 5.96 x 10- (d) s.96 x 10~3 ( ) Assertion (A) and the other is labelJed as Reason
2003
· 1he edge length of. face -centred unit cub·IC ce ll s IS. (R).
. .
,.' 508 pm. If the radms of the cation is 110 h Assertion (A) : In. a particular point defect, an ionic
._.· f th . . pm, t e solid is electrically neutral, even if few of its cations
'.> ·radius o e amon 1s
/ (a) 144 pm (b) 398 pm are missing from its unit cell.
(c) 288 pm (d) 618 pm (1998) Reason (R) : In an ionic solid, Frenkel defect arises
due to dislocation of cation from its lattice site
· _:' Calculations Involving Unit Cell to interstitial site, maintaining overall electrical
neutrality.
· Dimensions
In the light of the above statements, choose the most
Copper crystallises in fee unit cell with cell edge appropriate answer from the options given b~low:
. length of 3.608 x 10-s cm. The density of copper is (a) Both (A) and (R) are correct and (R) is the
. t.92 g cm-3• Calculate the atomic mass of copper. correct explanation of (A).
_···(a) 63.l u (b) 31.55 u (b) Both (A) and (R) are correct but (R) is not the
_·, (c) 60 u (d) 65 u (2022) correct explanation of (A).
Iron exhibits bee structure at room temperature. (c) (A) is correct but (R) is not correct.
Above 900°C, it transforms to fee structure. The (d) (A) is not correct but (R) is correct. (2022)
• ntio of density of iron at room temperature to that 46. Formula of nickel oxide with metal deficiency defect
· at 900°C (assuming molar mass and atomic radii of in its crystal is Nio. 98 0. The crystal contains Ni2+ and
.. iron remains constant with tem~erature) is Ni3+ ions. The fraction of nickel existing as Ni2+ ions
in the crystal is ·
✓
(a) -
3 (b) 4✓3 (c) 3✓3 (d). .!_ (2018)
(a) 0.96 (b) 0.04
(c) 0.50 (d) 0.3
" Ji 3✓2 4✓2 2
(Odisha NEET 2019)
,. Lithium has a bee structure. Its density is 47. The correct statement regarding defects in crystalline
: 5.30 kg m-3 and its atomic mass is 6.94 g mol- 1• solids is
; -Calculate the edge length of a unit cell of lithium (a) Frenkel defects decrease the density of
. l,lletaL {NA ;::: 6.02 x 1023 moI- 1) crystalline solids
:..,C,) 527 pm (b) 264 pm (b) Frenkel defect is a dislocation defect .
:Cc) 154 pm (d) 352 pm .. (c) Frenkel defect is found in halides of alkaline
(NEET-12016) metals
_:, . (d) Schottky defects have no effect on the density of
·, . ~etal has a fee lattice, The edge length of the umt
;! 3
IS 404 pm. The density of the metal is 2.72 g cm- •
. crystalline solids.
48. The appearance of colour in solid alkali metal
(2015)
' ·.· · molar mass of the metalis . : ·
•:<N.jAvogadro's constant= 6.02 x 1023 mot-•) halides is generally due to
J-> 27 g mo1-1 (b) 20 g moJ-1 . (a) interstitial positions (b} F-centres
· - , (c) Schottky defect (d) Frenkel defect. (2006)
40
(q g mol- 1 (d) 30 g mol· 1 · (2013}
,.t c:ystallises in
~ ~~nit ce)] length
a body-centred cubic lattice.
is 436.6 pm. Given that the
· 49. Schottky defect in crystals is observed when
(a) .density of the crystal is increased •·
(b) unequal number of cations · and . anions are
~;a..; le mass of Cs = 133 and that of Br ;:: BO amu ·· missing from the lattice .
'~Av. · o1-• h · . .. .
23
,~it ogadro n~ber being 6.02 x· 10 ~ , : ,.._t _ e (c) an ion leaves its normal site and occupies an ' · ·· ·
{If •Yof CsBris .., interstitial site ,· · · · · ·, .,· . . ,; , · · ·
,; t2s g/crn' ,. ,. ·g
'. 1 . . 3 . ·. ~- '. . , . .(d) equal number of cation$ and anions an~ 111:1ssing
~
0 125
(b) 42.5 cm ·· ,: / .,
· · fromlhelattke'.. ·•. · , : -: .. : .. ) 1998) :
·-~t:_' g/cm 3
, .i;:.'. ~d) 8.25 g/cm 3 '..:' ;:_a 006) /~· . ,
 6 M.-'bG- NEET-AIPMT Chapterwise Topicwise Solutions " ' -
4r ·
.[3a 40. (c) : For bcclattice: Z = 2, a= ✓3
r =- (a = edge length)
4
✓3 . . . For fee lattice : Z = 4, a= 2✓2 r
:. r= x351=151.8 pm (Given:a=351 pm)
( NZM)bee
4
3
33. (d) : Since Cu crystallises in a fc).ce-centred cubic lattice, a
dR.T. ½
Atomic radius, r = ar:: (a= edge length= 361 pm) d900 ° c - ( ZM )
2v2 3
361 NAa fee
r = r:: = 127.6 "" 128 pm
. 2v2 Given, molar mass and atomic radii are constant. .
3
34. (c) : Packing fraction for a cubic unit cell is given by

Z X ±1tr 3
= ¾(2!r]
✓3
= :Jz
f= 3
a3
41. (d) : For bee, Z = 2, p = 530 kg m·3,
where a = edge length, f = radius of cation and anion. at. mass of Li = 6.94 g mol- 1, NA= 6.02 x 1023 mol-1
Efficiency of packing in simple cubic or primitive cell 530Xl000g
p = 530 kgm- 3 = _ _ _.....:.... = 0.53 g cm· 3
= 1t/6 = 0.52 i.e. 52% of unit cell is occupied by atoms and 48%
lx(l00)3 cm 3
is empty.
ZxAt. mass
35. (c) : For simple cubic: r = a/2 p 3
NA xa
For body centi:ed : r = a✓3 I 4
3 Z x At. mass 2 x 6.94
. a a = -
For face-centred: r = r:: NA X P 6.02 X 1023 X 0.53
2v2
= 43.S x 10-l 4 cm3
where a =edge length, r =radius.
a av3 a
r: = a = 352 x 10- 10 cm= 352 pm
· Ratio of radii of the three will be - : - :~
2 4 2'/2 42. (u) : d = ZM (Z = 4 for fee)
N a3
36. (d) A 3
23 10
37. {d) : Molar volume from pyknometric density M= dxNA xa 3 = 2.72x6.023xlo x(404xlo- )
= M m3 Z 4
2.165X 10 3 M = 27gmo1- 1
3 43. (a) : Density of Cs Br= ; x M
~ olar volume from X-ray density= M m
2.178 X 103 · . a xNA
::: 1 x 213 =4.25 g/cm3
tolume occupied·=
{
~ 1 1
( -- - --)m3
IO 2.165 2.178
(436.6 X 10-lO)J X 6.023 X t<>2 3
(It has one formula unit in the unit cell, so Z = 1.) ·
{Fraction unoccupied 44. (d) : Cell edge= 400 pm; number of atoms In bce(Z)=l

~,: (0.013Mx10-
- - - -J/(Mxl0-3J
- - - = 5,96
3
X 10-3
and atomic mass= 100 glmol.
Since atomic mass is 100 g/mol, therefore mass ofeach llCID
/ 2.165x2.l 78 2.165
100 ' .
38. (a) : In the face-centred cubic lattice, the edge length of (m) = - - - - :;: 16.6 X 10· 23 g
. the unit cell, a =·r,+ 2R + r 6.023 X t<>2 3 . .
We know that volume of unit cell ~ (400' pm)3 :: ..·
·, where r = Radius of cation, R = Radius of anion
= (64 x 1<>6)pm3 = 64 x I0- 24 cin1 and · ,
:. ~ , 508 = 2 x 11 0 + 2R ~ R = 144 pm 23
mass of unit cell= Z x m = 2 x (16.6 x 10- ) ., · "·'
, 39. (a} : Density of unit cell
= 33.2 X 10-23 g
d= ZxM , · d ·ty· Mass of unit cell ·
N0 xa 3 There,ore ens1 = - - - - - - -
. .
Volume of23 unit cell ...
iven, a = 3.608 x 10-8 cm
·.:.. 8.92 g/cm3
:;: 33.2 x10- . --s.1ss g1cd : -: ;c:
. 4 (for fee) ·
. . , : 64x10-i4 ·.... · ·., ,'.: · ·>-,._:;,,,,
. 3 ... • . . . .. . ·45. (b) : Frenkel defect is shown by ion~~-~-
.NO X a Xd ;, 6.023 ~ 1023 X (3.608 X 1_0-s )3 X 8.92 ~on (~~ cation) is 4,islocated from itS_ . ~il!:J
·, z 4 mterstitial site. It creates a vacancy defect at itt .· .. ,.-:,~- 0

·= 63.08 u == 63.1 u . . an interstitial defect at its new locatioD- . ·., :;';:.ii-?jf '::'.
~-<:~··,
·,._ ~'\,~ 7.
>:~e Solid State elements of
as Ni2+ ion be 52. (b) : ff silicon is
doped with any of the·
on of meta] which exists
\ 46. (,1) : L~ t tJ1e fracti Tl) of the periodic table,- p-typ
e of :
as Ni3+ = 0.98 _ x 13 (B, Al, Ga, In,
:·t. Then the traction of metal grm ~p
ned.
=2 semiconductor will be obtai
:;.: .-~ 2x + 3(0.98 - x) e ·cation vacancy,
~ X = 0.94 53. (b ) : As each Sr2+ ion introduces on
· ~ 2x + 2.94 - 3x = 2 cation vacancies =mole %
of SrC12
t as smaller th_erefore, concentration of
t is a dislocation defec
/·•i. ( tl) : Frenkel defec
tions ) are dislocated from normal
sites to added.
·
·, tons (us ua lly ca cancies= 10-4 mole%
nds having Concentration of cation va
ers t
ti_ial s.ites. ~re nk el_ de fect is shown by compou
•i .int nce, alkali
of cations and anions he 10-4 17
large difference m the size
23 23 X 10
no t sh ow Fr en kel defect Also, Schottky
defect = lOO X 6.023 X 10 = 6.0
• metal ha lid es do
fect has no
of crystal while Frenkel de ctrons (as
: dec rea ses the de ns ity rity atom with 5 valence ele
l. 54. (a) : When an impu one of
: effuct on the density of crysta ssing and
ic) is introd uc ed in a ge rmanium crystal, it replaces
sites where anions are mi
arsen ons of the
~- :48. C!:-} : F-centres are the rs. ms . Fo ur of the five valence eJectr
pr es en t Th ey are responsible for colou
the ge rm an ium ato
electron
,'. instead ele ctr on s are
ions m co va len t bonds with each valence
y de fec t, eq ual no. of cations and an
im pu rit y ato m for
becomes
> 49. (.;) : In Sc ho ttk
ains neutral. an ium ato ms and fifth valence electron
m the lattice. So, the crystal remof fou r ge rm
acts as a
·. Ire mi ssi ng fro ounds of stal structure. 1h is free electron
on in highly ionic comp
fre e to mo ve in the cry
. 'Such defect is more comm impure germanium crysta
l js called
ic size, i.e. NaCl. charge carrier. Such as an
.: similar cationic and anion rmal lattice se in it charge carriers are
negative
{c) : ·w be n an ato m is missing from its no n-type semiconductor becau
.· 50. which involves
'. sbE, a lattice vacancy
is created. Such a defect, (free electrons) .
stal due to
er of c
- ati on an d an ion- vacancies in the cry
(a) : p-t yp e of sem ico nductors are produced (a)
.. tqual nu mb 55 . ng less
by adding impurity containi
fect.
:. lattice is called a Schottky de is favoured in those ionic metal deficiency defects (b) p 14 and
up 13). Ge belongs to Grou
(S l. (~, ..:) .: Frenkel de
fect electrons (i.e. atoms of gro iconductor
ference in the size of Hence on dopingp-type sem
rcom poun ds in ~ilich the re is large dif In or Ga to Gr ou p 13.
rease the electrical
s an d anions. is ob tai ne d. Th is doping of Ge with In inc
. . cation iency is shown
fects due to metal defic conductivity of the Ge cry
stal.
:Non~stoichlometric de
'· l,J hx O where x = 0.93 to 0.96.
❖❖❖
I

I
 4 w..-te- NEET-AIPMT Chapterwis
e Topicwise Solutions~
50. Ionic solids, with Sch
ottky defects, contain in the
structure ir (a) Selenium (b) Boron .· ·' ' :\
(a)
(c) Germanium · , (d) Arsenic . '. · ,. {ioo· ·
cation vacancies only
53. If NaCl is do ?ed..
~
(b) cation vacancies and intersti With ~o-4. mol ~ · of Src
tial cations )
(c) equal number of cation and the concentration of cat
anion vacancies ion· vacancies ·Will .~ ·
(d) anion vacancies and intersti (NA= 6.02 x 1023 mol- 1)
tial anions . (199 4) · · ·· , · · · > ...
(a) 6.02 X 1016 mo1- 1 (b) 6.02 X 10 17 mo1.,r ,;. .
tr.
v..::i.10.· Electrical Properties (c) 6.02 x 1014 molA (d) 6.02 x 1015 riiol-~ : <
5l. Which is the incorrect
stat ement? 54.
, · ·
If we mix
. . ··• · . ' :\ (2
007)
(a) Density decreases in a pentavalent impurity ma 4 C ·" • ..

cry
case of crystals with germaniu .
m, W hat type Of semic~ . d . stal latt. keof.
Schottky defect. n uctor ,fonnauon ·
(b) NaCl(sl is insulator, sili will occur? .
con is semiconductor, ,. . .. _· · .·
silver is conductor, quartz (a) n-type semiconductor
is piezoelectric (b) p-type semiconductor ·
.. '
crystal. : .-·, :.,· : ·
(c) Frenkel defect is favour (c) Both (a) and (b)
ed in . those . ionic
compounds in which sizes of (~) ~o ne of these '
~ation and anions ' (i996)
are almost equal. . . 55. On dop ing Ge me
. . .. tal wit h a htt le of In or Ga, one
(d) Fe 0 0 _98 has non-stoichiom . gets
etric metal .deficiency
defect. .. ·' · : ·
. · (2017) (a) p-type semiconductor
52. With which one ·"· .. , ,.
of the following Clements (b) n-type semicoi;tductor
. ,..
silicon should be doped so (c) insulator
0
as to ·give p-type of ,! ., .. ;..
semiconductor? • · (d) ~ectifier.
.,, ,. , ::

·~ '.'
... (1993)
: ~

-:~- -L ( i ANSWER KEY )

.. ..
1. ·(b) . 2. (c) (d) ' 4; ; .' (b)
3. 5. ., (a) 6. (d) 7. . (a)
11. (c) 12. (c) tc} · ..'14.-' ··(a)
13. '15. (d) 16. (c)
8. (b) 9. (d) ., 10. : ,(c)
.
21. (a) 22. (b) 23. (a:) 17. '(c) 18. (a) ' 19. (d) . 20; (c)
24. (d) 25. (c)
(a) 32. (a) 33. · (d) 34. (c)
26. (c) 27. (a) 28. (c)
35. (c) 29. .(d) 30. (a)
(d) 42. (a) . 36: (d) 37. (d)
43~ (aY 44. (d) 45·. . 38. (a) 39. (a) :, 40. ·. (c)
(c, d) 52. (b) 46. (a) 47. (b)
(b). 53. (b) 54. (a) 48. . (b) 49. (d) SO. • (c)
55. (a)

_·} i_i~t~_$(Explanations ·
1

(b) : Liquid crystals on hea

ting first become turbid and
on further heating turbidity com
pletely disappears. = Sx1- + 6x1- + 4 .=8
· ·-' (c) : Glass is a supercool 8 2
ed liquid which forms a non- (Corners) (Face
. e solid without a regular lattice. (Tetrahedral - , ·,

. centred) void)
~ - !. (d) : Crystal
s show good cleavage bec
~nstituent particles are arrange ause their 10. (c) : Here giv
d in planes. , en unit cell is shared equilly by
six.faces ill
.· .f. ·· (b) : The phenomenon of exi the fee wh ich is shared equally by six differe
stence of a substance in two nt~t'cells, ·
~ ·,. or more crystalline stru
ctures is called polymorphism
.·;:: 5. (a) : The electrostatic force of .
attraction which exists
·:'' ·. ~.etween oppositely charged
ions is called as ionic bond.
.::.·~~ : (d) : KI is an ionic com
pound while
·::.1;1 (a) : Out of 14 types ofBravais latt benzene is not. Q)
' , units cells are there which are ice, three body ce11tred
:
, cipiorhombic, tetragonal and
r ,it; ' ' •
cubic
~ ;. (b) .: For orthorhombic
system, a = ~ = 'Y = 90°
t·.,: (d) : Diamond is like ZnS (Zincb lende).
~h on forming eep (Jee) and .; ·•··: :··..,_.•. -;
also occupying half ~f tetrahedra
{ voids.,:.., . ., l
. .. 'n .:- (~} -:,h~p ~. a closed pa~
/\ Total n~. of carbon atoms . · · · . ·. · ·: · ·· eaarranselll:eI)~.1~\ ..~' , .·\f:;
.':}:Y.-- ,:
pet unit cell : · wµtcell is hexagorial andcoo · , ·. · be 1.s1V '
. - :..:-. . - rdiriationnum ,:.:,cli1;:.f
__ .~ .,~ ~ ~ ·~ .:
' " . -'\itfllif
~ ~ ~..,.;._c.:.~ ~- -- >\s':(:~
\>~ ; ~~~
·>,~
 ,5
:. \, solid State
._J/18 e contribution of eight atoms of face-centred . . ' 1 . ,
(c) : 111
-12· 1 Th . · 21 . (a) ~ ln a unit cell, X atom s at the corners = x 8 = l_
·• . 11 == 8 x - = 1 atom . . ere 1s one atom at each of 8
l
',,ubiCunit ce 8 . . . Y atoms at the face centres = - x 6 = 3
. _ which is shared by 2 umt cells each. The contribution 2
:~fal es, l · Ratio of X and Y = I : 3. Hence formula is XY:v
i.:rJ6 face· centred atoms = 6 X - = 3.
2 22. (b) : 'A' atoms are at '8' corners of the cube. Thus, no. of
'Jberefore n = l + 3 = 4 . . 1
. ·) • rec crystal contains 'A' atoms per unit ceJI = 8 x - = 1
. .I' 8
)'
-~ (t. 1 'B' atoms are at the face centre of six faces. Thus, no, of 'B'
. _ 8 x ! + 6 x - = 4 atoms in a Unit cell
- 8 2
atoms per unit cell = 6 x .! = 3
2
• The formula is AB3•
23. (a) : As or~ ion has larger si1,e than Li"' and 1- has larger
• • • • size than F-, so maximum distance between centres of cations
and anions is in Csl.

• 24. (d) : According to Bragg's equation, nA = 2d sin 0

As, n = 2, A= 1.ooA, 0 = 60°, d =?
4. (a) : Nwnber of atoms in hexagonal unit cell = N = 6 2dsin0 = nA
Number of octahedral void = N = 6
2dsin6O° = 2 x 1 A
ber of tetrahedral void= 21'1 = 12
(d) : Number of atoms per unit cell in hep = 6
er of octahedral void in hep = 6 ..
2dx ✓23=2 ~ d~ -v3~ -=l.15A (· : sin60°=
.
✓23J
ber of anions per unit cell = 6 ' : · · · ·· ·.'
. ·, . . : .' · .. ' ' 75 9 25. (c) : A body-centred cubic unit cell consists of 8 atoms at
er of octahedral voids occupied by cations = 6 x - =- the corners and one atom at the centre.
· 100 2 26. (c) : In fluorite (CaF2) structure, C.N. of Ca2+ = 8,
• I I I
C.N. ofF- =4.
(c) : In fluorite struc~r~, · Ca2+ \ons ~r; in . face- ' ,•, the . ✓3 . . .
d cubic arrangement; . Each . Ca + is . co~~ect~d to 27.
2 (a) :· For bee structure, r = -a, where- a· is the unit cell
. .. .. . ' 4 ..
P- ions below it and to another set -~f ,:4 F- ions above it i.e. edge length and r is the radius of the sphere (atom) . .
:2+ has a coordination number of 8 'a nd each F· ion has a · . ✓3 .· . .
dination number 4. r= x288pm
4
·:. - r . 0.98Xl0-lO ·
• (c) : Radius ratio + -----".~-0.541 28. (c)' ; Packing efficiency of bee lattice= 68%
·· ' r_ 1.s1x10-:-1<> Hence, empty space = 32%.
lb in the range of 0.414 to O.732 · hence, coordination 29. . (d) : The distance between the body- .fi.
r of each ion will be 6 as the compound will have NaCl
ltructure i.e., octahedral arrangement.
· '(• ) : Number of octahedral voids is same
' ;: ' '

\_, ;. : ·:·'
as number of :.:~:: : : : ~ : . : : : : atom h ~ . (!fJ .
.-{d) : Numberofclto~inet;;==4=,oi-
r of tetrahedral voids = Z X N-!' 2 >< 4 c 8
!•a 30. (;1) :. For a face-centlled cubic (fee) structure
·- a
.

~8 ·· ·
.
r=~,a:r;4O8pm, r:;i?"/'!"=144 pm
~::;;~rofAi+ions,~.sxi~-,~\/' : ::_t: · .-..· '-:,:; .-
2v2 •. . . _. , 2-./2
Diameter .'.'"' lr"" 2 x 144 = 288 pm
· · · ·· · • .. -i.' of Jr' ion& -" N =s,.
.· r ofoctahedral vows =i: Nut1auer ... •. . _ _: ., · >' . :n . •(a) 3 a ·•·· _ .
t Fora bcdattice, 2(r.,, + r_) ,._✓
._ p2-:A2+:B+=4:2 •: 4=2: l:Z , ,, · where·r-1- • radius of cation,,_= radius of anion··
. :,, of oxide = AB1Oi-' · . ··· a. ,. edge length . _ , · ·, .. · . ·
~ii,:; , ': r -. . : . : . , ./ixJs1i •.·_ : · ·· ,. ·· · \·_•·· ·.,,
- For Nae~. -t. = %~} 4. .:
r . ...... /,.:.(i+i+;_)• -. . . - ., • ~35. 15 pm• 335 pm , .. _ ,.
, ;l. ... • ·.
\"·'. ·,·, ..,.·,• ; . _.;- . . ;,.,,;.,: .· . . ·', .<.
:·~ac1ius of c~~io;~ too p;i? _;. 3l, (a) .~ .S~c:e 1:1 cr~•talJiaes in .body!'centred cubic·. crystal, . -; . , .

!E,;I(f1J(?~ . .
.;};,j,~~iilj~ii1 4
atomteradlua, · · ,'- ··· : -. ' - _.·.<
.: .~· .·_. ~-
•,-
'\_\ ,;~\'\· ,.'~·.'. ·.:_:·-
•
. ,-. . .

-~-:. • ,:- :...• ··-; " : > ~ ~ '

; <-..'(',:'.· ·: